DIN EN ISO 11885-2009 Water quality - Determination of selected elements by inductively coupled plasma optical emission spectrometry (ICP-OES) (ISO 11885 2007) English version of D.pdf

1、September 2009DEUTSCHE NORM English price group 16No part of this standard may be reproduced without prior permission ofDIN Deutsches Institut fr Normung e. V., Berlin. Beuth Verlag GmbH, 10772 Berlin, Germany,has the exclusive right of sale for German Standards (DIN-Normen).ICS 13.060.50!$YVe“15451

2、66www.din.deDDIN EN ISO 11885Water quality Determination of selected elements by inductively coupled plasmaoptical emission spectrometry (ICP-OES) (ISO 11885:2007)English version of DIN EN ISO 11885:2009-09Wasserbeschaffenheit Bestimmung von ausgewhlten Elementen durch induktiv gekoppeltePlasma-Atom

3、-Emissionsspektrometrie (ICP-OES) (ISO 11885:2007)Englische Fassung DIN EN ISO 11885:2009-09SupersedesDIN EN ISO 11885:1998-04www.beuth.deDocument comprises 36 pagesDIN EN ISO 11885:2009-09 2 National foreword This standard has been prepared by Technical Committee ISO/TC 147 “Water quality” in colla

4、boration with Technical Committee CEN/TC 230 “Water analysis” (Secretariat: DIN, Germany). The responsible German body involved in its preparation was the Normenausschuss Wasserwesen (Water Practice Standards Committee), Technical Committees NA 119-01-03-01-11 AK Atomspektrometrische Verfahren and N

5、A 119-01-03 AA Wasseruntersuchung. This standard is part of the series Deutsche Einheitsverfahren zur Wasser-, Abwasser- und Schlamm-untersuchung Kationen (Gruppe E) (German standard methods for the examination of water, waste water and sludge Cations (group E) and describes method E 22. Designation

6、 of method E 22 “Determination of selected elements by inductively coupled plasma optical emission spectrometry”: Method DIN EN ISO 11885 E 22 As a result of national implementation in Germany, the following should be noted: In 3.10 limit of detection XLD, in the key of s0, reference is made to ISO/

7、TS 13530:2009. s0is the standard deviation of the outlier-free results of at least ten measurements of a reagent blank solution (3.14). The DIN Standards corresponding to the International Standards referred to in this document are as follows: ISO 3696 DIN ISO 3696 ISO 5667-1 DIN EN ISO 5667-1 ISO 5

8、667-3 DIN EN ISO 5667-3 ISO 5667-15 E DIN EN ISO 5667-15 ISO 7027 DIN EN ISO 7027 ISO 8466-1 DIN 38402-51 ISO 15587-1 DIN EN ISO 15587-1 ISO 15587-2 DIN EN ISO 15587-2 Expert assistance and specialized laboratories will be required to perform the analysis described in this standard. Existing safety

9、regulations are to be taken into account. Depending on the objective of the analysis, a check shall be made on a case-by-case basis as to whether and to what extent additional conditions will have to be specified. German standard methods for the examination of water, waste water and sludge Standard

10、methods published as DIN Standards are obtainable from Beuth Verlag GmbH, either individually or grouped in volumes. The standard methods included in the loose-leaf publication entitled Deutsche Einheits-verfahren zur Wasser-, Abwasser- und Schlammuntersuchung will continue to be published jointly b

11、y Wiley-VCH Verlag and Beuth Verlag GmbH. All standard methods relevant to the Abwasserverordnung (Waste Water Regulation) (AbwV1) included in the new Regulation on Section 7a of the Gesetz zur Ordnung des Wasserhaushaltes (German Water Management Act1) concerning Anforderungen an das Einleiten von

12、Abwasser in Gewsser together with 1)Registered in the DITR database of DIN Software GmbH, obtainable from: Beuth Verlag GmbH, 10772 Berlin. DIN EN ISO 11885:2009-09 3 the Abwasserverordnung and the Gesetz zur Ordnung des Wasserhaushalts have been published by Beuth-Verlag GmbH as a loose-leaf collec

13、tion Analysenverfahren in der Abwasserverordnung Rechtsvorschriften und Normen (Supplements). Standards or draft standards bearing the group title “German standard methods for the examination of water, waste water and sludge” are classified under the following categories (main titles): General infor

14、mation (group A) (DIN 38402) Sensory analysis (group B) (DIN 38403) Physical and physicochemical parameters (group C) (DIN 38404) Anions (group D) (DIN 38405) Cations (group E) (DIN 38406) Substance group analysis (group F) (DIN 38407) Gaseous constituents (group G) (DIN 38408) Parameters characteri

15、zing effects and substances (group H) (DIN 38409) Biological-ecological methods of analysis (group M) (DIN 38410) Microbiological methods (group K) (DIN 38411) Test methods using water organisms (group L) (DIN 38412) Individual constituents (group P) (DIN 38413) Sludge and sediments (group S) (DIN 3

16、8414) Bio-assays with microorganisms (group T) (DIN 38415) In addition to the methods described in the DIN 38402 to DIN 38415 series of standards, there are a number of European and International Standards available as DIN EN, DIN EN ISO and DIN ISO Standards, which also form part of the collection

17、of German standard methods. Information on Parts of these series of standards that have already been published can be obtained from the offices of the Normenausschuss Wasserwesen, telephone +49 30 2601-2448, or from Beuth Verlag GmbH, Burggrafenstr. 6, 10787 Berlin. Amendments This standard differs

18、from DIN EN ISO 11885:1998-04 as follows: a) The standard has been brought in line with the state of the art. b) The performance data have been updated on the basis of new interlaboratory trials. c) The description of interferences has been given in more detail. d) The standard has been editorially

19、revised. Previous editions DIN 38406-22: 1988-03 DIN EN ISO 11885: 1998-04 DIN EN ISO 11885:2009-09 4 National Annex NA (informative) Bibliography DIN 32633, Chemical analysis Methods of Standard addition Procedure, evaluation DIN 38402-51, German standard methods for the examination of water, waste

20、 water and sludge General information (group A) Calibration of analytical methods, evaluation of analytical results and linear calibration functions used to determine the performance characteristics of analytical methods (A 51) DIN ISO 3696, Water for analytical laboratory use Specification and test

21、 methods DIN EN ISO 5667-1, Water quality Sampling Part 1: Guidance on the design of sampling programmes and sampling techniques DIN EN ISO 5667-3, Water quality Sampling Part 3: Guidance on the preservation and handling of water samples E DIN EN ISO 5667-15, Water quality Sampling Part 15: Guidance

22、 on preservation and handling of sludge and sediment samples DIN EN ISO 7027, Water quality Determination of turbidity DIN EN ISO 15587-1, Water quality Digestion for the determination of selected elements in water Part 1: Aqua regia digestion DIN EN ISO 15587-2, Water quality Digestion for the dete

23、rmination of elements in water Part 2: Nitric acid digestion EUROPEAN STANDARD NORME EUROPENNE EUROPISCHE NORM EN ISO 11885 May 2009 ICS 13.060.50 Supersedes EN ISO 11885:1997English Version Water quality - Determination of selected elements by inductively coupled plasma optical emission spectrometr

24、y (ICP-OES) (ISO 11885:2007) Qualit de leau - Dosage dlments choisis par spectroscopie dmission optique avec plasma induit par haute frquence (ICP-OES) (ISO 11885:2007) Wasserbeschaffenheit - Bestimmung von ausgewhlten Elementen durch induktiv gekoppelte Plasma-Atom-Emissionsspektrometrie (ICP-OES)

25、(ISO 11885:2007) This European Standard was approved by CEN on 14 May 2009. CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this European Standard the status of a national standard without any alteration. Up-to-date lists and biblio

26、graphical references concerning such national standards may be obtained on application to the CEN Management Centre or to any CEN member. This European Standard exists in three official versions (English, French, German). A version in any other language made by translation under the responsibility o

27、f a CEN member into its own language and notified to the CEN Management Centre has the same status as the official versions. CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Cyprus, Czech Republic, Denmark, Estonia, Finland, France,Germany, Greece, Hungary, Iceland, Irela

28、nd, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland and United Kingdom. EUROPEAN COMMITTEE FOR STANDARDIZATION COMIT EUROPEN DE NORMALISATION EUROPISCHES KOMITEE FR NORMUNG Management Centre: Avenue Marnix 17

29、, B-1000 Brussels 2009 CEN All rights of exploitation in any form and by any means reserved worldwide for CEN national Members. Ref. No. EN ISO 11885:2009: EDIN EN ISO 11885:2009-09 EN ISO 11885:2009 (E) 2 Contents Page Foreword3 Introduction .4 1 Scope 5 2 Normative references 5 3 Terms and definit

30、ions .6 4 Principle9 5 Recommended wavelengths, limits of quantification and important spectral interferences9 6 Interferences . 13 7 Reagents 15 8 Apparatus 18 9 Sampling and preservation 19 10 Procedure 22 11 Expression of results . 24 12 Test report . 24 Annex A (informative) Special digestion me

31、thods . 25 Annex B (informative) Precision data. 26 Annex C (informative) Description of the matrices of the samples used for the interlaboratory trial 30 Bibliography. 32 DIN EN ISO 11885:2009-09 EN ISO 11885:2009 (E) 3 Foreword The text of ISO 11885:2007 has been prepared by Technical Committee IS

32、O/TC 147 “Water quality” of the International Organization for Standardization (ISO) and has been taken over as EN ISO 11885:2009 by Technical Committee CEN/TC 230 “Water analysis” the secretariat of which is held by DIN. This European Standard shall be given the status of a national standard, eithe

33、r by publication of an identical text or by endorsement, at the latest by November 2009, and conflicting national standards shall be withdrawn at the latest by November 2009. Attention is drawn to the possibility that some of the elements of this document may be the subject of patent rights. CEN and

34、/or CENELEC shall not be held responsible for identifying any or all such patent rights. This document supersedes EN ISO 11885:1997. According to the CEN/CENELEC Internal Regulations, the national standards organizations of the following countries are bound to implement this European Standard: Austr

35、ia, Belgium, Bulgaria, Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland and the United Kingdom. Endorsemen

36、t notice The text of ISO 11885:2007 has been approved by CEN as EN ISO 11885:2009 without any modification. DIN EN ISO 11885:2009-09 EN ISO 11885:2009 (E) 4 Introduction When applying this International Standard, it is necessary in each case, depending on the range to be tested, to determine if and

37、to what extent additional conditions should be established. DIN EN ISO 11885:2009-09 EN ISO 11885:2009 (E) 5 WARNING Persons using this International Standard should be familiar with normal laboratory practice. This International Standard does not purport to address all of the safety problems, if an

38、y, associated with its use. It is the responsibility of the user to establish appropriate safety and health practices and to ensure compliance with any national regulatory conditions. IMPORTANT It is absolutely essential that tests conducted according to this International Standard be carried out by

39、 suitably trained staff. 1 Scope This International Standard specifies a method for the determination of dissolved elements, elements bound to particles (“particulate”) and total content of elements in different types of water (e.g. ground, surface, raw, potable and waste water) for the following el

40、ements: aluminium, antimony, arsenic, barium, beryllium, bismuth, boron, cadmium, calcium, chromium, cobalt, copper, gallium, indium, iron, lead, lithium, magnesium, manganese, molybdenum, nickel, phosphorus, potassium, selenium, silicon, silver, sodium, strontium, sulfur, tin, titanium, tungsten, v

41、anadium, zinc and zirconium. Taking into account the specific and additionally occurring interferences, these elements can also be determined in digests of water, sludges and sediments (for example, digests of water as specified in ISO 15587-1 or ISO 15587-2). The method is suitable for mass concent

42、rations of particulate matter in waste water below 2 g/l. The scope of this method may be extended to other matrices or to higher amounts of particulate matter if it can be shown that additionally occurring interferences are considered and corrected for carefully. It is up to the user to demonstrate

43、 the fitness for purpose. Recommended wavelengths, limits of quantification and important spectral interferences for the selected elements are given in Table 1. 2 Normative references The following referenced documents are indispensable for the application of this document. For dated references, onl

44、y the edition cited applies. For undated references, the latest edition of the referenced document (including any amendments) applies. ISO Guide 30, Terms and definitions used in connection with reference materials ISO 3696, Water for analytical laboratory use Specification and test methods ISO 5667

45、-1, Water quality Sampling Part 1: Guidance on the design of sampling programmes and sampling techniques ISO 5667-3, Water quality Sampling Part 3: Guidance on the preservation and handling of water samples ISO 7027, Water quality Determination of turbidity DIN EN ISO 11885:2009-09 EN ISO 11885:2009

46、 (E) 6 ISO 15587-1, Water quality Digestion for the determination of selected elements in water Part 1: Aqua regia digestion ISO 15587-2, Water quality Digestion for the determination of selected elements in water Part 2: Nitric acid digestion 3 Terms and definitions For the purposes of this documen

47、t, the following terms and definitions apply. 3.1 accuracy closeness of agreement between test result and the accepted reference value NOTE The term accuracy, when applied to a set of observed values, describes a combination of random error components and common systematic error components. Accuracy

48、 includes precision and trueness. 3.2 analyte element(s) to be determined 3.3 background equivalent concentration BEC elemental concentration required to produce an analyte signal with the same intensity as a background signal 3.4 calibration blank solution prepared in the same way as the calibratio

49、n solution but leaving out the analyte 3.5 calibration solution solution used to calibrate the instrument, prepared from (a) stock solution(s) or from a certified standard 3.6 calibration check solution solution of known composition within the range of the calibration solutions, but prepared independently 3.7 determination entire process from preparing the test sample solution up to and including measurement and calculation of the final result 3.8 instrument performance check solution solut