EN 61099-2010 en Insulating liquids - Specifications for unused synthetic organic esters for electrical purposes《绝缘液体 电气用新合成有机酯规范》.pdf

1、raising standards worldwideNO COPYING WITHOUT BSI PERMISSION EXCEPT AS PERMITTED BY COPYRIGHT LAWBSI Standards PublicationInsulating liquids Specifications for unused synthetic organic esters for electrical purposesBS EN 61099:2010National forewordThis British Standard is the UK implementation of EN

2、 61099:2010. It is identi-cal to IEC 61099:2010. It supersedes BS EN 61099:1992 which is withdrawn.The UK participation in its preparation was entrusted to Technical CommitteeGEL/10, Fluids for electrotechnical applications.A list of organizations represented on this committee can be obtained onrequ

3、est to its secretary.This publication does not purport to include all the necessary provisions of acontract. Users are responsible for its correct application. BSI 2010ISBN 978 0 580 65780 1ICS 29.040.99Compliance with a British Standard cannot confer immunity fromlegal obligations.This British Stan

4、dard was published under the authority of the StandardsPolicy and Strategy Committee on 31 December 2010.Amendments issued since publicationAmd. No. Date Text affectedBRITISH STANDARDBS EN 61099:2010EUROPEAN STANDARD EN 61099 NORME EUROPENNE EUROPISCHE NORM November 2010 CENELEC European Committee f

5、or Electrotechnical Standardization Comit Europen de Normalisation Electrotechnique Europisches Komitee fr Elektrotechnische Normung Management Centre: Avenue Marnix 17, B - 1000 Brussels 2010 CENELEC - All rights of exploitation in any form and by any means reserved worldwide for CENELEC members. R

6、ef. No. EN 61099:2010 E ICS 29.040 Supersedes EN 61099:1992 English version Insulating liquids - Specifications for unused synthetic organic esters for electrical purposes (IEC 61099:2010) Liquides isolants - Spcifications relatives aux esters organiques de synthse neufs destins aux matriels lectriq

7、ues (CEI 61099:2010) Isolierflssigkeiten - Anforderungen an neue synthetische organische Ester fr elektrotechnische Zwecke (IEC 61099:2010) This European Standard was approved by CENELEC on 2010-11-01. CENELEC members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the

8、conditions for giving this European Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references concerning such national standards may be obtained on application to the Central Secretariat or to any CENELEC member. This European Standard exists

9、in three official versions (English, French, German). A version in any other language made by translation under the responsibility of a CENELEC member into its own language and notified to the Central Secretariat has the same status as the official versions. CENELEC members are the national electrot

10、echnical committees of Austria, Belgium, Bulgaria, Croatia, Cyprus, the Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, the Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, S

11、witzerland and the United Kingdom. BS EN 61099:2010EN 61099:2010 - 2 - Foreword The text of document 10/813/FDIS, future edition 2 of IEC 61099, prepared by IEC TC 10, Fluids for electrotechnical applications, was submitted to the IEC-CENELEC parallel vote and was approved by CENELEC as EN 61099 on

12、2010-11-01. This European Standard supersedes EN 61099:1992. The main changes with respect to EN 61099:1992 relate to the aim of giving a more updated specification of synthetic organic esters when used as insulating liquids. Attention is drawn to the possibility that some of the elements of this do

13、cument may be the subject of patent rights. CEN and CENELEC shall not be held responsible for identifying any or all such patent rights. The following dates were fixed: latest date by which the EN has to be implemented at national level by publication of an identical national standard or by endorsem

14、ent (dop) 2011-08-01 latest date by which the national standards conflicting with the EN have to be withdrawn (dow) 2013-11-01 Annex ZA has been added by CENELEC. _ Endorsement notice The text of the International Standard IEC 61099:2010 was approved by CENELEC as a European Standard without any mod

15、ification. In the official version, for Bibliography, the following note has to be added for the standard indicated: IEC 61203 NOTE Harmonized as EN 61203. _ BS EN 61099:2010- 3 - EN 61099:2010 Annex ZA (normative) Normative references to international publications with their corresponding European

16、publications The following referenced documents are indispensable for the application of this document. For dated references, only the edition cited applies. For undated references, the latest edition of the referenced document (including any amendments) applies. NOTE When an international publicati

17、on has been modified by common modifications, indicated by (mod), the relevant EN/HD applies. Publication Year Title EN/HD Year IEC 60156 - Insulating liquids - Determination of the breakdown voltage at power frequency - Test method EN 60156 - IEC 60247 - Insulating liquids - Measurement of relative

18、 permittivity, dielectric dissipation factor (tan d) and d.c. resistivity EN 60247 - IEC 60475 - Method of sampling liquid dielectrics - - IEC 60628 1985 Gassing of insulating liquids under electrical stress and ionization HD 488 S1 1987 IEC 60814 - Insulating liquids - Oil-impregnated paper and pre

19、ssboard - Determination of water by automatic coulometric Karl Fischer titration EN 60814 - IEC 61039 - Classification of insulating liquids EN 61039 - IEC 61125 1992 Unused hydrocarbon-based insulating liquids - Test methods for evaluating the oxidation stability EN 61125 1993 IEC 61620 - Insulatin

20、g liquids - Determination of the dielectric dissipation factor by measurement of the conductance and capacitance - Test method EN 61620 - IEC 62021-1 - Insulating liquids - Determination of acidity - Part 1: Automatic potentiometric titration EN 62021-1 - IEC 62021-2 - Insulating liquids - Determina

21、tion of acidity - Part 2: Colourimetric titration EN 62021-2 - ISO 2211 - Liquid chemical products - Measurement of colour in Hazen units (platinum-cobalt scale) - - ISO 2592 - Determination of flash and fire points - Cleveland open cup method EN ISO 2592 - ISO 2719 - Determination of flash point -

22、Pensky-Martens closed cup method EN ISO 2719 - ISO 3016 - Petroleum products - Determination of pour point - - ISO 3104 - Petroleum products - Transparent and opaque liquids - Determination of kinematic viscosity and calculation of dynamic viscosity EN ISO 3104 - BS EN 61099:2010EN 61099:2010 - 4 -

23、Publication Year Title EN/HD Year ISO 3675 - Crude petroleum and liquid petroleum products - Laboratory determination of density - Hydrometermethod EN ISO 3675 - ISO 12185 - Crude petrolelum and petroleum products - Determination of density - Oscillating U-tube method EN ISO 12185 - OECD 301 1992 OE

24、CD guidelines for the testing of chemicals - Ready Biodegradability - - BS EN 61099:2010 2 61099 IEC:2010 CONTENTS INTRODUCTION.5 1 Scope.6 2 Normative references .6 3 Terms and definitions .7 4 General remarks.7 5 Health, safety and environment (HSE) properties (liquid properties related to safe ha

25、ndling and environment protection).8 5.1 Flash point and fire point.8 5.2 Biodegradation 8 5.3 Toxicity .8 6 Classification, identification, general delivery requirements, sampling, packaging and disposal.8 6.1 Classification.8 6.2 Identification and general delivery requirements, sampling, packagin

26、g and disposal.8 6.3 Storage .8 6.4 Representative sampling .9 6.5 Disposal and spillages.9 7 Properties of synthetic organic esters.9 7.1 Physical properties, significance and test methods9 7.1.1 Colour .9 7.1.2 Appearance .9 7.1.3 Density9 7.1.4 Kinematic viscosity 9 7.1.5 Flash point and fire poi

27、nt .9 7.1.6 Pour point9 7.1.7 Crystallization9 7.1.8 Water content9 7.1.9 Acidity .9 7.1.10 Oxidation stability10 8 Electrical properties10 8.1 Breakdown voltage10 8.2 Dielectric dissipation factor, permittivity and d.c. resistivity10 8.3 Gassing tendency10 9 Specifications for synthetic organic est

28、ers used in transformers .10 Annex A (informative) Determination of crystallization .12 Annex B (informative) Specifications for synthetic organic esters used in capacitors13 Bibliography14 BS EN 61099:201061099 IEC:2010 5 INTRODUCTION Health and safety This International Standard does not purport t

29、o address all the safety problems associated with its use. It is the responsibility of the user of the standard to establish appropriate health and safety practices and determine the applicability of regulatory limitations prior to use. Unused synthetic esters which are the subject of this standard

30、should be handled with due care with regard to personal hygiene. Direct contact with eyes may cause slight irritation. In the case of eye contact, irrigation with copious quantities of clean running water should be carried out and medical attention sought. Some of the tests specified in this standar

31、d involve the use of processes that could lead to a hazardous situation. Attention is drawn to the relevant standard for guidance. Environment The disposal of synthetic esters, chemicals and sample containers mentioned in this standard should be carried out in accordance with local regulations with

32、regard to their environmental impact. Precautions should be taken to prevent the release of synthetic esters into the environment. BS EN 61099:2010 6 61099 IEC:2010 INSULATING LIQUIDS SPECIFICATIONS FOR UNUSED SYNTHETIC ORGANIC ESTERS FOR ELECTRICAL PURPOSES 1 Scope This International Standard cover

33、s the specification and test methods for unused synthetic organic esters. It applies to synthetic organic esters, delivered to the agreed point and time of delivery intended, for use in transformers, switchgear and similar related equipment in which synthetic organic esters are required as an insula

34、nt and for heat transfer. These unused synthetic organic esters are obtained by chemical processing and physical treatments of fatty acids and polyols. NOTE Maintenance of synthetic organic esters in equipment is covered in a separate standard (IEC 61203). 2 Normative references The following refere

35、nced documents are indispensable for the application of this document. For dated references, only the edition cited applies. For undated references, the latest edition of the referenced document (including any amendments) applies. IEC 60156, Insulating liquids Determination of the breakdown voltage

36、at power frequency Test method. IEC 60247, Insulating liquids Measurement of relative permittivity, dielectric dissipation factor (tan ) and d.c. resistivity IEC 60475, Method of sampling liquid dielectrics IEC 60628:1985, Gassing of insulating liquids under electrical stress and ionization IEC 6081

37、4, Insulating liquids Oil-impregnated paper and pressboard Determination of water by automatic coulometric Karl Fischer titration IEC 61039, Classification of insulating liquids IEC 61125:1992, Unused hydrocarbon-based insulating liquids Test methods for evaluating the oxidation stability IEC 61620,

38、 Insulating liquids Determination of the dielectric dissipation factor by measurement of the conductance and capacitance Test method IEC 62021-1, Insulating liquids Determination of acidity Part 1: Automatic potentiometric titration IEC 62021-2, Insulating liquids Determination of acidity Part 2: Co

39、lourimetric titration ISO 2211, Liquid chemical products Measurement of colour in Hazen units (platinum-cobalt scale) BS EN 61099:201061099 IEC:2010 7 ISO 2592, Determination of flash and fire-points Cleveland open cup method ISO 2719, Determination of flash-point Pensky Martens closed cup method IS

40、O 3016, Petroleum products Determination of pour-point ISO 3104, Petroleum products Transparent and opaque liquids Determination of kinematic viscosity and calculation of dynamic viscosity ISO 3675, Crude petroleum and liquid petroleum products Laboratory determination of density Hydrometer method I

41、SO 12185, Crude petroleum and petroleum products Determination of density Oscillating U-tube method OECD 301:1992, OECD guideline for testing of chemicals Ready biodegradability 3 Terms and definitions For the purposes of this document the following terms and definitions apply. 3.1 unused synthetic

42、organic esters liquid based on synthetic organic esters as delivered by the supplier 3.2 additive suitable chemical substance/s which is/are deliberately added to a synthetic organic ester in order to improve certain characteristics, e.g. pour point, viscosity, foaming, oxidation stability NOTE If a

43、dditives are used, these should be mentioned by the supplier to the user, if requested. This may involve issues of confidentiality in an agreement. Additives, if used, need to comply with local regulations. 4 General remarks The unused synthetic organic esters to which this standard applies are liqu

44、ids which contain only carbon, hydrogen and oxygen. They are prepared from mono- or polyhydric alcohols and mono- or polybasic aliphatic or aromatic acids. Commercial products may be based on single esters or a mixture of esters and may contain oxidation inhibitors and other additives. Unused synthe

45、tic organic esters selected for use in transformers have high flash and fire points and are therefore relatively difficult to ignite. They may, however, have slightly higher viscosities than mineral insulating oils. Unused synthetic organic esters are more hygroscopic than mineral oils and this aspe

46、ct will need to be considered in their use and maintenance. NOTE Such a liquid, by definition, has not been used in, nor been in contact with, electrical equipment or other equipment not required for manufacture, storage or transport. The manufacturers and suppliers of unused synthetic organic ester

47、s will have taken all reasonable precautions to ensure that the liquid is not contaminated with polychlorinated biphenyls or terphenyls (PCB, PCT); used, reclaimed or dechlorinated oils; or other contaminants. BS EN 61099:2010 8 61099 IEC:2010 5 Health, safety and environment (HSE) properties (liqui

48、d properties related to safe handling and environment protection) 5.1 Flash point and fire point The safe operation of electrical equipment requires an adequately high fire point that is measured in accordance with ISO 2592 (Cleveland open cup). Flash point is measured with ISO 2719 (Pensky-Martens

49、closed cup procedure). 5.2 Biodegradation Unused synthetic organic esters as supplied in electrical applications are of interest because of their higher fire points and better environmental compatibility, relative to petroleum derived insulating mineral oil. Specific tests need to be undertaken to demonstrate biodegradability of these liquids. Tests include OECD 301 / OPPTS 835.3110 (US EPA). The biodegradability of unused synthetic ester fluids can be class