EN 62321-7-2-2017 en Determination of certain substances in electrotechnical products - Part 7-2 Hexavalent chromium - Determination of hexavalent chromium (Cr(VI)) in polymers and.pdf

1、Determination of certain substances in electrotechnical productsPart 7-2: Hexavalent chromium Determination of hexavalent chromium (Cr(VI) in polymers and electronics by the colorimetric method (IEC 62321-7-2:2017)BS EN 62321-7-2:2017BSI Standards PublicationWB11885_BSI_StandardCovs_2013_AW.indd 1 1

2、5/05/2013 15:06EUROPEAN STANDARD NORME EUROPENNE EUROPISCHE NORM EN 62321-7-2 June 2017 ICS 31.020; 71.040.50 Supersedes EN 62321:2009 (partially) English Version Determination of certain substances in electrotechnical products - Part 7-2: Hexavalent chromium - Determination of hexavalent chromium (

3、Cr(VI) in polymers and electronics by the colorimetric method (IEC 62321-7-2:2017) Dtermination de certaines substances dans les produits lectrotechniques - Partie 7-2: Chrome hexavalent - Dtermination du chrome hexavalent (Cr(VI) dans les polymres et les produits lectroniques par mthode colorimtriq

4、ue (IEC 62321-7-2:2017) Verfahren zur Bestimmung von bestimmten Substanzen in Produkten der Elektrotechnik - Teil 7-2: Bestimmung von sechswertigem Chrom (Cr(VI) in Polymeren und Elektronik durch kolorimetrische Verfahren (IEC 62321-7-2:2017) This European Standard was approved by CENELEC on 2017-05

5、-02. CENELEC members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this European Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references concerning such national standards may be obta

6、ined on application to the CEN-CENELEC Management Centre or to any CENELEC member. This European Standard exists in three official versions (English, French, German). A version in any other language made by translation under the responsibility of a CENELEC member into its own language and notified t

7、o the CEN-CENELEC Management Centre has the same status as the official versions. CENELEC members are the national electrotechnical committees of Austria, Belgium, Bulgaria, Croatia, Cyprus, the Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece

8、, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, the Netherlands, Norway, Poland, Portugal, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and the United Kingdom. European Committee for Electrotechnical Standardization Comit Europen de Normalisation

9、Electrotechnique Europisches Komitee fr Elektrotechnische Normung CEN-CENELEC Management Centre: Avenue Marnix 17, B-1000 Brussels 2017 CENELEC All rights of exploitation in any form and by any means reserved worldwide for CENELEC Members. Ref. No. EN 62321-7-2:2017 E National forewordThis British S

10、tandard is the UK implementation of EN 62321-7-2:2017. Together with BS EN 62321-1:2013, BS EN 62321-2:2013, BS EN 62321-3-1:2013, BS EN 62321-3-2:2013, BS EN 62321-4:2013, BS EN 62321-5:2013, BS EN 62321-6, BS EN 62321-7-1 and BS EN 62321-8 it supersedes BS EN 62321:2009, which will be withdrawn up

11、on publication of all parts of the BS EN 62321 series.The UK participation in its preparation was entrusted to Technical Committee GEL/111, Electrotechnical environment committee.A list of organizations represented on this committee can be obtained on request to its secretary.This publication does n

12、ot purport to include all the necessary provisions of a contract. Users are responsible for its correct application. The British Standards Institution 2017 Published by BSI Standards Limited 2017ISBN 978 0 580 74418 1ICS 71.040.50; 31.020Compliance with a British Standard cannot confer immunity from

13、 legal obligations.This British Standard was published under the authority of the Standards Policy and Strategy Committee on 31 August 2017.Amendments/corrigenda issued since publicationDate Text affectedBRITISH STANDARDBS EN 6232172:2017EUROPEAN STANDARD NORME EUROPENNE EUROPISCHE NORM EN 62321-7-2

14、 June 2017 ICS 31.020; 71.040.50 Supersedes EN 62321:2009 (partially) English Version Determination of certain substances in electrotechnical products - Part 7-2: Hexavalent chromium - Determination of hexavalent chromium (Cr(VI) in polymers and electronics by the colorimetric method (IEC 62321-7-2:

15、2017) Dtermination de certaines substances dans les produits lectrotechniques - Partie 7-2: Chrome hexavalent - Dtermination du chrome hexavalent (Cr(VI) dans les polymres et les produits lectroniques par mthode colorimtrique (IEC 62321-7-2:2017) Verfahren zur Bestimmung von bestimmten Substanzen in

16、 Produkten der Elektrotechnik - Teil 7-2: Bestimmung von sechswertigem Chrom (Cr(VI) in Polymeren und Elektronik durch kolorimetrische Verfahren (IEC 62321-7-2:2017) This European Standard was approved by CENELEC on 2017-05-02. CENELEC members are bound to comply with the CEN/CENELEC Internal Regula

17、tions which stipulate the conditions for giving this European Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references concerning such national standards may be obtained on application to the CEN-CENELEC Management Centre or to any CENELEC me

18、mber. This European Standard exists in three official versions (English, French, German). A version in any other language made by translation under the responsibility of a CENELEC member into its own language and notified to the CEN-CENELEC Management Centre has the same status as the official versi

19、ons. CENELEC members are the national electrotechnical committees of Austria, Belgium, Bulgaria, Croatia, Cyprus, the Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, the

20、 Netherlands, Norway, Poland, Portugal, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and the United Kingdom. European Committee for Electrotechnical Standardization Comit Europen de Normalisation Electrotechnique Europisches Komitee fr Elektrotechnische Normung CEN-CENELEC

21、 Management Centre: Avenue Marnix 17, B-1000 Brussels 2017 CENELEC All rights of exploitation in any form and by any means reserved worldwide for CENELEC Members. Ref. No. EN 62321-7-2:2017 E BS EN 6232172:2017EN 62321-7-2:2017 2 European foreword The text of document 111/408/CDV, future edition 1 o

22、f IEC 62321-7-2, prepared by IEC/TC 111 “Environmental standardization for electrical and electronic products and systems“ was submitted to the IEC-CENELEC parallel vote and approved by CENELEC as EN 62321-7-2:2017. The following dates are fixed: latest date by which the document has to be implement

23、ed at national level by publication of an identical national standard or by endorsement (dop) 2018-02-02 latest date by which the national standards conflicting with the document have to be withdrawn (dow) 2020-05-02 This document supersedes EN 62321:2009 (partially). Attention is drawn to the possi

24、bility that some of the elements of this document may be the subject of patent rights. CENELEC shall not be held responsible for identifying any or all such patent rights. Endorsement notice The text of the International Standard IEC 62321-7-2.2017 was approved by CENELEC as a European Standard with

25、out any modification. In the official version, for Bibliography, the following notes have to be added for the standards indicated: IEC 62321:2008 NOTE Harmonized as EN 62321:2009. IEC 62321-2 NOTE Harmonized as EN 62321-2. ISO 648 NOTE Harmonized as EN ISO 648. BS EN 6232172:2017EN 62321-7-2:2017 2

26、European foreword The text of document 111/408/CDV, future edition 1 of IEC 62321-7-2, prepared by IEC/TC 111 “Environmental standardization for electrical and electronic products and systems“ was submitted to the IEC-CENELEC parallel vote and approved by CENELEC as EN 62321-7-2:2017. The following

27、dates are fixed: latest date by which the document has to be implemented at national level by publication of an identical national standard or by endorsement (dop) 2018-02-02 latest date by which the national standards conflicting with the document have to be withdrawn (dow) 2020-05-02 This document

28、 supersedes EN 62321:2009 (partially). Attention is drawn to the possibility that some of the elements of this document may be the subject of patent rights. CENELEC shall not be held responsible for identifying any or all such patent rights. Endorsement notice The text of the International Standard

29、IEC 62321-7-2.2017 was approved by CENELEC as a European Standard without any modification. In the official version, for Bibliography, the following notes have to be added for the standards indicated: IEC 62321:2008 NOTE Harmonized as EN 62321:2009. IEC 62321-2 NOTE Harmonized as EN 62321-2. ISO 648

30、 NOTE Harmonized as EN ISO 648. EN 62321-7-2:2017 3 Annex ZA (normative) Normative references to international publications with their corresponding European publications The following documents, in whole or in part, are normatively referenced in this document and are indispensable for its applicati

31、on. For dated references, only the edition cited applies. For undated references, the latest edition of the referenced document (including any amendments) applies. NOTE 1 When an International Publication has been modified by common modifications, indicated by (mod), the relevant EN/HD applies. NOTE

32、 2 Up-to-date information on the latest versions of the European Standards listed in this annex is available here: www.cenelec.eu. Publication Year Title EN/HD Year IEC 62321-1 - Determination of certain substances in electrotechnical products - Part 1: Introduction and overview EN 62321-1 - ISO 369

33、6 - Water for analytical laboratory use - Specification and test methods EN ISO 3696 - BS EN 6232172:2017This page deliberately left blank 2 IEC 62321-7-2:2017 IEC 2017 CONTENTS FOREWORD . 3 INTRODUCTION . 5 1 Scope 6 2 Normative references 6 3 Terms, definitions and abbreviated terms 6 3.1 Terms an

34、d definitions 6 3.2 Abbreviated terms . 7 4 Reagents . 7 4.1 General . 7 4.2 Reagents 7 5 Apparatus 8 5.1 General . 8 5.2 Apparatus . 8 6 Sampling . 9 7 Test procedure 9 7.1 Extraction of Cr(VI) in soluble polymers ABS, PC and PVC matrixes 9 7.2 Extraction of Cr(VI) in insoluble/unknown polymers and

35、 electronics without Sb . 10 8 Calibration . 11 8.1 Permanent calibration instruments 11 8.2 Traditional calibration instruments 11 8.2.1 General . 11 9 Calculation 12 10 Precision . 13 11 Quality assurance and control . 14 11.1 General method 14 11.2 Matrix spike recovery correction method . 14 12

36、Limits of detection (LOD) and limits of quantification (LOQ) . 14 12.1 General . 14 12.2 Determination of LOD and LOQ 15 13 Test report . 16 Bibliography 17 Table 1 Statistical data of all IIS trails 13 Table 2 Method detection limit = t sn116 2 IEC 62321-7-2:2017 IEC 2017 CONTENTS FOREWORD . 3 INTR

37、ODUCTION . 5 1 Scope 6 2 Normative references 6 3 Terms, definitions and abbreviated terms 6 3.1 Terms and definitions 6 3.2 Abbreviated terms . 7 4 Reagents . 7 4.1 General . 7 4.2 Reagents 7 5 Apparatus 8 5.1 General . 8 5.2 Apparatus . 8 6 Sampling . 9 7 Test procedure 9 7.1 Extraction of Cr(VI)

38、in soluble polymers ABS, PC and PVC matrixes 9 7.2 Extraction of Cr(VI) in insoluble/unknown polymers and electronics without Sb . 10 8 Calibration . 11 8.1 Permanent calibration instruments 11 8.2 Traditional calibration instruments 11 8.2.1 General . 11 9 Calculation 12 10 Precision . 13 11 Qualit

39、y assurance and control . 14 11.1 General method 14 11.2 Matrix spike recovery correction method . 14 12 Limits of detection (LOD) and limits of quantification (LOQ) . 14 12.1 General . 14 12.2 Determination of LOD and LOQ 15 13 Test report . 16 Bibliography 17 Table 1 Statistical data of all IIS tr

40、ails 13 Table 2 Method detection limit = t sn116 BS EN 6232172:2017IEC 62321-7-2:2017 IEC 2017 3 INTERNATIONAL ELECTROTECHNICAL COMMISSION _ DETERMINATION OF CERTAIN SUBSTANCES IN ELECTROTECHNICAL PRODUCTS Part 7-2: Hexavalent chromium Determination of hexavalent chromium (Cr(VI) in polymers and ele

41、ctronics by the colorimetric method FOREWORD 1) The International Electrotechnical Commission (IEC) is a worldwide organization for standardization comprising all national electrotechnical committees (IEC National Committees). The object of IEC is to promote international co-operation on all questio

42、ns concerning standardization in the electrical and electronic fields. To this end and in addition to other activities, IEC publishes International Standards, Technical Specifications, Technical Reports, Publicly Available Specifications (PAS) and Guides (hereafter referred to as “IEC Publication(s)

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44、rates closely with the International Organization for Standardization (ISO) in accordance with conditions determined by agreement between the two organizations. 2) The formal decisions or agreements of IEC on technical matters express, as nearly as possible, an international consensus of opinion on

45、the relevant subjects since each technical committee has representation from all interested IEC National Committees. 3) IEC Publications have the form of recommendations for international use and are accepted by IEC National Committees in that sense. While all reasonable efforts are made to ensure t

46、hat the technical content of IEC Publications is accurate, IEC cannot be held responsible for the way in which they are used or for any misinterpretation by any end user. 4) In order to promote international uniformity, IEC National Committees undertake to apply IEC Publications transparently to the

47、 maximum extent possible in their national and regional publications. Any divergence between any IEC Publication and the corresponding national or regional publication shall be clearly indicated in the latter. 5) IEC itself does not provide any attestation of conformity. Independent certification bo

48、dies provide conformity assessment services and, in some areas, access to IEC marks of conformity. IEC is not responsible for any services carried out by independent certification bodies. 6) All users should ensure that they have the latest edition of this publication. 7) No liability shall attach t

49、o IEC or its directors, employees, servants or agents including individual experts and members of its technical committees and IEC National Committees for any personal injury, property damage or other damage of any nature whatsoever, whether direct or indirect, or for costs (including legal fees) and expenses arising out of the publication, use of, or reliance upon, this IEC Publication or any other IEC Publications. 8) Attention is drawn to the Normative references c