EN ISO 1523-2002 en Determination of Flash Point - Closed Cup Equilibrium Method《闪点测定 闭杯平衡法 ISO 1523-2002》.pdf

1、BRITISH STANDARD . . . . . . . . . . . . . . . . . . . . . . . . . Method of test for petroleum and its pro ducts Determination of flash BS 2000-492: point Closed cup equilibrium method (Identical with IP 492-2003) The European Standard EN IS0 1523:2002 has the status of a British Standard ICs 75.08

2、0: 87.040 BS EN IS0 1523 :2002 BS 2000-492: 2002 Incorporating Corrigendum No. 1 present to the responsible internationalEuropean committee any enquiries on the interpretation, or proposals for change, and keep the UK interests informed; monitor related international and European developments and pr

3、omulgate them in the UK. - A list of organizations represented on this committee can be obtained on request to its secretary. The Institute ofPetroleum publishes and sells all Parts ofBS 2000, and all BS EN petroleum test methods that would be Part of BS 2000, both in its annual publication “Standar

4、d methods for analysis and testing of petroleum and related products and British Standard 2000 parts” and individually. Further information is available from: The Institute of Petroleum, 61 New Cavendish Street, London, W1G 7AR. Tel: 020 7467 7100. Fax: 020 7255 1472. Cros s-r e fer en ces The Briti

5、sh Standards which implement international or European publications referred to in this document may be found in the BSI Standards Catalogue under the section entitled “International Standards Correspondence Index”, or by using the “Find” facility of the BSI Standards Electronic Catalogue. A British

6、 Standard does not purport to include all the necessary provisions of a contract. Users of British Standards are responsible for their correct application. Compliance with a British Standard does not of itself confer immunity from legal obligations. Summary of pages This document comprises a front c

7、over, an inside front cover, the EN IS0 title page, the EN IS0 foreword page, the IS0 title page, pages ii to v, a blank page, pages 1 to 11, the Annex ZApage, an inside back cover and a back cover. The BSI copyright date displayed in this document indicates when the document was last issued. O Inst

8、itute of Petroleum and BSI 12 June 2002 ISBN O 580 39225 2 EUROPEAN STANDARD NORME EUROPENNE EUROPISCHE NORM EN IS0 1523 March 2002 ICs 75.080; 87.040 English version Determination of flash point - Closed cup equilibrium method (IS0 1523:2002) Dtermination du point dclair - Mthode lquilibre en vase

9、clos (IS0 1523:2002) Bestimmung des Flammpunktes - Gleichgewichtsverfahren mit geschlossenem Tiegel (IS0 1523:2002) This European Standard was approved by CEN on 1 March 2002. CEN members are bound to comply with the CENICENELEC Internal Regulations which stipulate the conditions for giving this Eur

10、opean Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references concerning such national standards may be obtained on application to the Management Centre or to any CEN member. This European Standard exists in three official versions (English,

11、 French, German). A version in any other language made by translation under the responsibility of a CEN member into its own language and notified to the Management Centre has the same status as the official versions. CEN members are the national standards bodies of Austria, Belgium, Czech Republic,

12、Denmark, Finland, France, Germany, Greece, Iceland, Ireland, Italy, Luxembourg, Malta, Netherlands, Norway, Portugal, Spain, Sweden, Switzerland and United Kingdom. EUROPEAN COMMITTEE FOR STANDARDIZATION EUROPISCHES KOMITEE FR NORMUNG COMIT EUROPEN DE NORMALISATION Management Centre: rue de Stassart

13、, 36 B-1050 Brussels O 2002 CEN All rights of exploitation in any form and by any means reserved worldwide for CEN national Members. Ref. No. EN IS0 1523:2002 E EN IS0 1523:2002 I CORRECTED 2002-05-22 I Foreword This document (IS0 1523:2002) has been prepared by Technical Committee ISO/TC 28 “Petrol

14、eum products and lubricants“ in collaboration with Technical Committee CEN/TC 19 “Petroleum products, lubricants and related products“, the secretariat of which is held by NEN. This European Standard shall be given the status of a national standard, either by publication of an identical text or by e

15、ndorsement, at the latest by September 2002, and conflicting national standards shall be withdrawn at the latest by September 2002. According to the CENKENELEC Internal Regulations, the national standards organizations of the following countries are bound to implement this European Standard: Austria

16、, Belgium, Czech Republic, Denmark, Finland, France, Germany, Greece, Iceland, Ireland, Italy, Luxembourg, Malta, Netherlands, Norway, Portugal, Spain, Sweden, Switzerland and the United Kingdom. Endorsement notice The text of the International Standard IS0 1523:2002 has been approved by CEN as a Eu

17、ropean Standard without any modifications. NOTE Normative references to International Standards are listed in annex ZA (normative). INTERNATIONAL STANDARD IS0 1523 Third edition 2002-03-01 Determination of flash point - Closed cup equilibrium method Dferminafion du poinf dclair - Mfhode lquilibre en

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21、p Isaeei nforrn thtnec elar Secrteiraata t thsserdda eg leb nevwo. II EN IS0 1523:2002 Contents Page . iv Foreword Introduction . v 1 2 3 4 5 6 7 8 9 10 11 12 13 14 Scope . N or m a t i ve ref e re n ces . Term and definition . . 1 2 Apparatus . . Apparatus preparation . . 3 Sample handling Procedur

22、e . . Calculation . 6 Expression of result 7 Test report . 4 . Annex A (informative) Verification of apparatus . Bibliograph y . . 8 11 . 111 EN IS0 1523:2002 Foreword IS0 (the International Organization for Standardization) is a worldwide federation of national standards bodies (IS0 member bodies).

23、 The work of preparing International Standards is normally carried out through IS0 technical committees. Each member body interested in a subject for which a technical committee has been established has the right to be represented on that committee. International organizations, governmental and non-

24、governmental, in liaison with ISO, also take part in the work. IS0 collaborates closely with the International Electrotechnical Commission (IEC) on all matters of electrotechnical standardization. International Standards are drafted in accordance with the rules given in the ISO/IEC Directives, Part

25、3. The main task of technical committees is to prepare International Standards. Draft International Standards adopted by the technical committees are circulated to the member bodies for voting. Publication as an International Standard requires approval by at least 75 % of the member bodies casting a

26、 vote. Attention is drawn to the possibility that some of the elements of this International Standard may be the subject of patent rights. IS0 shall not be held responsible for identifying any or all such patent rights. IS0 1523 was prepared jointly by Technical Committees ISO/TC 28, Pefroleurn prod

27、ucfs and lubricanfs and ISO/TC 35, Painfs and varnishes. This third edition cancels and replaces the second edition (IS0 1523:1983), which has been technically revised. Annex A of this International Standard is for information only. iv EN IS0 1523:2002 I nt rod uction This International Standard des

28、cribes one of two closed cup equilibrium methods for the determination of the flash point of paints, varnishes, petroleum and related products, and it should be read in conjunction with the second equilibrium method, IS0 3679 (5 in the bibliography), when selecting a method. The determination of the

29、 flashho flash temperature using the same equipment is described in IS0 1516 (4 in the bibliography). By the procedure specified, differences between test apparatus of various standard designs are minimized by ensuring that the test is carried out only when the product under test and the air/vapour

30、mixture above it in the test vessel are considered to be in temperature equilibrium. V EN IS0 1523:2002 EN IS0 1523:2002 Determination of flash point - Closed cup equilibrium method WARNING - The use of this International Standard may involve hazardous materials, operations and equipment. This Inter

31、national Standard does not purport to address all of the safety problems associated with its use. It is the responsibility of the user of this International Standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. 1 Scope T

32、his International Standard specifies a method to determine the flash point of paints, varnishes, paint binders, solvents, petroleum or related products. This International Standard is not applicable to water-borne paints which may, however, be tested using IS0 3679 (5 in the bibliography). The metho

33、d is suitable for use over the temperature range -30 OC to 110 OC, depending on the use of different apparatus listed in Table 1. The interpretation of results obtained from solvent mixtures containing halogenated hydrocarbons should be considered with caution, as these mixtures can give anomalous r

34、esults. 2 Normative references The following normative documents contain provisions which, through reference in this text, constitute provisions of this International Standard. For dated references, subsequent amendments to, or revisions of, any of these publications do not apply. However, parties t

35、o agreements based on this International Standard are encouraged to investigate the possibility of applying the most recent editions of the normative documents indicated below. For undated references, the latest edition of the normative document referred to applies. Members of IS0 and IEC maintain r

36、egisters of currently valid International Standards. IS0 151 3: 1992, Painfs and varnishes - Examinafion and preparafion of samples for fesfing IS0 2719:-) , Pefroleum producfs and lubricanfs - Deferminafion of flash poinf - Pensky-Marfens closed cup mefhod IS0 31 70:1988, Pefroleum liquids - Manual

37、 sampling IS0 31 71 :I 988, Pefroleum liquids - Aufomafic pipeline sampling IS0 13736: 1997, Pefroleum producfs and ofher liquids - Deferminafion of flash poinf -Abel closed cup mefhod IS0 15528:2000, Painfs, varnishes and raw maferials for painfs and varnishes - Sampling ASTM D56-00, Sfandard Tesf

38、Mefhod for Flash Poinf by Tag Closed Tesfer DIN 51755:1974, Tesfing of mineral oils and ofher combusfible liquids; deferminafion of flash poinf by fhe closed fesfer according fo Abel-Pensky 1) To be published. (Revision of IS0 2719:1988) 1 EN IS0 1523:2002 3 Term and definition For the purposes of t

39、his International Standard, wherein ignition source is recognized as being a flame, the following term and definition apply. 3.1 flash point lowest temperature of the test portion, corrected to a barometric pressure of 101,3 kPa, at which application of an ignition source causes the vapour of the te

40、st portion to ignite and the flame to propagate across the surface of the liquid under the specified conditions of test 4 Principle The test portion is placed in a suitably designed closed cup mounted in a heating bath. The temperature of the bath is slowly raised at such a rate that the difference

41、in temperature between the liquid in the bath and the test portion in the cup never exceeds 2 OC, and the temperature of the test portion does not rise at a rate greater than approximately 0,5 OC in 13 min. During the heating-up period, ignition trials are carried out at intervals of not less than 1

42、,5 min. The lowest temperature at which a flash occurs is noted. 5 Chemicals and materials 5.1 Cleaning solvent, for removal of traces of the previous test portion from the test cup and cover. NOTE The choice of solvent will depend upon the previous material tested, and the tenacity of the residue.

43、Low volatility aromatic (benzene-free) solvents may be used to remove traces of oil, and mixed solvents such as toluene-acetone-methanol may be effective for the removal of gum-type deposits. 5.2 Verification liquids, see annex A. 6 Apparatus 6.1 standards listed in Table 1. Test cup and lid: a clos

44、ed cup with, where specified, an internal level indicator, and lid, as specified in the The test cup shall be fitted with a tightly fitting cover which carries an opening slide and an ignition device capable, when the slide is open, of positioning an ignition flame, with a diameter of between 3 mm a

45、nd 4 mm, at the approximate centre of the opening in the lid. When positioned, the tip of the ignition device shall be between the planes of the lower and upper surfaces of the lid at a point on a radius passing through the centre of the opening. The apparatus shall be designed such that an ignition

46、 trial can be performed by opening the slide, positioning and removing the nozzle of the ignition device, and closing the slide again in a period of between 2 s and 3 s. A mechanically driven device for carrying out this operation is permitted provided that it can be shown that it meets the specific

47、ation. NOTE The source of flame in the ignition device may be any suitable flammable gas. 6.2 Test cup thermometer, as specified for use with the test cup in the standards listed in Table 1. NOTE and have the same response as the thermometers specified in the standards listed in Table 1. Other types

48、 of temperature measuring devices may be used provided that they meet the requirements for accuracy 6.3 (see 10.10), and of adequate size and heat capacity to meet the requirements of 10.10. Heating bath, containing a suitable liquid, capable of being heated at the required temperature rate 2 EN IS0

49、 1523:2002 Standard test method IS0 2719 Pensky-Martens Table 1 -Applicable temperature range Temperature range “C 10 to 110 I IS0 13736 Abel I -30 to 80 I IASTM D56 Tag I up to 93 I I DIN 51755 Abel-Pensky I -30 to 65 I 6.4 the test cup thermometer (6.2). Heating bath thermometer, capable of measuring the test temperature with the same accuracy as that of 6.5 Support, designed such that the test cup is immersed in direct contact with the liquid in the heatingkooling bath, in such a position that the level of the test portion in the cup is the same as that o