DIN ISO 16000-13-2010 Indoor air - Part 13 Determination of total (gas and particle-phase) polychlorinated dioxin-like biphenyls (PCBs) and polychlorinated dibenzo-p-dioxins dibenz.pdf

1、March 2010 Translation by DIN-Sprachendienst.English price group 16No part of this translation may be reproduced without prior permission ofDIN Deutsches Institut fr Normung e. V., Berlin. Beuth Verlag GmbH, 10772 Berlin, Germany,has the exclusive right of sale for German Standards (DIN-Normen).ICS

2、13.040.20!$rc“1617964www.din.deDDIN ISO 16000-13Indoor air Part 13: Determination of total (gas and particle-phase) polychlorinateddioxin-like biphenyls (PCBs) and polychlorinateddibenzo-p-dioxins/dibenzofurans (PCDDs/PCDFs) Collection on sorbent-backed filters (ISO 16000-13:2008)English translation

3、 of DIN ISO 16000-13:2010-03Innenraumluftverunreinigungen Teil 13: Bestimmung der Summe gasfrmiger und partikelgebundener dioxin-hnlicherBiphenyle (PCB) und polychlorierter Dibenzo-p-dioxine/Dibenzofurane (PCDD/PCDF) Probenahme auf Filtern mit nachgeschalteten Sorbenzien (ISO 16000-13:2008)Englische

4、 bersetzung von DIN ISO 16000-13:2010-03Air intrieur Partie 13: Dosage des polychlorobiphnyles (PCB) de type dioxine et despolychlorodibenzo-p-dioxines (PCDD)/polychlorodibenzofuranes (PCDF) totaux (en phase gazeuse et en phase particulaire) Collecte sur des filtres adsorbants (ISO 16000-13:2008)Tra

5、duction anglaise de DIN ISO 16000-13:2010-03www.beuth.deDocument comprises pagesIn case of doubt, the German-language original shall be considered authoritative.38This standard has been included in the VDI/DIN Handbooks on air quality, volume 5. 02.10 Contents Page tion 7 1 Scope. 8 2 Normative refe

6、rences 8 3 Terms and definitions . 9 4 Abbreviated terms .10 5 Principle11 6 Apparatus and materials.11 7 Preparation of sampling media16 8 Sampling. 17 9 Minimum requirements for sampling 19 Annex A (informative) Details of samplers. 20 Annex B (normative) Determination of sampling efficiency or dy

7、namic retention efficiency 31 Annex C (informative) Structure, toxicity and calculation of toxicity equivalents. 32 Bibliography 37 DIN ISO 16000-13:2010-03 2National foreword .IntroducNational Annex NA (informative) Bibliograph . 53.A comma is used as the decimal marker. yDIN ISO 16000-13:2010-03 N

8、ational foreword International technical regulation pertaining to indoor air This standard has been prepared by Technical Committee ISO/TC 146 “Air quality”, Subcommittee SC 6 “Indoor air” (Secretariat: DIN, Germany). The responsible German body involved in its preparation was the Kommission Reinhal

9、tung der Luft (KRdL) im VDI und DIN Normenausschuss (Commission on Air Pollution Prevention of VDI and DIN Standards Committee), Section 4 Umweltmesstechnik. The method specified in this standard is based on Guideline VDI 3498 Part 1 and Part 2 and CEN/TS 1948-4. General and substance-specific aspec

10、ts which should be taken into account before and during sampling, as well as methods for determining individual substances or groups of substances and microorganisms in indoor air are described in the various parts of ISO 16000. The DIN Standards corresponding to the International Standards referred

11、 to in clause 2 of this standard are as follows: ISO 12884 DIN ISO 12884 ISO 16000-12 DIN EN ISO 16000-12 ISO 16000-14 DIN ISO 16000-14 National technical regulation pertaining to indoor air General conditions and other aspects to be taken into consideration when planning indoor air measurements are

12、 described for individual substances and substance groups in the VDI 4300 series (see also “National Annex NA”). Many of these served as the sole basis for parts of the ISO 16000 series (e.g. ISO 16000-1, ISO 16000-2, ISO 16000-5, ISO 16000-7, ISO 16000-12, ISO 16000-15, ISO 16000-16, ISO 16000-17 a

13、nd ISO 16000-18). The specific procedures (sampling, analysis) are described in the VDI 4301 series for individual substances and substance groups. Methods which can be used for both indoor and ambient air measurements are described in further VDI guidelines. DIN ISO 16000 series and DIN EN ISO 1600

14、0 series consist of the following parts, under the general title Indoor air: Part 1: General aspects of sampling strategy Part 2: Sampling strategy for formaldehyde Part 3: Determination of formaldehyde and other carbonyl compounds Active sampling method Part 4: Determination of formaldehyde Diffusi

15、ve sampling method Part 5: Sampling strategy for volatile organic compounds (VOCs) Part 6: Determination of volatile organic compounds in indoor and test chamber air by active sampling on Tenax TAsorbent, thermal desorption and gas chromatography using MS/FID Part 7: Sampling strategy for determinat

16、ion of airborne asbestos fibre concentrations Part 8: Determination of local mean ages of air in buildings for characterizing ventilation conditions 3 DIN ISO 16000-13:2010-03 Part 9: Determination of the emission of volatile organic compounds from building products and furnishing Emission test cham

17、ber method Part 10: Determination of the emission of volatile organic compounds from building products and furnishing Emission test cell method Part 11: Determination of the emission of volatile organic compounds from building products and furnishing Sampling, storage of samples and preparation of t

18、est specimens Part 12: Sampling strategy for polychlorinated biphenyls (PCBs), polychlorinated dibenzo-p-dioxins (PCDDs), polychlorinated dibenzofurans (PCDFs) and polycyclic aromatic hydrocarbons (PAHs) Part 13: Determination of total (gas and particle-phase) polychlorinated dioxin-like biphenyls (

19、PCBs) and polychlorinated dibenzo-p-dioxins/dibenzofurans (PCDDs/PCDFs) Collection on sorbent-backed filters Part 14: Determination of total (gas and particle-phase) polychlorinated dioxin-like biphenyls (PCBs) and polychlorinated dibenzo-p-dioxins/dibenzofurans (PCDDs/PCDFs) Extraction, clean-up an

20、d analysis by high-resolution gas chromatography/mass spectrometry Part 15: Sampling strategy for nitrogen dioxide (NO2) Part 16: Detection and enumeration of moulds Sampling by filtration Part 17: Detection and enumeration of moulds Culture-based method Part 18: Detection and enumeration of moulds

21、Sampling by impaction Part 23: Performance test for evaluating the reduction of formaldehyde concentrations by sorptive building materials Part 24: Performance test for evaluating the reduction of volatile organic compounds and carbonyl compounds without formaldehyde concentrations by sorptive build

22、ing materials Part 25: Determination of the emission of semi-volatile organic compounds by building products Micro-chamber method The following parts are under preparation: Part 19: Sampling strategy for moulds Part 26: Measurement strategy for carbon dioxide CO2 Part 27: Standard method for the qua

23、ntitative analysis of asbestos fibres in settled dust Part 28: Sensory evaluation of emissions from building materials and products The following parts are planned: Part 20: Detection and enumeration of moulds Sampling from house dust Part 21: Detection and enumeration of moulds Sampling from materi

24、als Part 22: Detection and enumeration of moulds Molecular methods 4 DIN ISO 16000-13:2010-03 National Annex NA (informative) Bibliography DIN CEN/TS 1948-4, Stationary source emissions Determination of the mass concentration of PCDDs/PCDFs and dioxin-like PCBs Part 4: Sampling and analysis of dioxi

25、n-like PCBs DIN EN ISO 9169, Air quality Definition and determination of performance characteristics of an automatic measuring system 1 DIN ISO 12219-1, Indoor air Road vehicles Part 1: Whole vehicle test chamber Specification and method for the determination of volatile organic compounds in car int

26、eriors (under preparation) 2 DIN ISO 12884, Ambient air Determination of total (gas and particle phase) polycyclic aromatic hydrocarbons Collection on sorbent-backed filters with gas chromatographic/mass spectrometric analysis DIN V ENV 13005, Guide to the expression of uncertainty in measurement DI

27、N EN 14412, Indoor air quality Diffusive samplers for the determination of concentrations of gases and vapours Guide for selection, use and maintenance DIN EN ISO 16017-1, Indoor, ambiant and workplace air Sampling and analysis of volatile organic compounds by sorbent tube/thermal desorption/capilla

28、ry gas chromatography Part 1: Pumped sampling 3 DIN EN ISO 16017-2, Indoor, ambient and workplace air Sampling and analysis of volatile organic compounds by sorbent tube/thermal desorption/capillary gas chromatography Part 2: Diffusive sampling 4 DIN ISO 16362, Ambient air Determination of particle-

29、phase polycyclic aromatic hydrocarbons by high performance liquid chromatography DIN EN ISO/IEC 17025, General requirements for the competence of testing and calibration laboratories VDI 2464 Part 1, Ambient air measurement Indoor air measurement Measurement of polychlorinated biphynyls (PCBs) GC/MS

30、 method for PCB 28, 52, 101, 138, 153, 180 VDI 2464 Part 2, Ambient air measurement Indoor air measurement Measurement of polychlorinated biphenyls (PCBs) HR-GC/HR-MS method for coplanar PCBs VDI 3484 Part 1, Gaseous ambient air measurements Indoor-air pollution measurements Test gases measurements

31、Measurement of the formaldehyde concentration with the sulfite pararosaniline method VDI 3484 Part 2, Gaseous ambient air measurements Indoor-air pollution measurements Measurement of the formaldehyde concentration with the ac tylacetone method eVDI 3498 Part 1, Ambient air measurement Indoor air me

32、asurement Measurement of polychlorinated dibenzo-p-dioxins and dibenzofurans Method using large filters VDI 3498 Part 2, Ambient air measurement Indoor air measurement Measurement of polychlorinated dibenzo-p-dioxins and dibenzofurans Method using small filters VDI 4300 Part 1, Indoor-air pollution

33、measurement General aspects of measurement strategy 5 DIN ISO 16000-13:2010-03 VDI 4300 Part 2, Indoor-air pollution measurement Measurement strategy for polycyclic aromatic hydro-carbons (PAHs), polychlorinated dibenzo-p-dioxins (PCDDs), polychlorinated dibenzofurans (PCDFs) and polychlorinated bip

34、henyls (PCBs) VDI 4300 Part 4, Indoor air pollution measurement Measurement strategy for pentachlorophenol (PCP) and -hexachlorocyclohexane (lindane) in indoor air VDI 4300 Part 5, Indoor air pollution measurement Measurement strategy for nitrogen dioxide (NO2) VDI 4300 Part 7, Indoor-air pollution

35、measurement Measurement of indoor air change rate VDI 4300 Part 8, Measurement of indoor air pollution Sampling of house dust VDI 4300 Part 9, Measurement of indoor air pollution Measurement strategy for carbon dioxide (CO2) VDI 4300 Part 10, Measurement of indoor air pollution Measurement strategie

36、s for determination of mould fungi in indoor environment VDI 4301 Part 1, Indoor air pollution measurement Determination of the concentration of nitrogen dioxide Manual photometric method (Saltzman) VDI 4301 Part 2, Indoor air pollution measurement Measurement of pentaclorophenol (PCP) and -hexa-chl

37、orocyclohexane (lindane) GC/MS-method VDI 4301 Part 3, Measurement of indoor air pollution Measurement pentaclorophenol (PCP) and -hexa-chlorocyclohexane (lindane) GC/ECD method VDI 4301 Part 4, Measurement of indoor air pollution Measurement of pyrethroids and piperonyl butoxide in air, house dust

38、and solvent wipe samples VDI 4301 Part 5, Measurement of indoor air pollution Measurement of flame retardants and plasticizers based on phosphor organic compounds Phosphoric acid ester The following VDI Guidelines are under preparation: VDI 2464 Part 3, Ambient air measurement Indoor air measurement

39、 Measurement of polybrominated diphenyl ethers (flame retardants) VDI 4300 Part 11, Measurement of indoor air pollution Measurement strategies for fine dust VDI 4301 Part 6, Measurement of indoor air pollution Measurement of phthalates 6 Indoor air Part 13: Determination of total (gas and particle-p

40、hase) polychlorinated dioxin-like biphenyls (PCBs) and polychlorinated dibenzo-p-dioxins/dibenzofurans (PCDDs/PCDFs) Collection on sorbent-backed filters Introduction The different parts of ISO 16000 describe general requirements relating to the measurement of indoor air pollutants and the important

41、 conditions to be observed before or during the sampling of individual pollutants or groups of pollutants as well as the measurement procedures themselves (see Foreword). This part of ISO 16000 is applicable to the collection from indoor air of dioxin-like polychlorinated biphenyls (PCBs), polychlor

42、inated dibenzo-p-dioxins (PCDDs) and polychlorinated dibenzofurans (PCDFs) and to the preparation of sampling media required for sampling. The same sampling methods described here are also applicable to polycyclic aromatic hydrocarbons (PAHs) made up of two or more fused aromatic rings. Procedures f

43、or preparation and extraction of sampling media for PAHs and for the analytical determination of PAHs are given in ISO 12884, and therefore are not included here. The sampling strategy to analyse PCBs, PCDDs/PCDFs and PAHs in indoor air is described in ISO 16000-12. Several PCBs and PCDDs/PCDFs are

44、considered to be potential human carcinogens. There are 209 individual PCBs (congeners), 75 PCDDs and 135 PCDFs. The most toxic PCBs are those that are coplanar and structurally similar to PCDDs. The most toxic PCDD is 2,3,7,8-tetrachlorodibenzodibenzo-p-dioxin (2,3,7,8-TCDD). PCBs are emitted into

45、the indoor air primarily from concrete sealers, certain paints, or electrical capacitors, all of which have been banned in recent years. The principal sources of PCDDs/PCDFs in indoor air are impurities in wood preservatives containing pentachlorophenol (PCP) and emissions from fires involving chlor

46、inated products. Tracked-in soil and emissions from nearby landfills and abandoned industrial sites may also contribute PCBs and PCDDs/PCDFs to the indoor environment. Total PCB concentrations (six marker PCBs: PCB-28, -52, -101, -138, -153, and -180 multiplied by 5) in urban outdoor air typically r

47、ange from 10 to several hundred picograms per cubic metre (pg/m3). PCDDs/PCDFs are usually found in urban outdoor air at extremely low concentrations; e.g. femtograms per cubic metre (fg/m3) to picograms per cubic metre (pg/m3). PCBs and PCDDs/PCDFs may be distributed between the gas and particle-as

48、sociated phases in ambient or indoor air, depending on the temperature, humidity, degree of chlorination, their concentration, and their capacity to associate with suspended particulate matter. These compounds, especially those having vapour pressures above 108kPa, will tend to vaporize from particl

49、e filters during sampling. Consequently, a back-up sorbent trap is included for efficient sampling. Separate analyses of the filter and sorbent trap will not reflect the original atmospheric phase distributions at normal ambient temperatures because of volatilization of compounds from the filter and should not be attempted. Shipping of PCDD/PCDF standards has to comply with