EN ISO 14527-3-1999 en Plastics - Urea-Formaldehyde and Urea Melamine-Formaldehyde Powder Moulding Compounds (UF- and UF MF-PMCs) - Part 3 Requirements for Selected Moulding Compou.pdf

1、 STD-BSI BS EN IS0 14527-3-ENGL 2000 I 3b24bb 0823432 347 BRITISH STANDARD Plastics - Urea-formaldehyde and uredmelamine- formaldehyde powder moulding compounds (UF- and UFYMF-PMCs) - Part 3: Requirements for selected moulding compounds The European Standard EN IS0 14527-3 1999 has the status of a B

2、ritish Standard ICs 83.080.10 BS EN IS0 1452 73:ZOOo NO COPYING WITHOUT BSI PERMISSION EXCEPT AS PERMITTED BY COPYRIGHT LAW STD.BSI BS EN IS0 14527-3-ENGL 2000 I Lh24bb9 0823413 083 been prepared under the Committee for Materiais and Chemicals, was published under the authority of the Standards Comm

3、ittee and comes into effect on 15 January 2000 direction of the Sector Amd. No. O BSI 01-2000 ISBN O 580 35878 X ES EN IS0 145273:2000 Date Comments National foreword This British Standard is the Enghsh language version of EN IS0 14527-3:1999. It ic identical with IS0 14527-3:1999. The UK participat

4、ion in its preparation was entrusted to Technical Committee PRV42, Fibre reinforced thermosetting plastics and prepregs, which has the responsibility to: - aid enquirers to understand the text; - present to the responsible internationallEuropean committee any enquiries on the interpretation, or prop

5、osals for change, and keep the UK interests informed; - monitor related international and European developments and promulgate them in the UK A list of organizations represented on this committee can be obtained on request to its secretary. Cross-references Attention is drawn to the fact that CEN an

6、d CENELEC Standards normally include an annex which lists normative references to international publications with their corresponding European publications. The British Standards which implement international or European publications referred to in this document may be found in the BSI Standards Cat

7、alogue under the section entitled “International Standards Correspondence Index”, or by using the “Find facility of the BSI standards Electronic Catalogue. A British Standard does not purport to include all the necessary provisions of a contract. Users of British Standards are responsible for their

8、correct application. Compliance with a British Standard does not of itself confer immunity from legal obligations. Summary of pages This document comprises a front cover, an inside front cover, the EN IS0 title page, the EN IS0 foreword page, the IS0 title page, pages ii and iii, a blank page, pages

9、 1 to 4, an inside back cover and a back cover. The BSI copyright notice displayed in this document indicates when the document was last issued. STD-BSI BS EN IS0 L4527-3-ENGL 2000 m 3b24bb9 0823434 TLT m EUROPEAN STANDARD NORME EUROPENNE EUROPISCHE NORM EN IS0 145274 November 1999 ICs 83.080.10 Eng

10、lish version Plastics - Urea-formaldehyde and uredmelamine-formaldehyde powder moulding compounds (UF- and UF/MF-PMCs) - Part 3: Requirements for selected moulding compounds (IS0 14527- 3: 1 999) Plastiques - Poudres mouler A base dure-fomialdhyde et duremlamine-formaldhyde (UF- et UF/MF-PMC) - Part

11、ie 3: Exigences relatives certaines poudres mouler (IS0 14527-31 999) This European Standard was approved by GEN on 13 October 1999. CEN members are bound to mpiy with the CENICENELEC internal Regulations which stipulate the conditions for giving this European Standard the status of a national stand

12、ard without any alteration. Up-to-date lists and bibiiographical references concerning such national standards may be obtained on application to the Central Secretariat or to any CEN member. This European Standard exists in three oficial versions (English, French, Geman). A version in any other lang

13、uage made by translatlon under the responsibility of a CEN member into its own language and notified to the Central Secretarial has the same status as the official versions. CEN members are the national standards bodies of Austria, Belgium, Czech Republic, Denmark, Finland, France, Gemany, Greece, I

14、celand, Ireland, Italy, Luxembourg, Netherlands. Norway, Portugal, Spain. Sweden, Switzerland and United Kingdom. EUROPEAN COMMlTEE FOR STANDARDIZATION COMITE EUROPEEN DE NORMALISATION EUROPISCHES KOMITEE FR NORMUNG Central Secretarlat: rue de Stassart, 36 B-1050 Brussels 0 1999 CEN All rights of ex

15、ploitation in any form and by any means reserved worldwide for CEN national Members. Ref. No. EN IC0 14527-3:1999 E STD.BSI BS EN IS0 14527-3-ENGL ZOO0 O lbZ4bb 0823415 75b EN IS0 14527-3:1999 Foreword The text of the International Standard IS0 14527-3:1999 has been prepared by Technical Committee I

16、SOiTC 61 “Plastics“ in collaboration with Technical Committee CENTTC 249 “Plastics“, the secretariat of which is held by IBN. This European Standard shall be given the status of a national standard, either by publication of an identical text or by endorsement, at the latest by May 2000, and conflict

17、ing national standards shall be withdrawn at the latest by May 2000. According to the CENCENELEC Internal Regulations, the national standards organizations of the following countries are bound to implement this European Standard: Austria, Belgium, Czech Republic, Denmark, Finland, France, Germany, G

18、reece, Iceland, Ireland, Italy, Luxembourg, Netherlands, Norway, Portugal, Spain, Sweden, Switzerland and the United Kingdom. NOTE FROM CENES: The foreword is susceptible to be amended on reception of the German language version. The confirmed or amended foreword, and when appropriate, the normative

19、 annex ZA for the references to international publications with their relevant European publications will be circulated with the German version. Endorsement notice The text of the international Standard IS0 14527-3:1999 was approved by CEN as a European Standard without any modification. STD.BS1 BS

20、EN IS0 14527-3-ENGL 2000 I Lb24669 0823436 892 E INTERNATIONAL STANDARD EN IS0 14527-3:1999 IS0 14527-3 First edition 1999-1 1-1 5 Plastics - Urea-formaldehyde and urea/melamine-formaldehyde powder moulding compounds (UF- and Part 3: Requirements for selected moulding compounds UFIMF-PMCS) - Plastiq

21、ues - Poudres mouler base dure-formaldhyde et dure/mlamine-formaldhyde (UF- et UF/MF-PMC) - Partie 3: Exigences relatives certaines poudres mouler Reference number IS0 14527-311 999( E) STD-BSI ES EN IS0 14527-3-ENGL 2000 3624bb 0823417 727 EN IS0 14527-3:1999 Foreword IS0 (the International Organiz

22、ation for Standardization) is a worldwide federation of national standards bodies (IS0 member bodies). The work of preparing International Standards is normally carried out through IS0 technical committees. Each member body interested in a subject for which a technical committee has been established

23、 has the right to be represented on that committee. International organizations, governmental and non-governmental, in liaison with ISO, also take part in the work. IS0 collaborates closely with the International Electrotechnical Commission (IEC) on all matters of electrotechnical standardization. I

24、nternational Standards are drafted in accordance with the rules given in the ISOAEC Directives, Part 3. Draft International Standards adopted by the technical committees are circulated to the member bodies for voting. Publication as an International Standard requires approval by at least 75 % of the

25、 member bodies casting a vote. Attention is drawn to the possibility that some of the elements of this part of IS0 14527 may be the subject of patent rights. IS0 shall not be held responsible for identifying any or all such patent rights. International Standard IS0 14527-3 was prepared by Technical

26、Committee ISOTTC 61, Plastics, Subcommittee SC 12, Thermosetting materials. After a transition period of, at the most, four years, the three parts of IS0 14527 (see below), together with the three parts of IS0 14528, will replace IS0 21 12:1990, of which they constitute a technical revision. IS0 145

27、27 consists of the following parts, under the general title Plastics - Urea-formaldehyde and uredmelamine-formaldehyde powder moulding compounds (UF- and UF/MF-PMCs): - Part 1: Designation system and basis for specifications - Part 2: Preparation of test specimens and determination of properties - P

28、art 3: Requirements for selected moulding compounds Annex A of this part of IS0 14527 is for information only. Previous page is blank . 111 EN IS0 14527-3:1999 Plastics - Urea-formaldehyde and urea/melamine-formaldehyde powder moulding compounds (UF- and UF/MF-PMCs) - Part 3: Requirements for select

29、ed moulding compounds 1 Scope This part of IS0 14527 specifies the requirements for the physical and chemical properties of urea-formaldehyde and urea/melamine-formaldehyde powder moulding compounds (UF- and UF/MF-PMCs) and compression- or injection-moulded test specimens produced from them. It is l

30、imited to those powder moulding compounds whose composition and properties are significantly different. It is further limited to those moulding compounds which are of general technical and/or economic importance. The properties which are used to characterize the moulding compounds, the test methods

31、and the test conditions are selected from those given in IS0 14527-2. The moulding compounds are divided into types according to their composition and properties. The various types are designated using the designation system defined in IS0 14527-1. 2 Normative references The following normative docu

32、ments contain provisions which, through reference in this text, constitute provisions of this part of IS0 14527. For dated references, subsequent amendments to, or revisions of, any of these publications do not apply. However, parties to agreements based on this part of IS0 14527 are encouraged to i

33、nvestigate the possibility of applying the most recent editions of the normative documents indicated below. For undated references, the latest edition of the normative document referred to applies. Members of IS0 and IEC maintain registers of currently valid International Standards. IS0 472:1999, Pl

34、astics - Vocabulav. IS0 21 12:1990, Plastics - Urea-formaldehyde moulding materials - Specification. IS0 14527-1 :1999, Plastics - Urea-formaldehyde and ureamelamine-formaldehyde powder moulding compounds (UF- and UF/MF-PMCs) - Part I: Designation system and basis for specifications. IS0 14527-2: 19

35、99, Plastics - Urea-formaldehyde and uredmelamine-formaldehyde powder moulding compounds (UF- and UF/MF-PMCs) - Part 2: Preparation of test specimens and determination of properties. 3 Terms and definitions For the purposes of this part of IS0 14527, the terms and definitions given in IS0 472, IS0 1

36、4527-1 and IS0 14527-2 apply. 1 STDOBSI BS EN IS0 L4527-3-ENGL 2000 LI Lb24667 0823YL7 STL 1111 EN IS0 14527-3:1999 4 Requirements 4.1 Property values ! 1 In order for a urea-formaldehyde or uredmelamine-formaldehyde powder moulding compound to be considered as complying with this part of IS0 14527,

37、 it shall meet the requirements given in Table 1. Table 1 gives the mean value obtained for the set of test specimens used to determine a particular property. Individual values of properties 2.1, 2.2, 2.3 and 2.4 shall be within 1 O % of the mean value, and individual values of properties 3.1 and 3.

38、2 shall be within 5 “C of the mean value. No specific limits are placed on rheological and processing properties. However, suitable rheological and processing properties are essential for the satisfactory use of a moulding compound. The test methods and test conditions used shall be as agreed betwee

39、n the interested parties. In addition, for some applications, it may be useful for information to be made available on other properties, for example: - cure time: - particle size; - moisture content. If this is so, these properties and test methods, as well as the test conditions to be used, shall b

40、e as agreed between the interested parties. 4.2 Filler/reinforcement type and content In order for a phenolic powder moulding compound to be considered as complying with this part of IS0 14527, the nature, form and content by mass of its fillerheinforcement shall be as given in the designation of th

41、e moulding compound (see IS0 14527-1 :1999, subclause 4.2). 2 STD-BSI BS EN IS0 14527-3-ENGL 2000 M 1b24bbq 0823420 213 E Pro- Max. Unit cess- or inga min. Property EN IS0 14527-3:1999 1 I 2 I 3 I 4 Type: PMC IS0 14527-. . . UF UF UF UFIMF to to to to (LDlO+MD30),X,E (LDlO+MDBO) (WD30+MD20) (LF2O+Cl

42、O) (LDSO+MDSO),X,E (LD20+MD20) (WD40+MD10) (LF30+S20) Table 1 - Property requirements for UF- and UF/MF-PMCs containing (LD+MD), (WD+MD) or (LD+S) as filler - 1 1.1 2 2.1 - - - - 2.2 2.3 - - 2.4 - 3 3.1 - - 3.2 - 3.3 - 4 4.1 - - 4.2 4.3 4.4 5 5.1 5.2 a - - - - - _. b Stress at break, crB Flexural st

43、rength, qu Charpy impact strength, uCu b Q a 45 45 35 55 55 40 Q a 80 80 70 80 - MPa MPa kJ/m2 3 - 1 O0 1 O00 80 a 775 7,5 5,O a Q 3 58 5,O 435 6,s - Mechanical properties Charpy notched impact strength, uCA kJ/m2 Q 2 191 1,1 1 ,o 1,5 - a 13 13 1 ,o Temperature of deflection under load, Tf1,8 Temper

44、ature of deflection under load, Tf8,0 BH Flammability (glow bar), Q = Compression moulding M = Injection moulding Limit will be inserted when agreed “C Q/M 3 1 30 130 130 130 OC WM 3 90 90 90 80 - Q/M G BH 2-10 BH 2-10 BH 2-10 b on Dissipation factor, tan S 100 Volume resistivity, p, Surface resisti

45、vity, c. Proof tracking index, PTI within - - - WM G 091 - Rcm Q/M a 102 - - 100 R QIM 3 1011 10“ 101 100 - Q/M a 600 600 600 500 TC6llSC12. Water absorption, W24 NOTE 1 See IS0 14527-2:1999, Tables 3 and 4, columns 3, 4, and 7, for the methods to be used for the preparation of tes specimens and the

46、 determination of properties. NOTE 2 In view of the differences between the property-value limits for compression-moulding and injection-moulding materials, thc likely variations in test results and the wide range of properties covered, it should not be assumed that materials having the samt designa

47、tion are exactly equivalent. mg 150 150 200 1 O0 yo by Q/M mass - - - - 3 EN IS0 14527-3:1999 National or International standard IS0 14527-3:1999 IS0 2112:1990 ASTM D 705-81 BS 1322: 1992 DIN 7708-3:1975 JIS K 6916:1995 NF Annex A (informative) 1 2 3 4 Type: PMC IS0 14527-. . . UF UF UF UFIMF (LDlO+

48、MD30),X,E (LD10+MD30) (W D30+M D20) (LF2O+SlO) to to to to (LDPO+MDPO),X,E (LD20+MD20) (W D40+MD 1 O) (LF30+S20) UF A10 UFA11 UF A20 - - - - - UF A10 UF Al1 UF A20 - 131.5 131 (130)a - UM-E UM-G - - - - - - Comparison of designations Table A.l - Comparison of designations used for UF- and UF/MF-PMCs

49、 in national and international standards 4 STD.BSI BS EN IS0 L4527-3-ENGL 2000 II Lb2Ybb 0623422 b 1111 BS EN IS0 14527-3:2000 BSI 389 Chiswick High Road London w4 4AL BSI - British Standards Institution BSI is the independent national body responsible for preparing British Standards. It presents the UK view on standards in Europe and at the intemational level. It is incorporated by Royal Charter. Revisions British Standards are updated by amendment or revision. Users of British Standards should make sure that they possess the latest