DIN EN ISO 25140-2010 Stationary source emissions - Automatic method for the determination of the methane concentration using flame ionisation detection (FID) (ISO 25140 2010) Germ.pdf

1、December 2010 Translation by DIN-Sprachendienst.English price group 16No part of this translation may be reproduced without prior permission ofDIN Deutsches Institut fr Normung e. V., Berlin. Beuth Verlag GmbH, 10772 Berlin, Germany,has the exclusive right of sale for German Standards (DIN-Normen).I

2、CS 13.040.40!$l_s“1736080www.din.deDDIN EN ISO 25140Stationary source emissions Automatic method for the determination of the methane concentrationusing flame ionisation detection (FID) (ISO 25140:2010)English translation of DIN EN ISO 25140:2010-12Emissionen aus stationren Quellen Automatisches Ver

3、fahren zur Bestimmung der Methan-Konzentration mit demFlammenionisationsdetektor (FID) (ISO 25140:2010)Englische bersetzung von DIN EN ISO 25140:2010-12missions de sources fixes Mthode automatique pour la dtermination de la concentration en mthane pardtection ionisation de flamme (FID) (ISO 25140:20

4、10)Traduction anglaise de DIN EN ISO 25140:2010-12www.beuth.deDocument comprises pagesIn case of doubt, the German-language original shall be considered authoritative.This standard has been included in the VDI/DIN Handbook on air quality, Volume 5. 3712.10 DIN EN ISO 25140:2010-12 2 A comma is used

5、as the decimal marker. National foreword This standard has been prepared by Technical Committee ISO/TC 146 “Air quality”, Subcommittee SC 1 “Stationary source emissions” in collaboration with Technical Committee CEN/TC 264 “Air quality” (Secretariat: DIN, Germany). The responsible German body involv

6、ed in its preparation was the Kommission Reinhaltung der Luft (KRdL) im VDI und DIN-Normenausschuss (Commission on Air Pollution Prevention of VDI and DIN Standards Committee), Section IV Umweltmesstechnik. The DIN Standards corresponding to the International Standards referred to in this document a

7、re as follows: ISO 5725-2 DIN ISO 5725-2 ISO 9169 DIN EN ISO 9169 ISO 14956 DIN EN ISO 14956 ISO 20988 DIN EN ISO 20988 ISO/IEC Guide 98-3 DIN V ENV 13005 National Annex NA (informative) Bibliography DIN V ENV 13005, Guide to the expression of uncertainty in measurement DIN EN ISO 9169, Air quality

8、Definition and determination of performance characteristics of an automatic measuring system DIN EN ISO 14956, Air quality Evaluation of the suitability of a measurement procedure by comparison with a required measurement uncertainty DIN EN ISO 20988, Air quality Guidelines for estimating measuremen

9、t uncertainty DIN ISO 5725-2, Accuracy (trueness and precision) of measurement methods and results Part 2: Basic method for the determination of repeatability and reproducibility of a standard measurement method VDI 2466 Part 1, Gaseous emission measurement Measurement of methane Manual gas chromato

10、gra-phy method VDI 2466 Part 2, Gaseous emission measurement Measurement of methane Automatic method Flame ionisation detector (FID) EUROPEAN STANDARD NORME EUROPENNE EUROPISCHE NORM EN ISO 25140 August 2010 ICS 13.040.40 English Version Stationary source emissions - Automatic method for the determi

11、nation of the methane concentration using flame ionisation detection (FID) (ISO 25140:2010) missions de sources fixes - Mthode automatique pour la dtermination de la concentration en mthane par dtection ionisation de flamme (FID) (ISO 25140:2010) Emissionen aus stationren Quellen - Automatisches Ver

12、fahren zur Bestimmung der Methan-Konzentration mit dem Flammenionisationsdetektor (FID) (ISO 25140:2010)This European Standard was approved by CEN on 26 May 2010. CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this European Standar

13、d the status of a national standard without any alteration. Up-to-date lists and bibliographical references concerning such national standards may be obtained on application to the CEN Management Centre or to any CEN member. This European Standard exists in three official versions (English, French,

14、German). A version in any other language made by translation under the responsibility of a CEN member into its own language and notified to the CEN Management Centre has the same status as the official versions. CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cy

15、prus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland and United Kingdom. EUROPEAN COMMITTEE FOR STANDARDIZATION

16、COMIT EUROPEN DE NORMALISATION EUROPISCHES KOMITEE FR NORMUNG Management Centre: Avenue Marnix 17, B-1000 Brussels 2010 CEN All rights of exploitation in any form and by any means reserved worldwide for CEN national Members. Ref. No. EN ISO 25140:2010: EContents DIN EN ISO 25140:2010-12 EN ISO 25140

17、:2010 (E) 2 Page Foreword3 Introduction .4 1 Scope 5 2 Normative references 5 3 Terms and definitions .5 4 Symbols and abbreviated terms 9 5 Apparatus and principles of operation10 6 Performance criteria and determination of the performance characteristics .13 7 Measurement procedure .15 8 Quality a

18、ssurance and quality control procedures17 9 Test report 21 Annex A (normative) Operational gases.23 Annex B (normative) Determination of the performance characteristics of an FID to be applied in the ongoing quality control (QA/QC) procedures 25 Annex C (normative) Safety measures .31 Annex D (infor

19、mative) Results of comparison tests32 Bibliography 35 Foreword This document (EN ISO 25140:2010) has been prepared by Technical Committee ISO/TC 146 “Air quality” in collaboration with Technical Committee CEN/TC 264 “Air quality” the secretariat of which is held by DIN. This European Standard shall

20、be given the status of a national standard, either by publication of an identical text or by endorsement, at the latest by February 2011, and conflicting national standards shall be withdrawn at the latest by February 2011. Attention is drawn to the possibility that some of the elements of this docu

21、ment may be the subject of patent rights. CEN and/or CENELEC shall not be held responsible for identifying any or all such patent rights. According to the CEN/CENELEC Internal Regulations, the national standards organizations of the following countries are bound to implement this European Standard:

22、Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland and the United Kingd

23、om. Endorsement notice The text of ISO 25140:2010 has been approved by CEN as a EN ISO 25140:2010 without any modification. DIN EN ISO 25140:2010-12 EN ISO 25140:2010 (E) 3 Introduction Methane (CH4) is a gas of relevance to the climate (greenhouse gas) and contributes directly to the atmospheric gr

24、eenhouse effect. The emissions of methane originate from natural and anthropogenic sources. Significant sources are, for example, cattle breeding, cultivation of rice, extraction and transport of natural gas, and landfills. Other important sources contributing to emissions of methane are, for exampl

25、e, composting plants, the use of biogas and natural gas, and biomass firings. This International Standard specifies a method of measurement for the determination of methane emissions from stationary sources. DIN EN ISO 25140:2010-12 EN ISO 25140:2010 (E) 4 1 Scope This International Standard specifi

26、es the principle, the essential performance criteria, and quality assurance and quality control procedures for an automatic method for measuring methane in the waste gas of stationary sources using flame ionisation detection. It is applicable to measurements of methane in dry or wet waste gases. The

27、 method allows continuous monitoring with permanently installed measuring systems as well as intermittent measurements of methane emissions. NOTE 1 This International Standard is specific to automatic methods for measuring methane in the waste gas of stationary sources using flame ionisation detecti

28、on. It supplements the general requirements of other international or national standards on performance testing, QA/QC procedures, and the test report as specified, for example, in EN 15267-37, EN 141815, and EN 152596. This International Standard does not specify an independent method of measuremen

29、t. NOTE 2 An independent method of measurement, e.g. to calibrate or validate permanently installed measuring systems, is specified in ISO 251393. NOTE 3 In EN 141815, “independent method of measurement” is called “standard reference method (SRM)”. 2 Normative references The following referenced doc

30、uments are indispensable for the application of this document. For dated references, only the edition cited applies. For undated references, the latest edition of the referenced document (including any amendments) applies. ISO 9169:2006, Air quality Definition and determination of performance charac

31、teristics of an automatic measuring system ISO 14956, Air quality Evaluation of the suitability of a measurement procedure by comparison with a required measurement uncertainty ISO 20988, Air quality Guidelines to estimating measurement uncertainty 3 Terms and definitions For the purposes of this do

32、cument, the following terms and definitions apply. 3.1 automatic measuring system AMS air quality measuring system interacting with the waste gas under investigation, returning an output signal proportional to the physical unit of the measurand in unattended operation NOTE 1 Adapted from ISO 9169:20

33、06, 2.1.2. DIN EN ISO 25140:2010-12 EN ISO 25140:2010 (E) 5 NOTE 2 In the sense of this document, an AMS is a system that can be attached to a duct to continuously or intermittently measure and record the mass concentrations of methane passing through the duct. 3.2 analyser stationary source emissio

34、ns analytical part in an extractive or in situ automatic measuring system NOTE Adapted from ISO 12039:20012, 3.3. 3.3 measurand particular quantity subject to measurement ISO/IEC Guide 98-3:20084, B.2.9 EXAMPLE The mass concentration of methane in air. 3.4 mass concentration stationary source emissi

35、ons concentration of a substance in an emitted waste gas expressed as mass per volume ISO 12039:20012, 3.10 NOTE Mass concentration is often expressed in milligrams per cubic metre. 3.5 independent reading stationary source emissions reading that is not influenced by a previous individual reading by

36、 separating two individual readings by at least four response times 3.6 individual reading stationary source emissions reading averaged over a time period equal to the response time of the automatic measuring system 3.7 interferent interfering substance air quality substance present in the air mass

37、under investigation, other than the measurand, that affects the response ISO 9169:2006, 2.1.12 3.8 adjustment automatic measuring system operation of bringing an automatic measuring system into a state of performance suitable for its use NOTE Adjustment can be automatic, semi-automatic or manual. IS

38、O 9169:2006, 2.1.5 3.9 calibration stationary source emissions procedure for establishing the statistical relationship between values of the measurand indicated by the automatic measuring system and the corresponding values given by an independent method of measurement implemented simultaneously at

39、the same measuring point DIN EN ISO 25140:2010-12 EN ISO 25140:2010 (E) 6 NOTE 1 An independent method of measurement for the purpose of calibration of permanently installed methane measuring systems is specified in ISO 251393. NOTE 2 In EN 141815, “independent method of measurement” is called “stan

40、dard reference method (SRM)”. 3.10 interference air quality negative or positive effect upon the response of the measuring system, due to a component of the sample that is not the measurand 3.11 zero gas stationary source emissions gas or gas mixture used to establish the zero point on a calibration

41、 curve within a given concentration range ISO 12039:20012, 3.4.2 3.12 span gas gas or gas mixture used to adjust and check a specific point on a calibration curve NOTE Adapted from ISO 12039:20012, 3.4.1. 3.13 reference gas stationary source emissions gas of known, reliable and stable composition th

42、at may be used to check the response of an automatic measuring system and to calibrate the automatic measuring system 3.14 zero point stationary source emissions specified value of the output quantity (measured signal) of the automatic measuring system and which, in the absence of the measured compo

43、nent, represents the zero crossing of the calibration line 3.15 span point value of the output quantity (measured signal) of the automatic measuring system for the purpose of calibration or adjustment that represents a correct measured value generated by a reference material NOTE This concentration

44、is often chosen to be around 80 % of the upper limit of the measuring range or around the emission limit value. 3.16 performance characteristic air quality one of the quantities assigned to equipment in order to define its performance NOTE Performance characteristics can be described by values, tole

45、rances or ranges. 3.17 response time air quality time interval between the instant when a stimulus is subjected to a specified abrupt change and the instant when the response reaches and remains within specified limits around its final stable value, determined as the sum of the lag time and the rise

46、 time in the rising mode, and the sum of the lag time and the fall time in the falling mode ISO 9169:2006, 2.2.4 DIN EN ISO 25140:2010-12 EN ISO 25140:2010 (E) 7 3.18 lag time air quality by convention, time taken for the output signal to reach 10 % of the final change in the output signal when a st

47、ep function is applied by applying a reference material to the automatic measuring system initially in the basic state ISO 9169:2006, 2.2.2 3.19 rise time air quality by convention, time taken for the output signal to pass from 10 % to 90 % of the final change in the output signal when a reference m

48、aterial is abruptly applied to the automatic measuring system initially in the basic state NOTE For instruments where transient oscillations occur in the approach to the final output signal, 90 % of the final change is considered as reached when the oscillations fall to less than 10 % of the final c

49、hange in the output signal. ISO 9169:2006, 2.2.3 3.20 fall time air quality by convention, time taken for the output signal to pass from 90 % to 10 % of the initial output signal produced by a reference material applied to the automatic measuring system, when the application of this reference material is abruptly terminated to put the automatic measuring system in the basic state NOTE For instruments where transient oscillations occur in the approach to the final o