DIN EN ISO 14403-1-2012 Water quality - Determination of total cyanide and free cyanide using flow analysis (FIA and CFA) - Part 1 Method using flow injection analysis (FIA) (ISO 1.pdf

1、October 2012 Translation by DIN-Sprachendienst.English price group 12No part of this translation may be reproduced without prior permission ofDIN Deutsches Institut fr Normung e. V., Berlin. Beuth Verlag GmbH, 10772 Berlin, Germany,has the exclusive right of sale for German Standards (DIN-Normen).IC

2、S 13.060.50!$|l“1918973www.din.deDDIN EN ISO 14403-1Water quality Determination of total cyanide and free cyanide using flow analysis Part 1: Method using flow injection analysis (FIA); (ISO 14403-1:2012);English version EN ISO 14403-1:2012,English translation of DIN EN ISO 14403-1:2012-10Wasserbesc

3、haffenheit Bestimmung von Gesamtcyanid und freiem Cyanid mittels Flieanalytik (FIA und CFA) Teil 1: Verfahren mittels Flieinjektionsanalyse (FIA) (ISO 14403-1:2012);Englische Fassung EN ISO 14403-1:2012,Englische bersetzung von DIN EN ISO 14403-1:2012-10Qualit de leau Dosage des cyanures totaux et d

4、es cyanures libres par analyse en flux (FIA et CFA) Partie 1: Mthode par analyse avec injection de flux (FIA) (ISO 14403-1:2012);Version anglaise EN ISO 14403-1:2012,Traduction anglaise de DIN EN ISO 14403-1:2012-10www.beuth.deIn case of doubt, the German-language original shall be considered author

5、itative.Document comprises 22 pages09.12(FIA and CFA) DIN EN ISO 14403-1:2012-10 2 A comma is used as the decimal marker. National foreword This standard has been prepared by Technical Committee ISO/TC 147 “Water quality” in collaboration with Technical Committee CEN/TC 230 “Water analysis” (Secreta

6、riat: DIN, Germany). The responsible German body involved in its preparation was the Normenausschuss Wasserwesen (Water Practice Standards Committee), Working Group NA 119-01-03-01-05 AK Flieanalysenverfahren of Working Committee NA 119-01-03 AA Wasseruntersuchung. ISO 14403 consists of the followin

7、g parts, under the general title Water quality Determination of total cyanide and free cyanide using flow analysis (FIA and CFA): Part 1: Method using flow injection analysis (FIA) Part 2: Method using continuous flow analysis (CFA) This standard is part of the series Deutsche Einheitsverfahren zur

8、Wasser-, Abwasser- und Schlamm-untersuchung Anionen (Gruppe D) (German standard methods for the examination of water, waste water and sludge Anions (group D) and describes method D 2. Designation of method D 2 “Determination of total cyanide and free cyanide using flow analysis (FIA and CFA) Part 1:

9、 Method using flow injection analysis (FIA) (D 2)”: Method DIN EN ISO 14403-1 D 2 During work on the revision ISO 14403:2002-03 has been divided into two parts. DIN EN ISO 14403-1 covers the new method using flow injection analysis (FIA), the text has been adjusted accordingly and the title has been

10、 changed. The method using continuous flow analysis (CFA) as specified in ISO 14403:2002 is now dealt with in DIN EN ISO 14403-2. The DIN Standards corresponding to the International Standards referred to in this document are as follows: ISO 3696 DIN ISO 3696 ISO 5667-3 DIN EN ISO 5667-3 ISO 5725-2

11、DIN ISO 5725-2 ISO 8466-1 DIN 38402-51 ISO 8466-2 DIN ISO 8466-2 Expert assistance and specialized laboratories will be required to perform the analysis described in this standard. Existing safety regulations are to be taken into account. Depending on the objective of the analysis, a check shall be

12、made on a case-by-case basis as to whether and to what extent additional conditions will have to be specified. DIN EN ISO 14403-1:2012-10 3 German standard methods for the examination of water, waste water and sludge Standard methods published as DIN Standards are obtainable from Beuth Verlag GmbH,

13、either individually or grouped in volumes. The standard methods included in the loose-leaf publication entitled Deutsche Einheitsverfahren zur Wasser-, Abwasser- und Schlammuntersuchung will continue to be published jointly by Wiley-VCH Verlag GmbH DGLJHVWLRQFRLORI)(3RU37)(LQWHUQDOGLDPHWHUPPOHQJWKPP

14、WXEHZDOOWKLFNQHVVDWPDLPXPPP HJQP89ODPSZLWK37)(FRLO 7KHHTXLSPHQWVKDOOEHVXFKWKDWQR89OLJKWZLWKDZDYHOHQJWKEHORZQPFDQUHDFKWKHVDPSOHRZWRDYRLGGHFRPSRVLWLRQRIWKLRFDQDWHWRFDQLGH7.1.6 Thermoreactor 1GLJHVWLRQFRLORI)(3ZLWKPPPPWXEHZDOOWKLFNQHVVDWPDLPXPPPZLWKDWHPSHUDWXUHRIV1LVWKHYROXPHRIVLOYHUQLWUDWHVROXWLRQ % F

15、RQVXPHGLQPLOOLOLWUHVc(AgNO3) is the concentration of silver nitrate solution in millimoles per litre;M2CNLVWKHPRODUPDVVRI&1 JPRO V LVWKHYROXPHRIWKHSRWDVVLXPFDQLGHVROXWLRQ LQPLOOLOLWUHV15DIN EN ISO 14403-1:2012-10 EN ISO 14403-1:2012 (E) Annex C (informative) Performance data$QLQWHUODERUDWRUWULDOIRUR

16、ZVVWHPVDVGHVFULEHGLQ&ODXVHZDVFDUULHGRXWLQ6SULQJ7KHUHVXOWVare shown in Tables C.1 and C.2.Table C.1 Statistical data for the determination of free cyanide by FIA LQDFFRUGDQFHZLWK,629)Sample MatrixalnoXxK sRCVRsrCVrJOJOJOJO1Drinking water2 90 75 2Drinking water2 89 63 3Surface water 2 89 113 4Surface

17、water 2498 75 5 Waste water 22 89 150 6 Waste water 23 93 63 l QXPEHURIODERUDWRULHVDIWHURXWOLHUUHMHFWLRQn QXPEHURILQGLYLGXDOWHVWUHVXOWVDIWHURXWOLHUUHMHFWLRQo percentage of outliersX assigned valuexoverall mean of results (without outliers)K UHFRYHUUDWHsRUHSURGXFLELOLWVWDQGDUGGHYLDWLRQCVRFRHIFLHQWRIY

18、DULDWLRQRIUHSURGXFLELOLWsrUHSHDWDELOLWVWDQGDUGGHYLDWLRQCVrFRHIFLHQWRIYDULDWLRQRIUHSHDWDELOLWaOrigin of the samples: VDPSOHVDQGVSLNHG&LWRI%HUOLQ VDPSOHVDQGVSLNHG/DQGZHKUNDQDO&LWRI%HUOLQ VDPSOHVDQGVSLNHG:DVWH:DWHU3ODQW%HUOLQ5XKOHEHQ16DIN EN ISO 14403-1:2012-10 EN ISO 14403-1:2012 (E) Table C.2 Statist

19、ical data for the determination of total cyanide by FIA LQDFFRUGDQFHZLWK,629)Sample MatrixalnoXxK sRCVRsrCVrJOJOJOJO1Drinking water25103 75 2Drinking water26107 126 3Drinking water25103 69 4Surface water 26106 113 5Surface water 26106 138 6Surface water 26107 132 7 Waste water 25 103 150 8 Waste wat

20、er 27 111 157 9 Waste water 27 110 113 )RUHSODQDWLRQRIVPEROVVHH7DEOH&aOrigin of the samples: VDPSOHVSLNHG&LWRI%HUOLQ VDPSOHVSLNHG/DQGZHKUNDQDO&LWRI%HUOLQ VDPSOHVSLNHG:DVWH:DWHU3ODQW%HUOLQ5XKOHEHQ127( ,QYHVWLJDWLRQVKDYHVKRZQWKDWWKHDGGLWLRQRISRWDVVLXPKHDFDQRIHUUDWH , WRWKHSDUWLFXODUZDVWHZDWHUPDWULXVHG

21、LQWKHLQWHUODERUDWRUWULDORQtotal cyanideZDVQRWIXOOUHFRYHUHG7KHUHFRYHUDFWXDOODFKLHYHGGHSHQG VRQWKHWLPHGHODEHWZHHQSUHSDUDWLRQRIWKHVSLNHGVROXWLRQDQGWKHPRPHQWRIDQDOVLV7KHVDPSOHVIRUWKHWRWDOFDQLGHWHVWZHUHVSLNHGZLWKKHDFDQRIHUUDWH , ,WLVDVVXPHGWKDWDSDUWRIWKLVUHDJHQWZDVUHGXFHGEFRPSRQHQWVRIWKHmatrix and that t

22、herefore a negative bias could have arisen.7KLVQGLQJHSODLQVWKHORZHUUHFRYHURIWRWDOFDQLGHLQZDVWHZDWHUVDPSOHVDQGDVREVHUYHGLQWKHLQWHUODERUDWRUWULDOEVHYHUDOSDUWLFLSDQWV1HYHUWKHOHVVWKLVHIIHFWLVKLJKOUHSURGXFLEOHDVVKRZQEWKHDEVHQFHRIRXWOLHUV7KHVHREVHUYDWLRQVDUHHSHFWHGWREHRIPLQRULPSRUWDQFHIRUSUDFWLFDOSXUSRVHV

23、EHFDXVHXVXDOOZDVWHZDWHUGRHVQRWFRQWDLQKHDFDQRIHUUDWH , LQPHDVXUDEOHFRQFHQWUDWLRQV,WFDQDOVREHDVVXPHGWKDWWKHSRVVLEOHUHGXFWLRQRIKHDFDQRIHUUDWH , EFRPSRQHQWVRIWKHZDVWHZDWHUKDVQLVKHGZKHQWKHVDPSOHLVWDNHQ17DIN EN ISO 14403-1:2012-10 EN ISO 14403-1:2012 (E) Bibliography (3$0HWKRGVIRUFKHPLFDODQDOVLVRIZDWHUDQG

24、ZDVWHV6WRUH1R&LQFLQQDWL2+(3$(3$&DQLGHWRWDO(colorimetric, automated UV 1(11):DWHUHQERGHP)RWRPHWULVFKHEHSDOLQJYDQKHWWRWDOHJHKDOWH DDQFDQLGHHQKHWgehalte aan vrij cyanide met behulp van een doorstroomanalysesysteem:DWHUDQGVRLO3KRWRPHWULFGHWHUPLQDWLRQRIWKHFRQWHQWRIWRWDODQGIUHHFDQLGHEFRQWLQXRXVRZDQDOVLV .

25、ELADA13$XWRPDWHGGLUHFWPHDVXUHPHQWVRIWRWDOFDQLGHVSHFLHVDQGWKLRFDQDWHVDQGWKHLUdistribution in waste water and sludge. -:DWHU3ROOXW&RQWU)HG61SS 0EEUSSEN -&/ 7EMMINGHOFF (-0 .EIZER 0* 1OVOZAMSKY , 6SHFWURSKRWRPHWULFGHWHUPLQDWLRQRIWRWDOFDQLGHLURQFDQLGHFRPSOHHVDQGWKLRFDQDWHLQZDWHUEDFRQWLQXRXVRZVVWHP$QDOVW

26、114SS TAUW INFRA CONSULT BV. Laboratory study on cyanide determination 3URMHFW 1R HYHQWHU %ERMAN5&HRISTMANN5ENN&$XWRPDWHGGHWHUPLQDWLRQRIZHDNDFLGGLVVRFLDEOHDQGWRWDOFDQLGHZLWKRXWWKLRFDQDWHLQWHUIHUHQFH$P(QYLURQ/DE 1993, 5SS (ATON$&LESCERI/6*REENBERG$(0HWKRG&1-&DQLGH,QStandard methods for WKHHDPLQDWLRQR

27、IZDWHUDQGZDVWHZDWHU:DVKLQJWRQ&$PHULFDQ3XEOLF+HDOWK$VVRFLDWLRQ 6EBROWSKI-2DE50HWKRGFRPSDULVRQDQGHYDOXDWLRQIRUWKHDQDOVLVRIZHDNDFLGGLVVRFLDEOHFDQLGH(QYLURQ6FL7HFKQRO 31SS ,62$FFXUDF WUXHQHVVDQGSUHFLVLRQ RIPHDVXUHPHQWPHWKRGVDQGUHVXOWV3DUW%DVLFmethod for the determination of repeatability and reproducibility of a standard measurement method1) $OVRVXLWDEOHIRUWKHGHWHUPLQDWLRQRIIUHHDQGWRWDOFDQLGHLQVRLODQGVOXGJH18DIN EN ISO 14403-1:2012-10 EN ISO 14403-1:2012 (E)