EN 15482-2012 en Chemicals used for treatment of water intended for human consumption - Sodium permanganate《化学物质用于治疗的水用于人类消费-高锰酸钠》.pdf

1、raising standards worldwideNO COPYING WITHOUT BSI PERMISSION EXCEPT AS PERMITTED BY COPYRIGHT LAWBSI Standards PublicationBS EN 15482:2012Chemicals used for treatmentof water intended for humanconsumption SodiumpermanganateBS EN 15482:2012 BRITISH STANDARDNational forewordThis British Standard is th

2、e UK implementation of EN 15482:2012. It supersedes BS EN 15482:2007 which is withdrawn.The UK participation in its preparation was entrusted to Technical Committee CII/59, Chemicals for drinking water treatment.A list of organizations represented on this committee can be obtained on request to its

3、secretary.This publication does not purport to include all the necessary provisions of a contract. Users are responsible for its correct application. The British Standards Institution 2013. Published by BSI Standards Limited 2013ISBN 978 0 580 77700 4 ICS 13.060.20; 71.100.80 Compliance with a Briti

4、sh Standard cannot confer immunity from legal obligations.This British Standard was published under the authority of the Standards Policy and Strategy Committee on 28 February 2013.Amendments issued since publicationDate T e x t a f f e c t e dBS EN 15482:2012EUROPEAN STANDARD NORME EUROPENNE EUROPI

5、SCHE NORM EN 15482 November 2012 ICS 71.100.80 Supersedes EN 15482:2007English Version Chemicals used for treatment of water intended for human consumption - Sodium permanganate Produits chimiques utiliss pour le traitement de leau destine la consommation humaine - Permanganate de sodium Produkte zu

6、r Aufbereitung von Wasser fr den menschlichen Gebrauch - Natriumpermanganat This European Standard was approved by CEN on 16 September 2012. CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this European Standard the status of a nati

7、onal standard without any alteration. Up-to-date lists and bibliographical references concerning such national standards may be obtained on application to the CEN-CENELEC Management Centre or to any CEN member. This European Standard exists in three official versions (English, French, German). A ver

8、sion in any other language made by translation under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC Management Centre has the same status as the official versions. CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus,

9、Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and United Kingdom

10、. EUROPEAN COMMITTEE FOR STANDARDIZATION COMIT EUROPEN DE NORMALISATION EUROPISCHES KOMITEE FR NORMUNG Management Centre: Avenue Marnix 17, B-1000 Brussels 2012 CEN All rights of exploitation in any form and by any means reserved worldwide for CEN national Members. Ref. No. EN 15482:2012: EBS EN 154

11、82:2012EN 15482:2012 (E) 2 Contents Page Foreword 3Introduction .41 Scope 52 Normative references 53 Description .53.1 Identification .53.2 Commercial forms .63.3 Physical properties 63.4 Chemical properties 74 Purity criteria 84.1 General 84.2 Composition of commercial product .84.3 Impurities and

12、main by-products .84.4 Chemical parameters 85 Test methods 95.1 Sampling .95.2 Analysis . 106 Labelling - Transportation - Storage . 136.1 Means of delivery 136.2 Labelling according to the EU legislation . 146.3 Transportation regulations and labelling . 146.4 Marking 146.5 Storage . 14Annex A (inf

13、ormative) General information on sodium permanganate 16A.1 Origin . 16A.1.1 Raw materials 16A.1.2 Manufacturing process 16A.2 Use . 16A.2.1 Function . 16A.2.2 Form in which the product is used . 16A.2.3 Treatment dose . 16A.2.4 Means of application 16A.2.5 Secondary effects . 17A.2.6 Removal of exce

14、ss product . 17Annex B (normative) General rules relating to safety 18B.1 Rules for safe handling and use . 18B.2 Emergency procedures 18B.2.1 First aid 18B.2.2 Spillage 18B.2.3 Fire . 18Bibliography . 19BS EN 15482:2012EN 15482:2012 (E) 3 Foreword This document (EN 15482:2012) has been prepared by

15、Technical Committee CEN/TC 164 “Water supply”, the secretariat of which is held by AFNOR. This European Standard shall be given the status of a national standard, either by publication of an identical text or by endorsement, at the latest by May 2013, and conflicting national standards shall be with

16、drawn at the latest by May 2013. Attention is drawn to the possibility that some of the elements of this document may be the subject of patent rights. CEN and/or CENELEC shall not be held responsible for identifying any or all such patent rights. This document supersedes EN 15482:2007. Significant t

17、echnical differences between this edition and EN 15482:2007 are as follows: a) Modification of Table 2 to show consistent limits for chemical parameters. b) Modification of 6.2 on labelling, deletion of the reference to EU Directive 80/778/EEC of 15 July 1980 in order to take account of the latest D

18、irective in force. This document is largely based on EN 12672:2008 3. According to the CEN/CENELEC Internal Regulations, the national standards organisations of the following countries are bound to implement this European Standard: Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark

19、, Estonia, Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and the United Kingdom. BS EN 15482:2012E

20、N 15482:2012 (E) 4 Introduction In respect of the potential adverse effects on the quality of water intended for human consumption caused by the product covered by this European Standard: a) this European Standard provides no information as to whether the product may be used without restriction in a

21、ny of the Member States of the EU or EFTA; b) it should be noted that, while awaiting the adoption of verifiable European criteria, existing national regulations concerning the use and/or the characteristics of this product remain in force. NOTE Conformity with this European Standard does not confer

22、 or imply acceptance or approval of the product in any of the Member States of the EU or EFTA. The use of the product covered by this European Standard is subject to regulation or control by National Authorities. BS EN 15482:2012EN 15482:2012 (E) 5 1 Scope This European Standard is applicable to sod

23、ium permanganate used for the treatment of water intended for human consumption. It describes the characteristics of sodium permanganate and specifies the requirements and the corresponding test methods for sodium permanganate. It provides information on its use in water treatment. 2 Normative refer

24、ences The following documents, in whole or in part, are normatively referenced in this document and are indispensable for its application. For dated references, only the edition cited applies. For undated references, the latest edition of the referenced document (including any amendments) applies. E

25、N 1233, Water quality Determination of chromium Atomic absorption spectrometric methods EN ISO 3696, Water for analytical laboratory use Specification and test methods (ISO 3696) EN ISO 11885, Water quality Determination of selected elements by inductively coupled plasma optical emission spectrometr

26、y (ICP-OES) (ISO 11885) EN ISO 11969, Water quality Determination of arsenic Atomic absorption spectrometric method (hydride technique (ISO 11969) EN ISO 12846, Water quality Determination of mercury Method using atomic absorption spectrometry (AAS) with and without enrichment (ISO 12846) ISO 3165,

27、Sampling of chemical products for industrial use Safety in sampling ISO 3856-2, Paints and varnishes Determination of “soluble“ metal content Part 2: Determination of antimony content Flame atomic absorption spectrometric method and Rhodamine B spectrophotometric method ISO 6206, Chemical products f

28、or industrial use Sampling Vocabulary ISO 8288, Water quality Determination of cobalt, nickel, copper, zinc, cadmium and lead Flame atomic absorption spectrometric methods ISO 9965, Water quality Determination of selenium Atomic absorption spectrometric method (hydride technique) 3 Description 3.1 I

29、dentification 3.1.1 Chemical name Sodium permanganate 3.1.2 Synonym or common name Permanganate acid sodium salt 3.1.3 Relative molecular mass BS EN 15482:2012EN 15482:2012 (E) 6 141,93 3.1.4 Empirical formula NaMnO43.1.5 Chemical formula NaMnO43.1.6 CAS Registry Number 1)10101-50-5 3.1.7 EINECS ref

30、erence 2)233-251-1 3.2 Commercial forms The sodium permanganate is usually available as a concentrated solution with a concentration within the range of mass fraction of 20 % to 40 %. The density of sodium permanganate solutions is given in Table 1. Table 1 Solution concentration Mass fraction in %

31、Densityg/ml at 22 C 10 1,07615 1,116 20 1,16425 1,21630 1,266 35 1,31640 1,3743.3 Physical properties 3.3.1 Appearance Sodium permanganate solution is a dark purple coloured solution. 3.3.2 Density The density of 40,00 % sodium permanganate solution is 1,37 g/cm3at 20 C. 1) Chemicals Abstracts Servi

32、ce Registry Number. 2) European Inventory of Existing Commercial Chemical Substances. BS EN 15482:2012EN 15482:2012 (E) 7 3.3.3 Solubility (in water) Sodium permanganate solution is soluble up to 40 % and miscible with water in all proportions. 3.3.4 Vapour pressure Not determined for sodium permang

33、anate solution, however, very similar to water. 3.3.5 Boiling point at 100 kPa3)Greater than 101 C. 3.3.6 Melting point Not applicable. 3.3.7 Specific heat Not determined. 3.3.8 Viscosity (dynamic) Less than 0,005 Pas for concentrations of 40 % or less 3.3.9 Critical temperature Not determined. 3.3.

34、10 Critical pressure Not determined. 3.3.11 Physical hardness Not applicable. 3.4 Chemical properties Sodium permanganate is a very strong oxidising agent. It is soluble in water and dissolves in various organic solvents (methanol, ethanol). NOTE The reaction with organics can be violent and is not

35、recommended. It decomposes at a high temperature and also in the presence of concentrated acids, hydrogen peroxide and organic compounds in general. It hydrolyses very slowly in contact with air, reducing to manganese dioxide (MnO2), a solid, brown to black colour product. 3) 100 kPa = 1 bar. BS EN

36、15482:2012EN 15482:2012 (E) 8 4 Purity criteria 4.1 General This European Standard specifies the minimum purity requirements for sodium permanganate used for the treatment of water intended for human consumption. Limits are given for impurities commonly present in the product. Depending on the raw m

37、aterial and the manufacturing process other impurities may be present and, if so, the user and when necessary relevant authorities shall be notified. Users of this product should check the national regulations to clarify whether it is of appropriate purity for treatment of water intended for human c

38、onsumption, taking into account raw water quality, required dosage, contents of other impurities and additives used in the product not stated in this product standard. Limits have been given for impurities and chemical parameters where these are likely to be present in significant quantities from th

39、e current production process and raw materials. If the production process or raw materials leads to significant quantities of impurities, by-products or additives being present, the user shall be notified. 4.2 Composition of commercial product The sodium permanganate is usually available in a concen

40、trated solution with a concentration within the range of mass fraction of 20 % to 40 %. The concentration of sodium permanganate solution shall be equal to or greater than the manufacturer specified value. 4.3 Impurities and main by-products The content of manganese dioxide (insoluble matter) shall

41、be no more than a mass fraction of 0,055 %. NOTE The product can contain fluoride or hexafluorosilicate. At typical levels of dosing, the added fluoride would be less than 40 g/l. 4.4 Chemical parameters The content of chemical parameters shall conform to the requirements specified in Table 2. Table

42、 2 Chemical parameters Parameter Limit mg/kg of NaMnO4(mass fraction 100 %) Arsenic (As) max. 20 Cadmium (Cd) max. 50 Chromium (Cr) max. 50 Mercury (Hg) max. 10 Nickel (Ni) max. 50 Lead (Pb) max. 50 Antimony (Sb) max. 50 Selenium (Se) max. 50 BS EN 15482:2012EN 15482:2012 (E) 9 5 Test methods 5.1 Sa

43、mpling 5.1.1 General Observe the general recommendations of ISO 3165 and take account those of ISO 6206. 5.1.2 Sampling from drums and bottles 5.1.2.1 General 5.1.2.1.1 Mix the contents of each container to be sampled by shaking the container, by rolling it or by rocking it from side to side, taking

44、 care not to damage the container or spill any of the liquid. 5.1.2.1.2 If the design of the container is such (for example, a narrow-necked bottle) that it is impracticable to use a sampling implement, take a sample by pouring after the contents have been thoroughly mixed. Otherwise, proceed as des

45、cribed in 5.1.2.1.3. 5.1.2.1.3 Examine the surface of the liquid. If there are signs of surface contamination, take samples from the surface as described in 5.1.2.2. Otherwise, take samples as described in 5.1.2.3. 5.1.2.2 Surface sampling Take a sample using a suitable ladle. Lower the ladle into t

46、he liquid until the rim is just below the surface, so that the surface layer runs into it. Withdraw the ladle just before it fills completely and allow any liquid adhering to the ladle to drain off. If necessary, repeat this operation so that, when the other selected containers have been sampled in

47、a similar manner, the total volume of sample required for subsequent analysis is obtained. 5.1.2.3 Bottom sampling Take a sample using an open sampling tube, or a bottom-valve sampling tube, suited to the size of container and the viscosity of the liquid. When using an open sampling tube, close it a

48、t the top and then lower the bottom end to the bottom of the container. Open the tube and move it rapidly so that the bottom of the tube traverses the bottom of the container before the tube is filled. Close the tube, withdraw it from the container and allow any liquid adhering to the outside of the

49、 tube to drain off. When using a bottom-valve sampling tube, close the valve before lowering the tube into the container and then proceed in a similar manner to that when using an open sampling tube. 5.1.3 Sampling from tanks and tankers From each access point, take samples as follows: a) from the surface of the liquid, using a ladle as described in 5.1.2.2; b) from the bottom