DIN EN ISO 15103-2-2007 Plastics - Poly(phenylene ether) (PPE) moulding and extrusion materials - Part 2 Preparation of test specimens and determination of properties (ISO 15103-2 .pdf

1、September 2007DEUTSCHE NORM English price group 9No part of this standard may be reproduced without prior permission ofDIN Deutsches Institut fr Normung e. V., Berlin. Beuth Verlag GmbH, 10772 Berlin, Germany,has the exclusive right of sale for German Standards (DIN-Normen).ICS 83.080.20!$I3a“138166

2、2www.din.deDDIN EN ISO 15103-2Plastics Poly(phenylene ether) (PPE) moulding and extrusion materials Part 2: Preparation of test specimens and determination of properties(ISO 15103-2:2007)English version of DIN EN ISO 15103-2:2007-09Kunststoffe Polyphenylether (PPE)-Formmassen Teil 2: Herstellung von

3、 Probekrpern und Bestimmung von Eigenschaften(ISO 15103-2:2007)Englische Fassung DIN EN ISO 15103-2:2007-09SupersedesDIN EN ISO 15103-2:2004-10www.beuth.deDocument comprises 12 pages11.07DIN EN ISO 15103-2:2007-09 2 National foreword This standard has been prepared by Technical Committee ISO/TC 61 “

4、Plastics” in collaboration with Technical Committee CEN/TC 249 “Plastics”, the secretariat of which is held by NBN (Belgium). The responsible German body involved in its preparation was the Normenausschuss Kunststoffe (Plastics Standards Committee), Technical Committee NA 054-02-08 AA Sonstige Therm

5、oplast-Formmassen. Attention is drawn to the possibility that some of the elements of this document may be the subject of patent rights. DIN shall not be held responsible for identifying any or all such patent rights. The DIN Standards corresponding to the International Standards (ISO and IEC) refer

6、red to in clause 2 of the EN are as follows: IEC 60093 DIN IEC 60093 IEC 60112 DIN EN 60112 IEC 60243-1 DIN EN 60243-1 IEC 60296 DIN EN 60296 IEC 60695-11-10 DIN EN 60695-11-10 ISO 62 DIN EN ISO 62 ISO 75-2 DIN EN ISO 75-2 ISO 178 DIN EN ISO 178 ISO 179-1 DIN EN ISO 179-1 ISO 180 DIN EN ISO 180 ISO

7、294-1 DIN EN ISO 294-1 ISO 527-1 DIN EN ISO 527-1 ISO 527-2 DIN EN ISO 527-2 ISO 1133 DIN EN ISO 1133 ISO 1183-1 DIN EN ISO 1183-1 ISO 1183-2 DIN EN ISO 1183-2 ISO 1183-3 DIN EN ISO 1183-3 ISO 3167 DIN EN ISO 3167 ISO 3451-1 DIN EN ISO 3451-1 ISO 8256 DIN EN ISO 8256 ISO 10350-1 DIN EN ISO 10350-1 I

8、SO 11357-3 DIN 53765 ISO 15103-1 DIN EN ISO 15103-1 ISO 15512 DIN EN ISO 15512 Amendments This standard differs from DIN EN ISO 15103-2:2004-10 as follows: a) The standard has been revised in form and substance. Previous editions DIN EN ISO 15103-2: 2004-10 DIN EN ISO 15103-2:2007-09 3 National Anne

9、x NA (informative) Bibliography DIN 53765, Testing of plastics and elastomeres Thermal analysis DSC-method DIN EN ISO 62, Plastics Determination of water absorption DIN EN ISO 75-2, Plastics Determination of temperature of deflection under load Part 2: Plastics and ebonite DIN EN ISO 178, Plastics D

10、etermination of flexural properties DIN EN ISO 179-1, Plastics Determination of Charpy impact properties Part 1: Non-instrumented impact test DIN EN ISO 180, Plastics Determination of Izod impact strength DIN EN ISO 294-1, Injection moulding of test specimens of thermoplastic materials Part 1: Gener

11、al princip-les, and moulding of multipurpose and bar test specimens DIN EN ISO 527-1, Plastics General principles for the determination of tensile properties DIN EN ISO 527-2, Determination of tensile properties of plastics Test conditions for moulding and extru-sion plastics DIN EN ISO 1133, Plasti

12、cs Determination of the melt mass-flow rate (MFR) and the melt volume-flow rate (MVR) of thermoplastics DIN EN ISO 1183-1, Plastics Methods for determining the density of non-cellular plastics Part 1: Immer-sion method, liquid pyknometer method and titration method DIN EN ISO 1183-2, Plastics Method

13、s for determining the density of non-cellular plastics Part 2: Density gradient column method DIN EN ISO 1183-3, Methods for determining the density of non-cellular plastics Part 3: Gas pyknometer method DIN EN ISO 3146, Plastics Determination of melting behaviour (melting temperature or melting ran

14、ge) of semi-crystalline polymers by capillary tube and polarizing-microscope methods DIN EN ISO 3167, Plastics Multipurpose test specimens DIN EN ISO 3451-1, Plastics Determination of ash Part 1: General methods DIN EN ISO 8256, Plastics Determination of tensile-impact strength DIN EN ISO 10350-1, P

15、lastics Acquisition and presentation of comparable single-point data Part 1: Moulding materials DIN EN ISO 15103-1, Plastics Poly(phenylene ether) (PPE) moulding and extrusion materials Part 1: Designation system and basis for specifications DIN EN ISO 15512, Plastics Determination of water content

16、DIN EN ISO 15103-2:2007-09 4 DIN IEC 60093, Methods of test for insulating materials for electrical purposes; volume resistivity and surface resistivity of solid electrical insulating materials DIN IEC 60112, Method for determining the comparative and the proof tracking indices of solid insulating m

17、aterials under moist conditions (DIN EN 60112 supersedes DIN IEC 60112 which has been withdrawn November 2003) DIN EN 60243-1, Electrical strength of insulating materials Test methods Part 1: Test at power frequen-cies DIN EN 60296, Fluids for electrotechnical applications Unused mineral insulating

18、oils for transformers and switchgear DIN EN 60695-11-10, Fire hazard testing Part 11-10: Test flames 50 W horizontal and vertical flame test methods EUROPEAN STANDARDNORME EUROPENNEEUROPISCHE NORMEN ISO 15103-2June 2007ICS 83.080.20 Supersedes EN ISO 15103-2:2004 English VersionPlastics - Poly(pheny

19、lene ether) (PPE) moulding and extrusionmaterials - Part 2: Preparation of test specimens anddetermination of properties (ISO 15103-2:2007)Plastiques - Matriaux base de poly(phnylne ther)(PPE) pour moulage et extrusion - Partie 2: Prparation desKunststoffe - Polyphenylether-(PPE-)Formmassen - Teil 2

20、:Herstellung von Probekrpern und Bestimmung vonEigenschaften (ISO 15103-2:2007)This European Standard was approved by CEN on 21 May 2007.CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this EuropeanStandard the status of a national

21、standard without any alteration. Up-to-date lists and bibliographical references concerning such nationalstandards may be obtained on application to the CEN Management Centre or to any CEN member.This European Standard exists in three official versions (English, French, German). A version in any oth

22、er language made by translationunder the responsibility of a CEN member into its own language and notified to the CEN Management Centre has the same status as theofficial versions.CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Cyprus, Czech Republic, Denmark, Estonia, F

23、inland,France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal,Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland and United Kingdom.EUROPEAN COMMITTEE FOR STANDARDIZATIONCOMIT EUROPEN DE NORMALISATIONEUROPISCHES KOM

24、ITEE FR NORMUNGManagement Centre: rue de Stassart, 36 B-1050 Brussels 2007 CEN All rights of exploitation in any form and by any means reservedworldwide for CEN national Members.Ref. No. EN ISO 15103-2:2007: E(ISO 15103-2:2007)prouvettes et dtermination des proprits EN ISO 15103-2:2007 (E) 2 Forewor

25、d This document (EN ISO 15103-2:2007) has been prepared by Technical Committee ISO/TC 61 “Plastics” in collaboration with Technical Committee CEN/TC 249 “Plastics”, the secretariat of which is held by NBN. This European Standard shall be given the status of a national standard, either by publication

26、 of an identical text or by endorsement, at the latest by December 2007, and conflicting national standards shall be withdrawn at the latest by December 2007. This document supersedes EN ISO 15103-2:2004. According to the CEN/CENELEC Internal Regulations, the national standards organizations of the

27、following countries are bound to implement this European Standard: Austria, Belgium, Bulgaria, Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia,

28、 Slovenia, Spain, Sweden, Switzerland and United Kingdom. Endorsement notice The text of ISO 15103-2:2007 has been approved by CEN as EN ISO 15103-2:2007 without any modifications. 1 Scope This part of ISO 15103 specifies the methods of preparation of test specimens and the test methods to be used i

29、n determining the properties of poly(phenylene ether) moulding and extrusion materials. Requirements for handling test material and for conditioning both the test material before moulding and the specimens before testing are given here. Procedures and conditions are described for the preparation of

30、test specimens, and procedures for measuring properties of the materials from which these specimens are made are given. Properties and test methods which are suitable and necessary to characterize poly(phenylene ether) moulding and extrusion materials are listed. The properties have been selected fr

31、om the general test methods in ISO 10350-1:1998. Other test methods in wide use for, or of particular significance to, these moulding and extrusion materials are also included in this part of ISO 15103, as are the designatory properties specified in ISO 15103-1. In order to obtain reproducible and c

32、omparable test results, it is necessary to use the methods of specimen preparation and conditioning, the specimen dimensions and the test procedures specified herein. Values determined will not necessarily be identical to those obtained using specimens of different dimensions or prepared using diffe

33、rent procedures. 2 Normative references The following referenced documents are indispensable for the application of this document. For dated references, only the edition cited applies. For undated references, the latest edition of the referenced document (including any amendments) applies. ISO 62, P

34、lastics Determination of water absorption ISO 75-2, Plastics Determination of temperature of deflection under load Part 2: Plastics and ebonite ISO 178, Plastics Determination of flexural properties ISO 179-1, Plastics Determination of Charpy impact properties Part 1: Non-instrumented impact test IS

35、O 180, Plastics Determination of Izod impact strength ISO 294-1, Plastics Injection moulding of test specimens of thermoplastic materials Part 1: General principles, and moulding of multipurpose and bar test specimens ISO 527-2, Plastics Determination of tensile properties Part 2: Test conditions fo

36、r moulding and extrusion plastics ISO 1133, Plastics Determination of the melt mass-flow rate (MFR) and the melt volume-flow rate (MVR) of thermoplastics EN ISO 15103-2:2007 (E)3ISO 1183-1, Plastics Methods for determining the density of non-cellular plastics Part 1: Immersion method, liquid pyknome

37、ter method and titration method ISO 1183-2, Plastics Methods for determining the density of non-cellular plastics Part 2: Density gradient column method ISO 1183-3, Plastics Methods for determining the density of non-cellular plastics Part 3: Gas pyknometer method ISO 3167, Plastics Multipurpose tes

38、t specimens ISO 3451-1, Plastics Determination of ash Part 1: General methods ISO 8256 Plastics Determination of tensile-impact strength ISO 10350-1:1998, Plastics Acquisition and presentation of comparable single-point data Part 1: Moulding materials ISO 11357-3, Plastics Differential scanning calo

39、rimetry (DSC) Part 3: Determination of temperature and enthalpy of melting and crystallization ISO 11359-2:1999, Plastics Thermomechanical analysis (TMA) Part 2: Determination of coefficient of linear thermal expansion and glass transition temperature ISO 15103-1, Plastics Poly(phenylene ether) (PPE

40、) moulding and extrusion materials Part 1: Designation system and basis for specifications ISO 15512, Plastics Determination of water content IEC 60093, Methods of test for volume resistivity and surface resistivity of solid electrical insulation materials IEC 60112, Method for the determination of

41、the proof and the comparative tracking indices of solid insulating materials IEC 60243-1, Electrical strength of insulating materials Test methods Part 1: Tests at power frequencies IEC 60250, Recommended methods for the determination of the permittivity and dielectric dissipation factor of electric

42、al insulating materials at power, audio and radio frequencies including metre wavelengths IEC 60296, Fluids for electrotechnical applications Unused mineral insulating oils for transformers and switchgear IEC 60695-11-10, Fire hazard testing Part 11-10: Test flames 50 W horizontal and vertical flame

43、 test methods 3 Preparation of test specimens 3.1 General It is essential that specimens are always prepared by the same procedure (injection moulding), using the same processing conditions. 3.2 Treatment of material before moulding Before processing, the moisture content of the material sample shal

44、l not exceed 0,05 % by mass. If the moisture level exceeds this limit, the sample shall be dried in accordance with the manufacturers instructions until the moisture content no longer exceeds the limit. EN ISO 15103-2:2007 (E)43.3 Injection moulding Specimens shall be prepared in accordance with ISO

45、 294-1, using the conditions specified in Table 1. Table 1 Conditions for injection moulding of test specimens Melt volume-flow rate Material Temperature of deflection under load (see ISO 15103-1) Filler content% by mass Conditions Value cm3/10 min Melt temperature C Mould temperatureC PPE A210 0 34

46、0 120 A080 0 220 50 30 220 0 250 C, 10 kg u 30 240 A090 0 but u 50 260 60 20 240 0 250 C, 10 kg u 20 260 20 260 A100 A110 0 but u 50 300 C, 5 kg u 20 280 70 5 280 0 250 C, 10 kg u 5 290 10 280 A120 A130 0 but u 50 300 C, 5 kg u 10 290 80 3 300 0 250 C, 10 kg u 3 310 4 290 A140 A150 0 but u 50 300 C,

47、 5 kg u 4 300 100 A160 u 50 310 120 A170 u 50 320 120 A180 A190 A200 u 50 340 120 PPE+PS A210 0 340 120 30 280 PPE+PA u 50 280 C, 5 kg u 30 300 100 5 250 PPE+PP u 50 250 C, 10 kg u 5 270 60 30 300 PPE+PPS u 70 300 C, 10 kg u 30 320 100 u 30 280 80 B180 30 but u 50 300 100 0 290 90 B190 0 but u 50 30

48、0 100 0 310 120 B200 0 but u 50 320 120 PPE+other B210 u 50 320 120 PPE+PS+other A200 u 50 320 120 Other injection-moulding conditions shall be as follows: For PPE, PPE+PS, PPE+PS+other For PPE+PA, PPE+PP, PPE+PPS, PPE+other Average injection velocity: 200 mm/s 100 mm/s Average injection velocity: 2

49、00 mm/s 100 mm/s Hold pressure: 70 MPa 30 MPa Hold pressure: 50 MPa 30 MPa Hold-pressure time: 20 s 5 s Hold pressure time: 20 s 5 s Total cycle time: u 50 s Total cycle time: u 50 s EN ISO 15103-2:2007 (E)54 Conditioning of test specimens 4.1 General Test specimens of all materials which are not modified with polyamides shall be conditioned for at