EN 15346-2014 en Plastics - Recycled plastics - Characterization of poly(vinyl chloride) (PVC) recyclates《塑料 再生塑料 氯乙烯(PVC)回收物的特性》.pdf

1、BSI Standards PublicationBS EN 15346:2014Plastics Recycled plastics Characterization of poly(vinylchloride) (PVC) recyclatesBS EN 15346:2014 BRITISH STANDARDNational forewordThis British Standard is the UK implementation of EN 15346:2014. Itsupersedes BS EN 15346:2007 which is withdrawn.The UK parti

2、cipation in its preparation was entrusted to TechnicalCommittee PRI/89, Plastics recycling.A list of organizations represented on this committee can beobtained on request to its secretary.This publication does not purport to include all the necessaryprovisions of a contract. Users are responsible fo

3、r its correctapplication. The British Standards Institution 2014. Published by BSI StandardsLimited 2014ISBN 978 0 580 81505 8ICS 13.030.50; 83.080.20Compliance with a British Standard cannot confer immunity fromlegal obligations.This British Standard was published under the authority of theStandard

4、s Policy and Strategy Committee on 30 November 2014.Amendments issued since publicationDate Text affectedBS EN 15346:2014EUROPEAN STANDARD NORME EUROPENNE EUROPISCHE NORM EN 15346 November 2014 ICS 13.030.50; 83.080.20 Supersedes EN 15346:2007English Version Plastics - Recycled plastics - Characteri

5、zation of poly(vinyl chloride) (PVC) recyclates Plastiques - Plastiques recycls - Caractrisation des recyclats de poly(chlorure de vinyle) (PVC) Kunststoffe - Kunststoff-Rezyklate - Charakterisierung von Polyvinylchlorid (PVC)-Rezyklaten This European Standard was approved by CEN on 20 September 201

6、4. CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this European Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references concerning such national standards may be obtained o

7、n application to the CEN-CENELEC Management Centre or to any CEN member. This European Standard exists in three official versions (English, French, German). A version in any other language made by translation under the responsibility of a CEN member into its own language and notified to the CEN-CENE

8、LEC Management Centre has the same status as the official versions. CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Ital

9、y, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and United Kingdom. EUROPEAN COMMITTEE FOR STANDARDIZATION COMIT EUROPEN DE NORMALISATION EUROPISCHES KOMITEE FR NORMUNG CEN-CENELEC Management Centre: Aven

10、ue Marnix 17, B-1000 Brussels 2014 CEN All rights of exploitation in any form and by any means reserved worldwide for CEN national Members. Ref. No. EN 15346:2014 EBS EN 15346:2014EN 15346:2014 (E) 2 Contents Page Foreword 4 Introduction .5 1 Scope 6 2 Normative references 6 3 Terms and definitions

11、.7 4 Characterization of PVC recyclates .7 5 Quality assurance 9 Annex A (informative) Typical compositions of PVC compounds 10 Annex B (normative) Determination of bulk density . 11 B.1 General . 11 B.2 Material 12 B.3 Apparatus 12 B.4 Preparation of test sample . 12 B.5 Procedure 12 B.6 Expression

12、 of results . 12 B.7 Test report . 13 Annex C (normative) Determination of tetrahydrofuran insoluble impurities 14 C.1 General . 14 C.2 Apparatus 14 C.3 Reagent 14 C.4 Procedure 15 C.5 Expression of results . 15 C.6 Test report . 16 Annex D (normative) Size and distribution of particles contained in

13、 micronized recycled PVC compounds by sieving . 17 D.1 General . 17 D.2 Reagents 17 D.3 Apparatus 17 D.4 Procedure 17 D.5 Number of determinations . 18 D.6 Determination and expression of the results 18 D.7 Test report . 19 Annex E (normative) Size and distribution of recycled PVC crushes by sieving

14、 20 E.1 General . 20 BS EN 15346:2014EN 15346:2014 (E) 3 E.2 Apparatus . 20 E.3 Procedure . 20 E.4 Number of determinations 21 E.5 Determination and expression of the results . 21 E.6 Test report 22 Annex F (normative) Fitness for processing of PVC recyclates by calendering 23 F.1 General . 23 F.2 A

15、pparatus . 23 F.3 Procedure . 23 Annex G (normative) Fitness for processing of PVC recyclates by extrusion . 25 G.1 General . 25 G.2 Apparatus . 25 G.3 Procedure . 25 Bibliography 26 BS EN 15346:2014EN 15346:2014 (E) 4 Foreword This document (EN 15346:2014) has been prepared by Technical Committee C

16、EN/TC 249 “Plastics”, the secretariat of which is held by NBN. This European Standard shall be given the status of a national standard, either by publication of an identical text or by endorsement, at the latest by May 2015 and conflicting national standards shall be withdrawn at the latest by May 2

17、015. Attention is drawn to the possibility that some of the elements of this document may be the subject of patent rights. CEN and/or CENELEC shall not be held responsible for identifying any or all such patent rights. This document supersedes EN 15346:2007. EN 15346:2014 includes the following sign

18、ificant technical change with respect to EN 15346:2007: revision of Annex C. This European Standard is one part of series of CEN publications on Plastics Recycling which is structured as follows: EN 15342, Plastics Recycled Plastics Characterization of polystyrene (PS) recyclates EN 15343, Plastics

19、Recycled Plastics Plastics recycling traceability and assessment of conformity and recycled content EN 15344, Plastics Recycled Plastics Characterization of Polyethylene (PE) recyclates EN 15345, Plastics Recycled Plastics Characterization of Polypropylene (PP) recyclates EN 15346, Plastics Recycled

20、 plastics Characterization of poly(vinyl chloride) (PVC) recyclates EN 15347, Plastics Recycled Plastics Characterization of plastics wastes EN 15348, Plastics Recycled plastics Characterization of poly(ethylene terephthalate) (PET) recyclates CEN/TR 15353, Plastics Recycled plastics Guidelines for

21、the development of standards for recycled plastics According to the CEN-CENELEC Internal Regulations, the national standards organizations of the following countries are bound to implement this European Standard: Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland,

22、 Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and the United Kingdom. BS EN 15346:2014EN 15346:2014 (E) 5

23、Introduction Recycling of plastics waste is one type of material recovery process intended to save resources (virgin raw materials, water, and energy), while minimizing harmful emissions into air, water and soil as well as any impacts on human health. The environmental impact of recycling has to be

24、assessed over the whole life cycle of the recycling system (from the waste generation point to the disposal of final residues). To ensure that recycling constitutes the best environmental option for treating the available waste, some prerequisites should preferably be met: recycling scheme being con

25、templated should generate lower environmental impacts than alternative recovery options; existing or potential market outlets should be identified that will secure a sustainable industrial recycling operation; collection and sorting schemes should be properly designed to deliver recyclable plastics

26、waste fractions fitting reasonably well with the available recycling technologies and with the (changing) needs of the identified market outlets, preferably at minimum costs to society. This European Standard has been produced in accordance with the guidance produced by CEN on Environmental Aspects

27、and in accordance with CEN/TR 15353. NOTE CEN/TR 15353 considers the general environmental aspects which are specific to the recycling process. It is often impossible to trace back each individual product at the end user stage and to check whether the product has been used correctly through its life

28、. Consequently products are out of industrial control for a period of time. It is possible that during this period contamination with other materials might occur that could affect the products suitability for recycling into the intended application. BS EN 15346:2014EN 15346:2014 (E) 6 1 Scope This E

29、uropean Standard defines a method of specifying delivery conditions for poly(vinyl chloride) (PVC) recyclates. It gives the most important characteristics and associated test methods for assessing of PVC recyclates intended for use in the production of semi-finished/finished products. It is intended

30、 to support parties involved in the use of recycled PVC to agree on specifications for specific and generic applications. This European Standard does not cover the characterization of plastics wastes. See EN 15347. This European Standard is applicable without prejudice to any existing legislation. 2

31、 Normative references The following documents, in whole or in part, are normatively referenced in this document and are indispensable for its application. For dated references, only the edition cited applies. For undated references, the latest edition of the referenced document (including any amendm

32、ents) applies. EN 12099, Plastics piping systems Polyethylene piping materials and components Determination of volatile content CEN/TR 15353, Plastics Recycled plastics Guidelines for the development of standards for recycled plastics EN ISO 182-2, Plastics Determination of the tendency of compounds

33、 and products based on vinyl chloride homopolymers and copolymers to evolve hydrogen chloride and any other acidic products at elevated temperatures Part 2: pH method (ISO 182 -2) EN ISO 182-3, Plastics Determination of the tendency of compounds and products based on vinyl chloride homopolymers and

34、copolymers to evolve hydrogen chloride and any other acidic products at elevated temperatures Part 3: Conductometric method (ISO 182 -3) EN ISO 182-4, Plastics Determination of the tend ency of compounds and products based on vinyl chloride homopolymers and copolymers to evolve hydrogen chloride and

35、 any other acidic products at elevated temperatures Part 4: Potentiometric method (ISO 182 -4) EN ISO 306, Plastics Thermoplastic materials Determination of Vicat softening temperature (VST) (ISO 306) EN ISO 472, Plastics Vocabulary (ISO 472) EN ISO 527-1, Plastics Determination of tensile propertie

36、s Part 1: General principles (ISO 527 -1) EN ISO 527-2, Plastics Determination of tens ile properties Part 2: Test conditions for moulding and extrusion plastics (ISO 527-2) EN ISO 868, Plastics and ebonite Determination of indentation hardness by means of a durometer (Shore hardness) (ISO 868) EN I

37、SO 1183-1, Plastics Methods for deter mining the density of non-cellular plastics Part 1: Immersion method, liquid pyknometer method and titration method (ISO 1183-1) BS EN 15346:2014EN 15346:2014 (E) 7 EN ISO 1269, Plastics Homopolymer and copolymer resins of vinyl chloride Determination of volatil

38、e matter (including water) (ISO 1269) EN ISO 3451-5, Plastics Determination of ash Part 5: Poly(vinyl chloride) (ISO 3451 -5) EN ISO 6186, Plastics Determination of pourability (ISO 6186) ISO 182-1, Plastics Determination of the tendency of compounds and products based on vinyl chloride homopolymers

39、 and copolymers to evolve hydrogen chloride and any other acidic products at elevated temperatures Part 1: Congo red method ISO 565, Test sieves Metal wire cloth, perforated metal plate and electroformed sheet Nominal sizes of openings 3 Terms and definitions For the purposes of this document, the t

40、erms and definitions given in EN ISO 472 and CEN/TR 15353 and the following apply. 3.1 sieve retention percentage of the recycled test sample retained on a sieve at the end of the test Note 1 to entry: The sieve retention is expressed in per cent (mass fraction). 3.2 container retention percentage o

41、f recycled material retained in the container at the bottom of a stack of sieves, or under a single sieve, at the end of the test compared to the mass of the sample tested 3.3 average particulate dimension single value of size, expressed to the nearest 0,001 mm, representing the dominant particle si

42、ze for the whole test sample 4 Characterization of PVC recyclates A single batch is the quantity of recyclate that has homogeneous characteristics within the specified tolerances. The characteristics of PVC recyclates, given in Table 1, are divided into two types: required characteristics needed to

43、characterize PVC recyclates in general, and required for all recyclates; optional characteristics needed to characterize PVC recyclates according to customer specifications and applications. These characteristics shall be assessed by using the test methods given in Table 1. A certificate of analysis

44、 giving the test results for each batch of recyclates shall be provided by the supplier to the purchaser upon request. NOTE Typical compositions of PVC compounds are given in Annex A. BS EN 15346:2014EN 15346:2014 (E) 8 The supplier shall provide the necessary information about the material composit

45、ion of the recyclates, as specified by the purchaser or required by the applicable regulations. Table 1 Characterization of PVC recyclates Characteristic Units Test method PVC-U PVC-P Comments Required Bulk density kg/m3Annex B X X Ash content % EN ISO 3451-5 Method A X X Linked with filler and mine

46、ral content Colour Visual Inspection X X e.g. natural colour, single, mixed Hardness EN ISO 868 X For calendering stiffness may be evaluated instead of hardness. See Annex F. Impurities % Annex C X X An alternative method agreed by both parties may also be used. Particle size and distribution g, % A

47、nnex D aAnnex E bX X Size distribution is needed for materials with a low particle size. Shape Visual X X e.g. micronized material, pellets, particles Optional Dry flow rate s EN ISO 6186 O O Recommended for micronized materials or small particle size recyclates Density kg/m3EN ISO 1183-1 Method A O

48、 O Fitness of processing of PVC recyclates by calendering by extrusion Annex F Annex G O O O O Residual humidity % EN 12099 cO O Weight loss, 105 C Tensile stress at yield MPa EN ISO 527-1 EN ISO 527-2 O O Tensile strain at break % EN ISO 527-1 EN ISO 527-2 O O Elongation Thermal stability min ISO 1

49、82-1 EN ISO 182-2 EN ISO 182-3 EN ISO 182-4 O O Linked to stabilizer content Specify which is used. Vicat softening temperature C EN ISO 306 Method B50 O BS EN 15346:2014EN 15346:2014 (E) 9 Volatile content % EN ISO 1269 O O Linked to moisture content Key X required characteristics to be quantified O optional characteristics to be quantified Other tests may be carried out by an agreement between the purchaser and the supplier. The test results sho