EN ISO 1716-2010 en Reaction to fire tests for products - Determination of the gross heat of combustion (calorific value)《建材着火试验反应 总燃烧热量测定(热值)》.pdf

1、raising standards worldwideNO COPYING WITHOUT BSI PERMISSION EXCEPT AS PERMITTED BY COPYRIGHT LAWBSI Standards PublicationBS EN ISO 1716:2010Reaction to fire tests forproducts Determination ofthe gross heat of combustion(calorific value) (ISO 1716:2010)BS EN ISO 1716:2010 BRITISH STANDARDNational fo

2、rewordThis British Standard is the UK implementation of EN ISO 1716:2010.It supersedes BS EN ISO 1716:2002 which is withdrawn.The UK participation in its preparation was entrusted to TechnicalCommittee FSH/21/1, Reaction to fire tests - European fire testmethods including ignitability tests.A list o

3、f organizations represented on this committee can beobtained on request to its secretary.This publication does not purport to include all the necessaryprovisions of a contract. Users are responsible for its correctapplication. BSI 2010ISBN 978 0 580 60498 0ICS 13.220.50; 91.100.01Compliance with a B

4、ritish Standard cannot confer immunity fromlegal obligations.This British Standard was published under the authority of theStandards Policy and Strategy Committee on 31 August 2010.Amendments issued since publicationDate Text affectedEUROPEAN STANDARD NORME EUROPENNE EUROPISCHE NORM EN ISO 1716 June

5、 2010 ICS 13.220.50; 91.100.01 Supersedes EN ISO 1716:2002English Version Reaction to fire tests for products - Determination of the gross heat of combustion (calorific value) (ISO 1716:2010) Essais de raction au feu de produits - Dtermination du pouvoir calorifique suprieur (valeur calorifique) (IS

6、O 1716:2010) Prfungen zum Brandverhalten von Bauprodukten - Bestimmung der Verbrennungswrme (des Brennwerts) (ISO 1716:2010) This European Standard was approved by CEN on 26 May 2010. CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving

7、this European Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references concerning such national standards may be obtained on application to the CEN Management Centre or to any CEN member. This European Standard exists in three official versio

8、ns (English, French, German). A version in any other language made by translation under the responsibility of a CEN member into its own language and notified to the CEN Management Centre has the same status as the official versions. CEN members are the national standards bodies of Austria, Belgium,

9、Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland and United Kingdom. EUROPEAN COMMITTEE

10、 FOR STANDARDIZATION COMIT EUROPEN DE NORMALISATION EUROPISCHES KOMITEE FR NORMUNG Management Centre: Avenue Marnix 17, B-1000 Brussels 2010 CEN All rights of exploitation in any form and by any means reserved worldwide for CEN national Members. Ref. No. EN ISO 1716:2010: EBS EN ISO 1716:2010EN ISO

11、1716:2010 (E) 3 Foreword This document (EN ISO 1716:2010) has been prepared by Technical Committee ISO/TC 92 “Fire safety“ in collaboration with Technical Committee CEN/TC 127 “Fire safety in buildings” the secretariat of which is held by BSI. This European Standard shall be given the status of a na

12、tional standard, either by publication of an identical text or by endorsement, at the latest by December 2010, and conflicting national standards shall be withdrawn at the latest by December 2010. Attention is drawn to the possibility that some of the elements of this document may be the subject of

13、patent rights. CEN and/or CENELEC shall not be held responsible for identifying any or all such patent rights. This document supersedes EN ISO 1716:2002. According to the CEN/CENELEC Internal Regulations, the national standards organizations of the following countries are bound to implement this Eur

14、opean Standard: Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland and

15、the United Kingdom. Endorsement notice The text of ISO 1716:2010 has been approved by CEN as a EN ISO 1716:2010 without any modification. BS EN ISO 1716:2010ISO 1716:2010(E) ISO 2010 All rights reserved iiiContents Page Foreword iv 1 Scope1 2 Normative references1 3 Terms and definitions .1 4 Princi

16、ple3 5 Test apparatus .3 5.1 General .3 5.2 Calorimetric bomb, constructed with the following characteristics .3 5.3 Calorimeter.3 6 Reagents and materials 4 7 Test specimens5 7.1 General .5 7.2 Sampling.5 7.3 Determination of surface density 6 7.4 Grinding6 7.5 Type of specimen 6 7.6 Conditioning 6

17、 7.7 Number of test specimens6 7.8 Determination of mass6 7.9 Crucible method 7 7.10 “Cigarette” method .7 8 Test procedure.8 8.1 General .8 8.2 Calibration procedure .8 8.3 Standard test procedure.8 9 Expression of results9 9.1 Corrections for manual apparatus.9 9.2 Corrections for isothermal calor

18、imeter (see Annex C).10 9.3 Calculation of the gross heat of combustion of the specimen.10 9.4 Calculation of the gross heat of combustion of the product11 10 Test report12 11 Validity of test results .13 Annex A (normative) Calculation of net heat of combustion.18 Annex B (informative) Precision of

19、 test method19 Annex C (informative) Calculation by graph of the corrective term, c, necessary because of the cooling of the calorimeter.22 Annex D (informative) Example of determination of the gross heat of combustion of a non-homogeneous product23 Bibliography26 BS EN ISO 1716:2010ISO 1716:2010(E)

20、 iv ISO 2010 All rights reservedForeword ISO (the International Organization for Standardization) is a worldwide federation of national standards bodies (ISO member bodies). The work of preparing International Standards is normally carried out through ISO technical committees. Each member body inter

21、ested in a subject for which a technical committee has been established has the right to be represented on that committee. International organizations, governmental and non-governmental, in liaison with ISO, also take part in the work. ISO collaborates closely with the International Electrotechnical

22、 Commission (IEC) on all matters of electrotechnical standardization. International Standards are drafted in accordance with the rules given in the ISO/IEC Directives, Part 2. The main task of technical committees is to prepare International Standards. Draft International Standards adopted by the te

23、chnical committees are circulated to the member bodies for voting. Publication as an International Standard requires approval by at least 75 % of the member bodies casting a vote. Attention is drawn to the possibility that some of the elements of this document may be the subject of patent rights. IS

24、O shall not be held responsible for identifying any or all such patent rights. ISO 1716 was prepared by Technical Committee ISO/TC 92, Fire safety, Subcommittee SC 1, Fire initiation and growth. This third edition cancels and replaces the second edition (ISO 1716:2002), which has been technically re

25、vised. BS EN ISO 1716:2010INTERNATIONAL STANDARD ISO 1716:2010(E) ISO 2010 All rights reserved 1Reaction to fire tests for products Determination of the gross heat of combustion (calorific value) WARNING The attention of all persons concerned with managing and carrying out this test is drawn to the

26、fact that fire testing may be hazardous and that there is a possibility that toxic and/or harmful gases may be evolved during the test. Operational hazards may also arise during the testing of specimens, such as the possibility of an explosion, and during the disposal of test residues. WARNING An as

27、sessment of all the potential hazards and risks to health should be made and safety precautions should be identified and provided. Written safety instructions should be issued. Appropriate training should be given to relevant personnel. Laboratory personnel should ensure that they follow written ins

28、tructions at all times. 1 Scope This International Standard specifies a method for the determination of the gross heat of combustion (QPCS) of products at constant volume in a bomb calorimeter. Annex A describes the calculation of the net heat of combustion (QPCI) when required. Information on the p

29、recision of the test method is given in Annex B. 2 Normative references The following referenced documents are indispensable for the application of this document. For dated references, only the edition cited applies. For undated references, the latest edition of the referenced document (including an

30、y amendments) applies. ISO 554, Standard atmospheres for conditioning and/or testing Specifications ISO 13943, Fire safety Vocabulary EN 13238, Reaction to fire tests for building products Conditioning procedures and general rules for selection of substrates 3 Terms and definitions For the purposes

31、of this document, the terms and definitions given in ISO 13943, and the following apply. 3.1 product material, element or component about which information is required 3.2 material single basic substance or uniformly dispersed mixture of substances EXAMPLE Metal, stone, timber, concrete, mineral woo

32、l with a uniformly dispersed binder and polymers. BS EN ISO 1716:2010ISO 1716:2010(E) 2 ISO 2010 All rights reserved3.3 homogeneous product product consisting of a single material having uniform density and composition throughout the product 3.4 non-homogeneous product product that does not satisfy

33、the requirements of a homogeneous product and which is composed of more than one component, substantial and/or non-substantial 3.5 substantial component material that constitutes a significant part of a non-homogeneous product, and that has a mass/unit area W 1,0 kg/m2or a thickness W 1,0 mm 3.6 non

34、-substantial component material that does not constitute a significant part of a non-homogeneous product and that has a layer with a mass/unit area 1,0 kg/m2and a thickness 1,0 mm 3.7 internal non-substantial component non-substantial component that is covered on both sides by at least one substanti

35、al component 3.8 external non-substantial component non-substantial component that is not covered on one side by a substantial component 3.9 heat of combustion calorific value (deprecated) thermal energy produced by combustion of unit mass of a given substance NOTE The heat of combustion is expresse

36、d in megajoules per kilogram. ISO 13943:2008 3.10 gross heat of combustion QPCSheat of combustion of a substance when the combustion is complete and any produced water is entirely condensed under specified conditions NOTE The gross heat of combustion is expressed in megajoules per kilogram. 3.11 net

37、 heat of combustion QPCIheat of combustion of a substance when the combustion is complete and any produced water is in the vapour state under specified conditions NOTE 1 The net heat of combustion may be calculated from the gross heat of combustion. NOTE 2 The net heat of combustion is expressed in

38、megajoules per kilogram. 3.12 latent heat of vaporization of water q heat which is required to change water from a liquid to a gas NOTE The latent heat of vaporization is expressed in megajoules per kilogram. BS EN ISO 1716:2010ISO 1716:2010(E) ISO 2010 All rights reserved 33.13 surface density mass

39、 per unit area NOTE The surface density is expressed in kilograms per square metre. 4 Principle In this test, a test specimen of specified mass is burned under standardized conditions, at constant volume, in an atmosphere of oxygen, in a bomb calorimeter calibrated by combustion of certified benzoic

40、 acid. The heat of combustion determined under these conditions is calculated on the basis of the observed temperature rise, taking account of heat loss and the latent heat of vaporization of water. This is a test method for determining an absolute value of the heat of combustion for a product and i

41、t does not take into account any inherent variability of the product. 5 Test apparatus 5.1 General The test apparatus (bomb calorimeter) shall be as illustrated in Figure 1, and as detailed in 5.2 to 5.5. Additional equipment shall be in accordance with 5.6 to 5.11. 5.2 Calorimetric bomb, constructe

42、d with the following characteristics The calorimetric bomb shall be constructed as follows: a) volume: (300 50) ml; b) mass not greater than 3,25 kg; c) casing thickness at least 1/10 of the inner diameter of the body. The lid is intended to receive the crucible and the electric firing device. The l

43、id, including any seals, shall be capable of withstanding an internal pressure of 21 MPa. NOTE These conditions define a bomb in which 1 g of coal under an initial oxygen pressure no greater than 3 MPa (pressure gauge method) is able to withstand, with a sufficient coefficient of safety, the maximum

44、 amount of pressure created under combustion, without a need for a calorimetric bomb of overlarge mass. The inner surface of the bomb shall be resistant to attack by products of combustion and, even when “fuels” rich in sulfur are used, it shall resist pitting and inter-crystalline corrosion by acid

45、s produced during combustion. 5.3 Calorimeter 5.3.1 Jacket, consisting of a double-walled container, which is thermally insulated together with an insulated lid. The jacket is filled with water. The dimensions of the jacket shall be such that there is at least 10 mm space around the calorimetric ves

46、sel. The calorimetric vessel shall be supported on an as small as possible area of non-conducting material, preferably a 3-point support. For an adiabatic calorimeter system, a heater and thermometer system shall be incorporated into the vessel such that the water temperature in the jacket is mainta

47、ined at the same temperature as the water in the calorimetric vessel. For an isothermal calorimeter system, the temperature of the water in the jacket shall be kept constant. For an isothermal calorimeter, the necessary corrections shall be made (see 9.2). BS EN ISO 1716:2010ISO 1716:2010(E) 4 ISO 2

48、010 All rights reserved5.3.2 Calorimetric vessel, consisting of a polished metal container designed to accommodate the bomb. The dimensions shall be such that the bomb can be immersed in water (see 8.3.7). 5.3.3 Stirrer, driven by a constant-speed motor. To prevent the transfer of heat to and from t

49、he calorimeter, the driving shaft of the stirrer shall have a thermally insulated section in a gasket between the jacket lid and the jacket. A magnetic stirring device with a similar performance is an acceptable alternative. 5.4 Temperature measuring device, capable of giving a resolution of 0,005 K. When using a mercury thermometer, this shall have at least 0,01 K graduations with a device, e.g. a lens, for taking readings to within 0,005 K. A mechanical vibrator shall also be used to gently tap the thermometer to ensure that the mercu