DIN ISO 16000-6-2012 Indoor air - Part 6 Determination of volatile organic compounds in indoor and test chamber air by active sampling on Tenax TA sorbent thermal desorption and ga.pdf

1、November 2012Translation by DIN-Sprachendienst.English price group 16No part of this translation may be reproduced without prior permission ofDIN Deutsches Institut fr Normung e. V., Berlin. Beuth Verlag GmbH, 10772 Berlin, Germany,has the exclusive right of sale for German Standards (DIN-Normen).IC

2、S 13.040.20!$B*“1923107www.din.deDDIN ISO 16000-6Indoor air Part 6: Determination of volatile organic compounds in indoor and testchamber air by active sampling on Tenax TA sorbent, thermaldesorption and gas chromatography using MS or MS-FID(ISO 16000-6:2011),English translation of DIN ISO 16000-6:2

3、012-11Innenraumluftverunreinigungen Teil 6: Bestimmung von VOC in der Innenraumluft und in Prfkammern, Probenahme aufTenax TA, thermische Desorption und Gaschromatographie mit MS oder MS-FID(ISO 16000-6:2011),Englische bersetzung von DIN ISO 16000-6:2012-11Air intrieur Partie 6: Dosage des composs o

4、rganiques volatils dans lair intrieur des locaux etchambres dessai par chantillonnage actif sur le sorbant Tenax TA, dsorptionthermique et chromatographie en phase gazeuse utilisant MS ou MS-FID(ISO 16000-6:2011),Traduction anglaise de DIN ISO 16000-6:2012-11SupersedesDIN ISO 16000-6:2004-12www.beut

5、h.deIn case of doubt, the German-language original shall be considered authoritative.Document comprises 38 pages10.12This standard has been included in the VDI/DIN Handbook on air quality, Volume 5.A comma is used as the decimal marker. ContentsPage National foreword .3 National Annex NA (informativ

6、e) Bibliography .5 Introduction .9 1 Scope .10 2 Normative references .10 3 Terms and definitions 10 4 Principle . 11 5 Reagents and materials . 11 6 Apparatus 13 7 Conditioning and storage of sorbent tubes .15 7.1 Conditioning .15 7.2 Storage of conditioned sorbent tubes before sampling 15 8 Sampli

7、ng 15 8.1 Indoor air sampling 15 8.2 Test chamber air sampling 15 8.3 Sampling volumes 16 8.4 Storage of loaded samples 16 8.5 Field blanks .16 9 Analysis .16 9.1 General 16 9.2 Thermal desorption 17 9.3 Temperature programme .17 9.4 Analysis of the samples .17 10 Identification of single VOCs.17 11

8、 Concentration of analytes in the sampled air 18 11.1 General 18 11.2 Volatile organic compounds 18 11.3 Total volatile organic compounds 19 11.4 VVOC and SVOC compounds observed outside the TVOC range 19 12 Performance characteristics .20 13 Test report .21 14 Quality control 21 Annex A (informativ

9、e) Examples of compounds detected in indoor air and from building products in test chambers .22 Annex B (informative) Safe sampling volumes for selected organic vapours sampled on Tenax TA.28 Annex C (informative) Storage recovery of solvents on Tenax TAsorbent tubes .30 Annex D (informative) Determ

10、ination of very volatile and semi-volatile organic compounds in conjunction with volatile organic compounds 32 Bibliography 37 2DIN ISO 16000-6:2012-11 National foreword International technical regulation pertaining to indoor air This standard has been prepared by Technical Committee ISO/TC 146 “Air

11、 quality”, Subcommittee SC 6 “Indoor air” (Secretariat: DIN, Germany), Working Group WG 3 “Determination of volatile organic compounds (VOC) in indoor air”. The responsible German body involved in its preparation was the Kommission Reinhaltung der Luft (KRdL) im VDI und DIN Normenausschuss (Commissi

12、on on Air Pollution Prevention of VDI and DIN Standards Committee), NA 134-04-04-01-06 AK Spiegelgremium zu ISO/TC 146/SC 6/WG3, WG 11 und WG 12 Messen von VOC of Section IV Umweltmesstechnik of Section IV Umweltmesstechnik. In this standard, the unit “inch” is used. It should, however, be noted tha

13、t the Gesetz ber Einheiten im Messwesen (German Law on units in metrology) prohibits the use of the unit “inch” for official and commercial purposes in Germany. The indication of this unit solely serves to facilitate the communication with those countries where this units is used (import-export busi

14、ness). General and substance-specific aspects which should be taken into account before and during sampling, as well as methods for determining individual substances or groups of substances and microorganisms in indoor air are described in the various parts of ISO 16000. The DIN Standards correspond

15、ing to the International Standards referred to in this document are as follows: ISO 16000-1 DIN EN ISO 16000-1 ISO 16017-1 DIN EN ISO 16017-1 Attention is drawn to the possibility that some of the elements of this document may be the subject of patent rights. DIN shall not be held responsible for id

16、entifying any or all such patent rights. National technical regulation pertaining to indoor air General conditions and other aspects to be taken into consideration when planning indoor air measurements are described for individual substances and substance groups in the VDI 4300 series (see also “Nat

17、ional Annex NA”). Many of these served as the sole basis for parts of the ISO 16000 series (e.g. ISO 16000-1, ISO 16000-2, ISO 16000-5, ISO 16000-7, ISO 16000-12, ISO 16000-15, ISO 16000-16, ISO 16000-17 and ISO 16000-18). The specific procedures (sampling, analysis) are described in the VDI 4301 se

18、ries for individual substances and substance groups. Methods which can be used for both indoor and ambient air measurements are described in further VDI guidelines. DIN ISO 16000 series and DIN EN ISO 16000 series consist of the following parts, under the general title Indoor air: DIN EN ISO 16000-1

19、, General aspects of sampling strategy DIN EN ISO 16000-2, Sampling strategy for formaldehyde DIN ISO 16000-3, Determination of formaldehyde and other carbonyl compounds Active sampling method DIN ISO 16000-4, Determination of formaldehyde Diffusive sampling method DIN EN ISO 16000-5, Sampling strat

20、egy for volatile organic compounds (VOCs) DIN ISO 16000-6, Determination of volatile organic compounds in indoor and test chamber air by active sampling on Tenax TAsorbent, thermal desorption and gas chromatography using MS/FID 3DIN ISO 16000-6:2012-11 DIN EN ISO 16000-7, Sampling strategy for deter

21、mination of airborne asbestos fibre concentrations DIN ISO 16000-8, Determination of local mean ages of air in buildings for characterizing ventilation conditions DIN EN ISO 16000-9, Determination of the emission of volatile organic compounds from building products and furnishing Emission test chamb

22、er method DIN EN ISO 16000-10, Determination of the emission of volatile organic compounds from building products and furnishing Emission test cell method DIN EN ISO 16000-11, Determination of the emission of volatile organic compounds from building products and furnishing Sampling, storage of sampl

23、es and preparation of test specimens DIN EN ISO 16000-12, Sampling strategy for polychlorinated biphenyls (PCBs), polychlorinated dibenzo-p-dioxins (PCDDs), polychlorinated dibenzofurans (PCDFs) and polycyclic aromatic hydrocarbons (PAHs) DIN ISO 16000-13, Determination of total (gas and particle-ph

24、ase) polychlorinated dioxin-like biphenyls (PCBs) and polychlorinated dibenzo-p-dioxins/dibenzofurans (PCDDs/PCDFs) Collection on sorbent-backed filters DIN ISO 16000-14, Determination of total (gas and particle-phase) polychlorinated dioxin-like biphenyls (PCBs) and polychlorinated dibenzo-p-dioxin

25、s/dibenzofurans (PCDDs/PCDFs) Extraction, clean-up and analysis by high-resolution gas chromatography and mass spectrometry DIN EN ISO 16000-15, Sampling strategy for nitrogen dioxide (NO2) DIN ISO 16000-16, Detection and enumeration of moulds Sampling by filtration DIN ISO 16000-17, Detection and e

26、numeration of moulds Culture-based method DIN ISO 16000-18, Detection and enumeration of moulds Sampling by impaction DIN ISO 16000-19, Sampling strategy for moulds DIN ISO 16000-21, Detection and enumeration of moulds Sampling from materials DIN ISO 16000-23, Performance test for evaluating the red

27、uction of formaldehyde concentrations by sorptive building materials DIN ISO 16000-24, Performance test for evaluating the reduction of volatile organic compounds and carbonyl compounds without formaldehyde concentrations by sorptive building materials DIN ISO 16000-25, Determination of the emission

28、 of semi-volatile organic compounds by building products Micro-chamber method DIN ISO 16000-26, Measurement strategy for carbon dioxide (CO2) DIN ISO 16000-28, Sensory evaluation of emissions from building materials and products DIN ISO 16000-29, Test methods for VOC detectors DIN ISO 16000-30, Sens

29、ory testing of indoor air DIN ISO 16000-31, Measurement of flame retardants and plasticizers based on organophosphorus com-pounds Phosphoric acid ester DIN ISO 16000-32, Investigation of constructions on pollutants and other injurious factors Inspections 4DIN ISO 16000-6:2012-11 The following parts

30、are under preparation: DIN ISO 16000-20, Detection and enumeration of moulds Sampling from house dust DIN ISO 16000-27, Standard method for the quantitative analysis of asbestos fibres in settled dust The following part is planned: DIN ISO 16000-22, Detection and enumeration of moulds Molecular meth

31、ods Amendments This standard differs from DIN ISO 16000-6:2004-12 as follows: a) Annex D “Determination of very volatile and semi-volatile organic compounds in conjunction with volatile organic compounds” has been added and some minor modifications have been made. Previous editions DIN ISO 16000-6:

32、2004-12 National Annex NA (informative) Bibliography DIN EN ISO 5492, Sensory analysis Vocabulary DIN EN ISO 8589, Sensory analysis General guidance for the design of test rooms DIN 50014, Climates and their technical application Standard atmospheres DIN EN ISO 8199, Water quality General guidance o

33、n the enumeration of micro-organisms by culture DIN EN ISO 9169, Air quality Definition and determination of performance characteristics of an automatic measuring system DIN ISO 12219-1, Indoor air of road vehicles Part 1: Whole vehicle test chamber Specification and method for the determination of

34、volatile organic compounds in cabin interiors DIN ISO 12219-2, Indoor air of road vehicles Part 2: Screening method for the determination of the emissions of volatile organic compounds from vehicle interior parts and materials Bag method DIN ISO 12219-3, Indoor air of road vehicles Part 3: Screening

35、 method for the determination of the emissions of volatile organic compounds from vehicle interior parts and materials Micro-chamber method DIN ISO 12219-4, Interior air of road vehicles Part 4: Screening method for the determination of the emissions of volatile organic compounds from vehicle interi

36、or parts and materials Small chamber method 5DIN ISO 16000-6:2012-11 DIN ISO 12219-5, Interior air of road vehicles Part 5: Screening method for the determination of the emissions of volatile organic compounds from vehicle interior parts and materials Static chamber method DIN ISO 12884, Ambient air

37、 Determination of total (gas and particle phase) polycyclic aromatic hydro-carbons Collection on sorbent-backed filters with gas chromatographic/mass spectrometric analysis DIN V EN V 13005, Guide to the expression of uncertainty in measurement DIN EN 14412, Indoor air quality Diffusive samplers for

38、 the determination of concentrations of gases and vapours Guide for selection, use and maintenance DIN EN ISO 16017-1, Indoor, ambiant and workplace air Sampling and analysis of volatile organic compounds by sorbent tube/thermal desorption/capillary gas chromatography Part 1: Pumped sampling DIN EN

39、ISO 16017-2, Indoor, ambient and workplace air Sampling and analysis of volatile organic compounds by sorbent tube/thermal desorption/capillary gas chromatography Part 2: Diffusive sampling DIN ISO 16362, Ambient air Determination of particle-phase polycyclic aromatic hydrocarbons by high performanc

40、e liquid chromatography DIN EN ISO/IEC 17025, General requirements for the competence of testing and calibration laboratories VDI 2464 Part 1, Ambient air measurement Indoor air measurement Measurement of polychlorinated biphynyls (PCBs) GC/MS method for PCB 28, 52, 101,138, 153, 180 VDI 2464 Part 2

41、, Ambient air measurement Indoor air measurement Measurement of polychlorinated biphenyls (PCBs) HR-GC/HR-MS method for coplanar PCBs VDI 2464 Part 3, Ambient air measurement Indoor air measurement Measurement of polybrominated diphenylether, hexabromocyclododecane and hexabromobenzene by GC/MS VDI

42、3484 Part 1, Gaseous ambient air measurements Indoor-air pollution measurements Test gases measurements Measurement of the formaldehyde concentration with the sulfite pararosaniline method VDI 3484 Part 2, Gaseous ambient air measurements Indoor-air pollution measurements Measurement of the formalde

43、hyde concentration with the acatylacetone method VDI 3498 Part 1, Ambient air measurement Indoor air measurement Measurement of polychlorinated dibenzo-p-dioxins and dibenzofurans Method using large filters VDI 3498 Part 2, Ambient air measurement Indoor air measurement Measurement of polychlorinate

44、d dibenzo-p-dioxins and dibenzofurans Method using small filters VDI 4252 Part 2, Measurement of airborne microorganisms and viruses in ambient air Active sampling of bioaerosols Separation of airborne mould on gelatine/polycarbonate filters VDI 4253 Part 2 Measurement of airborne microorganisms and

45、 viruses in ambient air Culture based method for the determination of the concentration of mould in air Indirect method after sampling with gelatine/polycarbonate filters VDI 4300 Part 1, Indoor-air pollution measurement General aspects of measurement strategy VDI 4300 Part 2, Indoor-air pollution m

46、easurement Measurement strategy for polycyclic aromatic hydro-carbons (PAHs), polychlorinated dibenzo-p-dioxins (PCDDs), polychlorinated dibenzofurans (PCDFs) and polychlorinated bibhenyle (PCBs) VDI 4300 Part 4, Indoor air pollution measurement Measurement strategy for pentachlorophenol (PCP) and -

47、hexachlorocyclohexane (lindane) in indoor air 6DIN ISO 16000-6:2012-11 VDI 4300 Part 5, Indoor air pollution measurement Measurement strategy for nitrogen dioxide (NO2) VDI 4300 Part 6, Measurement of indoor air pollution Measurement strategy for volatile organic compounds (VOCs) VDI 4300 Part 7, In

48、door-air pollution measurement Measurement of indoor air change rate VDI 4300 Part 8, Measurement of indoor air pollution Sampling of house dust VDI 4300 Part 9, Measurement of indoor air pollution Measurement strategy for carbon dioxide (CO2) VDI 4300 Part 10, Measurement of indoor air pollution Me

49、asurement strategies for determination of mould fungi in indoor environment VDI 4300 Part 11, Measurement of indoor air pollution Measurement strategies for determination of airborne particles in indoor environment Particles with equivalent diameter 2,5 m VDI 4301 Part 1, Indoor air pollution measurement Determination of the concentration of nitroge