EN ISO 20137-2017 en Leather - Chemical tests - Guidelines for testing critical chemicals in leather《皮革-化学测试-皮革中关键化学品测试指南(ISO 20137 2017)》.pdf

1、BS EN ISO 20137:2017Leather Chemical tests Guidelines for testing criticalchemicals in leather (ISO20137:2017)BSI Standards PublicationWB11885_BSI_StandardCovs_2013_AW.indd 1 15/05/2013 15:06BS EN ISO 20137:2017 BRITISH STANDARDNational forewordThis British Standard is the UK implementation of EN IS

2、O 20137:2017. The UK participation in its preparation was entrusted to Technical Committee TCI/69, Footwear, leather and coated fabrics.A list of organizations represented on this committee can be obtained on request to its secretary.This publication does not purport to include all the necessary pro

3、visions of a contract. Users are responsible for its correct application. The British Standards Institution 2017.Published by BSI Standards Limited 2017ISBN 978 0 580 87866 4 ICS 59.140.30 Compliance with a British Standard cannot confer immunity from legal obligations.This British Standard was publ

4、ished under the authority of the Standards Policy and Strategy Committee on 31 March 2017.Amendments/corrigenda issued since publicationDate T e x t a f f e c t e dEUROPEAN STANDARD NORME EUROPENNE EUROPISCHE NORM EN ISO 20137 March 2017 ICS 59.140.30 English Version Leather - Chemical tests - Guide

5、lines for testing critical chemicals in leather (ISO 20137:2017) Cuir - Essais chimiques - Lignes directrices pour les essais de produits chimiques critiques sur le cuir (ISO 20137:2017) Leder - Chemische Prfverfahren - Richtlinien fr die Prfung kritischer Chemikalien in Leder (ISO 20137:2017) This

6、European Standard was approved by CEN on 14 February 2017. CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this European Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical referen

7、ces concerning such national standards may be obtained on application to the CEN-CENELEC Management Centre or to any CEN member. This European Standard exists in three official versions (English, French, German). A version in any other language made by translation under the responsibility of a CEN m

8、ember into its own language and notified to the CEN-CENELEC Management Centre has the same status as the official versions. CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia,

9、France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and United Kingdom. EUROPEAN COMMITTEE FOR STANDARDIZATION COMIT EUROPEN DE NORMALISATION EU

10、ROPISCHES KOMITEE FR NORMUNG CEN-CENELEC Management Centre: Avenue Marnix 17, B-1000 Brussels 2017 CEN All rights of exploitation in any form and by any means reserved worldwide for CEN national Members. Ref. No. EN ISO 20137:2017 EBS EN ISO 20137:2017EN ISO 20137:2017 (E) 3 European foreword This d

11、ocument (EN ISO 20137:2017) has been prepared by Technical Committee IULTCS “International Union of Leather Technologists and Chemists Societies” in collaboration with Technical Committee CEN/TC 289 “Leather” the secretariat of which is held by UNI. This European Standard shall be given the status o

12、f a national standard, either by publication of an identical text or by endorsement, at the latest by September 2017, and conflicting national standards shall be withdrawn at the latest by September 2017. Attention is drawn to the possibility that some of the elements of this document may be the sub

13、ject of patent rights. CEN and/or CENELEC shall not be held responsible for identifying any or all such patent rights. According to the CEN-CENELEC Internal Regulations, the national standards organizations of the following countries are bound to implement this European Standard: Austria, Belgium, B

14、ulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Swit

15、zerland, Turkey and the United Kingdom. Endorsement notice The text of ISO 20137:2017 has been approved by CEN as EN ISO 20137:2017 without any modification. BS EN ISO 20137:2017ISO 20137:2017(E)IULTCS/IUC 36:2017(E)Foreword ivIntroduction v1 Scope . 12 Normative references 13 Terms and definitions

16、. 24 Chemical substances potentially found in leather 24.1 Chemical test methods for substances used by the leather industry with no legal restrictions for leather . 24.2 Chemical test methods for substances previously used by the leather industry 34.3 Chemical test methods for substances not used b

17、y the leather industry. 3Annex A (informative) Substances lists . 8Bibliography .11 ISO 2017 All rights reserved iiiContents PageBS EN ISO 20137:2017ISO 20137:2017(E)ForewordISO (the International Organization for Standardization) is a worldwide federation of national standards bodies (ISO member bo

18、dies). The work of preparing International Standards is normally carried out through ISO technical committees. Each member body interested in a subject for which a technical committee has been established has the right to be represented on that committee. International organizations, governmental an

19、d non-governmental, in liaison with ISO, also take part in the work. ISO collaborates closely with the International Electrotechnical Commission (IEC) on all matters of electrotechnical standardization.The procedures used to develop this document and those intended for its further maintenance are de

20、scribed in the ISO/IEC Directives, Part 1. In particular the different approval criteria needed for the different types of ISO documents should be noted. This document was drafted in accordance with the editorial rules of the ISO/IEC Directives, Part 2 (see www .iso .org/ directives).Attention is dr

21、awn to the possibility that some of the elements of this document may be the subject of patent rights. ISO shall not be held responsible for identifying any or all such patent rights. Details of any patent rights identified during the development of the document will be in the Introduction and/or on

22、 the ISO list of patent declarations received (see www .iso .org/ patents).Any trade name used in this document is information given for the convenience of users and does not constitute an endorsement.For an explanation on the voluntary nature of standards, the meaning of ISO specific terms and expr

23、essions related to conformity assessment, as well as information about ISOs adherence to the World Trade Organization (WTO) principles in the Technical Barriers to Trade (TBT) see the following URL: www .iso .org/ iso/ foreword .htmlThis document was prepared by the Chemical Tests Commission of the

24、International Union of Leather Technologists and Chemists Societies (IUC Commission, IULTCS) in collaboration with the European Committee for Standardization (CEN) Technical Committee CEN/TC 289, Leather, the secretariat of which is held by UNI, in accordance with the Agreement on technical cooperat

25、ion between ISO and CEN (Vienna Agreement).IULTCS, originally formed in 1897, is a world-wide organization of professional leather societies to further the advancement of leather science and technology. IULTCS has three Commissions, which are responsible for establishing international methods for th

26、e sampling and testing of leather. ISO recognizes IULTCS as an international standardizing body for the preparation of test methods for leather.IULTCS/IUC 36:2017(E)iv ISO 2017 All rights reservedBS EN ISO 20137:2017ISO 20137:2017(E)IntroductionThis document was prepared in collaboration by IULTCS a

27、nd by CEN/TC 289 Leather in order to provide an overview of chemical test methods for the leather industry. This can be used by those involved in setting specifications for leather, especially for those parameters relating to restricted chemical substances.Regulations restrict the use of certain che

28、micals in consumer products. The leather industry has already taken actions by replacing the restricted substances or assuming the limits imposed by these restrictions. Many brand name manufacturers require certificates of compliance from their suppliers but too often these refer to analytical metho

29、ds from other industries that are not suitable for use in testing leather.Through the collaboration of IULTCS and CEN/TC 289, a considerable number of leather specific EN and ISO standard test methods have been developed for the chemical analysis of leather. The International Standards are tested by

30、 inter-laboratory studies, have been proven scientifically valid and are subjected to updating processes according to ISO protocols.Chemical analysis of leatherLeather is a complex substrate to chemically analyse. After tanning, leather typically undergoes wet-processing in aqueous media at low temp

31、eratures (60 C) and in an acid pH range of 3,5 to 5,5. The characteristic properties of leather are achieved by mostly using a range of anionic retanning agents (natural and/or synthetic), polymers and oils, as well as anionic dyes for achieving the required colour. In analytical procedures, when le

32、ather is extracted, some of these substances can be removed and make a complex matrix for the analysis. This should be considered when establishing quantification limits for leather analyses. Too often unrealistic limits established in aqueous solutions, e.g. waste water analysis, are quoted in spec

33、ifications for leather.This document gives an overview of those internationally accepted chemical test procedures established specifically for leather.IULTCS/IUC 36:2017(E) ISO 2017 All rights reserved vBS EN ISO 20137:2017BS EN ISO 20137:2017Leather Chemical tests Guidelines for testing critical ch

34、emicals in leather1 ScopeThis document gives guidelines to apply the available chemical test methods for leather. This information can be used by those involved in setting specifications for leather, especially for those parameters relating to restricted chemical substances.Lists of restricted chemi

35、cals contain many substances that are not relevant to the leather industry. Those chemical substances that are not mentioned in this document do not need to be determined, thus avoiding unnecessary analytical costs.2 Normative referencesThe following documents are referred to in the text in such a w

36、ay that some or all of their content constitutes requirements of this document. For dated references, only the edition cited applies. For undated references, the latest edition of the referenced document (including any amendments) applies.ISO 4045, Leather Chemical tests Determination of pHISO 5398-

37、1, Leather Chemical determination of chromic oxide content Part 1: Quantification by titrationISO 5398-2, Leather Chemical determination of chromic oxide content Part 2: Quantification by colorimetric determinationISO 5398-3, Leather Chemical determination of chromic oxide content Part 3: Quantifica

38、tion by atomic absorption spectrometryISO 5398-4, Leather Chemical determination of chromic oxide content Part 4: Quantification by inductively coupled plasma - optical emission spectrometer (ICP-OES)ISO 13365, Leather Chemical tests Determination of the preservative (TCMTB, PCMC, OPP, OIT) content

39、in leather by liquid chromatographyISO 17070, Leather Chemical tests Determination of tetrachlorophenol-, trichlorophenol-, dichlorophenol-, monochlorophenol-isomers and pentachlorophenol contentISO 17072-1, Leather Chemical determination of metal content Part 1: Extractable metalsISO 17072-2, Leath

40、er Chemical determination of metal content Part 2: Total metal contentISO/17075-1, Leather Chemical determination of chromium (VI) content in leather Part 1: Colorimetric methodISO/17075-2, Leather Chemical determination of chromium (VI) content in leather Part 2: Chromatographic methodISO 17226-1,

41、Leather Chemical determination of formaldehyde content Part 1: Method using high performance liquid chromatographyISO 17226-3, Leather Chemical determination of formaldehyde content Part 3: Determination of formaldehyde emissions from leatherINTERNATIONAL STANDARDISO 20137:2017(E)IULTCS/IUC 36:2017(

42、E) ISO 2017 All rights reserved 1BS EN ISO 20137:2017ISO 20137:2017(E)ISO 17234-1, Leather Chemical tests for the determination of certain azo colorants in dyed leathers Part 1: Determination of certain aromatic amines derived from azo colorantsISO 17234-2, Leather Chemical tests for the determinati

43、on of certain azo colorants in dyed leathers Part 2: Determination of 4-aminoazobenzeneISO 18218-1, Leather Determination of ethoxylated alkylphenols Part 1: Direct methodISO 18218-2, Leather Determination of ethoxylated alkylphenols Part 2: Indirect methodISO 18219, Leather Determination of chlorin

44、ated hydrocarbons in leather Chromatographic method for short-chain chlorinated paraffins (SCCP)ISO 19070, Leather Chemical determination of N-methyl-2-pyrrolidone (NMP) in leatherISO/TS 16179, Footwear Critical substances potentially present in footwear and footwear components Determination of orga

45、notin compounds in footwear materialsISO/TS 16181, Footwear Critical substances potentially present in footwear and footwear components Determination of phthalates in footwear materialsISO/TS 16186, Footwear Critical substances potentially present in footwear and footwear components Test method to q

46、uantitatively determine dimethyl fumarate (DMFU) in footwear materialsISO/TS 16189, Footwear Critical substances potentially present in footwear and footwear components Test method to quantitatively determine dimethylformamide in footwear materialsISO/TS 16190, Footwear Critical substances potential

47、ly present in footwear and footwear components Test method to quantitatively determine polycyclic aromatic hydrocarbons (PAH) in footwear materialsEN 1122, Plastics Determination of cadmium - Wet decomposition methodEN 15987, Leather Terminology Key definitions for the leather tradeEN 16778, Protect

48、ive gloves The determination of Dimethylformamide in glovesCEN/TS 15968, Determination of extractable perfluorooctanesulphonate (PFOS) in coated and impregnated solid articles, liquids and fire fighting foams - Method for sampling, extraction and analysis by LC-qMS or LC-tandem/MS3 Terms and definit

49、ionsFor the purposes of this document, the terms and definitions given in EN 15987 apply.ISO and IEC maintain terminological databases for use in standardization at the following addresses: IEC Electropedia: available at h t t p :/ www .electropedia .org/ ISO Online browsing platform: available at h t t p :/ www .iso .org/ obp4 Chemical substances potentially found in leather4.1 Chemical test methods for substances used by the leather industry with