EN ISO 6744-1-2004 en Binders for paints and varnishes - Alkyd resins - Part 1 General methods of test《色漆和清漆用粘合剂 醇酸树脂 第1部分 通用试验方法 ISO 6744-1-1999》.pdf

1、BRITISH STANDARD BS EN ISO 6744-1:2004 BS 6782-16.1:2000 Incorporating Corrigendum No. 1 and Amendment No. 1 to BS 6782-16.1:2000 (Amendment No. 1 renumbers the BS as BS EN ISO 6744-1:2004) Binders for paints and varnishes Alkyd resins Part 1: General methods of test The European Standard EN ISO 674

2、4-1:2004 has the status of a British Standard ICS 87.060.20 BS EN ISO 6744-1:2004 This British Standard, having been prepared under the direction of Sector Committee for Materials and Chemicals, was published under the authority of the Standards Committee and comes into effect on 15 March 2000 BSI 1

3、3 July 2004 ISBN 0 580 34301 4 National foreword This British Standard is the official English language version of EN ISO 6744-1:2004. It is identical with ISO 6744-1:1999. The UK participation in its preparation was entrusted to Technical Committee STI/3, Paint media and related products, which has

4、 the responsibility to: A list of organizations represented on this committee can be obtained on request to its secretary. Cross-references The British Standards which implement international or European publications referred to in this document may be found in the BSI Catalogue under the section en

5、titled “International Standards Correspondence Index”, or by using the “Search” facility of the BSI Electronic Catalogue or of British Standards Online. This publication does not purport to include all the necessary provisions of a contract. Users are responsible for its correct application. Complia

6、nce with a British Standard does not of itself confer immunity from legal obligations. aid enquirers to understand the text; present to the responsible international/European committee any enquiries on the interpretation, or proposals for change, and keep the UK interests informed; monitor related i

7、nternational and European developments and promulgate them in the UK. Summary of pages This document comprises a front cover, an inside front cover, the EN ISO title page, the EN ISO foreword page, the ISO title page, pages ii and iii, a blank page, pages 1 to 4, the Annex ZA page and a back cover.

8、The BSI copyright notice displayed in this document indicates when the document was last issued. Amendments issued since publication Amd. No. Date Comments 10883 Corrigendum No. 1 December 2000 Change to identifier 15238 13 July 2004 Implementation of the European StandardEUROPEANSTANDARD NORMEEUROP

9、ENNE EUROPISCHENORM ENISO67441 May2004 ICS87.060.20 Englishversion BindersforpaintsandvarnishesAlkydresinsPart1:General methodsoftest(ISO67441:1999) LiantspourpeinturesetvernisRsinesalkydesPartie1: Mthodesgnralesdessai(ISO67441:1999) BindemittelfrBeschichtungsstoffeAlkydharzeTeil1: AllgemeinePrfverf

10、ahren(ISO67441:1999) ThisEuropeanStandardwasapprovedbyCENon8April2004. CENmembersareboundtocomplywiththeCEN/CENELECInternalRegulationswhichstipulatetheconditionsforgivingthisEurope an Standardthestatusofanationalstandardwithoutanyalteration.Uptodatelistsandbibliographicalreferencesconcernings uchnat

11、ional standardsmaybeobtainedonapplicationtotheManagementCentreortoanyCENmember. ThisEuropeanStandardexistsinthreeofficialversions(English,French,German).Aversioninanyotherlanguagemadebytra nslation undertheresponsibilityofaCENmemberintoitsownlanguageandnotifiedtotheManagementCentrehasthesamestatusas

12、the official versions. CENmembersarethenationalstandardsbodiesofAustria,Belgium,Cyprus,CzechRepublic,Denmark,Estonia,Finland,France, Germany,Greece,Hungary,Iceland,Ireland,Italy,Latvia,Lithuania,Luxembourg,Malta,Netherlands,Norway,Poland,Portugal, Slovakia, Slovenia,Spain,Sweden,SwitzerlandandUnited

13、Kingdom. EUROPEANCOMMITTEEFORSTANDARDIZATION COMITEUROPENDENORMALISATION EUROPISCHESKOMITEEFRNORMUNG ManagementCentre:ruedeStassart,36B1050Brussels 2004CEN Allrightsofexploitationinanyformandbyanymeansreserved worldwideforCENnationalMembers. Ref.No.ENISO67441:2004EINESO7644:12(400E) 2 Foreword Thete

14、xtofISO67441:1999hasbeenpreparedbyTechnicalCommitteeISO/TC35“Paintsand varnishes”oftheInternationalOrganizationforStandardization(ISO)andhasbeentakenover asENISO67441:2004byTechnicalCommitteeCEN/TC139“Paintsandvarnishes“,the secretariatofwhichisheldbyDIN. ThisEuropeanStandardshallbegiventhestatusofa

15、nationalstandard,eitherbypublicationof anidenticaltextorbyendorsement,atthelatestbyNovember2004,andconflictingnational standardsshallbewithdrawnatthelatestbyNovember2004. AccordingtotheCEN/CENELECInternalRegulations,thenationalstandardsorganizationsof thefollowingcountriesareboundtoimplementthisEuro

16、peanStandard:Austria,Belgium, Cyprus,CzechRepublic,Denmark,Estonia,Finland,France,Germany,Greece,Hungary, Iceland,Ireland,Italy,Latvia,Lithuania,Luxembourg,Malta,Netherlands,Norway,Poland, Portugal,Slovakia,Slovenia,Spain,Sweden,SwitzerlandandUnitedKingdom. Endorsementnotice ThetextofISO67441:1999ha

17、sbeenapprovedbyCENasENISO67441:2004withoutany modifications. NOTENormativereferencestoInternationalStandardsarelistedinAnnexZA(normative). ENISO67441:2004Reference number ISO 6744-1:1999(E) OSI 9991 INTERNATIONAL STANDARD ISO 6744-1 First edition 1999-12-01 Binders for paints and varnishes Alkyd res

18、ins Part 1: General methods of test Liants pour peintures et vernis Rsines alkydes Partie 1: Mthodes gnrales dessai ENISO67441:2004ii ENISO67441:2004ISO -44761:(9991)E ISO 9991 All irhgts seredevr iii Foreword ISO (the International Organization for Standardization) is a worldwide federation of nati

19、onal standards bodies (ISO member bodies). The work of preparing International Standards is normally carried out through ISO technical committees. Each member body interested in a subject for which a technical committee has been established has the right to be represented on that committee. Internat

20、ional organizations, governmental and non-governmental, in liaison with ISO, also take part in the work. ISO collaborates closely with the International Electrotechnical Commission (IEC) on all matters of electrotechnical standardization. International Standards are drafted in accordance with the ru

21、les given in the ISO/IEC Directives, Part 3. Draft International Standards adopted by the technical committees are circulated to the member bodies for voting. Publication as an International Standard requires approval by at least 75 % of the member bodies casting a vote. Attention is drawn to the po

22、ssibility that some of the elements of this part of ISO 6744 may be the subject of patent rights. ISO shall not be held responsible for identifying any or all such patent rights. International Standard ISO 6744-1 was prepared by Technical Committee ISO/TC 35, Paints and varnishes, Subcommittee SC 10

23、, Test methods for binders for paints and varnishes. Together with the other parts (see below), this part of ISO 6744 cancels and replaces ISO 6744:1984, which has been technically revised. ISO 6744 consists of the following parts, under the general title Binders for paints and varnishes Alkyd resin

24、s: Part 1: General methods of test Part 2: Determination of phthalic anhydride content Part 3: Determination of unsaponifiable matter content Part 4: Determination of fatty acid content ENISO67441:2004blank ENISO67441:2004INTENRATIONAL TSANDADR ISO -44761:(9991)E ISO 9991 All irhgts seredevr 1 Binde

25、rs for paints and varnishes Alkyd resins Part 1: General methods of test 1 Scope This part of ISO 6744 describes general methods of test for alkyd resins for use in paints, varnishes and similar products. It is also applicable to those solutions and similar preparations made from alkyd resins that a

26、re intended for use as binders for paints and varnishes. The test methods to be used for an individual alkyd resin shall be the subject of agreement between the interested parties. 2 Normative references The following normative documents contain provisions which, through reference in this text, cons

27、titute provisions of this part of ISO 6744. For dated references, subsequent amendments to, or revisions of, any of these publications do not apply. However, parties to agreements based on this part of ISO 6744 are encouraged to investigate the possibility of applying the most recent editions of the

28、 normative documents indicated below. For undated references, the latest edition of the normative document referred to applies. Members of ISO and IEC maintain registers of currently valid International Standards. ISO 1523:1983, Paints, varnishes, petroleum and related products Determination of flas

29、hpoint Closed cup equilibrium method. ISO 2431:1993, Paints and varnishes Determination of flow time by use of flow cups. ISO 2811-1:1997, Paints and varnishes Determination of density Part 1: Pyknometer method. ISO 3219:1993, Plastics Polymers/resins in the liquid state or as emulsions or dispersio

30、ns Determination of viscosity using a rotational viscometer with defined shear rate. ISO 3251:1993, Paints and varnishes Determination of non-volatile matter of paints, varnishes and binders for paints and varnishes. ISO 3679:1983, Paints, varnishes, petroleum and related products Determination of f

31、lashpoint Rapid equilibrium method. ISO 3681:1996, Binders for paints and varnishes Determination of saponification value Titrimetric method. ISO 3682:1996, Binders for paints and varnishes Determination of acid value Titrimetric method. ISO 4629:1996, Binders for paints and varnishes Determination

32、of hydroxyl value Titrimetric method. ISO 4630:1997, Binders for paints and varnishes Estimation of colour of clear liquids by the Gardner colour scale. ENISO67441:2004ISO -44761:(9991)E 2 ISO 9991 All irhgts seredevr ISO 6271:1997, Clear liquids Estimation of colour by the platinum-cobalt scale. IS

33、O 6744-2:1999, Binders for paints and varnishes Alkyd resins Part 2: Determination of phthalic anhydride content. ISO 6744-3:1999, Binders for paints and varnishes Alkyd resins Part 3: Determination of unsaponifiable matter content. ISO 6744-4: 1999, Binders for paints and varnishes Alkyd resins Par

34、t 4: Determination of fatty acid content. ISO 15716: 1) , Binders for paints and varnishes Storage stability. ASTM D 6166-97, Standard Test Method for Color of Naval Stores and Related Products (Instrumental Determination of Gardner Color). 3 Terms and definitions For the purposes of this part of IS

35、O 6744, the following terms and definitions apply. 3.1 alkyd resin synthetic resin resulting from the polycondensation of polyacids and fatty acids (or oils) with polyhydric alcohols 3.2 modified alkyd resin alkyd resin, modified in order to obtain specific properties, for example with rosin acids,

36、phenolic resins, vinyl toluene, styrene, isocyanates, polyamides or acrylic, epoxy or silicone compounds NOTE An alkyd resin based on tall-oil fatty acids containing not more than 4 % of rosin acids is regarded as an “alkyd resin“, not as a “modified alkyd resin“. 4 Classification Alkyd resins are c

37、lassified into the following groups: a) according to the content of fatty acid or oil (content of oil calculated as the triglyceride portion of the non- volatile matter): short-oil alkyd resins: less than about 40 % medium-oil alkyd resins: about 40 % to 60 % long-oil alkyd resins: above about 60 %

38、b) according to the content of dibasic acid (see ISO 6744-2); c) according to the modifying component (see 3.2). 1) To be published. ENISO67441:2004ISO -44761:(9991)E ISO 9991 All irhgts seredevr 3 5 Properties and methods of test Unless otherwise agreed, the properties to be measured and the test m

39、ethods to be used shall be as given in Table 1. Table 1 Properties and methods of test Property Method of test Colour ASTM D 6166 (Spectrophotometric test) IS O6 27 1(Pt-Cosca le ) ISO 4630 (Gardner scale) Flow time ISO 2431 Viscosity ISO 3219 Non-volatile matter a ISO 3251 Flashpoint a ISO 1523 ISO

40、 3679 Acid value b ISO 3682 Hydroxyl value b ISO 4629 Saponification value ISO 3681 Storage stability ISO 15716 Turbidity To be agreed between the interested parties. An International Standard is in preparation (ISO 15715). Density ISO 2811-1 Phthalic anhydride content c ISO 6744-2 Unsaponifiable ma

41、tter c ISO 6744-3 Fatty acid content c, d ISO 6744-4 a For alkyd resin solutions only. b The acid and hydroxyl values shall be calculated on the basis of the non-volatile matter of the resin solution. c These methods are not applicable to alkyd resins that contain benzoic acid or polybasic acids oth

42、er than o-phthalic and/or are modified by compounds such as rosin acids, vinyl toluene, styrene, isocyanates or acrylic, epoxy or silicone compounds. d Rosin acids will be found in tall-oil fatty acids together with the fatty acids. Calculation of these rosin acids as part of the fatty acids shall b

43、e subject to agreement between the interested parties. ENISO67441:2004ISO -44761:(9991)E 4 ISO 9991 All irhgts seredevr 6 Test report The test report shall contain at least the following information: a) a reference to this part of ISO 6744 (ISO 6744-1); b) all details necessary to identify the produ

44、ct tested; c) the results of the tests, and the methods used; d) any deviation, by agreement or otherwise, from the procedures specified; e) the dates of the tests. ENISO67441:2004INESO7644:12(400E) 3 AnnexZA (normative) Normativereferencestointernationalpublications withtheirrelevantEuropeanpublica

45、tions ThisEuropeanStandardincorporatesbydatedorundatedreference,provisionsfromother publications.Thesenormativereferencesarecitedattheappropriateplacesinthetextandthe publicationsarelistedhereafter.Fordatedreferences,subsequentamendmentstoorrevisionsof anyofthesepublicationsapplytothisEuropeanStanda

46、rdonlywhenincorporatedinitby amendmentorrevision.Forundatedreferencesthelatesteditionofthepublicationreferredto applies(includingamendments). NOTEWhereanInternationalPublicationhasbeenmodifiedbycommonmodifications,indicated by(mod.),therelevantEN/HDapplies. Publication Year Title EN Year ISO1523 200

47、2 DeterminationofflashpointClosed cupequilibriummethod ENISO1523 2002 ISO 2431 1993 Paintsandvarnishes Determinationofflowtimebyuseof flowcups ENISO2431 1996 ISO 28111 1997 Paintsandvarnishes DeterminationofdensityPart1: Pyknometermethod ENISO28111 2001 ISO3219 1993 Plastics Polymers/resins in the liquidstateorasemulsionsor dispersionsDeterminationof viscosityusingarotational viscometerwithdefineds