DIN EN ISO 3679-2015 Determination of flash no-flash and flash point - Rapid equilibrium closed cup method (ISO 3679 2015) German version EN ISO 3679 2015《无闪点和闪点的测定 快速平衡闭杯法 (ISO 36.pdf

1、June 2015Translation by DIN-Sprachendienst.English price group 14No part of this translation may be reproduced without prior permission ofDIN Deutsches Institut fr Normung e. V., Berlin. Beuth Verlag GmbH, 10772 Berlin, Germany,has the exclusive right of sale for German Standards (DIN-Normen).ICS 87

2、.040; 75.180.10!%CDp“2323377www.din.deDDIN EN ISO 3679Determination of flash no-flash and flash point Rapid equilibrium closed cup method (ISO 3679:2015);English version EN ISO 3679:2015,English translation of DIN EN ISO 3679:2015-06Bestimmung des Flammpunktes mit dem Ja/Nein-Verfahren Nach dem schn

3、ellen Gleichgewichtsverfahren mit geschlossenem Tiegel(ISO 3679:2015);Englische Fassung EN ISO 3679:2015,Englische bersetzung von DIN EN ISO 3679:2015-06Dtermination de lclair de type passe/ne passe pas et du point dclair Mthode rapide lquilibre en vase clos (ISO 3679:2015);Version anglaise EN ISO 3

4、679:2015,Traduction anglaise de DIN EN ISO 3679:2015-06SupersedesDIN EN ISO 3679:2004-07 andDIN EN ISO 3680:2004-07www.beuth.deIn case of doubt, the German-language original shall be considered authoritative.Document comprises 30 pages05.15 DIN EN ISO 3679:2015-06 2 A comma is used as the decimal ma

5、rker. National foreword This document (EN ISO 3679:2015) has been prepared by Technical Committee ISO/TC 28 “Petroleum products and related products of synthetic or biological origin” in collaboration with Technical Committee CEN/TC 19 “Gaseous and liquid fuels, lubricants and related products of pe

6、troleum, synthetic and biological origin” (Secretariat: NEN, Netherlands). The responsible German body involved in its preparation was the DIN-Normenausschuss Materialprfung (DIN Standards Committee Materials Testing), Working Committee NA 062-06-61 AA Prfung von Schmier-len, sonstigen len und Paraf

7、finen of the Fachausschuss Minerall- und Brennstoffnormung. The DIN Standards corresponding to the International Standards referred to in this document are as follows: ISO 1513 DIN EN ISO 1513 ISO 1516 DIN EN ISO 1516 ISO 1523 DIN EN ISO 1523 ISO 3170 DIN EN ISO 3170 ISO 3171 DIN EN ISO 3171 ISO 425

8、9 DIN EN ISO 4259 ISO 15528 DIN EN ISO 15528 IEC 60751 DIN EN 60751 Amendments This standard differs from DIN EN ISO 3679:2004-07 and DIN EN ISO 3680:2004-07 as follows: a) the title has been modified; b) temperature measuring device requirements have been revised; c) the ISO 3680 flash point techni

9、que has been incorporated into the flash/no flash technique as a separate procedure; d) new precision data have been included covering both gas and electric ignition. Previous editions DIN ISO 3679: 1977-12 DIN ISO 3680: 1977-12 DIN 55680: 1983-08 DIN 55679: 1985-12 DIN EN 456: 1991-09 DIN EN ISO 36

10、79: 2004-07 DIN EN ISO 3680: 2004-07 DIN EN ISO 3679:2015-06 3 National Annex NA (informative) Bibliography DIN EN ISO 1513, Paints and varnishes Examination and preparation of test samples DIN EN ISO 1516, Determination of flash/no flash Closed cup equilibrium method DIN EN ISO 1523, Determination

11、of flash point Closed cup equilibrium method DIN EN ISO 3170, Petroleum liquids Manual sampling DIN EN ISO 3171, Petroleum liquids Automatic pipeline sampling DIN EN ISO 4259, Petroleum products Determination and application of precision data in relation to methods of test DIN EN ISO 15528, Paints,

12、varnishes and raw materials for paints and varnishes Sampling DIN EN 60751, Industrial platinum resistance thermometers and platinum temperature sensors DIN EN ISO 3679:2015-06 4 This page is intentionally blank EN ISO 3679 March 2015 ICS 75.080; 87.040 Supersedes EN ISO 3679:2004, EN ISO 3680:2004E

13、nglish Version Determination of flash no-flash and flash point - Rapid equilibrium closed cup method (ISO 3679:2015) Dtermination de lclair de type passe/ne passe pas et du point dclair - Mthode rapide lquilibre en vase clos (ISO 3679:2015) Bestimmung des Flammpunktes mit dem Ja/Nein-Verfahren - Nac

14、h dem schnellen Gleichgewichtsverfahren mit geschlossenem Tiegel (ISO 3679:2015) This European Standard was approved by CEN on 14 January 2015. CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this European Standard the status of a n

15、ational standard without any alteration. Up-to-date lists and bibliographical references concerning such national standards may be obtained on application to the CEN-CENELEC Management Centre or to any CEN member. This European Standard exists in three official versions (English, French, German). A

16、version in any other language made by translation under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC Management Centre has the same status as the official versions. CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cypru

17、s, Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey andUnited Kingd

18、om. CEN-CENELEC Management Centre: Avenue Marnix 17, B-1000 Brussels 2015 CEN All rights of exploitation in any form and by any means reserved worldwide for CEN national Members. Ref. No. EN ISO 3679:2015 EEUROPEAN COMMITTEE FOR STANDARDIZATIONCOMIT EUROPEN DE NORMALISATIONEUROPISCHES KOMITEE FR NOR

19、MUNGEUROPEAN STANDARDNORME EUROPENNEEUROPISCHE NORMContentsPage Foreword . 3 Introduction . 4 1 Scope . 5 2 Normative references. 5 3 Terms and definitions 5 4 Principle 6 5 Reagents and materials . 6 6 Apparatus 6 7 Preparation of apparatus . 7 7.1 General 7 7.2 Location of apparatus 7 7.3 Cleaning

20、 of the test cup assembly and accessories 7 7.4 Apparatus verification . 8 8 Sampling . 8 9 Sample handling . 9 9.1 Petroleum products and fatty acid methyl esters . 9 9.1.1 Subsampling . 9 9.1.2 Samples liquid at ambient temperature . 9 9.1.3 Samples solid or semi-solid at ambient temperature . 9 9

21、.1.4 Samples containing dissolved or free water that is not part of the product . 9 9.2 Paints, varnishes, and related materials . 9 10 Procedure 9 10.1 General 9 10.2 Procedure A Flash no-flash test 10 10.3 Procedure B Flash point determination 11 11 Calculation 12 11.1 Conversion of barometric pre

22、ssure reading . 12 11.2 Correction of the detected flash point to standard atmospheric pressure 12 12 Expression of results . 12 13 Precision . 13 13.1 General . 13 13.2 Repeatability, r . 13 13.3 Reproducibility, R . 13 14 Test report . 14 Annex A (normative) Flash point apparatus . 15 Annex B (inf

23、ormative) Verification of apparatus. 20 Annex C (informative) The use of a cup insert 23 Annex D (normative) Sub-ambient testing for manual apparatus without integral test cup cooling facilities . 24 Annex E (normative) Temperature measuring device specifications . 25 Bibliography 26 2DIN EN ISO 367

24、9:2015-06 EN ISO 3679:2015 (E) Foreword This document (EN ISO 3679:2015) has been prepared by Technical Committee ISO/TC 28 Petroleum products and related products of synthetic or biological origin in collaboration Technical Committee CEN/TC 19 “Gaseous and liquid fuels, lubricants and related produ

25、cts of petroleum, synthetic and biological origin” the secretariat of which is held by NEN. This European Standard shall be given the status of a national standard, either by publication of an identical text or by endorsement, at the latest by September 2015, and conflicting national standards shall

26、 be withdrawn at the latest by September 2015. Attention is drawn to the possibility that some of the elements of this document may be the subject of patent rights. CEN and/or CENELEC shall not be held responsible for identifying any or all such patent rights. This document supersedes EN ISO 3679:20

27、04, EN ISO 3680:2004. According to the CEN-CENELEC Internal Regulations, the national standards organizations of the following countries are bound to implement this European Standard: Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of

28、Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and the United Kingdom. Endorsement notice The text of ISO 3679:2015 has been approved by

29、 CEN as EN ISO 3679:2015 without any modification. “”3DIN EN ISO 3679:2015-06EN ISO 3679:2015 (E)IntroductionThis International Standard is a closed cup equilibrium test method for the determination of the flash/no-flash and flash point of paints, varnishes, binders for paints and varnishes, solvent

30、s, adhesives, petroleum, and related products. ISO 15161and ISO 15232are also closed cup equilibrium test methods that are to be considered when selecting a method.The apparatus specified in this International Standard enables a similar test result to be determined using a more rapid procedure and a

31、 smaller test portion (2 ml or 4 ml) than that required in ISO 1516 and ISO 1523. In addition, the apparatus can be made portable to the extent of being suitable for on-site testing in addition to its more normal use in laboratories.Collaborative work3has shown that results obtained by these methods

32、 are comparable. The interpretation of flash point results obtained on solvent mixtures containing halogenated hydrocarbons should be considered with caution, as these mixtures can give anomalous results.4A limited study has indicated that some water borne paints can give an elevated flash point whe

33、n an electric ignitor is used with ISO 3679.Flash point can be used in shipping, storage, handling, and safety regulations, as a classification property to define “flammable” and “combustible” materials. Precise definition of the classes is given in each particular regulation.The flash point can ind

34、icate the presence of highly volatile material(s) in a relatively non-volatile or non-flammable material and flash point testing can be a preliminary step to other investigations into the composition of unknown materials.It is not appropriate for flash point determinations to be carried out on poten

35、tially unstable, decomposable, or explosive materials, unless it has been previously established that heating the specified quantity of such materials in contact with the metallic components of the flash point apparatus, within the temperature range required for the method, does not induce decomposi

36、tion, explosion or other adverse effects.The flash point is not a constant physical-chemical property of a material tested. It is a function of the apparatus design, the condition of the apparatus used, and the operational procedure carried out. Flash point can therefore only be defined in terms of

37、a standard test method, and no general valid correlation can be guaranteed between results obtained by different test methods or with test apparatus different from that specified.ISO/TR 296625(an adoption of CEN/TR 151386) gives useful advice in carrying out flash point tests and interpreting result

38、s.4DIN EN ISO 3679:2015-06 EN ISO 3679:2015 (E) WARNING The use of this International Standard can involve hazardous materials, operations, and equipment. This International Standard does not purport to address all of the safety problems associated with its use. It is the responsibility of the user

39、of this International Standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.1 ScopeThis International Standard specifies procedures for flash point tests, within the temperature range of 30 C to 300 C, for paints, includi

40、ng water-borne paints, varnishes, binders for paints and varnishes, adhesives, solvents, petroleum, and related products. The procedures are used to determine whether a product will or will not flash at a specified temperature (flash no-flash Procedure A) or the flash point of a sample (Procedure B)

41、. When used in conjunction with the flash detector (A.1.6), this International Standard is also suitable to determine the flash point of fatty acid methyl esters (FAME).2 Normative referencesThe following documents, in whole or in part, are normatively referenced in this document and are indispensab

42、le for its application. For dated references, only the edition cited applies. For undated references, the latest edition of the referenced document (including any amendments) applies.ISO 1513, Paints and varnishes Examination and preparation of test samplesISO 3170, Petroleum liquids Manual sampling

43、ISO 3171, Petroleum liquids Automatic pipeline samplingISO 4259, Petroleum products Determination and application of precision data in relation to methods of testISO 15528, Paints, varnishes and raw materials for paints and varnishes Sampling3 Terms and definitionsFor the purposes of this document,

44、the following terms and definitions apply.3.1flash pointlowest temperature, as measured in the prescribed manner, of the test portion corrected to a barometric pressure of 101,3 kPa, at which application of an ignition source causes the vapour of the test portion to ignite momentarily and the flame

45、to propagate across the surface of the liquid under the specified conditions of test3.2flash no-flashapplication of an ignition source at the specified temperature of the test portion, as measured in the prescribed manner, adjusted to a barometric pressure of 101,3 kPa, to determine whether the vapo

46、urs of the test portion ignite momentarily and a flame propagate across the surface of the liquid under the specified conditions of test5DIN EN ISO 3679:2015-06EN ISO 3679:2015 (E)3.3fatty acid methyl esterFAMEfuel comprising mono-alkyl esters of long chain fatty acids derived from vegetable oil or

47、animal fats, designated B100 or biodiesel (100 %)Note 1 to entry: FAME is specified in specifications such as EN 142147and ASTM D6751.84 PrincipleA test portion of specified volume is introduced into the test cup that is set and maintained at the required test temperature. After a specific time, an

48、ignition source is applied and a determination is made (Procedure A) as to whether or not a flash occurred. In order to determine the actual flash point of the sample, further tests, with fresh test portions at different test cup temperatures, are carried out (Procedure B) until the flash point is d

49、etermined.5 Reagents and materials5.1 Cleaning solvent, for the removal of traces of sample from the test cup and cover.The choice of solvent will depend upon the previous material tested and the tenacity of the residue. Low volatility aromatic (benzene-free) solvents can be used to remove traces of oil, and mixed solvents can be effective for the removal of gum-type deposits.5.2 Reference materials, series of ce