1、STD.BS1 BS EN IS0 LOS-ZLL-ENGL 2OOL D Lb24669 0892L09 3LT BRITISH STANDARD kS EN IS0 105-Z11:2001 Textiles - Tests for colour fastness - Part Z 11: Evaluation of speckiness of colorant dispersions The European Stancard EN IS0 105Z11:2 has the status of a British Standard ICs 59.080.01 NO COPYING WIT
2、BOUT BSI PERMISSION EXCEPT AS PERMITTED BY COPYBIGHI LAW STDaBSI BS EN IS0 105-ZLL-ENGL 2001 Lb24669 08921iLO 03L = BS EN IS0 106-Z11:2001 National foreword This British standard is the official English language version of EN IS0 105Zll:2000. It is identical with IS0 105211:1998. The UK participatio
3、n in its preparation was entrusted to Technical Committee TCI/l, Colour faslness and colour measurement, which has the responsibility to: - aid enquirers to understand the text; - present to the responsible internationavEuropean committee any enquiries on the interpretation, or proposals for change,
4、 and keep the UK interests informed; - monitor related intedonal and European developments and promulgate them in the UK A list of organizations represented on this committee can be obtained on request to its secretary. Cross-references Attention is ram to the fact that CEN and CENELEC Standards nor
5、mally include an annex which lists normative references to international publications with their corresponding European publications. The British Standards which implement international or European publications referred to in this document may be found in the BSI Standards Catalogue under the sectio
6、n entitled “International Standards Correspondence Index“, or by using the “Find“ facility of the BSI Standards Electronic Catalogue. A British Standard does not purport to include all the necessary provisions of a conlmct. Usem of British Standards are responsible for their correct application. Com
7、pliance with a British Standard does not of itself confer immunity from legal obligations. Summary of pages This document comprises a front cover, an inside front cover, the EN IS0 title page, the EN IS0 foreword page, the IS0 title page, page ii, pages 1 to 4, the annex ZA page and a back cover. Th
8、e BI copynght notice displayed in this document indicates when the document waslastissued. This British Standard, having been prepared under the direction of the Sector Committee for Materiais and Chemicals, was published under the authority of the Standards Committee and comes into effect on 15 Feb
9、ruary 2001 Q BSI 02-2001 Amendments issued since publication 1 comments I Amd. No. ISBN O 580 36684 7 STD-ES1 ES EN IS0 LOS-ZLL-ENGL 2OOL 1624667 0872LlL T78 EUROPEAN STANDARD EN IS0 105-211 NORME EUROPENNE EUROPISCHE NORM October 2000 ICs 59.080.01 English version Textiles - Tests for colour fastne
10、ss - Part Z1 1 : Evaluation of speckiness of colorant dispersions (IS0 105-Z11:1998) Textiles - Essais de solidit6 des teintures - Partie 21 1: Evaluation de luniformit des dispersions de colorants Textilien - Farbechtheitspriungen - Teil 21 1: Bestimmung der Stippenbildung von Farbdispersionen (IS0
11、 105- (IS0 105-21 i:i998) 21 i :i 998) This European Standard was approved by CEN on 4 October 2000. CEN members are bound to comply with the CENCENELEC Internal Regulations which stipulate the conditions for giving this European Standard the status of a national standard without any alteration. Up-
12、to-date lists and bibliographical references concerning such national standards may be obtained on application to the Management Centre or to any CEN member. This European Standard exists in three official versions (English, French, German). A version in any other language made by translation under
13、the responsibility of a CEN member into its own language and notified to the Management Centre has the same status as the official versions. CEN members are the national standards bodies of Austria, Belgium, Czech Republic, Denmark, Finland, France, Germany, Greece, Iceland, Ireland, Italy, Luxembou
14、rg, Netherlands, Norway, Portugal, Spain, Sweden, Switzerland and United Kingdom. EUROPEAN COMMIlTEE FOR STANDARDIZATION EUROPISCHES KOMITEE FOR NORMUNG COMITE EUROPEEN DE NORMALISATION Management Centre: rue de Stassart, 36 B-1050 Brussels Q 2000 CEN All rights of exploitation in any form and by an
15、y means reserved worldwide for CEN national Members. Ref. No. EN IS0 105-211:2000 E STD-BSI BS EN IS0 LOS-ZL1-ENGL 2001 1624669 0892112 904 EN IS0 105-Z11:2000 Foreword The text of the International Standard from Technical Committee ISOTTC 38 “textiles“ of the International Organization for Standard
16、ization (ISO) has been taken over as an European Standard by Technical Committee CEN/TC 248 “Textiles and textile products“, the secretariat of which is held by BSI. This European Standard shall be given the status of a national standard, either by publication of an identical text or by endorsement,
17、 at the latest by April 2001, and conflicting national standards shall be withdrawn at the latest by April 2001. According to the CENKENELEC Internal Regulations, the national standards organizations of the following countries are bound to implement this European Standard: Austria, Belgium, Czech Re
18、public, Denmark, Finland, France, Germany, Greece, Iceland, Ireland, Italy, Luxembourg, Netherlands, Norway, Portugal, Spain, Sweden, Switzerland and the United Kingdom. Endorsement notice The text of the International Standard IS0 105-21 1 :1998 has been approved by CEN as a European Standard witho
19、ut any modification. NOTE: Normative references to International Standards are listed in annex ZA (normative). STD-BSI BS EN IS0 105-ZLL-ENGL 2OOL Lb24669 0892113 840 EN IS0 106-Z11:2000 INTERNATIONAL STANDARD IS0 10521 1 First edition 1998-09-01 Textiles - Tests for colour fastness - Part 21 1 : Ev
20、aluation of speckiness of colorant dispersions Textiles - Essais de solidit des teintures - Partie Z7 I: Evaluation de /unifonnit des dispersions de colorants Reference number IS0 105-21 1:1998(E) STD-BSI BS EN IS0 LOS-ZLL-ENGL 2OOL Lb2YbbS 0892LL4 787 m EN IS0 106-Z11:2000 Textiles - Tests for colo
21、ur fastness - Part 21 1 : Evaluation of speckiness of colorant dispersions 1 Scope This International Standard describes a test method to determine speckiness primarily of disperse dye, vat dye and pigment dispersions. Agglomerates in colorant dispersions may become apparent as specks on a continuou
22、sly dyed (padded), or on a printed fabric, especially when pale and light shades are produced. 2 Normative reference The following standard contains provisions which, through reference in this text constitutes provisions of this part of IS0 105. At the time of publication, the edition indicated was
23、valid. All standards are subject to revision and parties to agreements based on this part of IS0 105 are encouraged to investigate the possibility of applying the most recent edition of the standard listed below. Members of IEC and IS0 maintain registers of currently valid International Standards. I
24、S0 105-A01:1994, TexMes - Tests for cokur fastness - fart A07: Gened principles of testing. 3 Definitions For the purposes of this Intemational Standard the following definitions apply. 3.1 disperse dye: non-ionic dye which is sparingly soluble in water and which has substantivity, when properly dis
25、persed, for polyester, polyamide and some other manufactured polymeric fibres. 3.2 dispersion: In textile dyeing and printing, a suspension of very fine colorant particles in a liquid phase. 3.3 pigment: colorant in particulate form which is insoluble in the substrate but which can be dispersed in t
26、he substrate to modify its colour. 3.4 speck small particle, such as an agglomerate in liquid dispersion, or a very small spot of dark colour on a dyed substrate. 3.5 speckiness: In textile dyeing and printing, the quality or state of containing specks. 3.6 vat dye: water-insoluble dye, usually cont
27、aining keto groups, which is normally applied to the fibre from an alkaline aqueous solution of the reduced enol (leuco) form which is subsequently oxidized in the fibre to the insoluble form. 1 STD.BSI BS EN IS0 LOS-ZLL-ENGL 2OOL Lb24bb 08921L5 hl13 EN IS0 105-Z11:2000 4 Principle A dispersion of a
28、 dye is filtered through a polyester/cotton blend fabric, then dried and thermofixed. The degree of speckiness is assessed visually. 5 Safety precautions Good laboratory practices should be followed. Wear safety glasses in all laboratory areas, All chemicals should be handled with care Use heat resi
29、stant gloves when working at hot air ovens and themofixation devices. Users should also comply with any national and local safety regulations. N0TE:These safety precautions are for information purposes only. The precautions are ancillary to the test procedure and are not intended to be all-inclusive
30、. It is the users responsibility to use safe and proper techniques in handling materials in this test method. Consult manufacturers for specific details such as material safety data sheets and other manufacturers recommendations. 6 Reagents 6.1 Sodium hydroxide, 30 % (dv) E 300 g/l. 6.2 Sodium hydro
31、sulfite, powder (N%S20,). 6.3 Hydrogen peroxide, 30 YO (dv) 2 300 gh. 6.4 Acetic acid, 80 % (dv) 2 800 g/l. 6.5 Grade 3 water, (see 8.1 of IS0 105-A01:1994). 7 Apparatus 7.1 Filter cloth, 65/35 (dm) polyesterkotton, bleached woven broad cloth (shirting weight, approximately 100 g/m), approximately 2
32、40 mm x 240 mm square. A fabric of similar construction and of varying blend ratios may be used, but it shall then be stated in the test report. NOTE The following fabric has been found to be suitable. - Warp and weft/filling yams: approximately 12 tex. - Construction: warp approximately 50 ends/cm
33、wefilling approximately 28 pickdcm - The fabric is desized, bleached, dried and framed to 150 cm to 155 cm and heat set at 200C. These processes are carried out in accordance with generally accepted industrial practice. 7.2 Buchner funnel, polypropylene, 110 mm diameter, with separate top and bottom
34、. Cut out the perforated bottom smoothly and even with the rim, using a knife or other suitable implement. Both parts are used in the test. 7.3 Filtering flask, 2 I, heavy wall with side tabulation. 2 STD.BSI BS EN IS0 105-ZLL-ENGL 2001 1b24bb 089211b 55T EN IS0 106-Z11:2000 7.4 Rubber stopper, 1 ho
35、le, to fit the filtering flask. 7.5 Stirrer, small propeller type, diameter approximately 20 mm, speed up to 2 200 rpm (37 s-). 7.6 Evaporating dishes, 1 I, glass or porcelain, (approximately 150 mm diameter), three, for testing vat dyes. 7.7 Ovens for the following operations: - Drying, without air
36、 circulation; - Themfixation. 8 Preparation of liquid dispersion for sampling Before removing a sample for testing, mix dispersions thoroughly in drums using a mechanical mixing device, such as a propeller stirrer or homogenizer, so that the liquid is smooth and free of sediment and lumps. Shake lab
37、oratory samples thoroughly to ensure that all dried material adhering to the cover and sides of the container is reincorporated into the liquid. Then remove the cover and stir the sample either mechanically, or by hand, until all sediment and/or lumps are completely redispersed. Replace the cover an
38、d once again shake to ensure complete homogeneity. Once the test sample has been removed for use and the balance of the dispersion is to be stored for future use, clean the lid and the containers lip thoroughly prior to closure. Test the sample immediately after homogenization. NOTE On prolonged sto
39、rage, liquid dispersions tend to settle and may develop a more or less tacky sediment. It is imperative to ensure complete homogenew of the dispersion prior to testing. 9 Procedure Identify the filter cloth with the experiment or sample number in one of the corners and ensure that it is free of extr
40、aneous specks. Clean and dry the funnel. Prepare the funnel assembly by placing the top part of the funnel upside down on a clean surface and drape the fabric over it as flat as possible with the identification mark facing down towards the surface. The side of the fabric with the identification will
41、 then be on top during filtration and is used for subsequent evaluation. Snap and press the bottom half of the funnel to the top half, causing the fabric to become a tight, smooth filter in the funnel. Place the assembled funnel straight on the filtering flask using the rubber stopper to ensure that
42、 the funnel remains upright (and the filter fabric horizontal) during filtration and rinsing. Weigh the powder or liquid dye into a weighing cup and transfer to a 400 ml graduated beaker containing grade 3 water at 20 OC to 30 OC. Rinse the weighing cup with water from a spray bottle. Record the qua
43、ntity of dye used. NOTE The amount of dye used is directly proportional to its dyeing strength and is typically (2,5 I 0,025) g for a very high strength solid brand to (20 +: 0,2) g for a low strength liquid. As a reference (75 f 0,075) g of a dye is used if it gives a 1/1 standard depth of shade fr
44、om 2 % (on mass of fibre) of dye applied (in an exhaust dyeing process). The masses of other dyes used in either liquid or solid forms are propottional to this reference. With powder and granular forms, stir for 3 min with a small propeller stirrer with the propeller in the centre and just above the
45、 container bottom, Adjust the speed to create a vortex terminating at the top of the propeller. With liquid forms, stir as for powders, but for 30 s. After the specified stirring time, transfer the dispersion to the 1 I beaker. Rinse the 400 ml beaker with 200 ml of water (6.5) at 20 OC to 30 OC and
46、 pour the rinse water into the 1 I beaker. Dilute the dispersion further to 800 ml. Pre-wet the fabric in the filter with 200 ml water (6.5). 3 STD-BSI BS EN IS0 105-ZLL-ENGL 2001 Lb24bb9 0892117 49b EN IS0 105-Z11:2000 Stir the dispersion in the beaker for approximately 30 s and pour it into the fu
47、nnel. Rinse the beaker with 200 ml water and pour it into the funnel. Rinse the funnel with an additional 200 ml water and let stand for about 1 min until dripping has completely stopped. Carefully remove the filter fabric from the funnel and place it on a blotting paper to remove excess water. Opti
48、onally, when the colorant under test is a vat dye, the filter fabric may be further treated, at this stage, in an evaporating dish and reducing solution followed by oxidation using the following procedure. a) Prepare 400 mi of a fresh reducing solution in an evaporating dish at 60 OC to 70 OC contai
49、ning: 1) 30 mVI sodium hydroxide (6.1); 2) 20 g/l sodium hydrosulfite (6.2). Fully immerse the filter fabric in the reducing solution in the evaporating dish for 5 min. Do not move the fabric during this time. b) Immerse the filter fabric for 1 min, without agitation in water (6.5) at 15 “C to 25 “C in an evaporating dish. c) Prepare 100 ml of an oxidizing solution in an evaporating dish at 40 OC to 50 OC containing 10 mill hydrogen peroxide (6.3). Fully immerse the filter fabric in the oxidizing solution in the evaporating dish for 2 min. Do not move
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