EN ISO 23936-2-2011 en Petroleum petrochemical and natural gas industries - Nonmetallic materials in contact with media related to oil and gas production - Part 2 Elastomers《石油 石化和.pdf

1、raising standards worldwideNO COPYING WITHOUT BSI PERMISSION EXCEPT AS PERMITTED BY COPYRIGHT LAWBSI Standards PublicationBS EN ISO 23936-2:2011Petroleum, petrochemical and natural gas industries Non-metallic materials in contact with media related to oil and gas productionPart 2: ElastomersBS EN IS

2、O 23936-2:2011 BRITISH STANDARDNational forewordThis British Standard is the UK implementation of EN ISO 23936-2:2011. The UK participation in its preparation was entrusted to Technical Committee PSE/17/-/7, UK experts in ISO TC 67 Working Groups.A list of organizations represented on this committee

3、 can be obtained on request to its secretary.This publication does not purport to include all the necessary provisions of a contract. Users are responsible for its correct application. BSI 2012 ISBN 978 0 580 71167 1 ICS 75.180.01 Compliance with a British Standard cannot confer immunity from legal

4、obligations.This British Standard was published under the authority of the Standards Policy and Strategy Committee on 31 January 2012.Amendments issued since publicationDate T e x t a f f e c t e dEUROPEAN STANDARD NORME EUROPENNE EUROPISCHE NORM EN ISO 23936-2 December 2011 ICS 75.180.01 English Ve

5、rsion Petroleum, petrochemical and natural gas industries - Non-metallic materials in contact with media related to oil and gas production - Part 2: Elastomers (ISO 23936-2:2011) Industries du ptrole, de la ptrochimie et du gaz naturel - Matriaux non mtalliques en contact avec les fluides relatifs l

6、a production de ptrole et de gaz - Partie 2: lastomres (ISO 23936-2:2011) Erdl-, petrochemische und Erdgasindustrie - Nichtmetallische Werkstoffe mit Medienkontakt bei der l- und Gasproduktion - Teil 2: Elastomere (ISO 23936-2:2011) This European Standard was approved by CEN on 14 December 2011. CEN

7、 members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this European Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references concerning such national standards may be obtained on appl

8、ication to the CEN-CENELEC Management Centre or to any CEN member. This European Standard exists in three official versions (English, French, German). A version in any other language made by translation under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC Ma

9、nagement Centre has the same status as the official versions. CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Neth

10、erlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland and United Kingdom. EUROPEAN COMMITTEE FOR STANDARDIZATION COMIT EUROPEN DE NORMALISATION EUROPISCHES KOMITEE FR NORMUNG Management Centre: Avenue Marnix 17, B-1000 Brussels 2011 CEN All rights of exploitation

11、 in any form and by any means reserved worldwide for CEN national Members. Ref. No. EN ISO 23936-2:2011: EBS EN ISO 23936-2:2011 EN ISO 23936-2:2011 (E) 3 Foreword This document (EN ISO 23936-2:2011) has been prepared by Technical Committee ISO/TC 67 “Materials, equipment and offshore structures for

12、 petroleum, petrochemical and natural gas industries“ in collaboration with Technical Committee CEN/TC 12 “Materials, equipment and offshore structures for petroleum, petrochemical and natural gas industries” the secretariat of which is held by AFNOR. This European Standard shall be given the status

13、 of a national standard, either by publication of an identical text or by endorsement, at the latest by June 2012, and conflicting national standards shall be withdrawn at the latest by June 2012. Attention is drawn to the possibility that some of the elements of this document may be the subject of

14、patent rights. CEN and/or CENELEC shall not be held responsible for identifying any or all such patent rights. According to the CEN/CENELEC Internal Regulations, the national standards organizations of the following countries are bound to implement this European Standard: Austria, Belgium, Bulgaria,

15、 Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland and the United Kingdom. Endorsement notice The

16、text of ISO 23936-2:2011 has been approved by CEN as a EN ISO 23936-2:2011 without any modification. BS EN ISO 23936-2:2011ISO 23936-2:2011(E) ISO 2011 All rights reserved iiiContents Page Foreword iv Introduction . v 1 Scope 1 2 Normative references 1 3 Terms, definitions and abbreviated terms 2 3.

17、1 Terms and definitions . 2 3.2 Abbreviated terms . 4 4 Technical requirements 4 5 Documentation requirements 5 6 Requirements for manufacturers . 6 6.1 General requirements . 6 6.2 Validation of compliance 7 7 Qualification of elastomer materials (ageing and RGD) 8 7.1 General . 8 7.2 Requirements

18、for ageing tests . 8 7.3 Requirements for rapid gas decompression testing . 9 8 Qualification of elastomeric materials in bonded flexible hose . 9 8.1 General . 9 8.2 Qualification of bonded flexible hose liner material 10 8.3 Qualification of bonded flexible hose Layers outside the liner . 14 9 Qua

19、lification of elastomeric materials in other large components 15 9.1 General . 15 9.2 Qualification of elastomeric materials in flexible joints 15 9.3 Qualification of elastomeric materials in blow-out preventers . 15 9.4 Qualification of elastomeric materials for packers 16 Annex A (normative) Test

20、 media, conditions, equipment and procedures for ageing of elastomeric materials 17 Annex B (normative) Test media, conditions, equipment and procedures for rapid gas decompression testing of elastomeric materials . 26 Annex C (informative) Most commonly used elastomeric materials . 40 Annex D (norm

21、ative) Procedure for estimation of material service life using the Arrhenius relationship 42 Annex E (informative) Physical and chemical ageing . 47 Annex F (informative) Rapid gas decompression (RGD) 62 Bibliography 66 BS EN ISO 23936-2:2011ISO 23936-2:2011(E) iv ISO 2011 All rights reservedForewor

22、d ISO (the International Organization for Standardization) is a worldwide federation of national standards bodies (ISO member bodies). The work of preparing International Standards is normally carried out through ISO technical committees. Each member body interested in a subject for which a technica

23、l committee has been established has the right to be represented on that committee. International organizations, governmental and non-governmental, in liaison with ISO, also take part in the work. ISO collaborates closely with the International Electrotechnical Commission (IEC) on all matters of ele

24、ctrotechnical standardization. International Standards are drafted in accordance with the rules given in the ISO/IEC Directives, Part 2. The main task of technical committees is to prepare International Standards. Draft International Standards adopted by the technical committees are circulated to th

25、e member bodies for voting. Publication as an International Standard requires approval by at least 75 % of the member bodies casting a vote. Attention is drawn to the possibility that some of the elements of this document may be the subject of patent rights. ISO shall not be held responsible for ide

26、ntifying any or all such patent rights. ISO 23936-2 was prepared by Technical Committee ISO/TC 67, Materials, equipment and offshore structures for petroleum, petrochemical and natural gas industries. ISO 23936 consists of the following parts, under the general title Petroleum, petrochemical and nat

27、ural gas industries Non-metallic materials in contact with media related to oil and gas production: Part 1: Thermoplastics Part 2: Elastomers The following parts are planned: Part 3: Thermosets Part 4: Fibre-reinforced composite Part 5: Other non-metallic materials BS EN ISO 23936-2:2011ISO 23936-2:

28、2011(E) ISO 2011 All rights reserved vIntroduction ISO 23936 is intended to be of benefit to a broad industry group, ranging from operators and suppliers to engineering companies and authorities. ISO 23936 covers relevant generic types of non-metallic material (thermoplastics, elastomers, thermosett

29、ing plastics, fibre-reinforced plastics, etc.) and draws upon a wide range of existing technical experience, which has never before been summarized in a technical standard. ISO 23936 does not cover polymeric coatings such as thermal insulation and paint that are applied to the outside of components

30、but that are not in contact with oilfield fluids. The evaluation and qualification process described in this part of ISO 23936 is intended to ensure that the user of non-metallic materials has sufficient understanding and knowledge of the applicable materials to obtain acceptable performance in the

31、specified environment, and that the user can rely on stable quality to meet given specifications. A quality system is useful to ensure compliance with the requirements of this part of ISO 23936. Successful qualification of a manufacturer and a specific material is intended to be valid for other proj

32、ects and different operators. The consideration of qualification of a manufacturer is at the discretion and determination of the purchaser, normally on the basis of documentation provided by the manufacturer, as required in this part of ISO 23936 or any specific additional documentation. The purchas

33、er is responsible for ensuring (if necessary, with external competence) that the manufacturers selected are qualified. This part of ISO 23936 is based on NORSOK standard M-710. BS EN ISO 23936-2:2011BS EN ISO 23936-2:2011INTERNATIONAL STANDARD ISO 23936-2:2011(E) ISO 2011 All rights reserved 1Petrol

34、eum, petrochemical and natural gas industries Non-metallic materials in contact with media related to oil and gas production Part 2: Elastomers 1 Scope ISO 23936 describes general principles and gives requirements and recommendations for the selection and qualification of non-metallic materials for

35、service in equipment used in oil and gas production environments, where the failure of such equipment could pose a risk to the health and safety of the public and personnel, or to the environment. It can be applied to help avoid failures of the equipment itself. It supplements, but does not replace,

36、 the material requirements given in the appropriate design codes, standards or regulations. This part of ISO 23936 describes the requirements and procedures for qualification of elastomeric material used in equipment for oil and gas production. 2 Normative references The following referenced documen

37、ts are indispensable for the application of this document. For dated references, only the edition cited applies. For undated references, the latest edition of the referenced document (including any amendments) applies. ISO 34-1:2010, Rubber, vulcanized or thermoplastic Determination of tear strength

38、 Part 1: Trouser, angle and crescent test pieces ISO 37, Rubber, vulcanized or thermoplastic Determination of tensile stress-strain properties ISO 48, Rubber, vulcanized or thermoplastic Determination of hardness (hardness between 10 IRHD and 100 IRHD) ISO 815-1, Rubber, vulcanized or thermoplastic

39、Determination of compression set Part 1: At ambient or elevated temperatures ISO 2781, Rubber, vulcanized or thermoplastic Determination of density ISO 2921, Rubber, vulcanized Determination of low-temperature retraction (TR test) ISO 3601-3:2005, Fluid power systems O-rings Part 3: Quality acceptan

40、ce criteria ISO 7619-1, Rubber, vulcanized or thermoplastic Determination of indentation hardness Part 1: Durometer method (Shore hardness) ISO 13628-10:2005, Petroleum and natural gas industries Design and operation of subsea production systems Part 10: Specification for bonded flexible pipe BS EN

41、ISO 23936-2:2011ISO 23936-2:2011(E) 2 ISO 2011 All rights reservedASTM D297, Standard Test Methods for Rubber Products Chemical Analysis ASTM D395, Standard Test Methods for Rubber Property Compression Set ASTM D412, Standard Test Methods for Vulcanized Rubber and Thermoplastic Elastomers Tension AS

42、TM D624, Standard Test Method for Tear Strength of Conventional Vulcanized Rubber and Thermoplastic Elastomers ASTM D1414, Standard Test Methods for Rubber O-Rings ASTM D1415, Standard Test Method for Rubber Property International Hardness ASTM D2240, Standard Test Method for Rubber Property Duromet

43、er Hardness API 17K, Specification for Bonded Flexible Pipe 3 Terms, definitions and abbreviated terms For the purposes of this document, the following terms, definitions and abbreviated terms apply. 3.1 Terms and definitions 3.1.1 accelerated test test undertaken under conditions designed to speed

44、material deterioration NOTE This is usually accomplished by increasing temperature, in order to raise chemical reaction rates, but fluid concentration and stress are variables which can also be manipulated. 3.1.2 asset operator person who operates an asset, who has knowledge of well parameters and w

45、ho transmits this information to the user (3.1.15) NOTE 1 An asset can be a well, a production train, a plant, etc. NOTE 2 Well parameters can be fluid exposure, temperatures, pressures, duration, etc. 3.1.3 compression set difference between the original sample height and the post-test height, divi

46、ded by the interference, expressed as a percentage 3.1.4 elastomer rubber amorphous material mechanically mixed with other constituents to form a rubber compound, which is then shaped by flow into articles by means of the manufacturing processes of moulding or extrusion, and then (invariably) chemic

47、ally cured at elevated temperature to form an elastic insoluble material 3.1.5 fluid medium such as a gas, liquid, supercritical gas, or a mixture of these BS EN ISO 23936-2:2011ISO 23936-2:2011(E) ISO 2011 All rights reserved 33.1.6 interference difference between the original sample height and the

48、 height of spacer bar, each measured in the same direction as the direction of compression 3.1.7 compound manufacturer manufacturer producer of the elastomer material or of semi-finished products made from elastomer materials 3.1.8 modulus tensile stress at a given elongation NOTE In the rubber indu

49、stry, the modulus at 50 % elongation is often chosen. 3.1.9 polymer high molecular weight molecule, natural or synthetic, whose chemical structure can be represented by repeated small units which collectively form molecular chains NOTE This material class has three main sub-groups: elastomers, thermoplastics and thermosets. 3.1.10 rapid gas decompression RGD depressurization explosive decompression rapid pressure-drop in a high pressure gas-containing system which disrupts the equilibrium be