DLA BB-H-886 E-2011 HYDROGEN.pdf

1、 Beneficial comments, recommendations, additions, deletions, clarifications, etc. and any data that may improve this document should be sent to: STDZNMGTdla.mil or Defense Logistics Agency Aviation VEB, 8000 Jefferson Davis Highway, Richmond, VA 23297-5616. Since contact information can change, you

2、may want to verify the currency of this address information using the ASSIST database at https:/assist.daps.dla.mil/. AMSC N/A FSC 6830 INCH-POUND BB-H-886E 24 February 2011 SUPERSEDING BB-H-886D 11 January 2001 FEDERAL SPECIFICATION HYDROGEN The General Services Administration has authorized the us

3、e of this federal specification by all federal agencies. 1. SCOPE AND CLASSIFICATION 1.1 Scope. This specification covers three grades of gaseous hydrogen for use in cutting and welding, and as a lifting medium for meteorological and other balloons; for fuel, hydrogenation, and water chemistry appli

4、cations; and for semiconductor, analytical and special applications (see 6.1). 1.2 Classification. The hydrogen shall be of the following grades, as specified (see 6.2). Grade A - 99.95 percent hydrogen Grade B - 99.99 percent hydrogen Grade C - 99.999 percent hydrogen 2. APPLICABLE DOCUMENTS 2.1 Go

5、vernment publications. The issues of the following documents, in effect on the date of invitation for bids or request for proposal, form a part of this specification to the extent specified herein. Federal Standard FED-STD-313 - Material Safety Data, Transportation Data and Disposal Data for Hazardo

6、us Materials Furnished to Government Activities Provided by IHSNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-BB-H-886E 2 Commercial Item Description A-A-59860 - Valves, Cylinder, Gas (for Compressed or Liquefied Gases) (Activities outside the federal government m

7、ay obtain copies of federal standards and commercial item descriptions as specified in the General Information section of the Index of Federal Specifications, Standards and Commercial Item Descriptions. The index is for sale on a subscription basis from the General Services Administration, Federal S

8、upply Service, Specification Section, East 470 LEnfant Plaza SW, Suite 8100, Washington, DC 20407.) (Single copies of this specification, and other federal specifications, standards, and commercial item descriptions required by activities outside the federal government for bidding purposes are avail

9、able without charge from the General Services Administration, Federal Supply Service, Specification Section, East 470 LEnfant Plaza SW, Suite 8100, Washington, DC 20407.) (Federal government activities may obtain copies of federal standardization documents and the Index of Federal Specifications, St

10、andards and Commercial Item Descriptions from established distribution points in their agencies. Electronic copies may be obtained from https:/assist.daps.dla.mil/.) Military Standards MIL-STD-101 - Color Code for Pipelines and for Compressed Gas Cylinders MIL-STD-1411 - Inspection and Maintenance o

11、f Compressed Gas Cylinders (Copies of military standards required by contractors in connection with specific procurement functions are available from the Standardization Document Order Desk, Building 4D, 700 Robbins Avenue, Philadelphia, PA 19111-5094. Electronic copies may be obtained from https:/a

12、ssist.daps.dla.mil/.) Federal Regulations 29 CFR 1910.1200 - Hazard Communication 49 CFR 171-185 - Hazardous Materials Regulations (The Code of Federal Regulations (CFR) is for sale on a subscription basis from the Superintendent of Documents, P.O. Box 371954, Pittsburgh, PA 15250-7954. When indicat

13、ed, reprints of certain regulations may be obtained from the federal agency responsible for issuing them. Electronic copies may be obtained from http:/www.gpoaccess.gov/ecfr/.) Provided by IHSNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-BB-H-886E 3 2.2 Other pub

14、lications. The following documents form a part of this specification to the extent specified herein. Unless a specific issue is identified, the issue in effect on the date of invitation for bids or request for proposal shall apply. Compressed Gas Association (CGA) CGA C-1 - Methods for Pressure Test

15、ing Compressed Gas Cylinders CGA C-5 - Wall Stress Requalification Criteria for High Pressure Seamless Steel Cylinders CGA C-6 - Standards for Visual Inspection of Steel Compressed Gas Cylinders CGA C-11 - Recommended Practices for Inspection of Compressed Gas Cylinders at Time of Manufacture CGA G-

16、5 - Hydrogen CGA G-5.3 - Commodity Specification for Hydrogen CGA P-15 - Filling of Industrial and Medical Nonflammable Compressed Gas Cylinders CGA S-1.1 - Pressure Relief Device Standards Part 1 - Cylinders for Compressed Gases CGA TB-17 - Test Methods for Evaluating Paints and Coatings on Refilla

17、ble Steel Compressed Gas Cylinders CGA V-9 - Compressed Gas Association Standard for Compressed Gas Cylinder Valves (Application for copies should be addressed to the Compressed Gas Association, 4221 Walney Road, 5th Floor, Chantilly, VA 20151-2923. Electronic copies may be obtained from http:/ 3. R

18、EQUIREMENTS 3.1 Material. The material shall conform to the requirements of type I (gaseous) hydrogen as specified in CGA G-5.3 and shown in table I. TABLE I. Requirements.1Limiting characteristics Grade A ppm (v/v)2Grade B ppm (v/v) Grade C ppm (v/v) CGA G-5.3 Quality Verification Level QVL B3QVL D

19、 QVL L Hydrogen, minimum (percent by volume) 99.95 99.99 99.999 Water vapor 34 3.5 3.5 Total hydrocarbon content (as methane) 10 5 1 1Additional information on the properties and handling of hydrogen may be found in CGA G-5. 2Quantities are in parts per million by volume (ppm (v/v) unless otherwise

20、noted. 3QVL B for type I (gaseous) hydrogen. Provided by IHSNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-BB-H-886E 4 3.2 Cylinders and valves. The hydrogen shall be contained in government-furnished cylinders in accordance with 49 CFR 171-185, and equipped with

21、valves in accordance with A-A-59860 (see 6.2). When specified (see 6.2), cylinders shall be furnished by the supplier, which shall be in accordance with 49 CFR 171-185, and shall be equipped with valves in accordance with A-A-59860. When specified (see 6.2), the hydrogen shall be contained in suppli

22、er-owned, Department of Transportation-approved cylinders, equipped with valves in accordance with CGA V-9 and pressure relief devices in accordance with CGA S-1.1. 3.2.1 Painting. Government-owned and furnished cylinders shall be color-coded and stenciled in accordance with MIL-STD-101. The paint a

23、nd the painting process shall be by any method or system that will provide a finish that meets the requirements of CGA TB-17. 3.3 Hydrogen cylinder and valve maintenance. a. Government-owned and furnished hydrogen cylinders shall be inspected, maintained, and when necessary, reconditioned in accorda

24、nce with MIL-STD-1411 to meet all serviceability requirements of 49 CFR 171-185. Supplier-owned hydrogen cylinders shall be inspected, maintained, and when necessary, reconditioned in accordance with CGA C-1, CGA C-5, CGA C-6, CGA C-11, and CGA S-1.1, to meet all serviceability requirements of 49 CF

25、R 171-185. b. Hydrogen valves requiring maintenance shall be repaired as applicable, and be cleaned free of insects, webs, dirt, paint, corrosion, oil, and grease. 3.4 Leakage. Cylinders and valves shall not leak after being filled (see 4.3.6). 3.5 Capacity. Unless otherwise specified (see 6.2), con

26、tainers of gaseous hydrogen shall be filled to their rated service pressure in accordance with CGA P-15. 3.6 Workmanship. Cylinders shall show no evidence of bulging or distortion. 3.7 Material safety data sheet (MSDS). Manufacturers shall prepare and submit a MSDS in accordance with FED-STD-313 and

27、 meeting the requirements of 29 CFR 1910.1200. 4. QUALITY ASSURANCE PROVISIONS 4.1 Responsibility for inspection. Unless otherwise specified in the contract or purchase order, the contractor is responsible for the performance of all inspection requirements (examinations and tests) as specified herei

28、n. Except as otherwise specified in the contract or purchase order, the contractor may use his own or any other facilities suitable for the performance of the inspection requirements specified herein, unless disapproved by the government. The government reserves the right to perform any of the inspe

29、ctions set forth in the specification where such inspections are deemed necessary to assure that supplies and services conform to the prescribed requirements. Provided by IHSNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-BB-H-886E 5 4.2 Quality conformance inspect

30、ion. 4.2.1 Tests and examinations. Perform the content and capacity tests, and examinations of table II. Any defects in the content or capacity tests shall be cause for rejection of the lot. A lot for testing the content and capacity shall be defined as the number of containers filled from the same

31、source during an uninterrupted filling sequence and offered for examination at one time. Any defects found in the examinations of the containers shall be cause for the rejection of only those defective containers. TABLE II. Tests and examinations of preparation for delivery. Test/Examinations Defect

32、 Inspection level Content Not as specified in 3.1 One sample per lot, as per 4.2.1 Container Not as specified in 3.2 100% Paint Not as specified in 3.2.1 100% Maintenance Not as specified in 3.3 100% Leakage Not as specified in 3.4 100% Capacity Not as specified in 3.5 One sample per lot, as per 4.2

33、.1 Workmanship Not as specified in 3.6 100% Marking on container Not as specified in 5.1 100% Packaging and packing Not as specified in 5.2 100% 4.3 Test methods. 4.3.1 Sampling. Samples for testing the content and capacity in table II shall be from filled containers and shall be one sample unit per

34、 lot. 4.3.2 Hydrogen content determination. Hydrogen content shall be determined in accordance with the analytical procedures specified by CGA G-5.3. The minimum hydrogen content shall be 99.95 percent for grade A, 99.99 percent for grade B, and 99.999 percent for grade C. Otherwise, compliance with

35、 the minimum requirements has not been met and shall constitute failure of this test. 4.3.3 Impurities determination. The sample shall be analyzed for the impurities listed as limiting characteristics in CGA G-5.3 using the analytical procedures specified therein. Unless otherwise specified in the c

36、ontract or purchase order (see 6.2), these impurities shall not exceed the maximum quantity specified for the appropriate QVL. 4.3.4 Documentation. Records of the analysis and the qualifying concentrations used must be kept on file for two years, and available upon the governments request. 4.3.5 Lea

37、kage. Each cylinder, after filling, shall be tested for leakage by applying a soap solution to all portions of the valve, the junction of the valve and cylinder, and the safety device on the cylinder. Care shall be taken to ensure that the solution used does not contaminate the valve outlet. Any evi

38、dence of gas leakage, as evidenced by bubbling of the soap solution, shall constitute failure of this test. Failure of this test shall be cause for rejection of the cylinder. Provided by IHSNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-BB-H-886E 6 5. PACKAGING 5.

39、1 Marking. The cylinders shall be marked in accordance with 49 CFR 171-185, and as specified in the contract or order (see 6.2). The markings shall not be omitted, incorrect, illegible, or of improper size, location, sequence, or method of application. 5.2 Packaging and packing. The hydrogen of a si

40、ngle grade shall be packaged and packed together in accordance with the contract or order (see 6.2). 6. NOTES INFORMATION FOR GUIDANCE ONLY. (This section contains information of a general or explanatory nature that is helpful, but is not mandatory.) 6.1 Intended use. Grade A hydrogen is intended fo

41、r use in general industrial applications such as cutting, welding, and as a lifting medium for meteorological and other balloons. Grade B hydrogen, a higher purity grade, is intended for use in fuel, hydrogenation and water chemistry applications. Grade C is of the highest purity and is use in semic

42、onductor, analytical and special applications. 6.2 Acquisition requirements. Acquisition documents should specify the following: a. Title, number, and date of this specification. b. Grade required (see 1.2). c. Type of cylinder and valve (see 3.2). d. When supplier is to furnish cylinders (see 3.2).

43、 e. When hydrogen is to be contained in supplier-owned cylinders (see 3.2). f. When cylinders are to be filled to less than their rated service pressure (see 3.5). g. Any allowable variance from specified impurity levels (see 4.3.3). h. Packaging requirements (see 5.1 and 5.2). 6.3 Part or identific

44、ation number (PIN). The following part or identification number numbering procedure is for government purposes and does not constitute a requirement for the contractor. BBH886 - X XXXXX Volume of cylinder1: 100CF = 100 cubic feet 200CF = 200 cubic feet 300CF = 300 cubic feet Grade: A = Grade A - 99.

45、95 percent hydrogen B = Grade B - 99.99 percent hydrogen C = Grade C - 99.999 percent hydrogen Federal specification number 1The volume of the cylinder may be modified for ease of procurement and is not otherwise limited. The volume codes listed above are not all inclusive and are provided only for

46、example. Provided by IHSNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-BB-H-886E 7 6.4 Basis of purchase. The basis of purchase should be the cubic foot, based upon normal atmospheric conditions. Hydrogen is commercially available in cylinders of various rated cap

47、acities, with capacities of approximately 200 and 300 cubic feet being common. The quantity in cubic feet for each cylinder size is provided in the characteristics data of the applicable stock number. Normally, hydrogen cylinders will be filled to the following standard conditions: 1800, 2000, 2265,

48、 or 2400 pounds per square inch gauge (psig) at 70 F (21.1 C). In cases where the only cylinder available is rated for a higher pressure than requested, Department of Transportation regulations allow for cylinders to be filled to less than the marked service pressure. Also, cylinders specially quali

49、fied under 49 CFR to bear the plus (+) mark, have been approved for special filling limits up to 10 percent above the marked service pressure. 6.5 Subject term (key word) listing. Balloon, meteorological Cutting Cylinder Gas chromatograph Lifting medium Valve Welding 6.6 Safety considerations. Hydrogen has a very wide flammability range of 4 to 74 percent in air, and burns with an almost invisi