DIN EN ISO 4619-2011 Driers for paints and varnishes (ISO 4619 1998) German version EN ISO 4619 2010《涂料和清漆用干燥剂(ISO 4619-1998) 德文版本EN ISO 4619-2010》.pdf

1、February 2011 Translation by DIN-Sprachendienst.English price group 13No part of this translation may be reproduced without prior permission ofDIN Deutsches Institut fr Normung e. V., Berlin. Beuth Verlag GmbH, 10772 Berlin, Germany,has the exclusive right of sale for German Standards (DIN-Normen).I

2、CS 87.060.99!$my$“1748601www.din.deDDIN EN ISO 4619Driers for paints and varnishes (ISO 4619:1998)English translation of DIN EN ISO 4619:2011-02Trockenstoffe fr Beschichtungsstoffe (ISO 4619:1998)Englische bersetzung von DIN EN ISO 4619:2011-02Siccatifs pour peintures et vernis (ISO 4619:1998)Traduc

3、tion anglaise de DIN EN ISO 4619:2011-02SupersedesDIN ISO 4619:2002-04www.beuth.deDocument comprises pagesIn case of doubt, the German-language original shall be considered authoritative.2402.11 DIN EN ISO 4619:2011-02 2 A comma is used as the decimal marker. National foreword This standard has been

4、 prepared by Technical Committee ISO/TC 35 “Paints and varnishes” (Secretariat: NEN, Netherlands) in collaboration with Technical Committee CEN/TC 139 “Paints and varnishes” (Secretariat: DIN, Germany). The responsible German body involved in its preparation was the Normenausschuss Beschichtungsstof

5、fe und Beschichtungen (Coatings and Coating Materials Standards Committee), Working Committee NA 002-00-02 AA Lackrohstoffe. ISO 4619 specifies that methods for the determination of the metal contents of driers containing more than one metal shall be agreed between the interested parties. Possible m

6、ethods are given in the German standard DIN 55901, Driers for paints and varnishes Methods for determination of metal contents of mixed driers. It is intended to introduce them in a future revision of ISO 4619. The DIN Standards corresponding to the International Standards referred to in this docume

7、nt are as follows: ISO 150 DIN EN ISO 150 ISO 842 DIN EN ISO 15528 ISO 1523 DIN EN ISO 1523 ISO 2431 DIN EN ISO 2431 ISO 2592 DIN EN ISO 2592 ISO 2811-1 DIN EN ISO 2811-1 ISO 3219 DIN EN ISO 3219 ISO 3251 DIN EN ISO 3251 ISO 3696 DIN ISO 3696 Amendments This standard differs from DIN ISO 4619:2002-0

8、4 as follows: a) the status of the standard has been changed to that of a European Standard; b) normative references have been updated; c) the standard has been editorially revised. Previous editions DIN 55901: 1954-05, 1968-04, 1988-03 DIN ISO 4619: 1982-09, 2002-04 DIN EN ISO 4619:2011-02 3 Nation

9、al Annex NA (informative) Bibliography DIN EN ISO 150, Raw, refined and boiled linseed oil for paints and varnishes Specifications and methods of test DIN EN ISO 1523, Determination of flash point Closed cup equilibrium method DIN EN ISO 2431, Determination of flow time of paints and varnishes by us

10、e of flow cups DIN EN ISO 2592, Petroleum products Determination of flash and fire points Cleveland open cup method DIN EN ISO 2811-1, Paints and varnishes Determination of density Part 1: Pyknometer method DIN EN ISO 3219, Determination of viscosity of polymers and resins in the liquid state or as

11、emulsions or dispersions using a rotational viscometer with defined shear rate DIN EN ISO 3251, Paints, varnishes and plastics Determination of non-volatile-matter content DIN EN ISO 15528, Paints, varnishes and raw materials for paints and varnishes Sampling DIN ISO 3696, Water for analytical labor

12、atory use Specification and test methods DIN EN ISO 4619:2011-02 4 This page is intentionally blank EUROPEAN STANDARD NORME EUROPENNE EUROPISCHE NORM EN ISO 4619 November 2010 ICS 87.060.99 English Version Driers for paints and varnishes (ISO 4619:1998) Siccatifs pour peintures et vernis (ISO 4619:1

13、998) Trockenstoffe fr Beschichtungsstoffe (ISO 4619:1998) This European Standard was approved by CEN on 16 October 2010. CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this European Standard the status of a national standard withou

14、t any alteration. Up-to-date lists and bibliographical references concerning such national standards may be obtained on application to the CEN Management Centre or to any CEN member. This European Standard exists in three official versions (English, French, German). A version in any other language m

15、ade by translation under the responsibility of a CEN member into its own language and notified to the CEN Management Centre has the same status as the official versions. CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Fi

16、nland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland and United Kingdom. EUROPEAN COMMITTEE FOR STANDARDIZATION COMIT EUROPEN DE NORMALISATION EUROPISCHES

17、 KOMITEE FR NORMUNG Management Centre: Avenue Marnix 17, B-1000 Brussels 2010 CEN All rights of exploitation in any form and by any means reserved worldwide for CEN national Members. Ref. No. EN ISO 4619:2010: EContents DIN EN ISO 4619:2011-02 EN ISO 4619:2010 (E) 2 Page Foreword3 1 Scope 4 2 Normat

18、ive references 4 3 Definition 5 4 Descriptions .5 4.1 Solid driers .5 4.2 Liquid driers .5 4.3 Metals used 5 4.4 Acids used5 5 Requirements and test methods5 6 Sampling.5 7 Methods of test for solid driers6 7.1 Appearance and consistency.6 7.2 Colour .6 7.3 Solubility (miscibility) in solvents, raw

19、linseed oil or other drying media 7 7.4 Stability of solution7 7.5 Suspended solid matter 7 7.6 Volatile matter 7 7.7 Acidity or basicity7 8 Methods of test for liquid driers.10 8.1 Appearance 10 8.2 Colour .10 8.3 Solubility (miscibility) in solvents, raw linseed oil or other drying media 10 8.4 St

20、ability of solution10 8.5 Viscosity .11 9 Methods for determination of metal content of driers containing only one metal .11 9.1 Cobalt (EDTA titrimetric method).11 9.2 Manganese (EDTA titrimetric method) 12 9.3 Lead (EDTA titrimetric method)13 9.4 Zinc (EDTA titrimetric method).14 9.5 Calcium (EDTA

21、 titrimetric method)15 9.6 Iron (iodometric method) 16 9.7 Zirconium (EDTA titrimetric method).17 9.8 Barium.18 10 Methods for determination of metal contents of mixed driers 20 11 Test report 20 Foreword The text of ISO 4619:1998 has been prepared by Technical Committee ISO/TC 35 “Paints and varnis

22、hes” of the International Organization for Standardization (ISO) and has been taken over as EN ISO 4619:2010 by Technical Committee CEN/TC 139 “Paints and varnishes” the secretariat of which is held by DIN. This European Standard shall be given the status of a national standard, either by publicatio

23、n of an identical text or by endorsement, at the latest by May 2011, and conflicting national standards shall be withdrawn at the latest by May 2011. Attention is drawn to the possibility that some of the elements of this document may be the subject of patent rights. CEN and/or CENELEC shall not be

24、held responsible for identifying any or all such patent rights. According to the CEN/CENELEC Internal Regulations, the national standards organizations of the following countries are bound to implement this European Standard: Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Esto

25、nia, Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland and the United Kingdom. Endorsement notice The text of ISO 4619:1998 has been approved by CEN

26、as a EN ISO 4619:2010 without any modification. DIN EN ISO 4619:2011-02 EN ISO 4619:2010 (E) 3 1 ScopeThis International Standard specifies the requirements and the corresponding test methods for driers for paints,varnishes and related products. The requirements relate to driers in the solid or liqu

27、id form.CAUTION The procedures described in this International Standard are intended to be carried out byqualified chemist or by other suitably trained and/or supervised personnel. The substances and proceduresused in this method may be injurious to health if adequate precautions are not taken. This

28、 InternationalStandard refers only to its technical suitability and does not absolve the user from statutory obligationsrelating to health and safety.Attention is particularly drawn to the health hazards of heavy metals which may be a constituent of driers(e.g. cobalt, lead, cerium, zirconium, vanad

29、ium; see clauses 3, 4 and 8).2 Normative referencesThe following standards contain provisions which, through reference in this text, constitute provisions of thisInternational Standard. At the time of publication, the editions indicated were valid. All standards are subject torevision, and parties t

30、o agreements based on this International Standard are encouraged to investigate thepossibility of applying the most recent editions of the standards indicated below. Members of IEC and ISO maintainregisters of currently valid International Standards.ISO 150:1980, Raw, refined and boiled linseed oil

31、for paints and varnishes Specifications and methods of test.ISO 842:1984, Raw materials for paints and varnishes Sampling.ISO 1523:1983, Paints and varnishes Determination of flashpoint Closed cup method.ISO 2431:1993, Paints and varnishes Determination of flow time by use of flow cups.ISO 2592:1973

32、, Petroleum products Determination of flash and fire points Cleveland open cup method.ISO 2811-1:1997, Paints and varnishes Determination of density Part 1: Pyknometer method.ISO 3219:1993, Plastics Polymers/resins in the liquid state or as emulsions or dispersions Determination ofviscosity using a

33、rotational viscometer with defined shear rate.ISO 3251:1993, Paints and varnishes Determination of non-volatile matter of paints, varnishes and binders forpaints and varnishes.ISO 3696:1987, Water for analytical laboratory use Specifications and test methods.ISO 4793:1980, Laboratory sintered (fritt

34、ed) filters Porosity grading, classification and designation.DIN EN ISO 4619:2011-02 EN ISO 4619:2010 (E) 4 3 DefinitionFor the purposes of this International Standard, the following definition applies.3.1 drier: A compound, usually a metallic soap, that is added to products drying by oxidation in o

35、rder to acceleratethis process.4 Descriptions4.1 Solid driersSolid driers are materials which may be manufactured in a hard, soft (highly viscous) or powder form.4.2 Liquid driersLiquid driers are materials which are supplied as solutions in organic solvents, usually white spirit.NOTE Emulsifiable d

36、riers are also available, but no requirements for this type are given in this International Standard.All these types of drier, when dissolved in solvents (normally hydrocarbons), impart specific drying propertiesdepending on the metal used.4.3 Metals usedThe following metals are used: cobalt, mangan

37、ese, lead, zinc, calcium, cerium (or other rare earths), iron,zirconium, vanadium, barium, aluminium, strontium, etc.NOTE In this International Standard, methods for determination of metal content are given only for those metals which arein common use.4.4 Acids usedThe following acids are used: fatt

38、y acids of linseed oils, tall-oil fatty acids, resinic acids, naphthenic acids,2-ethylhexanoic acid, fatty iso-acids with 9 carbon atoms, other fatty acids with 9 to 11 carbon atoms, etc.5 Requirements and test methods5.1 Driers for paints shall comply with the requirement given in table 1.5.2 Drier

39、s named according to the commercial name of the main acid used shall contain at least 90 % of this acid,except for driers based on naphthenic acids, which shall contain at least 70 % of these acids, expressed as apercentage of the total mass of acid present.NOTE If desired, the type and content of t

40、he acids may be determined by gas-chromatographic (GC) analysis, except inthe case of naphthenic acids.6 SamplingTake a representative sample of the drier to be tested, as described in ISO 842.DIN EN ISO 4619:2011-02 EN ISO 4619:2010 (E) 5 Table 1 Requirements and test methodsCharacteristic Requirem

41、ent Test methodSolid driers Liquid driersAppearance Clear and uniform; nosuspended matter orsedimentSubclause 7.1 Subclause 8.1Consistency, if required To be agreed betweenthe interested partiesColour As agreed between theinterested partiesSubclause 7.2 Subclause 8.2Solubility (miscibility) in solve

42、nt, raw linseed oiland other drying mediaNo separation ordepositSubclause 7.3 Subclause 8.3Stability of solution Clear solution; noclouding gelation orsedimentationSubclause 7.4 Subclause 8.4of liquid driers % (m/m) max. 0,1 Subclause 7.5 Subclause 7.5of solid driersAs agreed between theViscosity, o

43、nly for liquid driersinterested parties Subclause 8.5Volatile matter at 105 C Subclause 7.6 Subclause 7.6Flashpoint ISO 2592 ISO 1523Density To be agreed betweenthe interested partiesISO 2811-1Acidity or basicity Subclause 7.7 Subclause 7.7Drying characteristics To be agreed between the interested p

44、artiesup to 10 % (m/m) 0,2 % 1)Clause 9 or 10above 10 % (m/m)to 20 % (m/m) 0,3 % 1)above 20 % (m/m)to 30 % (m/m) 0,4 % 1)above 30 % (m/m) 0,5 % 1)1) Tolerance (absolute value) on the metal content declared or agreed.7 Methods of test for solid driersDuring the analysis, use only reagents of recogniz

45、ed analytical grade and only water of at least grade 3 purity inaccordance with ISO 3696.7.1 Appearance and consistencyExamine the sample visually for uniformity. If the consistency is specified, a method for its determination shall beagreed between the interested parties7.2 ColourDissolve 1 part by

46、 mass of the drier in 1 part by mass of white spirit or other agreed solvent and compare the colouragainst an agreed sample or colour standard.Suspended solidmatterMetal content(range)DIN EN ISO 4619:2011-02 EN ISO 4619:2010 (E) 6 7.3 Solubility (miscibility) in solvents, raw linseed oil or other dr

47、ying mediaSlowly heat, raising the temperature at a rate of 1 C/min, 5 g of the drier and 20 g of an agreed solvent (or dryingmedium) under reflux on a sand bath, with stirring, until a homogeneous solution is obtained.Allow to cool to room temperature and examine the solution for clarity, clouding

48、and any separation or deposit.7.4 Stability of solutionAllow three portions of the solution obtained by the method specified in 7.3 to stand for 7 days in stoppered bottles,one at each of the following temperatures:a) 0 C;b) ambient temperature;c) 50 C.After 1 day and again after 7 days, examine the

49、 solutions for clarity, clouding sedimentation or gelation.The bottle used for the test at 50 C shall be able to withstand the pressure generated.7.5 Suspended solid matterWeigh, to the nearest 0,1 g, 5 g of solid drier (or 10 g of liquid drier) into a glass flask and dissolve in (or dilute with)100 g of white spirit or an agreed solvent. Stopper the flask allow to stand at ambient temperature for 3 days, thenfilter off the sediment or suspended matter using a glass filt