EN 15940-2016 en Automotive fuels - Paraffinic diesel fuel from synthesis or hydrotreatment - Requirements and test methods《汽车燃料-合成或加氢处理所得石蜡基柴油燃料-要求和试验方法》.pdf

1、BS EN 15940:2016Automotive fuels Paraffinicdiesel fuel from synthesisor hydrotreatment Requirements and testmethodsBSI Standards PublicationWB11885_BSI_StandardCovs_2013_AW.indd 1 15/05/2013 15:06BS EN 15940:2016 BRITISH STANDARDNational forewordThis British Standard is the UK implementation of EN 1

2、5940:2016. The UK participation in its preparation was entrusted to Technical Committee PTI/2, Liquid Fuels.A list of organizations represented on this committee can be obtained on request to its secretary.This publication does not purport to include all the necessary provisions of a contract. Users

3、 are responsible for its correct application. The British Standards Institution 2016.Published by BSI Standards Limited 2016ISBN 978 0 580 87499 4 ICS 75.160.20 Compliance with a British Standard cannot confer immunity from legal obligations.This British Standard was published under the authority of

4、 the Standards Policy and Strategy Committee on 31 July 2016.Amendments/corrigenda issued since publicationDate T e x t a f f e c t e dBS EN 15940:2016EUROPEAN STANDARD NORME EUROPENNE EUROPISCHE NORM EN 15940 June 2016 ICS 75.160.20 Supersedes CEN/TS 15940:2012English Version Automotive fuels - Par

5、affinic diesel fuel from synthesis or hydrotreatment - Requirements and test methods Carburants pour automobiles - Gazoles paraffiniques de synthse ou obtenus par hydrotraitement - Exigences et mthodes dessais Kraftstoffe fr Kraftfahrzeuge - Paraffinischer Dieselkraftstoff aus Synthese oder Hydrieru

6、ngsverfahren - Anforderungen und Prfverfahren This European Standard was approved by CEN on 15 April 2016. CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this European Standard the status of a national standard without any alterati

7、on. Up-to-date lists and bibliographical references concerning such national standards may be obtained on application to the CEN-CENELEC Management Centre or to any CEN member. This European Standard exists in three official versions (English, French, German). A version in any other language made by

8、 translation under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC Management Centre has the same status as the official versions. CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia,

9、Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and United Kingdom. EUROPEAN COMMITTEE FOR STANDARDI

10、ZATION COMIT EUROPEN DE NORMALISATION EUROPISCHES KOMITEE FR NORMUNG CEN-CENELEC Management Centre: Avenue Marnix 17, B-1000 Brussels 2016 CEN All rights of exploitation in any form and by any means reserved worldwide for CEN national Members. Ref. No. EN 15940:2016 EBS EN 15940:2016EN 15940:2016 (E

11、) 2 Contents Page European foreword . 4 Introduction 6 1 Scope 7 2 Normative references 7 3 Sampling . 9 4 Pump marking 9 5 Requirements and test methods 9 5.1 Dyes and markers . 9 5.2 Additives . 9 5.2.1 General 9 5.2.2 Methylcyclopentadienyl Manganese Tricarbonyl (MMT) 9 5.3 Fatty acid methyl este

12、r (FAME) . 10 5.4 Cavitation prevention . 10 5.5 Seizure protection 10 5.6 Generally applicable requirements and related test methods 10 5.7 Climate dependent requirements and related test methods . 12 5.8 Precision and dispute . 13 Annex A (informative) Seizure protection . 14 Annex B (normative) D

13、etails of interlaboratory test programme 15 Annex C (normative) Details of HPLC procedure . 16 C.1 Warning . 16 C.2 Scope . 16 C.3 Terms and definitions 16 C.4 Principle 17 C.5 Reagents and materials 17 C.6 Apparatus 18 C.7 Sample handling and storage . 20 C.8 Apparatus preparation 20 C.9 Calibratio

14、n 22 C.10 Procedure 24 C.11 Calculation 26 C.11.1 Reference time 26 C.11.2 Column resolution . 27 C.11.3 Cut times 27 C.11.4 Aromatic hydrocarbons type content . 27 C.11.5 Total aromatic hydrocarbons content 27 C.12 Test precision 28 C.12.1 General . 28 C.12.2 Repeatability, r 28 C.12.3 Reproducibil

15、ity, R 28 C.13 Test report 28 Annex D (normative) Measurements and constants for paraffinic fuel products and components 29 D.1 General . 29 BS EN 15940:2016EN 15940:2016 (E) 3 D.2 Short abstract of density / temperature conversion formulae and constants . 29 D.3 Measurements and constants for paraf

16、finic diesel fuel products and components 30 D.4 Conclusions . 32 Bibliography . 33 BS EN 15940:2016EN 15940:2016 (E) 4 European foreword This document (EN 15940:2016) has been prepared by Technical Committee CEN/TC 19 “Gaseous and liquid fuels, lubricants and related products of petroleum, syntheti

17、c and biological origin”, the secretariat of which is held by NEN. This European Standard shall be given the status of a national standard, either by publication of an identical text or by endorsement, at the latest by December 2016, and conflicting national standards shall be withdrawn at the lates

18、t by December 2016. Attention is drawn to the possibility that some of the elements of this document may be the subject of patent rights. CEN and/or CENELEC shall not be held responsible for identifying any or all such patent rights. This document supersedes CEN/TS 15940:2012. Significant other tech

19、nical changes between this document and CEN/TS 15940:2012 are: a) the limits for distillation at 250 C and 350 C are included in line with EN 590 and the EU Common Customs tariff for diesel fuel; b) EN ISO 3924, also known as simulated distillation, has been incorporated in Table 1 as an additional

20、methodology to determine distillation characteristics; c) prEN 16906 (EN equivalent to DIN 51773, Testing of liquid fuels Determination of ignition quality (cetane number) of Diesel fuels with the BASF-engine) has been studied and allowed as an additional methodology to determine cetane number; d) i

21、n order to allow fitness for purpose product and to align it with EN 590 product that has proven functionality in diesel engines, the arctic climate viscosity limits and the distillation recovery at 180 C have been introduced in Table 3; e) in order to present all relevant requirements within the sa

22、me fuel specification, the necessary climate dependent properties from EN 590 have been introduced in 5.7; this required reference of some additional test methods in Clause 2; f) further clarification on the oxidation stability requirement, as a result of recent changes in EN 15751, has been introdu

23、ced; g) exclusion of special sampling procedures for clean paraffinic fuel as they apply to diesel fuel in general; h) to further underline the link with EN 590 that normative reference being stipulated without reference to a particular date of publication; i) introduction of an annex of the precisi

24、on data for test methods where different from normal diesel fuel in following the CEN/TC 19 interlaboratory study 1; j) introduction of an annex covering a test procedure for aromatics content determination being developed as part of a second interlaboratory study funded by the EC on three different

25、 HPLC techniques; BS EN 15940:2016EN 15940:2016 (E) 5 k) introduction of an annex on density temperature corrections being developed as part of a CEN/TC 19 investigation led by Mr. H. Th. Feuerhelm of DIN-FAM. In this document, all relevant characteristics, requirements and test methods are specifie

26、d. These specifications are relevant for the driveability of the vehicles and are currently known to prevent harm to the vehicles and their powertrains. Climate dependent requirements of this document may vary according to national adoptions of EN 590 and EN 14214, but should be indicated by a speci

27、fic National Annex. Several assessments of test methods for paraffinic diesel fuel have been executed and the results thereof 1 led to conclusions regarding the applicability of each of the test methods as required in Clause 5. The conclusion of these assessments, partially funded by the European Co

28、mmission, led to the possibility to upgrade the original Technical Specification into a full European Standard. Although it is its main actual use, the product is now no longer limited to captive fleet usage, but the scope defines the need to check the use of the product with the vehicle manufacture

29、r. There are no EU legislative needs to limit the product to captive fleets. Such restriction is not for the specification but for the market to decide upon. Therefore, and in the light of the defined need to check the use of the product with the vehicle manufacturer, all restrictions towards captiv

30、e fleet from the CEN/TS text have been deleted This document is based on current knowledge at the time of publishing, but will require revision when the specification for either regular automotive diesel fuel, EN 590, or FAME, EN 14214, has been determined (revised) by CEN/TC 19 or based on further

31、experiences with the use of paraffinic diesel fuel according to this document. Further background can be found in CEN/TR 16389 2. According to the CEN/CENELEC Internal Regulations, the national standards organizations of the following countries are bound to implement this European Standard: Austria,

32、 Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, S

33、witzerland, Turkey and the United Kingdom. BS EN 15940:2016EN 15940:2016 (E) 6 Introduction This document has been laid down to define a quality specification for diesel fuel on the basis of synthesis gas or of hydrotreated bio-oils or -fats. Its main use is as diesel fuel in dedicated diesel vehicl

34、e fleets and engines. Paraffinic diesel fuel does not meet the current diesel fuel specification, EN 590. The main differences between paraffinic diesel fuel and automotive diesel fuel are in the areas of density, sulfur, aromatics and cetane. Its density can be outside the regular diesel specificat

35、ion, and the described class A type fuel has a higher cetane number. Paraffinic diesel fuel is not validated for all vehicles, consult vehicle manufacturer before use. Paraffinic diesel is a high quality, clean burning fuel with virtually no sulfur and aromatics. Paraffinic diesel fuel can be used i

36、n diesel engines (see NOTE 1 under Clause 1 and the last paragraph of Clause 4), also to reduce regulated emissions. In order to have the greatest possible emissions reduction, a specific calibration may be necessary. Paraffinic diesel fuel can also offer a meaningful contribution to the target of i

37、ncreased non-petroleum and/or renewable content in transportation fuel pool. As some production processes result in a fuel containing cyclo-paraffins, as well as n-paraffins and iso-paraffins, they show different cetane number compared to other paraffinic diesel fuels. Hence, in this document, two c

38、lasses have been defined, one class showing improved ignition quality compared to regular diesel fuel. Blending of paraffinic diesel with biodiesel (FAME) is covered in this document. Against the background of the EU Renewable Energy Directive (RED, 2009/28/EC 3) and also the latest developments reg

39、arding European regular diesel specification, there is now a pressing requirement to allow for FAME blend variations of those paraffinic fuels, which are not already classified as being from renewable resources. As with CEN/TS 15940, this document allows for a paraffinic diesel specification other t

40、han the former CWA 15940, to “mirror” the current EN 590 diesel fuel quality specification. That is, allowing a blend variant of paraffinic diesel in the same way that CEN diesel quality specifications allow for refinery diesel up to 7 % (V/V) FAME blend percentage. Paraffinic diesel may also be use

41、d as a blending component for automotive diesel fuel, but this is not in the scope of this document. The document will be usable on a voluntary basis for engine clearance, fuel acceptance and fuelling station allowance, supporting both local regulations and international trade. BS EN 15940:2016EN 15

42、940:2016 (E) 7 1 Scope This European Standard describes requirements and test methods for marketed and delivered paraffinic diesel fuel containing a level of up to 7,0 % (V/V) fatty acid methyl ester (FAME). It is applicable to fuel for use in diesel engines and vehicles compatible with paraffinic d

43、iesel fuel. It defines two classes of paraffinic diesel fuel: high cetane and normal cetane. Paraffinic diesel fuel originates from synthesis or hydrotreatment processes. NOTE 1 For general diesel engine warranty, paraffinic automotive diesel fuel may need a validation step, which for some existing

44、engines may still need to be done (see also the Introduction to this document). The vehicle manufacturer needs to be consulted before use. NOTE 2 For the purposes of this document, the terms “% (m/m)” and “% (V/V)” are used to represent respectively the mass fraction and the volume fraction. 2 Norma

45、tive references The following documents, in whole or in part, are normatively referenced in this document and are indispensable for its application. For dated references, only the edition cited applies. For undated references, the latest edition of the referenced document (including any amendments)

46、applies. EN 116:2015, Diesel and domestic heating fuels Determination of cold filter plugging point Stepwise cooling bath method EN 12662:2014, Liquid petroleum products Determination of total contamination in middle distillates, diesel fuels and fatty acid methyl esters EN 14078:2014, Liquid petrol

47、eum products Determination of fatty acid methyl ester (FAME) content in middle distillates Infrared spectrometry method EN 14214:2012+A1:2014, Liquid petroleum products Fatty acid methyl esters (FAME) for use in diesel engines and heating applications Requirements and test methods EN 15195:2014, Liq

48、uid petroleum products Determination of ignition delay and derived cetane number (DCN) of middle distillate fuels by combustion in a constant volume chamber EN 15751:2014, Automotive fuels Fatty acid methyl ester (FAME) fuel and blends with diesel fuel Determination of oxidation stability by acceler

49、ated oxidation method EN 16136:2015, Automotive fuels Determination of manganese and iron content in unleaded petrol Inductively coupled plasma optical emission spectrometry (ICP OES) method EN 16329:2013, Diesel and domestic heating fuels Determination of cold filter plugging point Linear cooling bath method prEN 16906, Liquid petroleum products Determination of the ignition quality of diesel fuels BASF engine method EN 23015:1994, Petroleum products Determination of cloud point (ISO 3015:1992) EN ISO 1042:1999, Laboratory