EN 16766-2017 en Bio-based solvents - Requirements and test methods.pdf

1、Bio-based solvents Requirements and test methodsBS EN 16766:2017BSI Standards PublicationWB11885_BSI_StandardCovs_2013_AW.indd 1 15/05/2013 15:06EUROPEAN STANDARD NORME EUROPENNE EUROPISCHE NORM EN 16766 November 2017 ICS 13.020.55; 87.060.30 Supersedes CEN/TS 16766:2015English Version Bio-based sol

2、vents - Requirements and test methods Solvants biosourcs - Exigences et mthodes dessais Biobasierte Lsemittel - Anforderungen und Prfverfahren This European Standard was approved by CEN on 6 September 2017. CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the

3、 conditions for giving this European Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references concerning such national standards may be obtained on application to the CEN-CENELEC Management Centre or to any CEN member. This European Standard

4、exists in three official versions (English, French, German). A version in any other language made by translation under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC Management Centre has the same status as the official versions. CEN members are the national

5、 standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Serbia,

6、 Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and United Kingdom. EUROPEAN COMMITTEE FOR STANDARDIZATION COMIT EUROPEN DE NORMALISATION EUROPISCHES KOMITEE FR NORMUNG CEN-CENELEC Management Centre: Avenue Marnix 17, B-1000 Brussels 2017 CEN All rights of exploitation in any form and by any

7、 means reserved worldwide for CEN national Members. Ref. No. EN 16766:2017 ENational forewordThis British Standard is the UK implementation of EN 16766:2017. It supersedes PD CEN/TS 16766:2015, which is withdrawn.The UK participation in its preparation was entrusted to Technical Committee MI/2, Bio-

8、based products.A list of organizations represented on this committee can be obtained on request to its secretary.This publication does not purport to include all the necessary provisions of a contract. Users are responsible for its correct application. The British Standards Institution 2017 Publishe

9、d by BSI Standards Limited 2017ISBN 978 0 580 95144 2ICS 87.060.30; 13.020.55Compliance with a British Standard cannot confer immunity from legal obligations. This British Standard was published under the authority of the Standards Policy and Strategy Committee on 30 November 2017.Amendments/corrige

10、nda issued since publicationDate Text affectedBRITISH STANDARDBS EN 16766:2017EUROPEAN STANDARD NORME EUROPENNE EUROPISCHE NORM EN 16766 November 2017 ICS 13.020.55; 87.060.30 Supersedes CEN/TS 16766:2015English Version Bio-based solvents - Requirements and test methods Solvants biosourcs - Exigence

11、s et mthodes dessais Biobasierte Lsemittel - Anforderungen und Prfverfahren This European Standard was approved by CEN on 6 September 2017. CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this European Standard the status of a natio

12、nal standard without any alteration. Up-to-date lists and bibliographical references concerning such national standards may be obtained on application to the CEN-CENELEC Management Centre or to any CEN member. This European Standard exists in three official versions (English, French, German). A vers

13、ion in any other language made by translation under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC Management Centre has the same status as the official versions. CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, C

14、zech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and United

15、Kingdom. EUROPEAN COMMITTEE FOR STANDARDIZATION COMIT EUROPEN DE NORMALISATION EUROPISCHES KOMITEE FR NORMUNG CEN-CENELEC Management Centre: Avenue Marnix 17, B-1000 Brussels 2017 CEN All rights of exploitation in any form and by any means reserved worldwide for CEN national Members. Ref. No. EN 167

16、66:2017 EBS EN 16766:2017EN 16766:2017 (E) 2 Contents Page European foreword . 3 Introduction 4 1 Scope 6 2 Normative references 6 3 Terms and definitions . 7 4 General information on the purpose of solvents . 7 5 Performance . 7 5.1 General 7 5.2 Technical performance properties . 8 5.2.1 Chemical

17、composition . 8 5.2.2 Solvency power 8 5.2.3 Distillation characteristics 8 5.2.4 Evaporation rate 9 5.2.5 Colour 9 5.2.6 Density 9 5.2.7 Kinematic viscosity . 9 6 Health, safety and environmental requirements . 10 7 Bio-based content 10 8 Sustainability information 11 9 Declaration and product labe

18、lling . 12 Annex A (normative) Determination of Hansen solubility parameters 13 A.1 Generalities 13 A.2 Calculation of the Hansen solubility parameters for individual solvents . 14 A.2.1 General . 14 A.2.2 Estimated values 14 A.2.3 Experimental dispersion forces 15 A.2.4 Experimental dipole forces 1

19、5 A.2.5 Experimental hydrogen bonding 15 A.3 Calculation of Hansen solubility parameters for solvent blends 15 A.4 Reporting 15 Annex B (informative) Template for B2B communication. 16 Bibliography . 19 BS EN 16766:2017EN 16766:2017 (E) 3 European foreword This document (EN 16766:2017) has been prep

20、ared by Technical Committee CEN/TC 411 “Bio-based products”, the secretariat of which is held by NEN. This European Standard shall be given the status of a national standard, either by publication of an identical text or by endorsement, at the latest by May 2018, and conflicting national standards s

21、hall be withdrawn at the latest by May 2018. Attention is drawn to the possibility that some of the elements of this document may be the subject of patent rights. CEN shall not be held responsible for identifying any or all such patent rights. This document has been prepared under a mandate given to

22、 CEN by the European Commission and the European Free Trade Association. This document supersedes CEN/TS 16766:2015. M/491 1 requested the development of European Standards for solvents and surfactants in relation to bio-based product aspects. This document has been prepared by CEN/TC 411/WG 2 “Bio

23、based solvents”, the secretariat of which is held by the European Solvents Industry Group and NEN. The following is a list of significant technical changes between this European Standard and the Technical Specification: introduction of the (final) publications on bio-based content determination, sus

24、tainability and life-cycle assessment developed under CEN/TC 411; change of the requirement that a bio-based solvent shall comply to similar sustainability criteria as comparable regular solvents towards an option, because this is very hard to determine for a solvents producer and basically the task

25、 of the user; expanding the classification in Table 1 to fulfilling either bio-based carbon or bio-based content minima; further clarification of the sustainability requirements. According to the CEN-CENELEC Internal Regulations, the national standards organisations of the following countries are bo

26、und to implement this European Standard: Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portug

27、al, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and the United Kingdom. BS EN 16766:2017EN 16766:2017 (E) 4 Introduction Bio-based products from forestry and agriculture have a long history of application, such as paper, board and various chemicals and materials. The last

28、 decades have seen the emergence of new bio-based products in the market. Some of the reasons for the increased interest lie in the bio-based products benefits in relation to the depletion of fossil resources and climate change. Bio-based products may also provide additional product functionalities.

29、 This has triggered a wave of innovation with the development of knowledge and technologies allowing new transformation processes and product development. Acknowledging the need for common standards for bio-based products, the European Commission issued mandate M/4921), resulting in a series of stan

30、dards developed by CEN/TC 411, with a focus on bio-based products other than food, feed and biomass for energy applications. The standards of CEN/TC 411 “Bio-based products” provide a common basis on the following aspects: common terminology; bio-based content determination; life Cycle Assessment (L

31、CA); sustainability aspects; declaration tools. It is important to understand what the term bio-based product covers and how it is being used. The term bio-based means derived from biomass 2. Bio-based products (bottles, insulation materials, wood and wood products, paper, solvents, chemical interme

32、diates, composite materials, etc.) are products which are wholly or partly derived from biomass. It is essential to characterize the amount of biomass contained in the product by for instance its bio-based content or bio-based carbon content. The bio-based content of a product does not provide infor

33、mation on its environmental impact or sustainability, which may be assessed through LCA and sustainability criteria. In addition, transparent and unambiguous communication within bio-based value chains is facilitated by a harmonized framework for certification and declaration. This European Standard

34、 has been developed with the aim to fulfil part of a Mandate 1 to describe the technical requirements of bio-based solvents in relation to bio-based product aspects. Solvents are liquids which have the ability to dissolve, suspend or extract other materials. In Europe, thousands of producers and man

35、ufacturers and more than 10 million workers use solvents every day. The solvent producing industry is composed of both small and medium-sized enterprises (SMEs) as well as multinationals. Downstream users generally tend to be SMEs and micro-SMEs. Solvents are today mainly produced from fossil feedst

36、ock. There are efforts to replace these with solvents produced from renewable resources, i.e. bio-based solvents. The criteria of the Regulation on the Registration, Evaluation, Authorization and Restriction of Chemicals (REACH) 3 have been considered in the discussions that have led to this Europea

37、n Standard. 1) A Mandate is a standardization task embedded in European trade laws. Mandate M/492 is addressed to the European Standardization bodies, CEN, CENELEC and ETSI, for the development of horizontal European Standards for bio-based products. BS EN 16766:2017EN 16766:2017 (E) 5 This document

38、 provides an approach that can be taken to describe the technical requirements of bio-based solvents in relation to bio-based product. The purpose of this document is to define how the criteria of performance, health, safety and environment can be determined (measured and calculated) for the bio-bas

39、ed solvent placed on the market. This approach intends to strengthen the reputation of “bio-based solvents” and customer confidence. Future work by the solvents industry is planned to enable a comparison between bio-based and fossil-based solvents they intend to replace in terms of the impact on the

40、 three pillars of sustainability as in EN 16751. This information is essential to check the sustainability impact of the use of all solvents over their whole life cycle. This European Standard builds upon the horizontal standards on bio-based products developed by CEN/TC 411. It provides additional,

41、 product specific, details relevant for bio-based solvents. BS EN 16766:2017EN 16766:2017 (E) 6 1 Scope This European Standard sets the requirements for bio-based solvents in terms of their bio-based content, their technical properties and test methods. It lays down the characteristics and details f

42、or assessment of bio-based solvents that: are fit for purpose in terms of performance related properties; comply with the health, safety and environmental requirements which apply generally to solvents; and are derived from biomass. This European Standard specifies solvent classes, based on the perc

43、entage of bio-based carbon content and bio-based content. NOTE EN 16575 defines the term “bio-based” as derived from biomass and clarifies that “bio-based” does not imply “biodegradable”. In addition, “biodegradable” does not necessarily imply the use of “bio-based” material. In addition, this docum

44、ent sets requirements on information to be provided regarding sustainability aspects. 2 Normative references The following documents, in whole or in part, are normatively referenced in this document and are indispensable for its application. For dated references, only the edition cited applies. For

45、undated references, the latest edition of the referenced document (including any amendments) applies. EN 16640, Bio-based products - Bio-based carbon content - Determination of the bio-based carbon content using the radiocarbon method EN 16575, Bio-based products - Vocabulary EN 16751, Bio-based pro

46、ducts - Sustainability criteria EN 16760, Bio-based products - Life Cycle Assessment EN 16785-1, Bio-based products - Bio-based content - Part 1: Determination of the bio-based content using the radiocarbon analysis and elemental analysis prEN 16785-2:2016, Bio-based products - Bio-based content - P

47、art 2: Determination of the bio-based content using the material balance method EN 16848, Bio-based products - Requirements for Business to Business communication of characteristics using a Data Sheet EN 16935, Bio-based products - Requirements for Business-to-Consumer communication and claims EN IS

48、O 12185, Crude petroleum and petroleum products - Determination of density - Oscillating U-tube method (ISO 12185:1996) BS EN 16766:2017EN 16766:2017 (E) 7 3 Terms and definitions For the purposes of this document, the terms and definitions given in EN 16575 apply. 4 General information on the purpo

49、se of solvents Solvents are liquids which have the ability to dissolve, suspend or extract other materials. They make it possible to process, apply, clean or separate materials. Solvents have significantly changed modern living and are an invaluable solution for industries as diverse as pharmaceuticals and microelectronics to domestic cleaning and printing. In fact, without solvents, many of the products we use and rely on, from penicillin to industrial paint, would not perform to the standards we demand today. Organic solve