DIN ISO 12219-2-2012 Interior air of road vehicles - Part 2 Screening method for the determination of the emissions of volatile organic compounds from vehicle interior parts and ma.pdf

1、November 2012 Translation by DIN-Sprachendienst.English price group 12No part of this translation may be reproduced without prior permission ofDIN Deutsches Institut fr Normung e. V., Berlin. Beuth Verlag GmbH, 10772 Berlin, Germany,has the exclusive right of sale for German Standards (DIN-Normen).I

2、CS 13.040.20; 43.020!$H“1922537www.din.deDDIN ISO 12219-2Interior air of road vehicles Part 2: Screening method for the determination of the emissions ofvolatile organic compounds from vehicle interior parts and materials Bag method (ISO 12219-2:2012),English translation of DIN ISO 12219-2:2012-11In

3、nenraumluft von Straenfahrzeugen Teil 2: Screeningverfahren fr die Bestimmung von flchtigen organischen Verbindungenaus Fahrzeuginnenraumausstattungsteilen Probenbeutel-Verfahren (ISO 12219-2:2012),Englische bersetzung von DIN ISO 12219-2:2012-11Air intrieur des vhicules routiers Partie 2: Mthode de

4、 criblage pour la dtermination des missions de compossorganiques volatils des parties et des matriaux intrieurs des vhicules Mthode du sac (ISO 12219-2:2012),Traduction anglaise de DIN ISO 12219-2:2012-11www.beuth.deDocument comprises pagesIn case of doubt, the German-language original shall be cons

5、idered authoritative.This standard has been included in the VDI/DIN Handbooks on air quality, Volume 5. 2110.12 DIN ISO 12219-2:2012-11 2 A comma is used as the decimal marker. Contents Page National foreword .3 National Annex NA (informative) Bibliography Introduction .7 1 Scope 8 2 Normative refer

6、ences 8 3 Terms and definitions .8 4 Principle 9 5 Apparatus and materials .9 6 Test conditions . 11 6.1 General . 11 6.2 Test specimen size . 11 6.3 Curing conditions (storage period and storage conditions) . 11 6.4 Heating temperature . 11 6.5 Heating time 11 6.6 Gas amount to be filled in a sampl

7、ing bag 11 7 Verification of test conditions . 12 7.1 Monitoring of test conditions 12 7.2 Recovery rate 12 8 Test method . 12 8.1 Test equipment . 12 8.2 Preparation for testing . 12 8.3 Emission test . 12 8.4 Gas collection . 13 9 Analytical procedures 13 9.1 Analysis of VOCs 13 9.2 Analysis of fo

8、rmaldehyde and other carbonyl compounds . 13 10 Calculation of sampling bag values . 14 11 Test report . 14 12 Quality assurance/quality control . 15 Annex A (informative) General procedures for preparation and storage of test specimens . 18 Annex B (informative) Additional information on test repor

9、t and recovery rate . 19 Bibliography . 21 5DIN ISO 12219-2:2012-11 3 National foreword International technical regulation pertaining to indoor air This standard has been prepared by Technical Committee ISO/TC 146 “Air quality”, Subcommittee SC 6 “Indoor air” and Technical Committee ISO/TC 22 “Road

10、Vehicles”, Joint Working Group ISO/TC 22-ISO/TC 146/SC 6/WG 13 (JWG 13) “Determination of volatile organic components in car interiors” (Secretariat: DIN, Germany). The responsible German body involved in its preparation were the Kommission Reinhaltung der Luft (KRdL) im VDI und DIN Normenausschuss

11、(Commission on Air Pollution Prevention of VDI and DIN Standards Committee), Section IV Umweltmesstechnik and the Working Group Innenraumemission of the Verband der Automobilindustrie (VDA) (German Association of the Automotive Industry). Attention is drawn to the possibility that some of the elemen

12、ts of this document may be the subject of patent rights. DIN shall not be held responsible for identifying any or all such patent rights. The DIN Standards corresponding to the International Standards referred to in Clause 2 of this standard are as follows: ISO 16000-3 DIN ISO 16000-3 ISO 16000-6 DI

13、N ISO 16000-6 ISO 16017-1 DIN ISO 16017-1 National technical regulation pertaining to indoor air DIN ISO 12219 consists of the following parts, under the general title Interior air of road vehicles: Part 1: Whole vehicle test chamber Specification and method for the determination of volatile organic

14、 compounds in cabin interiors Part 2: Screening method for the determination of the emissions of volatile organic compounds from vehicle interior parts and materials Bag method Part 3: Screening method for the determination of the emissions of volatile organic compounds from vehicle interior parts a

15、nd materials Micro-scale chamber method Part 4: Screening method for the determination of the emissions of volatile organic compounds from vehicle interior parts and materials Small chamber method Part 5: Screening method for the determination of the emissions of volatile organic compounds from vehi

16、cle interior parts and materials Static chamber method In addition to the DIN ISO 12219 series, the following parts of DIN EN ISO 16000 have been published dealing with the determination of VOCs: DIN ISO 16000-3, Determination of formaldehyde and other carbonyl compounds Active sampling method DIN I

17、SO 16000-4, Determination of formaldehyde Diffusive sampling method DIN EN ISO 16000-5, Sampling strategy for volatile organic compounds (VOCs) DIN ISO 16000-6, Determination of volatile organic compounds in indoor and test chamber air by active sampling on Tenax TAsorbent, thermal desorption and ga

18、s chromatography using MS/FID DIN ISO 12219-2:2012-11 4 DIN EN ISO 16000-9, Determination of the emission of volatile organic compounds from building products and furnishing Emission test chamber method DIN EN ISO 16000-10, Determination of the emission of volatile organic compounds from building pr

19、oducts and furnishing Emission test cell method DIN EN ISO 16000-11, Determination of the emission of volatile organic compounds from building products and furnishing Sampling, storage of samples and preparation of test specimens DIN ISO 16000-24, Performance test for evaluating the reduction of vol

20、atile organic compounds and carbonyl compounds without formaldehyde concentrations by sorptive building materials DIN ISO 16000-25, Determination of the emission of semi-volatile organic compounds by building products Micro-chamber method Further, reference is made to the following standards coverin

21、g VOC measurement methods: DIN EN ISO 16017-1, Indoor, ambiant and workplace air Sampling and analysis of volatile organic compounds by sorbent tube/thermal desorption/capillary gas chromatography Part 1: Pumped sampling DIN EN ISO 16017-2, Indoor, ambient and workplace air Sampling and analysis of

22、volatile organic compounds by sorbent tube/thermal desorption/capillary gas chromatography Part 2: Diffusive sampling DIN ISO 12219-2:2012-11 5 National Annex NA (informative) Bibliography DIN ISO 12884, Ambient air Determination of total (gas and particle phase) polycyclic aromatic hydrocarbons Col

23、lection on sorbent-backed filters with gas chromatographic/mass spectrometric analysis DIN V EN V 13005, Guide to the expression of uncertainty in measurement DIN EN 14412, Indoor air quality Diffusive samplers for the determination of concentrations of gases and vapours Guide for selection, use and

24、 maintenance DIN EN ISO 16017-1, Indoor, ambiant and workplace air Sampling and analysis of volatile organic compounds by sorbent tube/thermal desorption/capillary gas chromatography Part 1: Pumped sampling DIN EN ISO 16017-2, Indoor, ambient and workplace air Sampling and analysis of volatile organ

25、ic compounds by sorbent tube/thermal desorption/capillary gas chromatography Part 2: Diffusive sampling DIN ISO 16362, Ambient air Determination of particle-phase polycyclic aromatic hydrocarbons by high performance liquid chromatography DIN EN ISO/IEC 17025, General requirements for the competence

26、of testing and calibration laboratories DIN 70010:2001-04, System of road vehicles Vocabulary of power-driven vehicles, combinations of vehicles and towed vehicles VDA 276, Determination of organic substances as emitted from automotive interior products using a 1 m3test cabinet VDA 277, Nichtmetalli

27、sche Werkstoffe der Kfz-Innenausstattung Bestimmung der Emission organischer Verbindungen (German version only) VDA 278, Thermal desorption analysis of organic emissions for the characterization of non-metallic materials for automobiles VDI 2464 Part 1, Ambient air measurement Indoor air measurement

28、 Measurement of polychlorinated biphynyls (PCBs) GC/MS method for PCB 28, 52, 101,138, 153, 180 VDI 2464 Part 2, Ambient air measurement Indoor air measurement Measurement of polychlorinated biphenyls (PCBs) HR-GC/HR-MS method for coplanar PCBs VDI 2464 Part 3, Ambient air measurement Indoor air mea

29、surement Measurement of polybrominated diphenylether, hexabromocyclododecane and hexabromobenzene by GC/MS VDI 3484 Part 1, Gaseous ambient air measurements Indoor-air pollution measurements Test gases measurements Measurement of the formaldehyde concentration with the sulfite pararosaniline method

30、VDI 3484 Part 2, Gaseous ambient air measurements Indoor-air pollution measurements Measurement of the formaldehyde concentration with the acatylacetone method VDI 3498 Part 1, Ambient air measurement Indoor air measurement Measurement of polychlorinated dibenzo-p-dioxins and dibenzofurans Method us

31、ing large filters VDI 3498 Part 2, Ambient air measurement Indoor air measurement Measurement of polychlorinated dibenzo-p-dioxins and dibenzofurans Method using small filters DIN ISO 12219-2:2012-11 6 VDI 4252 Part 2, Measurement of airborne microorganisms and viruses in ambient air Active sampling

32、 of bioaerosols Separation of airborne mould on gelatine/polycarbonate filters VDI 4253 Part 2, Measurement of airborne microorganisms and viruses in ambient air Culture based method for the determination of the concentration of mould in air Indirect method after sampling with gelatine/polycarbonate

33、 filters VDI 4300 Part 1, Indoor-air pollution measurement General aspects of measurement strategy VDI 4300 Part 2, Indoor-air pollution measurement Measurement strategy for polycyclic aromatic hydrocarbons (PAHs), polychlorinated dibenzo-p-dioxins (PCDDs), polychlorinated dibenzofurans (PCDFs) and

34、polychlorinated biphenyle (PCBs) VDI 4300 Part 4, Indoor air pollution measurement Measurement strategy for pentachlorophenol (PCP) and -hexachlorocyclohexane (lindane) in indoor air VDI 4300 Part 5, Indoor air pollution measurement Measurement strategy for nitrogen dioxide (NO2) VDI 4300 Part 6, Me

35、asurement of indoor air pollution Measurement strategy for volatile organic compounds (VOCs) VDI 4300 Part 7, Indoor air pollution measurement Measurement of indoor air change rate VDI 4300 Part 8, Measurement of indoor air pollution Sampling of house dust VDI 4300 Part 9, Measurement of indoor air

36、pollution Measurement strategy for carbon dioxide (CO2) VDI 4300 Part 10, Measurement of indoor air pollution Measurement strategies for determination of mould fungi in indoor environment VDI 4300 Part 11, Measurement of indoor air pollution Measurement strategies for determination of airborne parti

37、cles in indoor environment Particles with equivalent diameter 2,5 m VDI 4301 Part 1, Indoor air pollution measurement Determination of the concentration of nitrogen dioxide Manual photometric method (Saltzman) VDI 4301 Part 2, Indoor air pollution measurement Measurement of pentaclorphenol (PCP) and

38、 -hexachlorcyclohexane (lindane) GC/MS-method VDI 4301 Part 3, Measurement of indoor air pollution Measurement pentaclorophenol (PCP) and -hexachlorcyclohexane (lindane) GC/ECD method VDI 4301 Part 4, Measurement of indoor air pollution Measurement of pyrethroids and piperonyl butoxide in air, house

39、 dust and solvent wipe samples VDI 4301 Part 5, Measurement of indoor air pollution Measurement of flame retardants and plasticizers based on organophosphorous compounds Phosphoric acid ester VDI 4301 Part 6, Measurement of indoor air pollution Measurement of phthalates with GC/MS The following VDI

40、Guidelines are under preparation: VDI 4301 Part 7, Measurement of indoor air pollution Measurement of carboxylic acids VDI 2464 Part 4, Messen von Immissionen Messen von Innenraumluft Messen von persistenten, schwerflchtigen Organohalogenverbindungen (German version only) IntroductionVolatile organi

41、c compounds (VOCs) are widely used in industry and may be emitted by many everyday products and materials. They have attracted much attention in recent years because of their impact on indoor air quality. After homes and workplaces, people spend a lot of time in their vehicles. It is important to de

42、termine the material emissions of interior parts and to reduce them to an acceptable level, if required. Therefore it is necessary to obtain comprehensive and reliable information about the types of organic compounds in the interior air of vehicles and also their concentrations.This part of ISO 1221

43、9 outlines the sampling bag test method for the screening of VOCs, formaldehyde and other carbonyl compounds which diffuse from vehicle interior parts into the air inside road vehicles.Measuring VOCs from vehicle interior parts can be performed in several ways and the approach selected depends upon

44、the desired outcome and the material type. For example, to obtain diffusion data from complete assemblies (e.g. instrument panel, seat etc.) it is necessary to employ chambers / bags that have sufficient volume to house the complete assembly. Meanwhile, to obtain diffusion data from representative s

45、amples of homogeneous vehicle interior materials, the micro-scale chamber method can be chosen.Each measurement method such as bag/micro-scale chamber/small-chamber sampling offers a complementary approach.ISO 16000-3, ISO 16000-5,2ISO 16000-6, ISO 16000-9,3ISO 16000-10,4ISO 16000-11,5ISO 16000-24,6

46、ISO 16000-25,7as well as ISO 16017-1 and ISO 16017-28also focus on VOC measurements.Interior air of road vehicles Part 2: Screening method for the determination of the emissions of volatile organic compounds from vehicle interior parts and materials Bag method 7 DIN ISO 12219-2:2012-11 WARNING It is

47、 the responsibility of the user of this part of ISO 12219 to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. National regulations for precautions shall be followed.1 ScopeThis part of ISO 12219 specifies the sampling bag test

48、method for measuring volatile organic compounds (VOCs), formaldehyde and other carbonyl compounds which may diffuse from vehicle interior parts into the air inside road vehicles. This method is intended for evaluating and screening new vehicle interior parts and materials such as seats, the instrument panel, ceiling materials and so on.The test metho