EN ISO 10545-13-2016 en Ceramic tiles - Part 13 Determination of chemical resistance《瓷砖-第13部分 化学性能的测定(ISO 10545-13 2016)》.pdf

1、BS EN ISO 10545-13:2016Ceramic tilesPart 13: Determination of chemical r e s i s t a n c e ( I S O 1 0 5 4 5 - 1 3 : 2 0 1 6 )BSI Standards PublicationWB11885_BSI_StandardCovs_2013_AW.indd 1 15/05/2013 15:06BS EN ISO 10545-13:2016 BRITISH STANDARDNational forewordThis British Standard is the UK impl

2、ementation of EN ISO 10545-13:2016. It supersedes BS EN ISO 10545-13:1997 which is withdrawn.The UK participation in its preparation was entrusted to Technical Committee B/539, Ceramic tiles and other rigid tiling.A list of organizations represented on this committee can be obtained on request to it

3、s secretary.This publication does not purport to include all the necessary provisions of a contract. Users are responsible for its correct application. The British Standards Institution 2016.Published by BSI Standards Limited 2016ISBN 978 0 580 81801 1 ICS 91.100.23 Compliance with a British Standar

4、d cannot confer immunity from legal obligations.This British Standard was published under the authority of the Standards Policy and Strategy Committee on 31 December 2016.Amendments/corrigenda issued since publicationDate T e x t a f f e c t e dEUROPEAN STANDARD NORME EUROPENNE EUROPISCHE NORM EN IS

5、O 10545-13 December 2016 ICS 91.100.23 Supersedes EN ISO 10545-13:1997English Version Ceramic tiles - Part 13: Determination of chemical resistance (ISO 10545-13:2016) Carreaux et dalles cramiques - Partie 13: Dtermination de la rsistance chimique (ISO 10545-13:2016) Keramische Fliesen und Platten -

6、 Teil 13: Bestimmung der chemischen Bestndigkeit (ISO 10545-13:2016) This European Standard was approved by CEN on 28 October 2016. CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this European Standard the status of a national stan

7、dard without any alteration. Up-to-date lists and bibliographical references concerning such national standards may be obtained on application to the CEN-CENELEC Management Centre or to any CEN member. This European Standard exists in three official versions (English, French, German). A version in a

8、ny other language made by translation under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC Management Centre has the same status as the official versions. CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Rep

9、ublic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey andUnited Kingdom. EUROPEAN

10、 COMMITTEE FOR STANDARDIZATION COMIT EUROPEN DE NORMALISATION EUROPISCHES KOMITEE FR NORMUNG CEN-CENELEC Management Centre: Avenue Marnix 17, B-1000 Brussels 2016 CEN All rights of exploitation in any form and by any means reserved worldwide for CEN national Members. Ref. No. EN ISO 10545-13:2016 EB

11、S EN ISO 10545-13:2016EN ISO 10545-13:2016 (E) 3 European foreword This document (EN ISO 10545-13:2016) has been prepared by Technical Committee ISO/TC 189 “Ceramic tile“ in collaboration with Technical Committee CEN/TC 67 “Ceramic tiles” the secretariat of which is held by UNI. This European Standa

12、rd shall be given the status of a national standard, either by publication of an identical text or by endorsement, at the latest by June 2017, and conflicting national standards shall be withdrawn at the latest by June 2017. Attention is drawn to the possibility that some of the elements of this doc

13、ument may be the subject of patent rights. CEN and/or CENELEC shall not be held responsible for identifying any or all such patent rights. This document supersedes EN ISO 10545-13:1997. According to the CEN-CENELEC Internal Regulations, the national standards organizations of the following countries

14、 are bound to implement this European Standard: Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland,

15、 Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and the United Kingdom. Endorsement notice The text of ISO 10545-13:2016 has been approved by CEN as EN ISO 10545-13:2016 without any modification. BS EN ISO 10545-13:2016ISO 10545-13:2016(E)Foreword iv1 Scope . 12 Normative

16、references 13 Terms and definitions . 14 Principle 15 Aqueous test solutions . 15.1 Household chemicals . 15.2 Swimming pool salts 15.3 Acids and alkalis 15.3.1 Low concentrations (L) 15.3.2 High concentrations (H) 26 Apparatus . 27 Test specimens 27.1 Number of test specimens . 27.2 Size of test sp

17、ecimens . 37.3 Preparation of test specimens . 38 Procedure. 38.1 Application of test solutions 38.2 Determination of class 48.2.1 General 48.2.2 Normal classification 48.2.3 Alternative visual classification 49 Test report . 5Bibliography 9 ISO 2016 All rights reserved iiiContents PageBS EN ISO 105

18、45-13:2016ISO 10545-13:2016(E)ForewordISO (the International Organization for Standardization) is a worldwide federation of national standards bodies (ISO member bodies). The work of preparing International Standards is normally carried out through ISO technical committees. Each member body interest

19、ed in a subject for which a technical committee has been established has the right to be represented on that committee. International organizations, governmental and non-governmental, in liaison with ISO, also take part in the work. ISO collaborates closely with the International Electrotechnical Co

20、mmission (IEC) on all matters of electrotechnical standardization.The procedures used to develop this document and those intended for its further maintenance are described in the ISO/IEC Directives, Part 1. In particular the different approval criteria needed for the different types of ISO documents

21、 should be noted. This document was drafted in accordance with the editorial rules of the ISO/IEC Directives, Part 2 (see www.iso.org/directives).Attention is drawn to the possibility that some of the elements of this document may be the subject of patent rights. ISO shall not be held responsible fo

22、r identifying any or all such patent rights. Details of any patent rights identified during the development of the document will be in the Introduction and/or on the ISO list of patent declarations received (see www.iso.org/patents).Any trade name used in this document is information given for the c

23、onvenience of users and does not constitute an endorsement.For an explanation on the meaning of ISO specific terms and expressions related to conformity assessment, as well as information about ISOs adherence to the World Trade Organization (WTO) principles in the Technical Barriers to Trade (TBT) s

24、ee the following URL: www.iso.org/iso/foreword.html.The committee responsible for this document is ISO/TC 189, Ceramic tile.This second edition cancels and replaces the first edition (ISO 10545-13:1995), which has been technically revised.A list of all parts in the ISO 10545 series can be found on t

25、he ISO website.iv ISO 2016 All rights reservedBS EN ISO 10545-13:2016INTERNATIONAL STANDARD ISO 10545-13:2016(E)Ceramic tiles Part 13: Determination of chemical resistance1 ScopeThis document specifies a test method for determining the chemical resistance of ceramic tiles at room temperature. The me

26、thod is applicable to all types of ceramic tiles.2 Normative referencesThe following documents are referred to in the text in such a way that some or all of their content constitutes requirements of this document. For dated references, only the edition cited applies. For undated references, the late

27、st edition of the referenced document (including any amendments) applies.ISO 3585, Borosilicate glass 3.3 Properties3 Terms and definitionsNo terms and definitions are listed in this document.ISO and IEC maintain terminological databases for use in standardization at the following addresses: IEC Ele

28、ctropedia: available at http:/www.electropedia.org/ ISO Online browsing platform: available at http:/www.iso.org/obp4 PrincipleSubjection of the test specimens to the action of the test solutions and visual determination of attack after a defined period.5 Aqueous test solutions5.1 Household chemical

29、sAmmonium chloride solution, 100 g/l.5.2 Swimming pool saltsSodium hypochlorite solution, 20 mg/l, prepared from technical grade sodium hypochlorite solution 5 % (W/V).5.3 Acids and alkalis5.3.1 Low concentrations (L)a) Hydrochloric acid solution, 3 % (V/V), prepared from concentrated hydrochloric a

30、cid ( = 1,19 g/ml).b) Citric acid solution, 100 g/l. ISO 2016 All rights reserved 1BS EN ISO 10545-13:2016ISO 10545-13:2016(E)c) Potassium hydroxide solution, 30 g/l.5.3.2 High concentrations (H)a) Hydrochloric acid solution, 18 % (V/V), prepared from concentrated hydrochloric acid ( = 1,19 g/ml).b)

31、 Lactic acid solution, 5 % (V/V) prepared from 85 % lactic acid.c) Potassium hydroxide solution, 100 g/l.For special cases, other test solutions may, upon agreement by the parties concerned, be tested using the procedure specified in this document. For these cases, no requirement is applicable.6 App

32、aratus6.1 Vessel with a lid, made of borosilicate glass 3.3 (ISO 3585) or any other suitable material.6.2 Cylinder of borosilicate glass 3.3 (ISO 3585) or any other suitable material having a lid or an opening for filling.6.3 Drying oven, capable of being operated at (110 5)C.Microwave, infrared or

33、other drying systems allowing shorter drying times may be used provided that it has been determined that the same results are obtained.6.4 Chamois lather.6.5 White cloth, made of cotton or flax.6.6 Sealing material (for example, plasticine).6.7 Balance, accurate to 0,05 g.6.8 Pencil, of HB hardness

34、(or equivalent).NOTE For more information, see ISO 9177-21.6.9 Electric lamp, of 40 W, white inside (for example, siliconized).7 Test specimens7.1 Number of test specimensThe minimum number of test specimens is reported in Table 1. Test specimens shall be representative of the sample. Where tiles ha

35、ve different colours or decorative effects on parts of the surface, care should be taken to include all distinctive parts.2 ISO 2016 All rights reservedBS EN ISO 10545-13:2016ISO 10545-13:2016(E)Table 1 Number of test specimensTile Maximum area, A (cm2)Tot al noof test specimens (tiles)200 3 600 3Wh

36、en A is 200 cm2, the total no of test specimens (tiles) should be sufficient to cover an area of 200 cm2.7.2 Size of test specimensUse undamaged test specimens which may be either whole tiles or parts of tiles.For procedure with partial immersion, cut a square test specimen (50 mm 50 mm) from each t

37、ile under test.7.3 Preparation of test specimensThoroughly clean the surface with a suitable solvent, for example, ethanol. Do not use test specimens with surface defects.8 Procedure8.1 Application of test solutionsDry each test specimens in the drying oven (6.3) maintained over 105 C 5 C during at

38、least 2 h and then cool them until they reach room temperature. Test specimens shall be tested not later than 3 h after they have reached room temperature.Apply a uniform layer of the sealing material (6.6) 3 mm thick to the rim of the cylinder (6.2). Turn the cylinder upside down onto a fresh part

39、of the proper surface and seal around the rim. Pour the test solution through the inlet to a height of (20 1) mm.If it is not practical to maintain a constant level of solution, immerse the test specimens vertically to a depth of 25 mm in the vessel (6.1) containing the test solution. Cover with the

40、 lid (6.1).The test solution shall be all of those listed in 5.1, 5.2 and 5.3.1; if required, the test solutions listed in 5.3.2 may be used.Maintain the test assembly at (20 5) C.For testing the resistance to household chemicals, swimming pool salts and citric acid, maintain the test solutions in c

41、ontact with the test specimen for 24 h. Remove the cylinder and clean the proper surface with a suitable solvent to completely remove the sealing material. When the procedure by partial immersion is used, maintain the test solutions in contact with the test specimens for 24 h, then remove the test s

42、pecimens.For testing the resistance to hydrochloric acid, lactic acid and potassium hydroxide, maintain the test solution in contact with the test specimen for a total of (96 + 1) h. Ensure that the level of the test solution does not change. Replace the test solution after (48 + 1) h. After more (4

43、8 + 1) h, remove the cylinder and clean the surface with a suitable solvent to completely remove the sealing material.When the procedure by partial immersion is followed, maintain the test solutions in contact with the test specimens for (96 + 1) h, then remove the test specimens.Thoroughly rinse th

44、e specimens under running water for a period of 10 min to remove any residual testing solution. If needed, clean the surface with a soft bristle brush to remove test solutions. ISO 2016 All rights reserved 3BS EN ISO 10545-13:2016ISO 10545-13:2016(E)Dry each test specimens in the drying oven maintai

45、ned over 105 C 5 C and cool to room temperature before evaluation.8.2 Determination of class8.2.1 GeneralIn order to assess whether the pencil test (described in 8.2.2.2) is applicable, draw several lines with the pencil (6.8) on untreated parts of the proper face of the tile and attempt to remove t

46、he marks with a wet cloth (6.5).If the pencil marks cannot be removed, the classification system of Figure 1 is not applicable and these tiles shall be reported as “Normal classification not possible”. An alternative visual classification is provided for these tiles in 8.2.3.8.2.2 Normal classificat

47、ionFor tiles passing the pencil test, carry out the operations described in 8.2.2.1, 8.2.2.2 and 8.2.2.3 and apply the classification system indicated in Figure 1.8.2.2.1 Visual examinationExamine the proper surface that has been tested from all angles from a standard distance of 25 cm and under a m

48、inimum artificial illumination of 300 lx 10 lx, with the naked eye or with spectacles if usually worn, for any difference in appearance from a untreated surface, for example, for change in colour, reflection, surface texture or the development of brilliance. After examination, if there is no visible

49、 effect, perform the pencil test described in 8.2.2.2. If there is a visible effect, perform the reflection test described in 8.2.2.3.8.2.2.2 Pencil testDraw several lines with the pencil (6.8) both on the surface under test and on the untreated surface. Attempt to remove the pencil lines with the wet cloth (6.5). If the pencil marks are removed from the treated surface, the surface corresponds to class A. If they are not removed, the surface corresponds to class B.8.2.2.3 Reflection testHold the tile so that the image of the