EN 16738-2015 en Emission safety of combustible air fresheners - Test methods《易燃空气清新剂的排放安全性 测试方法》.pdf

1、BSI Standards PublicationBS EN 16738:2015Emission safety of combustibleair fresheners Test methodsBS EN 16738:2015 BRITISH STANDARDNational forewordThis British Standard is the UK implementation of EN 16738:2015.The UK participation in its preparation was entrusted to TechnicalCommittee EH/2/5, Emis

2、sions to internal environments.A list of organizations represented on this committee can beobtained on request to its secretary.This publication does not purport to include all the necessaryprovisions of a contract. Users are responsible for its correctapplication. The British Standards Institution

3、2015.ublished by BSI Standards Limited 2015ISBN 978 0 580 86158 1ICS 13.040.20Compliance with a British Standard cannot confer immunity fromlegal obligations.This British Standard was published under the authority of theStandards Policy and Strategy Committee on 30 November 2015.Amendments/corrigend

4、a issued since publicationDate T e x t a f f e c t e dBS EN 16738:2015EUROPEAN STANDARD NORME EUROPENNE EUROPISCHE NORM EN 16738 November 2015 ICS 13.040.20 English Version Emission safety of combustible air fresheners - Test methods Scurit des missions des dsodorisants combustion - Mthodes dessais

5、Emissionssicherheit brennbarer Lufterfrischer - Testverfahren This European Standard was approved by CEN on 17 October 2015. CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this European Standard the status of a national standard wi

6、thout any alteration. Up-to-date lists and bibliographical references concerning such national standards may be obtained on application to the CEN-CENELEC Management Centre or to any CEN member. This European Standard exists in three official versions (English, French, German). A version in any othe

7、r language made by translation under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC Management Centre has the same status as the official versions. CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic,

8、Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and United Kingdom. EUROPEAN COMMI

9、TTEE FOR STANDARDIZATION COMIT EUROPEN DE NORMALISATION EUROPISCHES KOMITEE FR NORMUNG CEN-CENELEC Management Centre: Avenue Marnix 17, B-1000 Brussels 2015 CEN All rights of exploitation in any form and by any means reserved worldwide for CEN national Members. Ref. No. EN 16738:2015 EBS EN 16738:20

10、15EN 16738:2015 (E) 2 Contents Page European foreword . 3 1 Scope 4 2 Normative references 4 3 Terms and definitions . 5 4 Test methods 6 4.1 Principles . 6 4.2 Apparatus . 7 4.3 General test conditions . 7 4.3.1 General 7 4.3.2 Test chamber volume 7 4.3.3 Number of test specimens at the same time i

11、n the test chamber 7 4.3.4 Positioning of test specimens in the test chamber 8 4.3.5 Air supply quality and background concentration . 9 4.3.6 Test specimen preparation and ignition 9 4.3.7 Temperature inside the test chamber during the test . 10 4.3.8 Relative air humidity inside the test chamber d

12、uring the test 10 4.3.9 Oxygen concentration inside the test chamber during the test 10 4.3.10 Control of the burning process 10 4.3.11 Burn rates . 11 4.3.12 Sampling and analysis of VOC (benzene, naphthalene) . 11 4.3.13 Sampling and analysis of formaldehyde 11 4.3.14 Sampling and analysis of NO2(

13、nitrogen dioxide) . 12 4.3.15 Sampling and analysis of SO2(sulfur dioxide) . 12 4.3.16 Sampling analysis of CO . 12 4.4 Procedures of testing 12 4.5 Calculation of results 12 5 Test report 13 Annex A (informative) Description of sorbent types 14 Bibliography . 15 BS EN 16738:2015EN 16738:2015 (E) 3

14、European foreword This document (EN 16738:2015) has been prepared by Technical Committee CEN/TC 421 “Project Committee - Emission safety of combustible air fresheners”, the secretariat of which is held by UNI. This European Standard shall be given the status of a national standard, either by publica

15、tion of an identical text or by endorsement, at the latest by May 2016, and conflicting national standards shall be withdrawn at the latest by May 2016. Attention is drawn to the possibility that some of the elements of this document may be the subject of patent rights. CEN and/or CENELEC shall not

16、be held responsible for identifying any or all such patent rights. According to the CEN-CENELEC Internal Regulations, the national standards organizations of the following countries are bound to implement this European Standard: Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, E

17、stonia, Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and the United Kingdom. BS EN 16738:2015EN 1

18、6738:2015 (E) 4 1 Scope This European standard specifies a test method for the determination of emissions resulting from the use of combustible air fresheners into indoor air by means of chamber operation according to EN ISO 16000-9. This standard defines specific testing conditions for the measurem

19、ent of the emissions from combustible air fresheners which minimize the effect of the testing on the combustion process. This standard provides a measurement method for the determination of the following non-exhaustive list of target substances emitted directly from the burning process: VOC; Benzene

20、; Naphthalene; Formaldehyde. The measurement method can allow the determination of other substances. This standard provides additional information on the optional measurement of the following substances: SO2; NOx; CO. This standard is not suitable for the quantitative determination of particulate ma

21、tter. This standard does not apply to non-combustible air fresheners and loose incenses. Any scented candle with burning time shorter than 2,5 h is outside the scope of the standard. 2 Normative references The following documents, in whole or in part, are normatively referenced in this document and

22、are indispensable for its application. For dated references, only the edition cited applies. For undated references, the latest edition of the referenced document (including any amendments) applies. EN 717-1, Wood-based panels - Determination of formaldehyde release - Part 1: Formaldehyde emission b

23、y the chamber method EN 14211, Ambient air - Standard method for the measurement of the concentration of nitrogen dioxide and nitrogen monoxide by chemiluminescence EN 14212, Ambient air - Standard method for the measurement of the concentration of sulphur dioxide by ultraviolet fluorescence EN 1462

24、6, Ambient air - Standard method for the measurement of the concentration of carbon monoxide by non-dispersive infrared spectroscopy EN 14789, Stationary source emissions - Determination of volume concentration of oxygen (O2) - Reference method - Paramagnetism BS EN 16738:2015EN 16738:2015 (E) 5 EN

25、14792, Stationary source emissions - Determination of mass concentration of nitrogen oxides (NOx) - Reference method: Chemiluminescence EN 15058, Stationary source emissions - Determination of the mass concentration of carbon monoxide (CO) - Reference method: Non-dispersive infrared spectrometry EN

26、15426, Candles - Specification for sooting behaviour EN ISO 16000-9, Indoor air - Part 9: Determination of the emission of volatile organic compounds from building products and furnishing - Emission test chamber method (ISO 16000-9) EN ISO 16017-1, Indoor, ambient and workplace air - Sampling and an

27、alysis of volatile organic compounds by sorbent tube/thermal desorption/capillary gas chromatography - Part 1: Pumped sampling (ISO 16017-1) ISO 16000-3, Indoor air Part 3: Determination of formaldehyde and other carbonyl compounds in indoor air and test chamber air Active sampling method ISO 16000-

28、6, Indoor air Part 6: Determination of volatile organic compounds in indoor and test chamber air by active sampling on Tenax TA sorbent, thermal desorption and gas chromatography using MS or MS-FID 3 Terms and definitions For the purposes of this document, the following terms and definitions apply.

29、3.1 combustible air freshener product constituted by a fragranced combustible material which by action of combustion releases in the air smelling substances which it contains (e.g.: scented candle, incense, catalytic lamp, etc.) 3.2 candle one or more combustible wicks supported by a material that c

30、onstitutes a fuel, which is solid, semisolid or quasi-rigid at room temperature (20 C to 27 C), the combined function of which is to sustain a light-producing flame Note 1 to entry: It can also contain additives, which are used for colour, odour, stability, or to modify the burning characteristics;

31、including candles with decoration attached to or contained within them. 3.2.1 scented candle candle in the fuel of which a fragrance intended to be released is added 3.3 indoor air air within an enclosed space, e.g. dwelling or public building 3.4 scented oil lamp (for indoor use) container in which

32、 scented oil is burned at the wick BS EN 16738:2015EN 16738:2015 (E) 6 3.5 incense dried plants (herbs or wood) which are pulverized and mixed with resins Note 1 to entry: The sticks in incense sticks may be of sandalwood, bamboo or similar material that has the ability to burn together with the wra

33、pped plant ingredients. Some incense mixtures are composed of dried and finely chopped herbs, woods and roots, others from resins and balsams as small pellets or granules. Incense may be mixtures but may also consist of one single type of incense based on single plants or plant parts. Besides, natur

34、al or synthetic essential oils can be added. Four common types of incense exist: loose incense (granulate or powder), cones, incense sticks with and without solid stick. 3.6 catalytic lamp system based on the catalytic combustion of a combustible liquid by using a catalytic burner composed of porous

35、 material which is made of synthetic or mineral materials Note 1 to entry: The product requires also a wick that feeds the burner from the liquid container by capillarity, a cap designed to stop operation of the catalytic lamp and openwork mounting for protection and ventilation. The catalytic lamp

36、diffuses perfume and combustibles in the air. It perfumes and destroys smells, at the same time. 3.6.1 catalytic burner burner composed of a porous material made from synthetic or mineral material and a specific catalyst in the catalytic oxidation of solvent which favours the production of carbon di

37、oxide and water 3.7 unit specific emission rate SERUproduct specific rate describing the mass of a volatile organic compound emitted per unit (U) of combustible air freshener per unit of time at a given time from the start of the test 3.8 burn rate BR mass of material burned per unit of time under t

38、est conditions 3.9 background of the test chamber emission level of the test chamber operated with all the equipment except the specimen 3.10 test specimen sample intended for emission testing in an emission test chamber 4 Test methods 4.1 Principles The principle of the test is to determine the uni

39、t specific emission rate (SERu) of emissions resulting from the use of combustible air fresheners. The test is performed under controlled conditions in an emission test chamber according to EN ISO 16000-9. The air in the emission test chamber is fully mixed and measurements of a substance concentrat

40、ion in the air at the test chamber outlet are representative of the emission test chamber concentrations for that substance. BS EN 16738:2015EN 16738:2015 (E) 7 Unit specific emission rates, SERU, at a given time, t, are calculated from the emission test chamber air concentrations, C, the air change

41、 rate, n, and number of test specimens at the same time in the test chamber, N. With knowledge of the concentration in the outlet air, the air flow through the emission test chamber and the number of the test specimens, the unit specific emission rates of emissions from the product under test can be

42、 determined. 4.2 Apparatus Dynamic environmental emission test chamber according to EN ISO 16000-9, and a suitable number of wire mesh cylinders type 2 according to EN 15426. 4.3 General test conditions 4.3.1 General Combustible air fresheners are ignited and burned in the test chamber using the par

43、ameters specified in Table 1 until a state of equilibration is reached. Dynamic emission test chamber according to EN ISO 16000-9 using inlet air at 23 C and 50 % relative humidity with 2 air changes per hour. If the burn rates data outside the chamber are not available the data can be provided by a

44、 burning test run outside the test chamber and for candles it will be according to EN 15426 for the minimum testing time in the test chamber. The test protocol and test conditions of the chamber experiment are defined in such a way that standardized (well controlled) burning processes inside the cha

45、mber are guaranteed. Parameters to be controlled are: air mixing inside the chamber; avoidance of disturbance of the flame, burning in draught free conditions and no flickering; composition of the stand on which the candle is positioned; temperature; relative humidity; oxygen concentration. 4.3.2 Te

46、st chamber volume The test chamber volume shall be 1,0 m3 0,1 m3. Test chambers with larger volumes may be accepted provided that sufficient data support evidence of comparable results. Sufficient data requires a validation study with a minimum of 10 comparative tests between a 1 m3chamber and anoth

47、er chamber and successful participation in the Round Robin Test with a minimum of 5 participating laboratories. 4.3.3 Number of test specimens at the same time in the test chamber Number of test specimens as defined in Table 1. BS EN 16738:2015EN 16738:2015 (E) 8 Table 1 Chamber test Type of test sp

48、ecimen Burning time in h Air change per hour (n) in h1Timeeq(equilibration time before air sampling) in minutes Number of specimens inside the chamber Number of specimens outside the chamber Sampling time in minutes Scented candle 4 2,0 0,2 120 5 2 3 60 5 Scented candle 2,5 and 4 2,0 0,2 120 5 1 1 6

49、0 5 Sampling for incense shall be stopped at the end of combustion of the first test specimen to a maximum of 60 min. 4.3.4 Positioning of test specimens in the test chamber 4.3.4.1 Scented candle, incense and oil lamp Place the test specimens in an upright position on a heat resistant, non-flammable surface. Non free-standing candles and incense sticks are placed in a suitable holder which does not affect the burning property and the emissions. Free-standing test specimens are placed on a glass surface that does not a