EN ISO 12086-2-2006 en Plastics - Fluoropolymer dispersions and moulding and extrusion materials - Part 2 Preparation of test specimens and determination of properties《塑料 含氟聚合物分散体模.pdf

1、BRITISH STANDARDBS EN ISO 12086-2:2006Incorporating Technical Corrigendum No. 1Plastics Fluoropolymer dispersions and moulding and extrusion materials Part 2: Preparation of test specimens and determination of propertiesThe European Standard EN ISO 12086-2:2006 has the status of a British StandardIC

2、S 83.080.20g49g50g3g38g50g51g60g44g49g42g3g58g44g55g43g50g56g55g3g37g54g44g3g51g40g53g48g44g54g54g44g50g49g3g40g59g38g40g51g55g3g36g54g3g51g40g53g48g44g55g55g40g39g3g37g60g3g38g50g51g60g53g44g42g43g55g3g47g36g58BS EN ISO 12086-2:2006This British Standard was published under the authority of the Stan

3、dards Policy and Strategy Committee on 31 March 2006 BSI 2006ISBN 0 580 47996 XNational forewordThis British Standard was published by BSI. It is the UK implementation of EN ISO 12086-2:2006. It is identical with ISO 12086-2:2006, incorporating Technical Corrigendum August 2006. It supersedes BS EN

4、ISO 12086-2:2001, which is withdrawn.The UK participation in its preparation was entrusted to Technical Committee PRI/82, Thermoplastic materials.A list of organizations represented on this PRI/82 can be obtained on request to its secretary.This publication does not purport to include all the necess

5、ary provisions of a contract. Users are responsible for its correct application. Compliance with a British Standard cannot confer immunity from legal obligations.Amendments issued since publicationAmd. No. Date Comments16756 Corrigendum No. 130 November 2006 Correction to Table 2 and Annex BEUROPEAN

6、 STANDARDNORME EUROPENNEEUROPISCHE NORMEN ISO 12086-2February 2006ICS 83.080.20 Supersedes EN ISO 12086-2:1999 English VersionPlastics - Fluoropolymer dispersions and moulding and extrusionmaterials - Part 2: Preparation of test specimens anddetermination of properties (ISO 12086-2:2006)Plastiques -

7、 Polymres fluors: dispersions et matriauxpour moulage et extrusion - Partie 2: Prparation desprouvettes et dtermination des proprits (ISO 12086-2:2006)Kunststoffe - Fluorpolymerdispersionen, Formmassen undExtrusionsmaterialien - Teil 2: Herstellung vonProbekrpern und Bestimmung von Eigenschaften (IS

8、O12086-2:2006)This European Standard was approved by CEN on 13 February 2006.CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this EuropeanStandard the status of a national standard without any alteration. Up-to-date lists and biblio

9、graphical references concerning such nationalstandards may be obtained on application to the Central Secretariat or to any CEN member.This European Standard exists in three official versions (English, French, German). A version in any other language made by translationunder the responsibility of a C

10、EN member into its own language and notified to the Central Secretariat has the same status as the officialversions.CEN members are the national standards bodies of Austria, Belgium, Cyprus, Czech Republic, Denmark, Estonia, Finland, France,Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia,

11、Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania,Slovakia, Slovenia, Spain, Sweden, Switzerland and United Kingdom.EUROPEAN COMMITTEE FOR STANDARDIZATIONCOMIT EUROPEN DE NORMALISATIONEUROPISCHES KOMITEE FR NORMUNGManagement Centre: rue de Stassart, 36 B-1050 Brussels 2006

12、 CEN All rights of exploitation in any form and by any means reservedworldwide for CEN national Members.Ref. No. EN ISO 12086-2:2006: EForeword This document (EN ISO 12086-2:2006) has been prepared by Technical Committee ISO/TC 61 “Plastics“ in collaboration with Technical Committee CEN/TC 249 “Plas

13、tics“, the secretariat of which is held by IBN. This European Standard shall be given the status of a national standard, either by publication of an identical text or by endorsement, at the latest by August 2006, and conflicting national standards shall be withdrawn at the latest by August 2006. Thi

14、s document supersedes EN ISO 12086-2:1999. According to the CEN/CENELEC Internal Regulations, the national standards organizations of the following countries are bound to implement this European Standard: Austria, Belgium, Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, H

15、ungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland and United Kingdom. Endorsement notice The text of ISO 12086-2:2006 has been approved by CEN as EN ISO 12086-2:2006 without any modifi

16、cations. EN ISO 12086-2:2006Reference numberISO 12086-2:2006(E)INTERNATIONAL STANDARD ISO12086-2Second edition2006-02-15Plastics Fluoropolymer dispersions and moulding and extrusion materials Part 2: Preparation of test specimens and determination of properties Plastiques Polymres fluors: dispersion

17、s et matriaux pour moulage et extrusion Partie 2: Prparation des prouvettes et dtermination des proprits EN ISO 12086-2:2006ii iiiContents Page Foreword iv 1 Scope . 1 2 Normative references . 1 3 Terms and definitions. 3 4 Abbreviated terms and symbols . 4 5 Sampling 5 6 Preparation of test specime

18、ns 5 7 Conditioning and test conditions 5 8 General testing of fluoropolymers 5 8.1 Electrical properties . 6 8.2 Mechanical properties 8 8.3 Thermal-transition temperatures 10 8.4 Density . 11 8.5 Flammability by oxygen index. 11 8.6 Particle size and size distribution. 11 9 Testing of fluoropolyme

19、r dispersions 17 9.1 General. 17 9.2 Preparation of test samples. 18 9.3 Isolation of PTFE from dispersion 18 9.4 Coagulum in dispersions. 19 9.5 Percentage polymer and surfactant in aqueous dispersion 19 9.6 PTFE solids content by hydrometer . 20 9.7 pH of dispersions 21 10 Testing of PTFE and clos

20、ely related materials 21 10.1 General. 21 10.2 Preparation of test specimens by moulding 21 10.3 Bulk density. 23 10.4 Extrusion pressure . 27 10.5 Powder-flow time 32 10.6 Standard specific gravity (SSG), extended specific gravity (ESG) and thermal-instability index (TII) . 34 10.7 Stretching-void

21、index (SVI) 37 11 Testing of conventionally melt-processible fluoropolymers . 38 11.1 Preparation of test specimens by moulding 38 11.2 Melt mass-flow rate (MFR) and melt volume-flow rate (MVR) 39 12 Other test methods used with fluoropolymers 41 12.1 Brittleness temperature of plastics and elastome

22、rs by impact . 41 12.2 Coefficients of static and kinetic friction . 41 12.3 Zero-strength time 41 Annex A (informative) Listing of test methods (alphabetical order). 42 Annex B (informative) Designatory properties for common fluoropolymer types with cross-reference listing to the tables for codes i

23、n ISO 12086-1 and the test methods in ISO 12086-2 43 Bibliography . 45 EN ISO 12086-2:2006iv Foreword ISO (the International Organization for Standardization) is a worldwide federation of national standards bodies (ISO member bodies). The work of preparing International Standards is normally carried

24、 out through ISO technical committees. Each member body interested in a subject for which a technical committee has been established has the right to be represented on that committee. International organizations, governmental and non-governmental, in liaison with ISO, also take part in the work. ISO

25、 collaborates closely with the International Electrotechnical Commission (IEC) on all matters of electrotechnical standardization. International Standards are drafted in accordance with the rules given in the ISO/IEC Directives, Part 2. The main task of technical committees is to prepare Internation

26、al Standards. Draft International Standards adopted by the technical committees are circulated to the member bodies for voting. Publication as an International Standard requires approval by at least 75 % of the member bodies casting a vote. Attention is drawn to the possibility that some of the elem

27、ents of this document may be the subject of patent rights. ISO shall not be held responsible for identifying any or all such patent rights. ISO 12086-2 was prepared by Technical Committee ISO/TC 61, Plastics, Subcommittee SC 9, Thermoplastic materials. This second edition cancels and replaces the fi

28、rst edition (ISO 12086-2:1995), which has been technically revised. ISO 12086 consists of the following parts, under the general title Plastics Fluoropolymer dispersions and moulding and extrusion materials: Part 1: Designation system and basis for specifications Part 2: Preparation of test specimen

29、s and determination of properties EN ISO 12086-2:20061Plastics Fluoropolymer dispersions and moulding and extrusion materials Part 2: Preparation of test specimens and determination of properties SAFETY STATEMENT Persons using this document should be familiar with normal laboratory practice, if appl

30、icable. This document does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user to establish appropriate safety and health practices and to ensure compliance with any regulatory requirements. The warnings in Subclauses 8.6.2.1, 9.7

31、and 10.6.1.4 point out specific hazards. 1 Scope 1.1 This part of ISO 12086 describes the preparation of test specimens and provides test methods to define characteristics of thermoplastic fluoropolymer resins. Results from the testing may be used as the basis for designation, material specification

32、s or both. This part of ISO 12086 describes the conditions of test for determining both designatory and other properties of the homopolymers and various copolymers of fluoromonomers, as dispersions or powders for moulding, extrusion and other uses. The test procedures included are appropriate for, b

33、ut are not restricted to, the fluoropolymers listed in Clause 4 and for which designatory properties are specified in ISO 12086-1. 1.2 The properties of semi-finished and finished products made from fluoropolymer resins depend on the material used, the shape of the product, the physical and morpholo

34、gical state of the material resulting from the processing operations, and on the test conditions. Therefore, to obtain reproducible test results, the defined methods of preparation of test specimens and defined test conditions given in this part of ISO 12086 must be applied. 1.3 Agreements between v

35、endor and purchaser should preferably be based on properties measured using the specimens and test conditions described in this part of ISO 12086. 2 Normative references The following referenced documents are indispensable for the application of this document. For dated references, only the edition

36、cited applies. For undated references, the latest edition of the referenced document (including any amendments) applies. ISO 75-2, Plastics Determination of temperature of deflection under load Part 2: Plastics and ebonite ISO 178, Plastics Determination of flexural properties ISO 179-1, Plastics De

37、termination of Charpy impact properties Part 1: Non-instrumented impact test ISO 180, Plastics Determination of lzod impact strength ISO 291, Plastics Standard atmospheres for conditioning and testing ISO 293, Plastics Compression moulding of test specimens of thermoplastic materials ISO 472, Plasti

38、cs Vocabulary ISO 527-1, Plastics Determination of tensile properties Part 1: General principles EN ISO 12086-2:20062 ISO 527-2, Plastics Determination of tensile properties Part 2: Test conditions for moulding and extrusion plastics ISO 527-3, Plastics Determination of tensile properties Part 3: Te

39、st conditions for films and sheets ISO 565, Test sieves Metal wire cloth, perforated metal plate and electroformed sheet Nominal sizes of openings ISO 976, Rubber and plastics Polymer dispersions and rubber latices Determination of pH ISO 1043-1, Plastics Symbols and abbreviated terms Part 1: Basic

40、polymers and their special characteristics ISO 1043-2, Plastics Symbols and abbreviated terms Part 2: Fillers and reinforcing materials ISO 1133:2005, Plastics Determination of the melt mass-flow rate (MFR) and the melt volume-flow rate (MVR) of thermoplastics ISO 1183-1, Plastics Methods for determ

41、ining the density of non-cellular plastics Part 1: Immersion method, liquid pyknometer method and titration method ISO 1183-2, Plastics Methods for determining the density of non-cellular plastics Part 2: Density gradient column method ISO 4589 (all parts), Plastics Determination of burning behaviou

42、r by oxygen index ISO 11357-2, Plastics Differential scanning calorimetry (DSC) Part 2: Determination of glass transition temperature ISO 11357-3, Plastics Differential scanning calorimetry (DSC) Determination of temperature and enthalpy of melting and crystallization ISO 12086-1, Plastics Fluoropol

43、ymer dispersions and moulding and extrusion materials Part 1: Designation system and basis for specifications ISO 13320-1, Particle size analysis Laser diffraction methods General principles IEC 60093, Methods of test for volume resistivity and surface resistivity of solid electrical insulating mate

44、rials IEC 60243-1, Electrical strength of insulating materials Test methods Part 1: Tests at power frequencies IEC 60250, Recommended methods for the determination of the permittivity and dielectric dissipation factor of electrical insulating materials at power, audio and radio frequencies including

45、 metre wavelengths ASTM D 746, Standard Test Method for Brittleness Temperature of Plastics and Elastomers by Impact ASTM D 1430, Standard Classification System for Polychlorotrifluoroethylene (PCTFE) Plastics ASTM D 1894, Standard Test Method for Static and Kinetic Coefficients of Friction of Plast

46、ic Film and Sheeting ASTM D 3418, Standard Test Method for Transition Temperatures of Polymers by Differential Scanning Calorimetry ASTM D 4052, Standard Test method for Density and Relative Density of Liquids by Digital Density Meter ASTM D 4591, Standard Test Method for Determining Temperatures an

47、d Heats of Transitions of Fluoropolymers by Differential Scanning Calorimetry ASTM D 4894, Standard Specification for Polytetrafluoroethylene (PTFE) Granular Molding and Ram Extrusion Materials ASTM D 4895, Standard Specification for Polytetrafluoroethylene (PTFE) Resin Produced from Dispersion BS 4

48、641:1986, Method for specifying electroplated coatings of chromium for engineering purposes EN ISO 12086-2:200633 Terms and definitions For the purposes of this document, the terms and definitions given in ISO 472 and the following terms and definitions apply. The terms listed in 3.1 to 3.3 are repe

49、ated from ISO 472 to be sure there is no misunderstanding. 3.1 dispersion heterogeneous system in which a finely divided material is distributed in another material 3.2 fluoroplastic plastic based on polymers made with monomers containing one or more atoms of fluorine, or copolymers of such monomers with other monomers, the fluoromonomer being in the greatest amount by mass 3.3 latex colloidal aqueous dispersion of a polymeric material 3.4 amorphous noncrystalline