DIN ISO 12219-4-2013 Interior air of road vehicles - Part 4 Method for the determination of the emissions of volatile organic compounds from vehicle interior parts and materials - .pdf

1、December 2013 Translation by DIN-Sprachendienst.English price group 13No part of this translation may be reproduced without prior permission ofDIN Deutsches Institut fr Normung e. V., Berlin. Beuth Verlag GmbH, 10772 Berlin, Germany,has the exclusive right of sale for German Standards (DIN-Normen).I

2、CS 13.040.20; 43.020!%*j“2077127www.din.deDDIN ISO 12219-4Interior air of road vehicles Part 4: Method for the determination of the emissions of volatile organiccompounds from vehicle interior parts and materials Small chamber method (ISO 12219-4:2013),English translation of DIN ISO 12219-4:2013-12I

3、nnenraumluft von Straenfahrzeugen Teil 4: Verfahren fr die Bestimmung von flchtigen organischen Verbindungen ausFahrzeuginnenraumausstattungsteilen Kleinprfkammer-Verfahren (ISO 12219-4:2013),Englische bersetzung von DIN ISO 12219-4:2013-12Air intrieur des vhicules routiers Partie 4: Mthode pour la

4、dtermination des missions de composs organiques volatilsdes parties et des matriaux intrieurs des vhicules Mthode de la petite chambre (ISO 12219-4:2013),Traduction anglaise de DIN ISO 12219-4:2013-12www.beuth.deDocument comprises 25 pagesThis standard has been included in the VDI/DIN Handbooks on a

5、ir quality, Volume 5.In case of doubt, the German-language original shall be considered authoritative.11.13 Contents PageNational Foreword 3Introduction 91 Scope 102 Normative references 103 Terms and definitions 114 Symbols . 135 Principle . 146 Emission test bed preparation 146.1 Components 146.2

6、Small chamber 146.3 Small chamber temperature control . 156.4 Air humidification . 156.5 Clean air supply . 167 Quality control . 167.1 General 167.2 Airtightness . 167.3 Recovery and sink effects 177.4 Supply air 188 Component or automotive interior product .198.1 General 198.2 History of the compo

7、nent or automotive interior product .198.3 Packaging, transport and storage of the component or automotive interior product .199 Standard emission test procedure 199.1 General 199.2 Cleaning and purification 209.3 Test . 2010 Calculation of emission rate 2211 Test report 2212 Quality assurance/quali

8、ty control (QA/QC) . 23Bibliography . 25A comma is used as the decimal marker. National Annex NA (informative) Bibliography . 5DIN ISO 12219-4:2013-122 National foreword International technical regulation pertaining to indoor air This document (ISO 12219-4:2013) has been prepared by Technical Commit

9、tee ISO/TC 146 “Air quality”, Subcommittee SC 6 “Indoor air” and Technical Committee ISO/TC 22 “Road Vehicles”, Joint Working Group ISO/TC 22-ISO/TC 146/SC 6/WG 13 (JWG 13) “Determination of volatile organic components in car interiors” (Secretariat: DIN, Germany). The responsible German bodies invo

10、lved in its preparation were the Kommission Reinhaltung der Luft (KRdL) im VDI und DIN Normenausschuss (Commission on Air Pollution Prevention of VDI and DIN Standards Committee), Section IV Umweltmesstechnik and the Working Group Innenraumemission of the Verband der Automobilindustrie (VDA) (German

11、 Association of the Automotive Industry). The DIN Standards corresponding to the International Standards referred to in Clause 2 of this standard are as follows: ISO 16000-3 DIN ISO 16000-3 ISO 16000-6 DIN ISO 16000-6 ISO 16000-9 DIN EN ISO 16000-9 ISO 16000-11 DIN EN ISO 16000-11 ISO 16017-1 DIN EN

12、 ISO 16017-1 Attention is drawn to the possibility that some of the elements of this document may be the subject of patent rights. DIN shall not be held responsible for identifying any or all such patent rights. National technical regulation pertaining to indoor air DIN ISO 12219 consists of the fol

13、lowing parts, under the general title Interior air of road vehicles: Part 1: Whole vehicle test chamber Specification and method for the determination of volatile organic compounds in cabin interiors Part 2: Screening method for the determination of the emissions of volatile organic compounds from v

14、ehicle interior parts and materials Bag method Part 3: Screening method for the determination of the emissions of volatile organic compounds from vehicle interior parts and materials Micro-scale chamber method Part 4: Screening method for the determination of the emissions of volatile organic compou

15、nds from vehicle interior parts and materials Small chamber method Part 5: Screening method for the determination of the emissions of volatile organic compounds from vehicle interior parts and materials Static chamber method (in preparation) In addition to the DIN ISO 12219 series, the following par

16、ts of DIN EN ISO/DIN ISO 16000 have been published dealing with the determination of VOCs: DIN ISO 12219-4:2013-12 3 DIN ISO 16000-3, Indoor air Part 3: Determination of formaldehyde and other carbonyl compounds in indoor air and test chamber air Active sampling method DIN ISO 16000-4, Indoor air Pa

17、rt 4: Determination of formaldehyde Diffusive sampling method DIN EN ISO 16000-5, Indoor air Part 5: Sampling strategy for volatile organic compounds (VOCs) DIN ISO 16000-6, Indoor air Part 6: Determination of volatile organic compounds in indoor and test chamber air by active sampling on Tenax TA s

18、orbent, thermal desorption and gas chromatography using MS/FID DIN EN ISO 16000-9, Indoor air Part 9: Determination of the emission of volatile organic compounds from building products and furnishing Emission test chamber method DIN EN ISO 16000-10, Indoor air Part 10: Determination of the emission

19、of volatile organic compounds from building products and furnishing Emission test cell method DIN EN ISO 16000-11, Indoor air Part 11: Determination of the emission of volatile organic compounds from building products and furnishing Sampling, storage of samples and preparation of test specimens DIN

20、ISO 16000-24, Indoor air Part 24: Performance test for evaluating the reduction of volatile organic compounds and carbonyl compounds without formaldehyde concentrations by sorptive building materials DIN ISO 16000-25, Indoor air Part 25: Determination of the emission of semi-volatile organic compoun

21、ds by building products Micro-chamber method Further, reference is made to the following standards covering VOC measurement methods: DIN EN ISO 16017-1, Indoor, ambient and workplace air Sampling and analysis of volatile organic compounds by sorbent tube/thermal desorption/capillary gas chromatograp

22、hy Part 1: Pumped sampling and DIN EN ISO 16017-2, Indoor, ambient and workplace air Sampling and analysis of volatile organic compounds by sorbent tube/thermal desorption/capillary gas chromatography Part 2: Diffusive sampling DIN ISO 12219-4:2013-124 National Annex NA (informative) Bibliography DI

23、N 70010, System of road vehicles Vocabulary of power-driven vehicles, combinations of vehicles and towed vehicles DIN EN 14412, Indoor air quality Diffusive samplers for the determination of concentrations of gases and vapours Guide for selection, use and maintenance DIN EN ISO 9169, Air quality Def

24、inition and determination of performance characteristics of an automatic measuring system DIN EN ISO 16000-9, Indoor air Part 9: Determination of the emission of volatile organic compounds from building products and furnishing Emission test chamber method DIN EN ISO 16000-11, Indoor air Part 11: Det

25、ermination of the emission of volatile organic compounds from building products and furnishing Sampling, storage of samples and preparation of test specimens DIN EN ISO 16017-1, Indoor, ambient and workplace air Sampling and analysis of volatile organic compounds by sorbent tube/thermal desorption/c

26、apillary gas chromatography Part 1: Pumped sampling DIN EN ISO 16017-2, Indoor, ambient and workplace air Sampling and analysis of volatile organic compounds by sorbent tube/thermal desorption/capillary gas chromatography Part 2: Diffusive sampling DIN EN ISO/IEC 17025, General requirements for the

27、competence of testing and calibration laboratories DIN ISO 12884, Ambient air Determination of total (gas and particle phase) polycyclic aromatic hydrocarbons Collection on sorbent-backed filters with gas chromatographic/mass spectrometric analysis DIN ISO 16000-3, Indoor air Part 3: Determination o

28、f formaldehyde and other carbonyl compounds in indoor air and test chamber air Active sampling method DIN ISO 16000-6, Indoor air Part 6: Determination of volatile organic compounds in indoor and test chamber air by active sampling on Tenax TAsorbent, thermal desorption and gas chromatography using

29、MS/FID DIN ISO 16362, Ambient air Determination of particle-phase polycyclic aromatic hydrocarbons by high performance liquid chromatography DIN V ENV 13005, Guide to the expression of uncertainty in measurement VDA 276, Determination of organic substances as emitted from automotive interior product

30、s using a 1 m3test cabinet VDA 277, Non-metal automotive interior materials Determination of the emission of organic compounds VDA 278, Thermal desorption analysis of organic emissions for the characterization of non-metallic materials for automobiles VDI 2464 Part 1, Ambient air measurement Indoor

31、air measurement Measurement of polychlorinated biphenyls (PCBs) GC/MS method for PCB 28, 52, 101,138, 153, 180 VDI 2464 Part 2, Ambient air measurement Indoor air measurement Measurement of polychlorinated biphenyls (PCBs); HR-GC/HR-MS method for coplanar PCBs DIN ISO 12219-4:2013-12 5 VDI 2464 Part

32、 3, Ambient air measurement Indoor air measurement Measurement of polybrominated diphenylether, hexabromocyclododecane and hexabromobenzene VDI 3484 Part 1, Gaseous ambient air measurements Indoor-air pollution measurements Test gases measurements Measurement of the formaldehyde concentration with t

33、he sulfite pararosaniline method VDI 3484 Part 2, Gaseous ambient air measurements Indoor-air pollution measurements Measurement of the formaldehyde concentration with the acetylacetone method VDI 3498 Part 1, Ambient air measurement Indoor air measurement Measurement of polychlorinated dibenzo-p-di

34、oxins and dibenzofurans Method using large filters VDI 3498 Part 2, Ambient air measurement Indoor air measurement Measurement of polychlorinated dibenzo-p-dioxins and dibenzofurans Method using small filters VDI 4252 Part 2, Measurement of airborne microorganisms and viruses in ambient air Active s

35、ampling of bioaerosols Separation of airborne mould on gelatine/polycarbonate filters VDI 4253 Part 2, Measurement of airborne microorganisms and viruses in ambient air Culture based method for the determination of the concentration of mould in air Indirect method after sampling with gelatine/polyca

36、rbonate filters VDI 4300 Part 1, Indoor-air pollution measurement General aspects of measurement strategy VDI 4300 Part 2, Indoor-air pollution measurement Measurement strategy for polycyclic aromatic hydrocarbons (PAHs), polychlorinated dibenzo-p-dioxins (PCDDs), polychlorinated dibenzofurans (PCDF

37、s) and polychlorinated biphenyls (PCBs) VDI 4300 Part 4, Indoor air pollution measurement Measurement strategy for pentachlorophenol (PCP) and -hexachlorocyclohexane (lindane) in indoor air VDI 4300 Part 5, Indoor air pollution measurement Measurement strategy for nitrogen dioxide (NO2) VDI 4300 Par

38、t 6, Measurement of indoor air pollution Measurement strategy for volatile organic compounds (VOCs) VDI 4300 Part 7, Indoor-air pollution measurement Measurement of indoor air change rate VDI 4300 Part 8, Measurement of indoor air pollution Sampling of house dust VDI 4300 Part 9, Measurement of indo

39、or air pollution Measurement strategy for carbon dioxide (CO2) VDI 4300 Part 10, Measurement of indoor air pollution Measurement strategies for determination of mould fungi in indoor environment VDI 4301 Part 1, Indoor air pollution measurement Determination of the concentration of nitrogen dioxide

40、Manual photometric method (Saltzman) VDI 4301 Part 2, Indoor air pollution measurement Measurement of pentachlorophenol (PCP) and -hexachlorocyclohexane (lindane) GC/MS-method VDI 4301 Part 3, Measurement of indoor air pollution Measurement of pentachlorophenol (PCP) and -hexachlorocyclohexane (lind

41、ane) GC/ECD method VDI 4301 Part 4, Measurement of indoor air pollution Measurement of pyrethroids and piperonyl butoxide in air, house dust and solvent wipe samples VDI 4301 Part 5, Measurement of indoor air pollution Measurement of flame retardants and plasticizers based on phosphor organic compou

42、nds Phosphoric acid ester VDI 4301 Part 6, Measurement of indoor air pollution Measurement of phthalates with GC/MS DIN ISO 12219-4:2013-126 The following VDI Guidelines are under preparation: VDI 4300 Part 11, Measurement of indoor air pollution Measurement strategies for determination of airborne

43、particles in indoor environment PM2,5fraction VDI 4301 Part 7, Measurement of indoor air pollution Measurement of carboxylic acids DIN ISO 12219-4:2013-12 7 This page is intentionally blank DIN ISO 12219-4:2013-128 IntroductionVolatile organic compounds (VOCs) are widely used in industry and can be

44、emitted by many everyday products and materials. They have attracted attention in recent years because of their impact on indoor air quality. After homes and workplaces, people spend a lot of time in their vehicles. It is important to determine the material emissions of interior parts and to reduce

45、them to an acceptable level, if required. Therefore, it is necessary to obtain comprehensive and reliable information about the types of organic compounds in the interior air of vehicles and also their concentrations.Monitoring emissions from vehicle trim components can be performed in several ways

46、and the approach selected depends upon the desired outcome and the material type. For example, to obtain emissions data from complete assemblies (e.g. a dashboard or seat) it is necessary to employ emissions chambers or bags that have sufficient volume to house the complete assembly (typically 4 m3)

47、. Such tests may take several hours or even days to perform, depending on specified equilibration times and the requirements of the relevant test protocol.This part of ISO 12219 outlines a method of measuring the types and levels of VOCs in vehicle trim components under controlled conditions using a small emission test chamber (small chamber). It describes requirements for a small cham