EN 16170-2016 en Sludge treated biowaste and soil - Determination of elements using inductively coupled plasma optical emission spectrometry (ICP-OES)《污泥 处理过的生物废弃物和土壤-利用电感耦合等离子体发射光.pdf

1、BS EN 16170:2016Sludge, treated biowasteand soil Determination ofelements using inductivelycoupled plasma opticalemission spectrometry(ICP-OES)BSI Standards PublicationBS EN 16170:2016 BRITISH STANDARDNational forewordThis British Standard is the UK implementation of EN 16170:2016.BSI, as a member o

2、f CEN, is obliged to publish EN 16170 as a British Standard. However, attention is drawn to the fact that during the development of this European Standard, the UK committee voted against its approval as a European Standard.The UK committee is concerned that some of the conditions attached to the val

3、idation trials lack clarity.It is also the opinion of the UK committee that validation trials for horizontal methods should include conditions for the preparation and extraction of the original sample.The UK participation in its preparation was entrusted by Technical Committee H/-, Health and Enviro

4、nment Sector Policy and Strategy Committee, to Subcommittee H/-/4, Environmental Testing Programmes.A list of organizations represented on this subcommittee can be obtained on request to its secretary.This publication does not purport to include all the necessary provisions of a contract. Users are

5、responsible for its correct application. The British Standards Institution 2016. Published by BSI Standards Limited 2016ISBN 978 0 580 91016 6ICS 13.030.01; 13.080.10Compliance with a British Standard cannot confer immunity from legal obligations.This British Standard was published under the authori

6、ty of the Standards Policy and Strategy Committee on 30 November 2016.Amendments/corrigenda issued since publicationDate Text affectedBS EN 16170:2016g8g24g21g18g19g8g4g17g3g22g23g4g17g7g4g21g7g3g17g18g21g16g8g3g8g24g21g18g19g50g8g17g17g8g3g8g24g21g18g19g34g12g22g6g11g8g3g17g18g21g16g3EN 16170 g18g1

7、33g150g145g132g135g148g3g884g882g883g888g3g12g6g22g3g883g885g484g882g885g882g484g882g883g482g3g883g885g484g882g890g882g484g883g882g3 g22g151g146g135g148g149g135g134g135g149g3g6g8g17g512g23g22g3g883g888g883g889g882g483g884g882g883g884g8g144g137g142g139g149g138g3g25g135g148g149g139g145g144g3g22g142g15

8、1g134g137g135g481g3g150g148g135g131g150g135g134g3g132g139g145g153g131g149g150g135g3g131g144g134g3g149g145g139g142g3g486g3g7g135g150g135g148g143g139g144g131g150g139g145g144g3g145g136g3g135g142g135g143g135g144g150g149g3g151g149g139g144g137g3g139g144g134g151g133g150g139g152g135g142g155g3g133g145g151g14

9、6g142g135g134g3g146g142g131g149g143g131g3g145g146g150g139g133g131g142g3g135g143g139g149g149g139g145g144g3g149g146g135g133g150g148g145g143g135g150g148g155g3g523g12g6g19g486g18g8g22g524g3g5g145g151g135g149g481g3g132g139g145g486g134g177g133g138g135g150g149g3g150g148g131g139g150g177g149g3g135g150g3g149g

10、145g142g149g3g486g3g7g177g150g135g148g143g139g144g131g150g139g145g144g3g134g135g149g3g177g142g177g143g135g144g150g149g3g135g144g3g150g148g131g133g135g149g3g146g131g148g3g149g146g135g133g150g148g145g143g177g150g148g139g135g3g134g821g177g143g139g149g149g139g145g144g3g145g146g150g139g147g151g135g3g131g

11、152g135g133g3g146g142g131g149g143g131g3g139g144g134g151g139g150g3g146g131g148g3g138g131g151g150g135g3g136g148g177g147g151g135g144g133g135g3g523g12g6g19g486g18g8g22g524g3g22g133g138g142g131g143g143g481g3g132g135g138g131g144g134g135g142g150g135g148g3g5g139g145g131g132g136g131g142g142g3g151g144g134g3g5

12、g145g134g135g144g3g486g3g5g135g149g150g139g143g143g151g144g137g3g152g145g144g3g8g142g135g143g135g144g150g135g144g3g143g139g150g150g135g142g149g3g145g146g150g139g149g133g138g135g148g3g8g143g139g149g149g139g145g144g149g149g146g135g141g150g148g145g143g135g150g148g139g135g3g143g139g150g3g139g144g134g151

13、g141g150g139g152g3g137g135g141g145g146g146g135g142g150g135g143g3g19g142g131g149g143g131g3g523g12g6g19g486g18g8g22g524g3g23g138g139g149g3g8g151g148g145g146g135g131g144g3g22g150g131g144g134g131g148g134g3g153g131g149g3g131g146g146g148g145g152g135g134g3g132g155g3g6g8g17g3g145g144g3g883g891g3g16g131g148g

14、133g138g3g884g882g883g888g484g3g3g6g8g17g3g143g135g143g132g135g148g149g3g131g148g135g3g132g145g151g144g134g3g150g145g3g133g145g143g146g142g155g3g153g139g150g138g3g150g138g135g3g6g8g17g512g6g8g17g8g15g8g6g3g12g144g150g135g148g144g131g142g3g21g135g137g151g142g131g150g139g145g144g149g3g153g138g139g133g

15、138g3g149g150g139g146g151g142g131g150g135g3g150g138g135g3g133g145g144g134g139g150g139g145g144g149g3g136g145g148g3g137g139g152g139g144g137g3g150g138g139g149g3g8g151g148g145g146g135g131g144g3g22g150g131g144g134g131g148g134g3g150g138g135g3g149g150g131g150g151g149g3g145g136g3g131g3g144g131g150g139g145g1

16、44g131g142g3g149g150g131g144g134g131g148g134g3g153g139g150g138g145g151g150g3g131g144g155g3g131g142g150g135g148g131g150g139g145g144g484g3g24g146g486g150g145g486g134g131g150g135g3g142g139g149g150g149g3g131g144g134g3g132g139g132g142g139g145g137g148g131g146g138g139g133g131g142g3g148g135g136g135g148g135g

17、144g133g135g149g3g133g145g144g133g135g148g144g139g144g137g3g149g151g133g138g3g144g131g150g139g145g144g131g142g3g149g150g131g144g134g131g148g134g149g3g143g131g155g3g132g135g3g145g132g150g131g139g144g135g134g3g145g144g3g131g146g146g142g139g133g131g150g139g145g144g3g150g145g3g150g138g135g3g6g8g17g486g6

18、g8g17g8g15g8g6g3g16g131g144g131g137g135g143g135g144g150g3g6g135g144g150g148g135g3g145g148g3g150g145g3g131g144g155g3g6g8g17g3g143g135g143g132g135g148g484g3g23g138g139g149g3g8g151g148g145g146g135g131g144g3g22g150g131g144g134g131g148g134g3g135g154g139g149g150g149g3g139g144g3g150g138g148g135g135g3g145g1

19、36g136g139g133g139g131g142g3g152g135g148g149g139g145g144g149g3g523g8g144g137g142g139g149g138g481g3g9g148g135g144g133g138g481g3g10g135g148g143g131g144g524g484g3g4g3g152g135g148g149g139g145g144g3g139g144g3g131g144g155g3g145g150g138g135g148g3g142g131g144g137g151g131g137g135g3g143g131g134g135g3g132g155g

20、3g150g148g131g144g149g142g131g150g139g145g144g3g151g144g134g135g148g3g150g138g135g3g148g135g149g146g145g144g149g139g132g139g142g139g150g155g3g145g136g3g131g3g6g8g17g3g143g135g143g132g135g148g3g139g144g150g145g3g139g150g149g3g145g153g144g3g142g131g144g137g151g131g137g135g3g131g144g134g3g144g145g150g1

21、39g136g139g135g134g3g150g145g3g150g138g135g3g6g8g17g486g6g8g17g8g15g8g6g3g16g131g144g131g137g135g143g135g144g150g3g6g135g144g150g148g135g3g138g131g149g3g150g138g135g3g149g131g143g135g3g149g150g131g150g151g149g3g131g149g3g150g138g135g3g145g136g136g139g133g139g131g142g3g152g135g148g149g139g145g144g149

22、g484g3g6g8g17g3g143g135g143g132g135g148g149g3g131g148g135g3g150g138g135g3g144g131g150g139g145g144g131g142g3g149g150g131g144g134g131g148g134g149g3g132g145g134g139g135g149g3g145g136g3g4g151g149g150g148g139g131g481g3g5g135g142g137g139g151g143g481g3g5g151g142g137g131g148g139g131g481g3g6g148g145g131g150g

23、139g131g481g3g6g155g146g148g151g149g481g3g6g156g135g133g138g3g21g135g146g151g132g142g139g133g481g3g7g135g144g143g131g148g141g481g3g8g149g150g145g144g139g131g481g3g9g139g144g142g131g144g134g481g3g9g145g148g143g135g148g3g28g151g137g145g149g142g131g152g3g21g135g146g151g132g142g139g133g3g145g136g3g16g13

24、1g133g135g134g145g144g139g131g481g3g9g148g131g144g133g135g481g3g10g135g148g143g131g144g155g481g3g10g148g135g135g133g135g481g3g11g151g144g137g131g148g155g481g3g12g133g135g142g131g144g134g481g3g12g148g135g142g131g144g134g481g3g12g150g131g142g155g481g3g15g131g150g152g139g131g481g3g15g139g150g138g151g13

25、1g144g139g131g481g3g15g151g154g135g143g132g145g151g148g137g481g3g16g131g142g150g131g481g3g17g135g150g138g135g148g142g131g144g134g149g481g3g17g145g148g153g131g155g481g3g19g145g142g131g144g134g481g3g19g145g148g150g151g137g131g142g481g3g21g145g143g131g144g139g131g481g3g22g142g145g152g131g141g139g131g48

26、1g3g22g142g145g152g135g144g139g131g481g3g22g146g131g139g144g481g3g22g153g135g134g135g144g481g3g22g153g139g150g156g135g148g142g131g144g134g481g3g23g151g148g141g135g155g3g131g144g134g3g24g144g139g150g135g134g3g14g139g144g137g134g145g143g484g3g8g24g21g18g19g8g4g17g3g6g18g16g16g12g23g23g8g8g3g9g18g21g3g

27、22g23g4g17g7g4g21g7g12g29g4g23g12g18g17g3g6g18g16g12g23g50g3g8g24g21g18g19g50g8g17g3g7g8g3g17g18g21g16g4g15g12g22g4g23g12g18g17g3g8g24g21g18g19g34g12g22g6g11g8g22g3g14g18g16g12g23g8g8g3g9g111g21g3g17g18g21g16g24g17g10g3g3CEN-CENELECg3Management Centre: Avenue Marnix 17, B-1000 Brussels g825g3g884g88

28、2g883g888g3g6g8g17g3 g4g142g142g3g148g139g137g138g150g149g3g145g136g3g135g154g146g142g145g139g150g131g150g139g145g144g3g139g144g3g131g144g155g3g136g145g148g143g3g131g144g134g3g132g155g3g131g144g155g3g143g135g131g144g149g3g148g135g149g135g148g152g135g134g3g153g145g148g142g134g153g139g134g135g3g136g14

29、5g148g3g6g8g17g3g144g131g150g139g145g144g131g142g3g16g135g143g132g135g148g149g484g3g21g135g136g484g3g17g145g484g3g8g17g3g883g888g883g889g882g483g884g882g883g888g3g8BS EN 16170:2016EN 16170:2016 (E) 2 Contents Page European foreword . 3 Introduction 4 1 Scope 5 2 Normative references 5 3 Principle .

30、5 4 Interferences 5 5 Reagents . 6 6 Apparatus . 8 7 Procedure. 9 7.1 Test sample solution 9 7.2 Test solution . 9 7.3 Instrument set-up . 9 7.4 Calibration 10 7.5 Sample measurement . 10 8 Calculation 11 9 Expression of results . 11 10 Performance characteristics 11 10.1 Calibration check . 11 10.2

31、 Interference . 12 10.3 Recovery 12 10.4 Performance data . 12 11 Test report 12 Annex A (informative) Repeatability and reproducibility data . 13 Annex B (informative) Wavelengths, spectral interferences and estimated instrumental detection limits . 19 Annex C (informative) Inter-element correction

32、 . 23 Bibliography . 25 BS EN 16170:2016EN 16170:2016 (E) 3 European foreword This document (EN 16170:2016) has been prepared by Technical Committee CEN/TC 444 “Test methods for environmental characterization of solid matrices”, the secretariat of which is held by NEN. This European Standard shall b

33、e given the status of a national standard, either by publication of an identical text or by endorsement, at the latest by April 2017, and conflicting national standards shall be withdrawn at the latest by April 2017. Attention is drawn to the possibility that some of the elements of this document ma

34、y be the subject of patent rights. CEN and/or CENELEC shall not be held responsible for identifying any or all such patent rights. This document supersedes CEN/TS 16170:2012. The preparation of the previous edition of this analytical method by CEN is based on a mandate by the European Commission (Ma

35、ndate M/330), which assigned the development of standards on sampling and analytical methods for hygienic and biological parameters as well as inorganic and organic determinants, aiming to make these standards applicable to sludge, treated biowaste and soil as far as this is technically feasible. Th

36、is document contains the following technical changes in comparison with the previous edition: repeatability and reproducibility data have been added from a European interlaboratory comparison organized by the German Federal Institute for Materials Research and Testing BAM in 2013 (see Annex A). Acco

37、rding to the CEN/CENELEC Internal Regulations, the national standards organizations of the following countries are bound to implement this European Standard: Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia, France, Germany

38、, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and the United Kingdom. BS EN 16170:2016EN 16170:2016 (E) 4 Introduction This European Standard is applicable and v

39、alidated for several types of matrices as indicated in Table 1 (see Annex A for the results of validation). Table 1 Matrices for which this European Standard is applicable and validated Matrix Materials used for validation Sludge Municipal sludge Biowaste Compost Soil Soil WARNING Persons using this

40、 European Standard should be familiar with usual laboratory practice. This European Standard does not purport to address all of the safety problems, if any, associated with its use. It is the responsibility of the user to establish appropriate safety and health practices and to ensure compliance wit

41、h any national regulatory conditions. IMPORTANT It is absolutely essential that tests conducted according to this European Standard be carried out by suitably trained staff. BS EN 16170:2016EN 16170:2016 (E) 5 1 Scope This European Standard specifies a method for the determination of the following e

42、lements in aqua regia or nitric acid digest solutions of sludge, treated biowaste and soil: Aluminium (Al), antimony (Sb), arsenic (As), barium (Ba), beryllium (Be), bismuth (Bi), boron (B), cadmium (Cd), calcium (Ca), cerium (Ce), chromium (Cr), cobalt (Co), copper (Cu), gallium (Ga), indium (In),

43、iron (Fe), lanthanum (La), lead (Pb), lithium (Li), magnesium (Mg), manganese (Mn), mercury (Hg), molybdenum (Mo), neodymium (Nd), nickel (Ni), phosphorus (P), potassium (K), praseodymium (Pr), samarium (Sm), scandium (Sc), selenium (Se), silicon (Si), silver (Ag), sodium (Na), strontium (Sr), sulfu

44、r (S), tellurium (Te), thallium (Tl), thorium (Th), tin (Sn), titanium (Ti), tungsten (W), uranium (U), vanadium (V), zinc (Zn) and zirconium (Zr). The method has been validated for the elements given in Table A.1. The method is applicable for the other elements listed above, provided the user has v

45、erified the applicability. 2 Normative references The following documents, in whole or in part, are normatively referenced in this document and are indispensable for its application. For dated references, only the edition cited applies. For undated references, the latest edition of the referenced do

46、cument (including any amendments) applies. EN 15934, Sludge, treated biowaste, soil and waste Calculation of dry matter fraction after determination of dry residue or water content EN 16173, Sludge, treated biowaste and soil Digestion of nitric acid soluble fractions of elements EN 16174, Sludge, tr

47、eated biowaste and soil Digestion of aqua regia soluble fractions of elements EN ISO 3696, Water for analytical laboratory use Specification and test methods (ISO 3696) 3 Principle Digests of sludge, treated biowaste or soil with nitric acid or aqua regia (see EN 16173 and EN 16174) are analysed by

48、inductively coupled plasma optical emission spectrometry (ICP-OES) using sequential or simultaneous optical systems and axial or radial viewing of the plasma. The instrument measures characteristic emission spectra by optical spectrometry. Analyte species originating in the digest solution are nebul

49、ised and the resulting aerosol is transported to the plasma torch. Element-specific emission spectra are produced by a radio-frequency inductively coupled plasma. The spectra are dispersed by a grating spectrometer, and the intensities of the emission lines are monitored by photosensitive devices. NOTE For the determination of tin only aqua regia extraction applies (EN 16174). 4 Interferences Background correction is required for trace element determination. Background correction is not required in cases of line broadening where a background correction measurement