EN 16192-2011 en Characterization of waste - Analysis of eluates《废物特性描述 洗出液的分析》.pdf

1、raising standards worldwideNO COPYING WITHOUT BSI PERMISSION EXCEPT AS PERMITTED BY COPYRIGHT LAWBSI Standards PublicationBS EN 16192:2011Characterization of waste Analysis of eluatesBS EN 16192:2011 BRITISH STANDARDNational forewordThis British Standard is the UK implementation of EN 16192:2011.It

2、supersedes BS EN 12506:2003 and BS EN 13370:2003 which arewithdrawn.The UK participation in its preparation was entrusted to TechnicalCommittee B/508/3, Characterization of waste.A list of organizations represented on this committee can beobtained on request to its secretary.This publication does no

3、t purport to include all the necessaryprovisions of a contract. Users are responsible for its correctapplication. The British Standards Institution 2012. Published by BSI StandardsLimited 2012ISBN 978 0 580 72731 3ICS 13.030.99Compliance with a British Standard cannot confer immunity fromlegal oblig

4、ations.This British Standard was published under the authority of theStandards Policy and Strategy Committee on 30 April 2012.Amendments issued since publicationDate T e x t a f f e c t e dBS EN 16192:2011EUROPEAN STANDARD NORME EUROPENNE EUROPISCHE NORM EN 16192 November 2011 ICS 13.030.99 Supersed

5、es EN 12506:2003, EN 13370:2003English Version Characterization of waste - Analysis of eluates Caractrisation des dchets - Analyse des luats Charakterisierung von Abfllen - Analyse von Eluaten This European Standard was approved by CEN on 15 October 2011. CEN members are bound to comply with the CEN

6、/CENELEC Internal Regulations which stipulate the conditions for giving this European Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references concerning such national standards may be obtained on application to the CEN-CENELEC Management Cen

7、tre or to any CEN member. This European Standard exists in three official versions (English, French, German). A version in any other language made by translation under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC Management Centre has the same status as th

8、e official versions. CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romani

9、a, Slovakia, Slovenia, Spain, Sweden, Switzerland and United Kingdom. EUROPEAN COMMITTEE FOR STANDARDIZATION COMIT EUROPEN DE NORMALISATION EUROPISCHES KOMITEE FR NORMUNG Management Centre: Avenue Marnix 17, B-1000 Brussels 2011 CEN All rights of exploitation in any form and by any means reserved wo

10、rldwide for CEN national Members. Ref. No. EN 16192:2011: EBS EN 16192:2011EN 16192:2011 (E) 2 Contents Page Foreword 3Introduction .41 Scope 52 Normative references 53 Terms and definitions .64 Sample pretreatment .75 Blank determination 76 Interference 87 Selection of the suitable test method 88 E

11、xpression of results . 119 Test report . 11Annex A (informative) Validation of EN 12506:2003 and EN 13370:2003 . 12A.1 General . 12A.2 Interlaboratory study 12A.3 Selection of laboratories 12A.4 Selection of samples 12A.5 Validation scope . 13A.6 Results and statistics . 16A.7 Conclusion 24Annex B (

12、informative) Additional validation data . 25B.1 Round robin test for the determination of Ba, Cd, Cr, Mo, Sb and Se in eluates 25B.1.1 General . 25B.1.2 Round robin samples . 25B.1.3 Results of the round robin test . 25B.1.4 Conclusion from the round robin test 29B.2 Round robin tests in the framewo

13、rk of acceptability of waste at landfills . 29Bibliography . 31BS EN 16192:2011EN 16192:2011 (E) 3 Foreword This document (EN 16192:2011) has been prepared by Technical Committee CEN/TC 292 “Characterization of waste”, the secretariat of which is held by NEN. This European Standard shall be given th

14、e status of a national standard, either by publication of an identical text or by endorsement, at the latest by May 2012, and conflicting national standards shall be withdrawn at the latest by May 2012. Attention is drawn to the possibility that some of the elements of this document may be the subje

15、ct of patent rights. CEN and/or CENELEC shall not be held responsible for identifying any or all such patent rights. This document supersedes EN 12506:2003 and EN 13370:2003. Details of significant technical changes between this European Standard and the previous edition are: This European Standard,

16、 EN 16192, is now a single document (instead of two) for the analysis of eluates specifying methods for the determination of the parameters pH, ammonium, AOX, As, Ba, Cd, Cl-, easily liberatable CN-, Co, Cr, Cr(VI), Cu, DOC/TOC, electrical conductivity, F-, Hg, Mo, Ni, NO2-, Pb, phenol index, total

17、S, Sb, Se, SO42-, TDS, V and Zn in aqueous eluates for the characterization of waste. In Clause 7 the parameters, previously described in two documents, are now all integrated in Table 1. In Table 1 for all parameters EN and ISO standards are updated, removed if withdrawn and new relevant standards

18、are added, i.e.: addition of the parameters Sb and Se together with the related analytical methods; revision of the standards EN ISO 11885 (ICP-OES) and EN ISO 10304-1 (IC); addition of the ICP-MS method (EN ISO 17294-1:2006 and EN ISO 17294-2:2004); addition of the AAS with graphite furnace techniq

19、ue (EN ISO 15586:2003); addition of the flow analysis techniques for Cl-(EN ISO 15682:2001), Cr(VI) (EN ISO 23913:2009) and SO42-(ISO 22743:2006); addition of the parameter TDS (total dissolved solids) together with the related analytical method; addition of the parameter DOC (dissolved organic carb

20、on) to the parameter TOC (total organic carbon); revision of the standards EN ISO 11732 (ammonium by flow analyser); replacement of EN 1485 (AOX) by EN ISO 9562:2004; revision and addition of new standards for Hg determination EN 1483 and EN ISO 17852. In Annex B (informative) additional validation

21、data are added obtained from a round robin test for the determination of Ba, Cd, Cr, Mo, Sb and Se in eluates and from round robin tests in the framework of acceptability of waste at landfills, both organized in Belgium. According to the CEN/CENELEC Internal Regulations, the national standards organ

22、izations of the following countries are bound to implement this European Standard: Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Por

23、tugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland and United Kingdom. BS EN 16192:2011EN 16192:2011 (E) 4 Introduction This European standard is intended to be used for the characterization of waste as defined in the Council Directive 75/442/EEC on waste, as amended by Council Directive

24、 91/156/EEC of 18th March 1991, and national regulations, whose final destination for disposal is landfill. In the Council Decision of 19 December 2002 establishing criteria and procedures for the acceptance of waste at landfills pursuant to Article 16 of and Annex II to Directive 1999/31/EC, the te

25、st methods are described for determining the acceptability of waste at landfills. In section 3 of the Annex of this Decision the European standards EN 12506 and EN 13370 are included which are replaced by this European Standard. This European Standard deals with the determination of chemical constit

26、uents, electrical conductivity, pH and total dissolved solids (TDS) in eluates which have been obtained by leaching of waste samples for example using EN 12457 “Characterization of waste - Leaching - Compliance test for leaching of granular waste materials and sludges” (Part 1 to Part 4). In princip

27、le, it may be used for the analysis of every kind of eluate as long as the performance characteristics of the applied analytical method fulfill the specific requirements. BS EN 16192:2011EN 16192:2011 (E) 5 1 Scope This European Standard specifies methods for the determination of the parameters pH,

28、ammonium, AOX, As, Ba, Cd, Cl-, easily liberatable CN-, Co, Cr, Cr(VI), Cu, DOC/TOC, electrical conductivity, F-, Hg, Mo, Ni, NO2-, Pb, phenol index, total S, Sb, Se, SO42-, TDS, V and Zn in aqueous eluates for the characterization of waste. 2 Normative references The following referenced documents

29、are indispensable for the application of this document. For dated references, only the edition cited applies. For undated references, the latest edition of the referenced document (including any amendments) applies. EN 1483:2007, Water quality Determination of mercury Method using atomic absorption

30、spectrometry EN 1484:1997, Water analysis Guidelines for the determination of total organic carbon (TOC) and dissolved organic carbon (DOC) EN 15216:2007, Characterization of waste Determination of total dissolved solids (TDS) in water and eluates EN 26777:1993, Water quality Determination of nitrit

31、e Molecular absorption spectrometric method (ISO 6777:1984) EN 27888:1993, Water quality Determination of electrical conductivity (ISO 7888:1985) prEN ISO 5667-3, Water quality Sampling Part 3: Preservation and handling of water samples (ISO/DIS 5667-3:2010) EN ISO 9562:2004, Water quality Determina

32、tion of adsorbable organically bound halogens (AOX) (ISO 9562:2004) EN ISO 10304-1:2009, Water quality Determination of dissolved anions by liquid chromatography of ions Part 1: Determination of bromide, chloride, fluoride, nitrate, nitrite, phosphate and sulfate (ISO 10304-1:2007) EN ISO 10304-3:19

33、97, Water quality Determination of dissolved anions by liquid chromatography of ions Part 3: Determination of chromate, iodide, sulfite, thiocyanate and thiosulfate (ISO 10304-3:1997) EN ISO 11732:2005, Water quality Determination of ammonium nitrogen Method by flow analysis (CFA and FIA) and spectr

34、ometric detection (ISO 11732:2005) EN ISO 11885:2009, Water quality Determination of selected elements by inductively coupled plasma optical emission spectrometry (ICP-OES) (ISO 11885:2007) EN ISO 11969:1996, Water quality Determination of arsenic Atomic absorption spectrometric method (hydride tech

35、nique) (ISO 11969:1996) EN ISO 13395:1996, Water quality Determination of nitrite nitrogen and nitrate nitrogen and the sum of both by flow analysis (CFA and FIA) and spectrometric detection (ISO 13395:1996) EN ISO 14402:1999, Water quality Determination of the phenol index by flow analysis (FIA and

36、 CFA) (ISO 14402:1999) EN ISO 14403:2002, Water quality Determination of total cyanide and free cyanide by continuous flow analysis (ISO 14403:2002) EN ISO 14911:1999, Water quality Determination of dissolved Li+, Na+, NH4+, K+, Mn2+, Ca2+, Mg2+, Sr2+and Ba2+using ion chromatography Method for water

37、 and waste water (ISO 14911:1998) EN ISO 15586:2003, Water quality Determination of trace elements using atomic absorption spectrometry with graphite furnace (ISO 15586:2003) BS EN 16192:2011EN 16192:2011 (E) 6 EN ISO 15682:2001, Water quality Determination of chloride by flow analysis (CFA and FIA)

38、 and photometric and potentiometric detection (ISO 15682:2000) EN ISO 17294-1:2006, Water quality Application of inductively coupled plasma mass spectrometry (ICP-MS) Part 1: General guidelines (ISO 17294-1:2004) EN ISO 17294-2:2004, Water quality Application of inductively coupled plasma mass spect

39、rometry (ICP-MS) Part 2: Determination of 62 elements (ISO 17294-2:2003) EN ISO 17852:2008, Water quality Determination of mercury Method using atomic fluorescence spectrometry (ISO 17852:2006) EN ISO 23913:2009, Water quality Determination of chromium(VI) Method using flow analysis (FIA and CFA) an

40、d spectrometric detection (ISO 23913:2006) ISO 6439:1990, Water quality Determination of phenol index 4-Aminoantipyrine spectrometic methods after distillation ISO 6703-2:1984, Water quality Determination of cyanide Part 2: Determination of easily liberatable cyanide ISO 7150-1:1984, Water quality D

41、etermination of ammonium Part 1: Manual spectrometric method ISO 8288:1986, Water quality Determination of cobalt, nickel, copper, zinc, cadmium and lead Flame atomic absorption spectrometric methods ISO 9297:1989, Water quality Determination of chloride Silver nitrate titration with chromate indica

42、tor (Mohrs method) ISO 9965:1993, Water quality Determination of selenium Atomic absorption spectrometric method (hydride technique) ISO 10359-1:1992, Water quality Determination of fluoride Part 1: Electrochemical probe method for potable and lightly polluted water ISO 10523:2008, Water quality Det

43、ermination of pH ISO 11083:1994, Water quality Determination of chromium (VI) Spectrometric method using 1,5-diphenylcarbazide ISO 22743:2006, Water quality Determination of sulfates Method by continuous flow analysis (CFA) 3 Terms and definitions For the purposes of this document, the following ter

44、ms and definitions apply. 3.1 sample portion of material selected from a larger quantity of material 3.2 eluate solution obtained by a leaching test 3.3 laboratory sample sample or subsample(s) sent to or received by the laboratory 3.4 test sample; analytical sample sample, prepared from the laborat

45、ory sample, from which test portions are removed for testing or analysis BS EN 16192:2011EN 16192:2011 (E) 7 3.5 test portion; analytical portion quantity of material of proper size for measurement of the concentration or other properties of interest, removed from the test sample NOTE 1 The test por

46、tion can be taken from the laboratory sample directly if no preparation of sample is required (e.g. with liquids), but usually it is taken from the prepared test sample. NOTE 2 A unit or increment of proper homogeneity, size and fineness, needing no further preparation, can be a test portion. 3.6 le

47、achant aqueous solution used in a leaching test 3.7 leaching test laboratory test for the determination of the release of matter from a waste into water or an aqueous solution 4 Sample pretreatment The eluate shall be analyzed for the total content of its constituents. If precipitation occurs betwee

48、n the preparation of the eluate and the analysis it is necessary to ensure by appropriate methods (e.g. redissolution, separate analysis of solution and precipitate) that the total content of the parameters of interest is determined. If the eluate results from a procedure including 0,45 m membrane f

49、iltration analytical results refer to the content dissolved by the leaching process. Eluates are susceptible to be changed to different extents as a result of physical, chemical or biological reactions which may take place between the time of leaching and the analysis. pH shall be determined immediately after preparation of the eluates and prior to sample pretreatment. It is therefore ess