EN 71-5-2013 0625 Safety of toys - Part 5 Chemical toys (sets) other than experimental sets《玩具安全 第5部分 除实验套外的化学玩具》.pdf

1、raising standards worldwideNO COPYING WITHOUT BSI PERMISSION EXCEPT AS PERMITTED BY COPYRIGHT LAWBSI Standards PublicationBS EN 71-5:2013Safety of toysPart 5: Chemical toys (sets) other thanexperimental setsCopyright European Committee for Standardization Provided by IHS under license with CENNot fo

2、r ResaleNo reproduction or networking permitted without license from IHS-,-,-BS EN 71-5:2013 BRITISH STANDARDNational forewordThis British Standard is the UK implementation of EN 71-5:2013.It supersedes BS EN 71-5:1993+A2:2009/BS 5665-5:1993 which iswithdrawn.The UK participation in its preparation

3、was entrusted to TechnicalCommittee CW/15, Safety of toys.A list of organizations represented on this committee can beobtained on request to its secretary.This publication does not purport to include all the necessaryprovisions of a contract. Users are responsible for its correctapplication. The Bri

4、tish Standards Institution 2013. Published by BSI StandardsLimited 2013ISBN 978 0 580 77049 4ICS 71.040.99; 97.200.50Compliance with a British Standard cannot confer immunity fromlegal obligations.This British Standard was published under the authority of theStandards Policy and Strategy Committee o

5、n 30 June 2013.Amendments issued since publicationDate Text affectedCopyright European Committee for Standardization Provided by IHS under license with CENNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-BS EN 71-5:2013EUROPEAN STANDARD NORME EUROPENNE EUROPISCHE NO

6、RM EN 71-5 June 2013 ICS 97.200.50 Supersedes EN 71-5:1993English Version Safety of toys - Part 5: Chemical toys (sets) other than experimental sets Scurit des jouets - Partie 5: Jeux chimiques (coffrets) autres que les coffrets dexpriences chimiques Sicherheit von Spielzeug - Teil 5: Chemisches Spi

7、elzeug (Sets) ausgenommen Experimentierksten This European Standard was approved by CEN on 29 May 2013. CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this European Standard the status of a national standard without any alteration.

8、 Up-to-date lists and bibliographical references concerning such national standards may be obtained on application to the CEN-CENELEC Management Centre or to any CEN member. This European Standard exists in three official versions (English, French, German). A version in any other language made by tr

9、anslation under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC Management Centre has the same status as the official versions. CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Fin

10、land, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and United Kingdom. EUROPEAN COMMITTEE FOR STANDARDIZAT

11、ION COMIT EUROPEN DE NORMALISATION EUROPISCHES KOMITEE FR NORMUNG Management Centre: Avenue Marnix 17, B-1000 Brussels 2013 CEN All rights of exploitation in any form and by any means reserved worldwide for CEN national Members. Ref. No. EN 71-5:2013: ECopyright European Committee for Standardizatio

12、n Provided by IHS under license with CENNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-BS EN 71-5:2013EN 71-5:2013 (E) 2 Contents Page Foreword . 4 Introduction 6 1 Scope 7 2 Normative references . 7 3 Terms and definitions 7 4 Plaster of Paris (gypsum) moulding s

13、ets 9 4.1 Marking . 9 4.2 First aid information . 9 4.3 Safety rules. 9 5 Ceramic and vitreous enamelling materials supplied in miniature workshop sets 10 5.1 Chemical mixtures . 10 5.2 Marking . 10 5.3 First aid information . 10 5.4 Safety rules. 11 6 Oven-hardening plasticised PVC modelling clay s

14、ets 11 6.1 Chemical substances . 11 6.2 Marking . 12 6.3 First aid information . 12 6.4 Safety rules. 12 7 Plastic moulding sets. 12 7.1 Polystyrene granules . 12 7.2 Embedding sets . 13 8 Adhesives, paints, lacquers, varnishes, thinners and cleaning agents (solvents) supplied or recommended in mode

15、l sets . 14 8.1 General . 14 8.2 Adhesives . 14 8.3 Water-based paints and lacquers 20 8.4 Solvent-based paints, lacquers, thinners and cleaning solvents 22 9 Marking . 24 9.1 General . 24 9.2 Marking of the primary packaging . 24 9.3 Marking of individual containers and any packagings . 24 10 Instr

16、uctions for use 25 10.1 General . 25 10.2 Contents list . 25 10.3 Advice for adult supervision 25 10.4 Safety rules. 26 10.5 Instructions for carrying out the activities 26 10.6 Spills and disposal of chemicals . 26 11 Test methods 27 11.1 General . 27 11.2 Determination of elements in ceramic and v

17、itreous enamelling materials 27 11.3 Determination of plasticisers in oven-hardening polyvinyl chloride (PVC) modelling clay sets . 32 11.4 Determination of the emission of benzene, toluene and xylenes from oven-hardening plasticised PVC modelling clay sets and plastic moulding sets 44 Copyright Eur

18、opean Committee for Standardization Provided by IHS under license with CENNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-BS EN 71-5:2013EN 71-5:2013 (E) 3 11.5 Determination of styrene content in polystyrene granules 47 11.6 Determination of organic solvents 50 11

19、.7 Combined approach for the determination of plasticisers in solvent-based adhesives and in solvent-based paints and lacquers, film-forming agents in paints and lacquers and modifiers in solvent-based paints and lacquers . 70 Annex A (normative) Environmental, health and safety precautions . 82 Ann

20、ex B (informative) Organic solvents 83 Annex C (informative) Maximum permitted element concentrations for the compounds permitted in ceramic and vitreous enamelling materials 85 Annex D (informative) Validation of test methods . 86 Annex E (informative) Rationale . 87 E.1 General remark . 87 E.2 Pri

21、mary packaging (4.1; 5.2; 6.2; 7.1.2; 7.2.2; 8.2.1.2.2; 8.2.2.6; 8.3.2; 8.4.3; 9.2) . 87 E.3 Minimum age (4.1; 5.2; 6.2; 7.1.2; 7.2.3; 8.2.1.2.3; 8.2.1.3.3; 8.2.2.6; 8.3.3; 8.4.3) . 87 E.4 Phthalates (6.1 Table 2; 8.2.2; 8.4.1) 87 E.5 Benzene (6.1, Table 3; 8.2.2.4, Table 12; 8.4.1, Table 16) 88 E.6

22、 Preservatives (7.2.1; 8.2.1.1; 8.3.1) 88 Annex F (informative) Significant technical changes between this European Standard and the previous version . 89 Annex ZA (informative) Relationship between this European Standard and the Essential Requirements of EU Directive 2009/48/EC 90 Bibliography 91 C

23、opyright European Committee for Standardization Provided by IHS under license with CENNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-BS EN 71-5:2013EN 71-5:2013 (E) 4 Foreword This document (EN 71-5:2013) has been prepared by Technical Committee CEN/TC 52 “Safety

24、of toys”, the secretariat of which is held by DS. This European Standard shall be given the status of a national standard, either by publication of an identical text or by endorsement, at the latest by December 2013, and conflicting national standards shall be withdrawn at the latest by December 201

25、3. Attention is drawn to the possibility that some of the elements of this document may be the subject of patent rights. CEN and/or CENELEC shall not be held responsible for identifying any or all such patent rights. This document supersedes EN 71-5:1993. This document has been prepared under a mand

26、ate given to CEN by the European Commission and the European Free Trade Association, and supports essential requirements of EU Directive(s). For relationship with EU Directive 2009/48/EC, see informative Annex ZA, which is an integral part of this document. The significant changes from the previous

27、edition of this standard are detailed in Annex F. This standard is Part 5 of the European Standard for safety of toys, EN 71. This Part 5 of the EN 71 series is intended to be read in conjunction with EN 71, Part 1, Part 2 and Part 3, particularly the Introduction and Clause 1 of Part 1. EN 71, Safe

28、ty of toys, consists of the following parts: Part 1: Mechanical and physical properties; Part 2: Flammability; Part 3: Migration of certain elements; Part 4: Experimental sets for chemistry and related activities; Part 5: Chemical toys (sets) other than experimental sets; Part 7: Finger paints Requi

29、rements and test methods; Part 8: Activity toys for domestic use; Part 9: Organic chemical compounds Requirements; Part 10: Organic chemical compounds Sample preparation and extraction; Part 11: Organic chemical compounds Methods of analysis; Part 12: N-Nitrosamines and N-nitrosatable substances; Pa

30、rt 13: Olfactory board games, gustative board games, cosmetic kits and gustative kits; Copyright European Committee for Standardization Provided by IHS under license with CENNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-BS EN 71-5:2013EN 71-5:2013 (E) 5 Part 14:

31、Trampolines for domestic use. NOTE 1 In addition to the above parts of EN 71, the following guidance documents have been published: CEN Report, CR 14379, Classification of toys Guidelines, CEN Technical Report CEN/TR 15071, Safety of toys National translations of warnings and instructions for use in

32、 EN 71, and CEN Technical Report CEN/TR 15371, Safety of toys Replies to requests for interpretation of EN 71-1, EN 71-2, and EN 71-8. NOTE 2 Words in italics are defined in Clause 3 (Terms and definitions). According to the CEN-CENELEC Internal Regulations, the national standards organisations of t

33、he following countries are bound to implement this European Standard: Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Nether

34、lands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and the United Kingdom. Copyright European Committee for Standardization Provided by IHS under license with CENNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-BS EN 71-

35、5:2013EN 71-5:2013 (E) 6 Introduction This European Standard is intended to reduce the risks which may present health hazards to a child when the chemical toys are used as intended or in a foreseeable way, bearing in mind the behaviour of children. When using these chemical toys, potential risks sho

36、uld be kept to a minimum by inclusion of appropriate information to give special attention to possible hazards, risks and other problems. Chemical Abstract Service Registry Number (CAS) and European Inventory of Existing Chemical Substances Number (EINECS) given in various tables are provided for in

37、formation purposes only. Copyright European Committee for Standardization Provided by IHS under license with CENNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-BS EN 71-5:2013EN 71-5:2013 (E) 7 1 Scope This European Standard specifies requirements and test methods

38、for the substances and materials used in chemical toys (sets) other than experimental sets. These substances and mixtures are: those classified as dangerous by the EC-legislation applying to dangerous substances and dangerous mixtures 5; substances and mixtures which in excessive amounts could harm

39、the health of the children using them and which are not classified as dangerous by the above mentioned legislation; and any other chemical substance(s) and mixture(s) delivered with the chemical toy. NOTE The terms “substance” and “mixture” are defined in the REACH regulation No. (EC)1907/2006 and i

40、n the CLP regulation (EC) No. 1272/2008. Additionally, requirements are specified for markings, warnings, safety rules, contents list, instructions for use and first aid information. This Part of EN 71 applies to: plaster of Paris (gypsum) moulding sets; ceramic and vitreous enamelling materials sup

41、plied in miniature workshop sets; oven-hardening plasticised PVC modelling clay sets; plastic moulding sets; embedding sets; adhesives, paints, lacquers, varnishes, thinners and cleaning agents (solvents), supplied or recommended in model sets. 2 Normative references The following documents, in whol

42、e or in part, are normatively referenced in this document and are indispensable for its application. For dated references, only the edition cited applies. For undated references, the latest edition of the referenced document (including any amendments) applies. EN ISO 3104, Petroleum products Transpa

43、rent and opaque liquids Determination of kinematic viscosity and calculation of dynamic viscosity (ISO 3104) EN ISO 3219, Plastics Polymers/resins in the liquid state or as emulsions or dispersions Determination of viscosity using a rotational viscometer with defined shear rate (ISO 3219) EN ISO 369

44、6, Water for analytical laboratory use Specification and test methods (ISO 3696) EN ISO 22854, Liquid petroleum products Determination of hydrocarbon types and oxygenates in automotive-motor gasoline Multidimensional gas chromatography method (ISO 22854) 3 Terms and definitions For the purposes of t

45、his document, the following terms and definitions apply. Copyright European Committee for Standardization Provided by IHS under license with CENNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-BS EN 71-5:2013EN 71-5:2013 (E) 8 3.1 chemical toy toy intended for the d

46、irect handling of chemical substances and mixtures and which is used in a manner appropriate to a given age-group and under the supervision of an adult SOURCE: EN 71-4:2013, 3.1 3.2 experimental set chemical toy where the experimental and explorative character in playing with single chemical substan

47、ces and mixtures along strict instructions dominates over the creative ideas of the user SOURCE: EN 71-4:2013, 3.2 3.3 plaster of Paris (gypsum) moulding set toy containing moulds into which a mixture of water and gypsum is poured and allowed to harden Note 1 to entry: The gypsum consists predominan

48、tly of calcium sulfate hemihydrate CaSO4 0,5 H2O. Note 2 to entry: Plaster of Paris (gypsum) moulding sets are for example used for preparing figures and plates. 3.4 ceramic and vitreous enamelling materials supplied in miniature workshop set toy containing ceramic glazes and vitreous enamels (transparent, opaque or coloured) which after addition of water are painted on ceramic and metallic bodies to obtain smooth coatings, after which it is dried and fired at temperatures above 700 C 3.5 oven-hardening plasticised PVC modelling clay se