EN ISO 12086-1-2006 en Plastics - Fluoropolymer dispersions and moulding and extrusion materials - Part 1 Designation system and basis for specifications (Incorporating Corrigendum.pdf

1、BRITISH STANDARDBS EN ISO 12086-1:2006Incorporating corrigendum August 2006Plastics Fluoropolymer dispersions and moulding and extrusion materials Part 1: Designation system and basis for specificationsICS 83.080.20g49g50g3g38g50g51g60g44g49g42g3g58g44g55g43g50g56g55g3g37g54g44g3g51g40g53g48g44g54g5

2、4g44g50g49g3g40g59g38g40g51g55g3g36g54g3g51g40g53g48g44g55g55g40g39g3g37g60g3g38g50g51g60g53g44g42g43g55g3g47g36g58BS EN ISO 12086-1:2006This British Standard was published under the authority of the Standards Policy and Strategy Committee on 31 March 2006 BSI 2008ISBN 978 0 580 61541 2National fore

3、wordThis British Standard is the UK implementation of EN ISO 12086-1:2006, incorporating corrigendum November 2007. It is identical with ISO 12086-1:2006, incorporating corrigendum August 2006. It supersedes BS EN ISO 12086-1:2001 which is withdrawn.The start and finish of text introduced or altered

4、 by corrigendum is indicated in the text by tags. Text altered by ISO corrigendum August 2006 is indicated in the text by .The UK participation in its preparation was entrusted to Technical Committee PRI/82, Thermoplastic materials.A list of organizations represented on this committee can be obtaine

5、d on request to its secretary.This publication does not purport to include all the necessary provisions of a contract. Users are responsible for its correct application. Compliance with a British Standard cannot confer immunity from legal obligations.Amendments/corrigenda issued since publicationDat

6、e Comments31 March 2008 Implementation of ISO corrigendum August 2006 with CEN endorsement corrigendum November 2007EUROPEAN STANDARDNORME EUROPENNEEUROPISCHE NORMEN ISO 12086-1February 2006ICS 83.080.20Supersedes EN ISO 12086-1:1999 English VersionPlastics - Fluoropolymer dispersions and moulding a

7、nd extrusionmaterials - Part 1: Designation system and basis forspecifications (ISO 12086-1:2006)Plastiques - Polymres fluors: dispersions et matriauxpour moulage et extrusion - Partie 1: Systme dedsignation et base de spcification (ISO 12086-1:2006)Kunststoffe - Fluorpolymerdispersionen, Formmassen

8、 undExtrusions-materialien - Teil 1: Bezeichnungssystem undBasis fr Spezifikationen (ISO 12086-1:2006)This European Standard was approved by CEN on 13 February 2006.CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this EuropeanStanda

9、rd the status of a national standard without any alteration. Up-to-date lists and bibliographical references concerning such nationalstandards may be obtained on application to the Central Secretariat or to any CEN member.This European Standard exists in three official versions (English, French, Ger

10、man). A version in any other language made by translationunder the responsibility of a CEN member into its own language and notified to the Central Secretariat has the same status as the officialversions.CEN members are the national standards bodies of Austria, Belgium, Cyprus, Czech Republic, Denma

11、rk, Estonia, Finland, France,Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania,Slovakia, Slovenia, Spain, Sweden, Switzerland and United Kingdom.EUROPEAN COMMITTEE FOR STANDARDIZATIONCOMIT EUROPEN DE NORMALISATIONE

12、UROPISCHES KOMITEE FR NORMUNGManagement Centre: rue de Stassart, 36 B-1050 Brussels 2006 CEN All rights of exploitation in any form and by any means reservedworldwide for CEN national Members.Ref. No. EN ISO 12086-1:2006: EIncorporating CEN corrigendum November 2007 Foreword This document (EN ISO 12

13、086-1:2006) has been prepared by Technical Committee ISO/TC 61 “Plastics“ in collaboration with Technical Committee CEN/TC 249 “Plastics“, the secretariat of which is held by IBN. This European Standard shall be given the status of a national standard, either by publication of an identical text or b

14、y endorsement, at the latest by August 2006, and conflicting national standards shall be withdrawn at the latest by August 2006. This document supersedes EN ISO 12086-1:1999. According to the CEN/CENELEC Internal Regulations, the national standards organizations of the following countries are bound

15、to implement this European Standard: Austria, Belgium, Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland an

16、d United Kingdom. Endorsement notice The text of ISO 12086-1:2006 has been approved by CEN as EN ISO 12086-1:2006 without any modifications. BS EN ISO 12068-1:2006Reference numberISO 12086-1:2006(E)INTERNATIONAL STANDARD ISO12086-1Second edition2006-02-15Plastics Fluoropolymer dispersions and mouldi

17、ng and extrusion materials Part 1: Designation system and basis for specifications Plastiques Polymres fluors: dispersions et matriaux pour moulage et extrusion Partie 1: Systme de dsignation et base de spcification BS EN ISO 12068-1:2006ii iiiContents Page Foreword iv 1 Scope . 1 2 Normative refere

18、nces . 2 3 Terms and definitions. 3 4 Abbreviated terms and symbols . 5 5 Designation system 6 5.1 General. 6 5.2 Data block 1. 6 5.3 Data block 2. 7 5.4 Data block 3. 9 5.4.1 General. 9 5.4.2 Transition temperatures. 9 5.4.3 Relative molecular mass 11 5.4.4 Mechanical properties 12 5.4.5 Density .

19、14 5.4.6 Percentage fluoropolymer and surfactant . 14 5.4.7 Particle size . 15 5.4.8 Bulk density. 15 5.4.9 Powder-flow time 16 5.4.10 Extrusion pressure . 16 5.4.11 Contamination. 16 5.5 Data block 4. 16 5.6 Data block 5. 17 5.7 Designatory properties for fluoropolymers . 17 5.7.1 Designatory prope

20、rties applicable to all fluoropolymers. 17 5.7.2 Designatory properties specific to particular classes of fluoropolymer 18 6 Example of a designation 19 7 Specifications for fluoropolymers 19 8 Packaging and marking . 21 8.1 Packaging 21 8.2 Marking 21 9 Sampling 21 Annex A (normative) Designatory p

21、roperties for common fluoropolymer types 22 Annex B (normative) Designatory properties for common fluoropolymer types with cross-reference listing to the tables for codes in ISO 12086-1 and the test methods in ISO 12086-2 24 Annex C (informative) The fluoropolymer family 26 Annex D (informative) Sta

22、ndard specifications for fluoropolymers . 28 Annex E (informative) Listing of test methods included in ISO 12086-2 (in alphabetical order) . 29 Annex F (informative) Brief instructions for use of this part of ISO 12086 30 BS EN ISO 12068-1:2006iv Foreword ISO (the International Organization for Stan

23、dardization) is a worldwide federation of national standards bodies (ISO member bodies). The work of preparing International Standards is normally carried out through ISO technical committees. Each member body interested in a subject for which a technical committee has been established has the right

24、 to be represented on that committee. International organizations, governmental and non-governmental, in liaison with ISO, also take part in the work. ISO collaborates closely with the International Electrotechnical Commission (IEC) on all matters of electrotechnical standardization. International S

25、tandards are drafted in accordance with the rules given in the ISO/IEC Directives, Part 2. The main task of technical committees is to prepare International Standards. Draft International Standards adopted by the technical committees are circulated to the member bodies for voting. Publication as an

26、International Standard requires approval by at least 75 % of the member bodies casting a vote. Attention is drawn to the possibility that some of the elements of this document may be the subject of patent rights. ISO shall not be held responsible for identifying any or all such patent rights. ISO 12

27、086-1 was prepared by Technical Committee ISO/TC 61, Plastics, Subcommittee SC 9, Thermoplastic materials. This second edition cancels and replaces the first edition (ISO 12086-1:1995), which has been technically revised. ISO 12086 consists of the following parts, under the general title Plastics Fl

28、uoropolymer dispersions and moulding and extrusion materials: Part 1: Designation system and basis for specifications Part 2: Preparation of test specimens and determination of properties BS EN ISO 12068-1:20061Plastics Fluoropolymer dispersions and moulding and extrusion materials Part 1: Designati

29、on system and basis for specifications 1 Scope 1.1 This part of ISO 12086 establishes a system of designation for fluoropolymer materials that may be used as the basis for specifications. It covers the homopolymers and various copolymers of fluoromonomers used as dispersions and for moulding, extrus

30、ion and other specialized applications. This part of ISO 12086 describes the designation system and provides codes and tables of values for the designatory properties. The designation system is applicable both to conventional thermoplastic fluoropolymers, processed by various techniques, and those m

31、aterials that are processed by the unique operations required for the non-conventional thermoplastic polytetrafluoroethylene. The materials include both the fluorocarbon polymers and the various other fluoropolymers as virgin polymers or processed for reuse or recycling. This part of ISO 12086 also

32、includes an extension of the designation system that provides a basis for specification of the materials. This basis for specification may be used to prepare specifications related to well-defined applications. As explained in Clause 5, these specifications will use data blocks 1 to 4 and, if necess

33、ary, data block 5 as a complement, the last-mentioned data block containing the specific requirements in relation to the application. Fluoroelastomers are specifically excluded. 1.2 Fluoropolymers are long-chain homopolymers and copolymers of fluoromonomers. Fluoropolymers can be modified with small

34、 amounts of different fluoromonomers. In general, provided the polymer is not modified with more than five percent by mass of modifying fluoromonomer(s), it can be classed as the base polymer. PVDF is classed as the base polymer when it is modified during polymerization with up to two percent by mas

35、s of additional fluoromonomers in the polymer structure. For PTFE, up to one percent by mass of a modifying comonomer is the limit for the material to be classed as polytetrafluoroethylene. A general discussion of members of the fluoropolymer family is included in Annex C. This part of ISO 12086 is

36、particularly concerned with, but is not limited to, the materials listed in 4.2. The accepted abbreviated term for each material is included in 4.2. 1.3 The various types of fluoropolymer are differentiated from each other by a classification system based on the fluoropolymer genus and appropriate l

37、evels of the designatory properties, along with information about basic polymer parameters, intended application or method of processing, important properties, additives, colorants, fillers and reinforcing materials. Designatory properties for each fluoropolymer are selected from the general list in

38、 5.4, and those properties to be designated for each fluoropolymer are listed in 5.7 and in Annexes A and B. 1.4 Provision is made for designation of materials involved in reuse and recycling of the fluoropolymers covered by this part of ISO 12086. A set of designatory properties is provided for rep

39、rocessed PTFE because of its special requirements. For non-virgin conventional thermoplastic fluoropolymers, the same designatory properties as used for virgin materials are used with inclusion of the code Z1, Z2 or Z3 in data block 1 as specified in Table 1. 1.5 It is not intended to imply that mat

40、erials having the same designation necessarily give the same performance. The converse should also be emphasized, i.e. materials with different designations may be suitable for use in the same application. This part of ISO 12086 does not provide engineering data, performance data or processing condi

41、tions which may be required to specify materials for particular end-use applications (see the discussion on use of data block 5 in Clauses 5 and 7). If such additional properties are required, they can be determined in accordance with the test methods specified in ISO 12086-2, if suitable. BS EN ISO

42、 12068-1:20062 2 Normative references The following referenced documents are indispensable for the application of this document. For dated references, only the edition cited applies. For undated references, the latest edition of the referenced document (including any amendments) applies. ISO 472, Pl

43、astics Vocabulary ISO 527-2, Plastics Determination of tensile properties Part 2: Test conditions for moulding and extrusion plastics ISO 1043-1, Plastics Symbols and abbreviated terms Part 1: Basic polymers and their special characteristics ISO 1043-2, Plastics Symbols and abbreviated terms Part 2:

44、 Fillers and reinforcing materials ISO 1133, Plastics Determination of the melt mass-flow rate (MFR) and the melt volume-flow rate (MVR) of thermoplastics ISO 1183-1, Plastics Methods for determining the density of non-cellular plastics Part 1: Immersion method, liquid pyknometer method and titratio

45、n method ISO 1183-2, Plastics Methods for determining the density of non-cellular plastics Part 2: Density gradient column method ISO 12000, Plastics/rubber Polymer dispersions and rubber latices (natural and synthetic) Definitions and review of test methods ISO 12086-2, Plastics Fluoropolymer dispe

46、rsions and moulding and extrusion materials Part 2: Preparation of test specimens and determination of properties ASTM D 1430, Standard Classification System for Polychlorotrifluoroethylene (PCTFE) Plastics ASTM D 1600, Standard Terminology for Abbreviated Terms Relating to Plastics ASTM D 3222, Sta

47、ndard Specification for Unmodified Poly(Vinylidene Fluoride) (PVDF) Molding, Extrusion and Coating Materials ASTM D 3418, Standard Test Method for Transition Temperatures of Polymers by Differential Scanning Calorimetry ASTM D 3892, Standard Practice for Packaging/Packing of Plastics ASTM D 4591, St

48、andard Test Method for Determining Temperatures and Heats of Transitions of Fluoropolymers by Differential Scanning Calorimetry ASTM D 4895, Standard Specification for Polytetrafluoroethylene (PTFE) Resin Produced from Dispersion ASTM D 5033, Standard Guide for Development of ASTM Standards Relating

49、 to Recycling and Use of Recycled Plastics BS EN ISO 12068-1:200633 Terms and definitions For the purposes of this document, the terms and definitions given in ISO 472 and the following terms and definitions apply. The terms listed in 3.1 to 3.3 are repeated from ISO 472 to be sure there is no misunderstanding. 3.1 dispersion heterogeneous system in which a finely divided material is distributed in another material 3.2 fluoroplastic plastic based on polymers made with monomers containing one or more atoms of flu