EN 1977-2013 en Copper and copper alloys - Copper drawing stock (wire rod)《铜和铜合金 铜坯(线材)》.pdf

1、raising standards worldwideNO COPYING WITHOUT BSI PERMISSION EXCEPT AS PERMITTED BY COPYRIGHT LAWBSI Standards PublicationBS EN 1977:2013Copper and copper alloys Copper drawing stock (wirerod)BS EN 1977:2013 BRITISH STANDARDNational forewordThis British Standard is the UK implementation of EN 1977:2

2、013. It supersedes BS EN 1977:1998 which is withdrawn.The UK participation in its preparation was entrusted to Technical Committee NFE/34, Copper and copper alloys.A list of organizations represented on this committee can be obtained on request to its secretary.This publication does not purport to i

3、nclude all the necessary provisions of a contract. Users are responsible for its correct application. The British Standards Institution 2013. Published by BSI Standards Limited 2013ISBN 978 0 580 76406 6 ICS 77.150.30 Compliance with a British Standard cannot confer immunity from legal obligations.T

4、his British Standard was published under the authority of the Standards Policy and Strategy Committee on 28 February 2013.Amendments issued since publicationDate T e x t a f f e c t e dBS EN 1977:2013EUROPEAN STANDARD NORME EUROPENNE EUROPISCHE NORM EN 1977 January 2013 ICS 77.150.30 Supersedes EN 1

5、977:1998English Version Copper and copper alloys - Copper drawing stock (wire rod) Cuivre et alliages de cuivre - Fil machine en cuivre Kupfer und Kupferlegierungen - Vordraht aus Kupfer This European Standard was approved by CEN on 24 November 2012. CEN members are bound to comply with the CEN/CENE

6、LEC Internal Regulations which stipulate the conditions for giving this European Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references concerning such national standards may be obtained on application to the CEN-CENELEC Management Centre o

7、r to any CEN member. This European Standard exists in three official versions (English, French, German). A version in any other language made by translation under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC Management Centre has the same status as the off

8、icial versions. CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands

9、, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and United Kingdom. EUROPEAN COMMITTEE FOR STANDARDIZATION COMIT EUROPEN DE NORMALISATION EUROPISCHES KOMITEE FR NORMUNG Management Centre: Avenue Marnix 17, B-1000 Brussels 2013 CEN All rights of exploitatio

10、n in any form and by any means reserved worldwide for CEN national Members. Ref. No. EN 1977:2013: EBS EN 1977:2013EN 1977:2013 (E) 2 Contents Page Foreword . 3 Introduction 4 1 Scope 5 2 Normative references . 5 3 Terms and definitions 5 4 Designations 5 4.1 Material . 5 4.2 Product . 6 5 Ordering

11、information 7 6 Requirements . 7 6.1 Composition . 7 6.2 Elongation 7 6.3 Electrical properties . 7 6.4 Annealability . 12 6.5 Hydrogen embrittlement 12 6.6 Scale adhesion . 13 6.7 Dimensions and tolerances . 13 6.8 Surface condition . 13 6.9 Joins . 13 7 Sampling . 13 7.1 General . 13 7.2 Analysis

12、(oxygen only) and measurement of diameter of Cu-ETP1 (CW003A) drawing stock . 14 7.3 Annealability testing of Cu-ETP1 (CW003A) drawing stock . 14 7.4 Analysis (other than oxygen) and measurement of elongation and electrical properties of Cu-ETP1 (CW003A) drawing stock 14 7.5 Tests on drawing stock i

13、n grades other than Cu-ETP1 (CW003A). 14 8 Test methods 15 8.1 Analysis 15 8.2 Elongation 15 8.3 Electrical resistivity 15 8.4 Annealability . 16 8.5 Hydrogen embrittlement 16 8.6 Scale adhesion . 16 8.7 Rounding of results . 16 9 Declaration of conformity and inspection documentation . 16 9.1 Decla

14、ration of conformity 16 9.2 Inspection documentation . 17 10 Marking . 17 Annex A (informative) Information on electrical resistivity and conductivity relationships . 18 A.1 Volume resistivity. 18 A.2 Standard annealed copper (IACS) . 18 A.3 Commercial annealed copper 18 A.4 Nominal mass resistivity

15、 18 A.5 Differences between measured and nominal values 19 Annex B (normative) Rapid Elongation Test method (AR-Test) for diameter 8 mm Cu-ETP1 wire rod . 20 B.1 General . 20 B.2 Procedure . 20 B.3 Test results . 22 Bibliography 23 BS EN 1977:2013EN 1977:2013 (E) 3 Foreword This document (EN 1977:20

16、13) has been prepared by Technical Committee CEN/TC 133 “Copper and copper alloys”, the secretariat of which is held by DIN. This European Standard shall be given the status of a national standard, either by publication of an identical text or by endorsement, at the latest by July 2013, and conflict

17、ing national standards shall be withdrawn at the latest by July 2013. Attention is drawn to the possibility that some of the elements of this document may be the subject of patent rights. CEN and/or CENELEC shall not be held responsible for identifying any or all such patent rights. This document su

18、persedes EN 1977:1998. This document is one of a series of European Standards for products manufactured from refined copper grades. Other products are specified as follows: EN 1976, Copper and copper alloys Cast unwrought copper products EN 1978, Copper and copper alloys Copper cathodes EN 13602, Co

19、pper and copper alloys Drawn, round copper wire for the manufacture of electrical conductors In comparison with EN 1977:1998, the following significant technical changes were made: a) Table 2, Cu-FRHC, Other elements: content has been modified and a new footnote “d” has been added; b) 6.4 and 8.4 “A

20、nnealability” have been modified; c) A.2 “Standard annealed copper (IACS)” has been modified; d) Annex B (normative) “Rapid Elongation Test method (AR-Test) for diameter 8 mm Cu-ETP1 wire rod” has been added. According to the CEN/CENELEC Internal Regulations, the national standards organisations of

21、the following countries are bound to implement this European Standard: Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Nethe

22、rlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and the United Kingdom. BS EN 1977:2013EN 1977:2013 (E) 4 Introduction Copper drawing stock (wire rod) is normally manufactured by one of the following process routes: continuous casting and hot rolling

23、 in tandem; continuous or semi-continuous casting and cold rolling; rolling of wire bar or billets; or extrusion. Annex A (informative) gives information on the relationships between electrical resistivity and conductivity (of copper). Annex B (normative) describes the rapid elongation test method (

24、AR-Test) for diameter 8 mm Cu-ETP1 wire rod. BS EN 1977:2013EN 1977:2013 (E) 5 1 Scope This European Standard specifies the composition, mechanical, electrical and physical properties for high conductivity copper drawing stock (wire rod) suitable for fabrication into wire by cold drawing, principall

25、y for the manufacture of electrical conductors. This European Standard covers drawing stock (wire rod), in nine grades of copper and nine silver-bearing copper grades. Normally, the cross-section is approximately circular, in a range of diameters from 6 mm. 2 Normative references The following docum

26、ents, in whole or in part, are normatively referenced in this document and are indispensable for its application. For dated references, only the edition cited applies. For undated references, the latest edition of the referenced document (including any amendments) applies. EN 1655, Copper and copper

27、 alloys Declarations of conformity EN 10204, Metallic products Types of inspection documents EN 12893, Copper and copper alloys Determination of spiral elongation number EN ISO 2626, Copper Hydrogen embrittlement test (ISO 2626) EN ISO 6892-1:2009, Metallic materials Tensile testing Part 1: Method o

28、f test at room temperature (ISO 6892-1:2009) IEC 60468, Method of measurement of resistivity of metallic materials ISO 4746, Oxygen-free copper Scale adhesion test 3 Terms and definitions For the purposes of this document, the following terms and definitions apply. 3.1 drawing stock wire rod interme

29、diate solid wrought product, of uniform cross-section along its whole length, supplied in coils 4 Designations 4.1 Material 4.1.1 General The material is designated either by symbol or number (see Tables 1 to 4). 4.1.2 Symbol The material symbol designation is based on the designation system given i

30、n ISO 1190-1. NOTE Although material symbol designations used in this standard might be the same as those in other standards using the designation system given in ISO 1190-1, the detailed composition requirements are not necessarily the same. 4.1.3 Number The material number designation is in accord

31、ance with the system given in EN 1412. BS EN 1977:2013EN 1977:2013 (E) 6 4.2 Product The product designation provides a standardized pattern of designation from which a rapid and unequivocal description of a product is conveyed in communication. It provides mutual comprehension at the international

32、level with regard to products which meet the requirements of the relevant European Standard. The product designation is no substitute for the full content of the standard. The product designation for products to this European Standard shall consist of: denomination (copper drawing stock); number of

33、this European Standard (EN 1977); material designation, either symbol or number (see Tables 1 to 4); nominal diameter; nominal coil mass; surface condition (the following designations shall be used, as appropriate: M for as manufactured, CL for cleaned). The derivation of a product designation is sh

34、own in the following example. EXAMPLE Drawing stock (wire rod) conforming to this standard, in material designated either Cu-ETP or CW004A, nominal diameter 8 mm, in 1 000 kg coils, cleaned surface condition, shall be designated as follows: Copper drawing stock EN 1977 Cu-ETP 8 1 000 CL or Copper dr

35、awing stock EN 1977 CW004A 8 1 000 CL Denomination Number of this European Standard Material designation Nominal diameter in millimetres Nominal coil mass in kilograms Surface condition BS EN 1977:2013 EN 1977:2013 (E) 7 5 Ordering information In order to facilitate the enquiry, order and informatio

36、n of order procedures between the purchaser and the supplier, the purchaser shall state on his enquiry and order the following information: a) quantity of product required (mass or number of coils); b) denomination (copper drawing stock); c) number of this European Standard (EN 1977); d) material de

37、signation (see Tables 1 to 4); e) nominal diameter; f) nominal coil mass; g) surface condition (see 6.8). It is recommended that the product designation as described in 4.2 is used for items b) to g). In addition, the purchaser shall also state on the enquiry and order any of the following, if requi

38、red: h) whether joins are permitted in the coils (see 6.9); i) additional tests, if any, which the purchaser requires to be carried out by the manufacturer on the material, selected from the tests appropriate to each copper grade given in Table 5; j) whether a declaration of conformity is required (

39、see 9.1); k) whether an inspection document is required, and if so which type (see 9.2). EXAMPLE Ordering details for 5 000 kg of drawing stock conforming to EN 1977, in material designated either Cu-ETP or CW004A, nominal diameter 8 mm, in 1 000 kg coils, cleaned surface condition: 5 000 kg Copper

40、drawing stock EN 1977 Cu-ETP 8 1 000 CL or 5 000 kg Copper drawing stock EN 1977 CW004A 8 1 000 CL 6 Requirements 6.1 Composition The composition shall conform to the requirements for the appropriate grade given in Tables 1 to 4. 6.2 Elongation Hot-finished drawing stock shall have a minimum elongat

41、ion of 30 %. The test shall be carried out in accordance with 8.2. No elongation requirements are specified for cold-finished drawing stock. If such requirements are necessary, they should be agreed between the purchaser and the supplier. 6.3 Electrical properties The maximum volume resistivity at 2

42、0 C of hot-finished drawing stock shall conform to the appropriate requirements given in Table 6. The test shall be carried out in accordance with 8.3. BS EN 1977:20138 Table 1 Composition of copper grades made from Cu-CATH-1 (CR001A) Material designation Composition % (mass fraction) ElementCu Ag A

43、s Bi Cd Co Cr Fe Mn Ni O P Pb S Sb Se Si Sn Te Zn Elements listed in this table other than copper Symbol Number totalexcludingCu-ETP1 CW003Amin. max. 0,002 5 0,000 5a 0,000 20b a c a 0,001 0c a c 0,040 a 0,000 5 0,001 5 0,000 4a 0,000 20b c c 0,000 20b c 0,006 5 O Cu-OF1 CW007Amin. max. 0,002 5 0,00

44、0 5a 0,000 20b a c a 0,001 0c a c d a 0,000 5 0,001 5 0,000 4a 0,000 20b c c 0,000 20b c 0,006 5 O Cu-OFE CW009Amin. max. 99,99 0,002 5 0,000 5 0,000 20 0,000 1 0,001 0 0,0005 0,0010 d 0,000 3 0,000 5 0,001 5 0,000 4 0,000 20 0,000 2 0,000 20 0,000 1 Cu-PHCE CW022Amin. max. 99,99 0,002 5 0,000 5 0,0

45、00 20 0,000 1 0,001 0 0,0005 0,0010 d0,001 0,006 0,000 5 0,001 5 0,000 4 0,000 20 0,000 2 0,000 20 0,000 1 a(As + Cd + Cr + Mn + P + Sb) max. 0,001 5 %. b(Bi + Se + Te) max. 0,000 3 %, of which (Se + Te) max. 0,000 30 %. c(Co + Fe + Ni + Si + Sn + Zn) max. 0,002 0 %. dThe oxygen content shall be con

46、trolled by the manufacturer so that the material conforms to the hydrogen embrittlement requirements. BS EN 1977:2013 EN 1977:2013 (E) BS EN 1977:2013EN 1977:2013 (E) 9 Table 2 Composition of copper grades, other than those made from Cu-CATH-1 (CR001A) Material designation Composition % (mass fracti

47、on) Element Cu aBi O Pb other elements (see Note) Symbol Number total excluding Cu-ETP CW004A min. max. 99,90 0,000 5 0,040 b 0,005 0,03 Ag, O Cu-FRHC CW005A min. max. 99,90 0,040 b 0,06 dAg, O Cu-OF CW008A min. max. 99,95 0,000 5 c 0,005 0,03 Ag NOTE The total of other elements (than copper) is def

48、ined as the sum of Ag, As, Bi, Cd, Co, Cr, Fe, Mn, Ni, O, P, Pb, S, Sb, Se, Si, Sn, Te and Zn, subject to the exclusion of any individual elements indicated. aIncluding silver, up to a maximum of 0,015 %. bOxygen content up to 0,060 % is permitted, subject to agreement between the purchaser and the supplier. cThe oxygen content shall be controlled by the manufacturer so that the material conforms to the hydrogen embrittlement requirements. dHigher total impurities content is permitted, subject to agreement between the purchaser and the supplier. Table 3 Composition of phospho