ImageVerifierCode 换一换
格式:PDF , 页数:20 ,大小:456.41KB ,
资源ID:725537      下载积分:10000 积分
快捷下载
登录下载
邮箱/手机:
温馨提示:
如需开发票,请勿充值!快捷下载时,用户名和密码都是您填写的邮箱或者手机号,方便查询和重复下载(系统自动生成)。
如填写123,账号就是123,密码也是123。
特别说明:
请自助下载,系统不会自动发送文件的哦; 如果您已付费,想二次下载,请登录后访问:我的下载记录
支付方式: 支付宝扫码支付 微信扫码支付   
注意:如需开发票,请勿充值!
验证码:   换一换

加入VIP,免费下载
 

温馨提示:由于个人手机设置不同,如果发现不能下载,请复制以下地址【http://www.mydoc123.com/d-725537.html】到电脑端继续下载(重复下载不扣费)。

已注册用户请登录:
账号:
密码:
验证码:   换一换
  忘记密码?
三方登录: 微信登录  

下载须知

1: 本站所有资源如无特殊说明,都需要本地电脑安装OFFICE2007和PDF阅读器。
2: 试题试卷类文档,如果标题没有明确说明有答案则都视为没有答案,请知晓。
3: 文件的所有权益归上传用户所有。
4. 未经权益所有人同意不得将文件中的内容挪作商业或盈利用途。
5. 本站仅提供交流平台,并不能对任何下载内容负责。
6. 下载文件中如有侵权或不适当内容,请与我们联系,我们立即纠正。
7. 本站不保证下载资源的准确性、安全性和完整性, 同时也不承担用户因使用这些下载资源对自己和他人造成任何形式的伤害或损失。

版权提示 | 免责声明

本文(EN ISO 15181-1-2007 en Paints and varnishes Determination of release rate of biocides from antifouling paints Part 1 General method for extraction of biocides《涂料和清漆 防污涂料中生物杀灭剂释放率的测.pdf)为本站会员(jobexamine331)主动上传,麦多课文库仅提供信息存储空间,仅对用户上传内容的表现方式做保护处理,对上载内容本身不做任何修改或编辑。 若此文所含内容侵犯了您的版权或隐私,请立即通知麦多课文库(发送邮件至master@mydoc123.com或直接QQ联系客服),我们立即给予删除!

EN ISO 15181-1-2007 en Paints and varnishes Determination of release rate of biocides from antifouling paints Part 1 General method for extraction of biocides《涂料和清漆 防污涂料中生物杀灭剂释放率的测.pdf

1、BRITISH STANDARDBS EN ISO 15181-1:2007Paints and varnishes Determination of release rate of biocides from antifouling paints Part 1: General method for extraction of biocidesThe European Standard EN ISO 15181-1:2007 has the status of a British StandardICS 87.040g49g50g3g38g50g51g60g44g49g42g3g58g44g

2、55g43g50g56g55g3g37g54g44g3g51g40g53g48g44g54g54g44g50g49g3g40g59g38g40g51g55g3g36g54g3g51g40g53g48g44g55g55g40g39g3g37g60g3g38g50g51g60g53g44g42g43g55g3g47g36g58BS EN ISO 15181-1:2007This British Standard was published under the authority of the Standards Policy and Strategy Committee on 28 Septemb

3、er 2007 BSI 2007ISBN 978 0 580 55942 6National forewordThis British Standard is the UK implementation of EN ISO 15181-1:2007. It supersedes BS EN ISO 15181-1:2004 which is withdrawn.The UK participation in its preparation was entrusted to Technical Committee STI/10, Test methods for paints.A list of

4、 organizations represented on this committee can be obtained on request to its secretary.This publication does not purport to include all the necessary provisions of a contract. Users are responsible for its correct application.Compliance with a British Standard cannot confer immunity from legal obl

5、igations.Amendments issued since publicationAmd. No. Date CommentsEUROPEAN STANDARDNORME EUROPENNEEUROPISCHE NORMEN ISO 15181-1June 2007ICS 87.040 Supersedes EN ISO 15181-1:2004 English VersionPaints and varnishes - Determination of release rate of biocidesfrom antifouling paints - Part 1: General m

6、ethod for extraction ofbiocides (ISO 15181-1:2007)Peintures et vernis - Dtermination du taux de lixiviationdes biocides contenus dans les peintures antisalissures -Partie 1: Mthode gnrale dextraction des biocides (ISO15181-1:2007)Beschichtungsstoffe - Bestimmung der Auswaschrate vonBioziden aus Anti

7、fouling-Beschichtungen - Teil 1:Allgemeines Verfahren zur Extraktion von Bioziden (ISO15181-1:2007)This European Standard was approved by CEN on 16 May 2007.CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this EuropeanStandard the s

8、tatus of a national standard without any alteration. Up-to-date lists and bibliographical references concerning such nationalstandards may be obtained on application to the CEN Management Centre or to any CEN member.This European Standard exists in three official versions (English, French, German).

9、A version in any other language made by translationunder the responsibility of a CEN member into its own language and notified to the CEN Management Centre has the same status as theofficial versions.CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Cyprus, Czech Republic,

10、 Denmark, Estonia, Finland,France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal,Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland and United Kingdom.EUROPEAN COMMITTEE FOR STANDARDIZATIONCOMIT EUROPEN DE NORMALIS

11、ATIONEUROPISCHES KOMITEE FR NORMUNGManagement Centre: rue de Stassart, 36 B-1050 Brussels 2007 CEN All rights of exploitation in any form and by any means reservedworldwide for CEN national Members.Ref. No. EN ISO 15181-1:2007: EForeword This document (EN ISO 15181-1:2007) has been prepared by Techn

12、ical Committee ISO/TC 35 “Paints and varnishes“ in collaboration with Technical Committee CEN/TC 139 “Paints and varnishes“, the secretariat of which is held by DIN. This European Standard shall be given the status of a national standard, either by publication of an identical text or by endorsement,

13、 at the latest by December 2007, and conflicting national standards shall be withdrawn at the latest by December 2007. This document supersedes EN ISO 15181-1:2004. According to the CEN/CENELEC Internal Regulations, the national standards organizations of the following countries are bound to impleme

14、nt this European Standard: Austria, Belgium, Bulgaria, Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland an

15、d United Kingdom. Endorsement notice The text of ISO 15181-1:2007 has been approved by CEN as EN ISO 15181-1:2007 without any modifications. EN ISO 15181-1:2007Reference numberISO 15181-1:2007(E)INTERNATIONAL STANDARD ISO15181-1Second edition2007-06-01Paints and varnishes Determination of release ra

16、te of biocides from antifouling paints Part 1: General method for extraction of biocidesPeintures et vernis Dtermination du taux de lixiviation des biocides contenus dans les peintures antisalissures Partie 1: Mthode gnrale dextraction des biocides EN ISO 15181-1:2007ii iiiContents Page Foreword iv

17、Introduction v 1 Scope . 1 2 Normative references . 1 3 Principle. 2 4 Required supplementary information. 2 5 Apparatus 2 6 Reagents and materials . 4 7 Sampling 5 8 Preparation of test cylinders . 5 9 Procedure 6 10 Extraction method 6 11 Test report . 7 Annex A (normative) Supplementary informati

18、on 8 Bibliography . 9 EN ISO 15181-1:2007iv Foreword ISO (the International Organization for Standardization) is a worldwide federation of national standards bodies (ISO member bodies). The work of preparing International Standards is normally carried out through ISO technical committees. Each membe

19、r body interested in a subject for which a technical committee has been established has the right to be represented on that committee. International organizations, governmental and non-governmental, in liaison with ISO, also take part in the work. ISO collaborates closely with the International Elec

20、trotechnical Commission (IEC) on all matters of electrotechnical standardization. International Standards are drafted in accordance with the rules given in the ISO/IEC Directives, Part 2. The main task of technical committees is to prepare International Standards. Draft International Standards adopt

21、ed by the technical committees are circulated to the member bodies for voting. Publication as an International Standard requires approval by at least 75 % of the member bodies casting a vote. Attention is drawn to the possibility that some of the elements of this document may be the subject of paten

22、t rights. ISO shall not be held responsible for identifying any or all such patent rights. ISO 15181-1 was prepared by Technical Committee ISO/TC 35, Paints and varnishes, Subcommittee SC 9, General test methods for paints and varnishes. This second edition cancels and replaces the first edition (IS

23、O 15181-1:2000), which has been technically revised, in particular to extend the use of the general extraction method to the later parts of ISO 15181. ISO 15181 consists of the following parts, under the general title Paints and varnishes Determination of release rate of biocides from antifouling pa

24、ints: Part 1: General method for extraction of biocides Part 2: Determination of copper-ion concentration in the extract and calculation of the release rate Part 3: Calculation of the zinc ethylene-bis(dithiocarbamate) (zineb) release rate by determination of the concentration of ethylenethiourea in

25、 the extract Part 4: Determination of pyridine-triphenylborane (PTPB) concentration in the extract and calculation of the release rate Part 5: Calculation of the tolylfluanid and dichlofluanid release rate by determination of the concentration of dimethyltolylsulfamide (DMST) and dimethylphenylsulfa

26、mide (DMSA) in the extract EN ISO 15181-1:2007vIntroduction By using standard conditions of temperature, salinity and pH at low biocide concentrations in the surrounding artificial seawater, a repeatable value of the release rate under the specified laboratory conditions can be determined using the

27、method given in this part of ISO 15181, which can be used for quality assurance and material selection purposes. The actual release rate of biocides from antifouling paints on ships hulls into the environment will, however, depend on many factors, such as ship operating schedules, length of service,

28、 berthing conditions, paint condition, as well as the temperature, salinity, pH, pollutants and biological community in a particular area. The results of this test do not reflect environmental biocide release rates for antifouling products and are not suitable for direct use in the process of genera

29、ting environmental-risk assessments, producing environmental-loading estimates or for establishing release rate limits for regulatory purposes. In comparison with copper and organotin release rates obtained either by direct or indirect measurements of the copper release rate from ships hulls and fro

30、m measurements made on panels exposed in harbours, all available data indicate that the results obtained using this generic test method significantly overestimate the release rates of biocides under in-service conditions. Published results demonstrate that the results of this test method are general

31、ly higher than direct in situ measurements of copper and organotin release rates from in-service ship hulls by a factor of about 10 or more for several commercial antifouling coatings1, 2. A similar relationship is expected to be found for other biocides. Realistic estimates of the biocide release r

32、ate from a ships hull under in-service conditions can only be obtained from this test method if this difference is taken into account. Where the results of this test method are used in the process of generating environmental-risk assessments, producing environmental-loading estimates or for regulato

33、ry purposes, it is most strongly recommended that the relationship between laboratory release rates and actual environmental inputs be taken into account to allow a more accurate estimate of the biocide release rate from antifouling coatings under real-life conditions to be obtained. This can be acc

34、omplished through the application of appropriate correction factors2. EN ISO 15181-1:2007blank1Paints and varnishes Determination of release rate of biocides from antifouling paints Part 1: General method for extraction of biocides 1 Scope This part of ISO 15181 specifies a general method for extrac

35、ting biocides from antifouling paint films into artificial seawater under specified laboratory conditions. It is used in conjunction with the other parts of ISO 15181 to determine the amounts of specific biocides in the extract, for example copper and/or certain organic biocides, and to enable the r

36、elease rate of those biocides from the paint film under the specified laboratory conditions to be calculated. 2 Normative references The following referenced documents are indispensable for the application of this document. For dated references, only the edition cited applies. For undated references

37、, the latest edition of the referenced document (including any amendments) applies. ISO 1513, Paints and varnishes Examination and preparation of samples for testing ISO 2808, Paints and varnishes Determination of film thickness ISO 3696, Water for analytical laboratory use Specification and test me

38、thods ISO 15181-2, Paints and varnishes Determination of release rate of biocides from antifouling paints Part 2: Determination of copper-ion concentration in the extract and calculation of the release rate ISO 15181-3, Paints and varnishes Determination of release rate of biocides from antifouling

39、paints Part 3: Calculation of the zinc ethylene-bis(dithiocarbamate) (zineb) release rate by determination of the concentration of ethylenethiourea in the extract ISO 15181-4, Paints and varnishes Determination of release rate of biocides from antifouling paints Part 4: Determination of pyridine-tri

40、phenylborane (PTPB) concentration in the extract and calculation of the release rate ISO 15181-5, Paints and varnishes Determination of release rate of biocides from antifouling paints Part 5: Calculation of the tolylfluanid and dichlofluanid release rate by determination of the concentration of dim

41、ethyltolylsulfamide (DMST) and dimethylphenylsulfamide (DMSA) in the extract ISO 15528, Paints, varnishes and raw materials for paints and varnishes Sampling ASTM D 1141-98(2003), Standard Practice for the Preparation of Substitute Ocean Water EN ISO 15181-1:20072 3 Principle Test cylinders painted

42、with antifouling paint are immersed, together with reference cylinders, in flowing artificial seawater in a holding tank. At specified time intervals, the cylinders are removed and exposed for a defined period in individual release rate measuring containers containing the same artificial seawater be

43、fore being replaced in the holding tank. The concentration of the biocide released into the water of the individual release rate measuring containers is then determined. This operation is repeated at defined time intervals and hence the release rate of the biocide under the specified laboratory cond

44、itions can be calculated. 4 Required supplementary information For each application, the items of supplementary information listed in Annex A shall be supplied as appropriate to enable the test method given in this part of ISO 15181 to be carried out. 5 Apparatus NOTE Some biocides have a strong ten

45、dency to adsorb onto certain glass or plastic substrates. 5.1 Test cylinder, made of an inert material see Annex A, item A.2 a), having a diameter of (64 5) mm and length of (178 15) mm, and closed at both ends so that it is watertight. 5.2 Rotating device, capable of rotating a test cylinder (5.1)

46、in the centre of the release rate measuring container (5.3) such that the rotational speed of the outside of the test cylinder through the artificial seawater is (60 5) r/min (0,2 0,02) m/s. The device itself shall not be allowed to come into contact with the artificial seawater. 5.3 Release rate me

47、asuring container (see Figure 1), made of an inert material see Annex A, item A.2 b), of nominal capacity (2 0,2) litres, 120 mm to 150 mm in diameter and 170 mm to 210 mm high. The container shall be fitted with three evenly spaced baffles around the inside of the container to prevent swirling duri

48、ng test cylinder rotation. The baffles shall consist of circular rods of diameter 5 mm to 7 mm running from the bottom of the container to a level at least above that of the artificial seawater. They shall be fixed in place using an inert adhesive or solvent. There shall be a means of maintaining th

49、e container and its contents at (25 1) C. NOTE Placing the container in a thermostatically controlled water bath has been found to be a suitable means of maintaining the temperature at the correct level; alternatively, the test may be performed in a conditioned room at the specified temperature. If the release rate of a highly photosensitive biocide is being determined, then the container shall be protected from natural and artificial visible-light sources. Details of this requirement to protect

copyright@ 2008-2019 麦多课文库(www.mydoc123.com)网站版权所有
备案/许可证编号:苏ICP备17064731号-1