1、BRITISH STANDARDBS EN ISO 16103:2005Packaging Transport packages for dangerous goods Recycled plastics materialThe European Standard EN ISO 16103:2005 has the status of a British StandardICS 13.300; 55.020g49g50g3g38g50g51g60g44g49g42g3g58g44g55g43g50g56g55g3g37g54g44g3g51g40g53g48g44g54g54g44g50g49
2、g3g40g59g38g40g51g55g3g36g54g3g51g40g53g48g44g55g55g40g39g3g37g60g3g38g50g51g60g53g44g42g43g55g3g47g36g58BS EN ISO 16103:2005This British Standard was published under the authority of the Standards Policy and Strategy Committee on 21 February 2006 BSI 21 February 2006ISBN 0 580 47824 6National forew
3、ordThis British Standard is the official English language version of EN ISO 16103:2005. It is identical with ISO 16103:2005.The UK participation in its preparation was entrusted to Technical Committee PKW/0, Packaging, which has the responsibility to: A list of organizations represented on this comm
4、ittee can be obtained on request to its secretary.Cross-referencesThe British Standards which implement international or European publications referred to in this document may be found in the BSI Catalogue under the section entitled “International Standards Correspondence Index”, or by using the “Se
5、arch” facility of the BSI Electronic Catalogue or of British Standards Online.This publication does not purport to include all the necessary provisions of a contract. Users are responsible for its correct application. Compliance with a British Standard does not of itself confer immunity from legal o
6、bligations. aid enquirers to understand the text; present to the responsible international/European committee any enquiries on the interpretation, or proposals for change, and keep UK interests informed; monitor related international and European developments and promulgate them in the UK.Summary of
7、 pagesThis document comprises a front cover, an inside front cover, the EN ISO title page, the EN ISO foreword page, the ISO title page, pages ii to iv, pages 1 to 8, an inside back cover and a back cover.The BSI copyright notice displayed in this document indicates when the document was last issued
8、.Amendments issued since publicationAmd. No. Date CommentsEUROPEAN STANDARDNORME EUROPENNEEUROPISCHE NORMEN ISO 16103July 2005ICS 13.300; 55.020English VersionPackaging - Transport packages for dangerous goods -Recycled plastics material (ISO 16103:2005)Emballages - Emballages de transport pour marc
9、handisesdangereuses - Matriaux plastiques recycls (ISO16103:2005)Verpackung - Verpackungen zur Befrderung gefhrlicherGter - Recycling-Kunststoffe (ISO 16103:2005)This European Standard was approved by CEN on 1 June 2005.CEN members are bound to comply with the CEN/CENELEC Internal Regulations which
10、stipulate the conditions for giving this EuropeanStandard the status of a national standard without any alteration. Up-to-date lists and bibliographical references concerning such nationalstandards may be obtained on application to the Central Secretariat or to any CEN member.This European Standard
11、exists in three official versions (English, French, German). A version in any other language made by translationunder the responsibility of a CEN member into its own language and notified to the Central Secretariat has the same status as the officialversions.CEN members are the national standards bo
12、dies of Austria, Belgium, Cyprus, Czech Republic, Denmark, Estonia, Finland, France,Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Slovakia,Slovenia, Spain, Sweden, Switzerland and United Kingdom.EUROPEAN COMMITTEE FOR
13、STANDARDIZATIONCOMIT EUROPEN DE NORMALISATIONEUROPISCHES KOMITEE FR NORMUNGManagement Centre: rue de Stassart, 36 B-1050 Brussels 2005 CEN All rights of exploitation in any form and by any means reservedworldwide for CEN national Members.Ref. No. EN ISO 16103:2005: EForeword This document (EN ISO 16
14、103:2005) has been prepared by Technical Committee ISO/TC 122 “Packaging“ in collaboration with Technical Committee CEN/TC 261 “Packaging“, the secretariat of which is held by AFNOR. This European Standard shall be given the status of a national standard, either by publication of an identical text o
15、r by endorsement, at the latest by January 2006, and conflicting national standards shall be withdrawn at the latest by January 2006. According to the CEN/CENELEC Internal Regulations, the national standards organizations of the following countries are bound to implement this European Standard: Aust
16、ria, Belgium, Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Slovakia, Slovenia, Spain, Sweden, Switzerland and United Kingdom. Endorsement notice The text of I
17、SO 16103:2005 has been approved by CEN as EN ISO 16103:2005 without any modifications. EN ISO 16103:2005Reference numberISO 16103:2005(E)INTERNATIONAL STANDARD ISO16103First edition2005-07-01Packaging Transport packaging for dangerous goods Recycled plastics material Emballages Emballages de transpo
18、rt pour marchandises dangereuses Matriaux plastiques recycls EN ISO 16103:2005ii iiiForeword ISO (the International Organization for Standardization) is a worldwide federation of national standards bodies (ISO member bodies). The work of preparing International Standards is normally carried out thro
19、ugh ISO technical committees. Each member body interested in a subject for which a technical committee has been established has the right to be represented on that committee. International organizations, governmental and non-governmental, in liaison with ISO, also take part in the work. ISO collabor
20、ates closely with the International Electrotechnical Commission (IEC) on all matters of electrotechnical standardization. International Standards are drafted in accordance with the rules given in the ISO/IEC Directives, Part 2. The main task of technical committees is to prepare International Standa
21、rds. Draft International Standards adopted by the technical committees are circulated to the member bodies for voting. Publication as an International Standard requires approval by at least 75 % of the member bodies casting a vote. Attention is drawn to the possibility that some of the elements of t
22、his document may be the subject of patent rights. ISO shall not be held responsible for identifying any or all such patent rights. ISO 16103 was prepared by Technical Committee ISO/TC 122, Packaging, Subcommittee SC 3, Performance requirements and tests for means of packaging, packages and unit load
23、s (as required by ISO/TC 122). EN ISO 16103:2005iv Introduction The aim of this International Standard is to specify sufficiently the necessary controls for the use of recycled plastics materials as identified in the United Nations Recommendations on the Transport of Dangerous Goods, by selection in
24、to batches. Packagings produced from each batch of recycled plastics material undergo mechanical testing as in design type testing. These Recommendations are given legal entity by the provisions of a series of modal agreements for the international transport of dangerous goods: the European Agreemen
25、t concerning the International Carriage of Dangerous Goods by Road (ADR) (see 1 in the Bibliography); the International Civil Aviation Organizations Technical Instructions for the Safe Transport of Dangerous Goods by Air (see 2 in the Bibliography); the International Maritime Dangerous Goods Code (s
26、ee 3 in the Bibliography); the Regulations concerning the International Carriage of Dangerous Goods by Rail (RID) (see 4 in the Bibliography). The application of this International Standard needs to take account of the requirements of these international agreements and the relevant national regulati
27、ons for domestic transport of dangerous goods. EN ISO 16103:20051Packaging Transport packaging for dangerous goods Recycled plastics material 1 Scope This International Standard specifies the requirements and test methods for the production of recycled plastics materials to be used for packagings fo
28、r the transport of dangerous goods. This includes guidance on the quality assurance programme. NOTE The quality assurance programme for the production of packagings is described in ISO 16106 (see 5 in the Bibliography). 2 Normative references The following referenced documents are indispensable for
29、the application of this document. For dated references, only the edition cited applies. For undated references, the latest edition of the referenced document (including any amendments) applies. ISO 527-1, Plastics Determination of tensile properties Part 1: General principles ISO 527-2, Plastics Det
30、ermination of tensile properties Part 2: Test conditions for moulding and extrusion plastics ISO 1133, Plastics Determination of the melt mass-flow rate (MFR) and the melt volume-flow rate (MVR) of thermoplastics ISO 1183-1, Plastics Methods for determining the density of non-cellular plastics Part
31、1: Immersion method, liquid pyknometer method and titration method ISO 12048, Packaging Complete, filled transport packages Compression and stacking tests using a compression tester ISO 16101, Packaging Transport packaging for dangerous goods Plastics compatibility testing ISO 16104, Packaging Trans
32、port packaging for dangerous goods Test methods United Nations Recommendations on the Transport of Dangerous Goods Model Regulations, ST/SG/AC. 10/1/Rev.13: United Nations, ISBN 92-1-139090-7 3 Terms and definitions For the purposes of this document, the following terms and definitions apply. 3.1 re
33、cycled plastics material material recovered from used industrial packagings that has been cleaned and prepared for processing into new packagings EN ISO 16103:20052 3.2 batch of recycled plastics materials defined quantity, maximum 25 t, of homogeneous material with known parameters (melt flow rate,
34、 density and tensile stress at yield) 3.3 competent authority national regulatory body or authority designated or otherwise recognized as such for any purpose in connection with the regulations specified in the Bibliography 4 General framework The specific properties of recycled plastics material us
35、ed for production of new packaging shall be assured and documented as part of a quality assurance programme. This record shall be maintained under the following headings: a) collection of packagings; b) incoming inspection; c) process control; d) final quality control; e) mechanical testing of packa
36、gings; f) documentation. NOTE Where regulatory requirements apply, this may require recognition by the competent authority. 5 Requirements 5.1 Collection 5.1.1 The collection shall be restricted to industrial packagings, e.g. drums, jerricans, large packagings, and intermediate bulk containers (IBCs
37、). 5.1.2 All packagings shall have the following characteristics: a) have evidence of previous contents, including identification of dangerous goods; b) be embossed with the accepted international material code symbol (see Annex A) or be identified by other means; c) be marked with the month and yea
38、r of manufacture. 5.1.3 Uncleaned packagings which are UN-marked shall a) display the required hazard identification labels, if applicable; b) be closed suitable for transport; c) be empty, i.e. all residues that can be removed by the emptier have been removed using the practices commonly employed t
39、o remove residues from that type of packaging (pouring, aspirating, shaking, scraping, chipping, etc. or, if necessary, a combination of these). EN ISO 16103:200535.2 Incoming inspection An incoming inspection shall be carried out in order to ensure that the requirements of collection (listed in 5.1
40、) have been met. Different types of plastics materials shall not be mixed. Packagings produced from different manufacturing processes (e.g. extrusion blow moulding, rotational moulding, injection moulding) should not be mixed. 5.3 Packagings excluded 5.3.1 All packagings displaying the characteristi
41、cs shown in 5.3.2 to 5.3.7. All packagings shall be segregated by their material code symbol. 5.3.2 Packagings having contained products which have affected the plastics material (e.g. certain highly oxidizing substances), making it unsuitable for reprocessing. 5.3.3 Packagings that have contained c
42、ertain specific substances hazardous to health and safety and/or the environment, listed in Division 6.1 Toxic substances, Division 6.2 Infectious substances and Class 7 Radioactive material of the United Nations Recommendations on the Transport of Dangerous Goods Model Regulations, and all substanc
43、es with toxic secondary risks. 5.3.4 Packagings that are more than 10 years old. 5.3.5 Packagings that show signs of deterioration, e.g. by the effect of UV radiation causing degradation. 5.3.6 Packagings produced from material that cannot be reprocessed (e.g. cross-linked polyethylene). 5.3.7 Packa
44、gings marked with the symbol REC. 5.4 Process control 5.4.1 All closures and gaskets shall be excluded. 5.4.2 All labels made of materials other than those indicated by the material code symbol from the container body shall be totally removed. 5.4.3 The packagings shall be cleaned in such a way as t
45、o remove all residues from the inside and the outside. NOTE Such cleaning may be undertaken by using, for example, one of the following methods: a) physical measures (e.g. drip-dry through ventilation); b) cleaning of the packaging (e.g. triple rinsing); c) chemical alteration of the residue (e.g. c
46、hemical passivation). 5.4.4 The packagings shall be size reduced, e.g. by shredding, regrinding or re-pelletizing, and homogenized sufficiently to give consistent material properties throughout the batch. EN ISO 16103:20054 5.5 Final quality control 5.5.1 Verification It shall be verified that each
47、batch of the recycled plastics material has the specified melt flow rate, density, and tensile yield strength. These three parameters shall be tested to the following standards: ISO 1133 for melt flow rate; ISO 1183-1 for density; ISO 527-1 and ISO 527-2 for tensile yield strength/elongation at brea
48、k (testing speed: 50 mm/min). Sufficient samples shall be taken from each batch to demonstrate homogeneity and repeatability of these parameters, i.e. at least three samples representative of the whole batch. The determined values shall not deviate from the specifications laid down in the test repor
49、t of the design type by more than 30 % for melt flow rate; 5 kg/m3for density. The tensile elongation at break shall not be less than 75 % of the original value. NOTE Additional methods may be used to verify the recycled material is free from contamination, e.g. analytical methods such as differential scanning calorimetry (DSC) (see ISO 11357-1 and ISO 11357-3). 5.5.2 Mechanical design type testing of packagings Packagings produced from each batch of recycled plastics material shall undergo mech
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