FORD WSS-M4D1028-A1-2013 POLYPROPYLENE (PP) COPOLYMER MEDIUM IMPACT COMPOUND TO BE USED WITH FORD WSS-M99P1111-A .pdf

1、 ENGINEERING MATERIAL SPECIFICATION Date Action Revisions Rev. 1 2013 12 13 Revised Editorial See Summary of Revisions R. Harris, NA 2013 10 25 Released R. Harris, NA Controlled document at www.MATS Copyright 2013, Ford Global Technologies, LLC Page 1 of 5 POLYPROPYLENE (PP) COPOLYMER, WSS-M4D1028-A

2、1 MEDIUM IMPACT COMPOUND 1. SCOPE The material defined by this specification is an extrusion, and blow moldable thermoplastic material based on polypropylene copolymer. 2. APPLICATION This specification was released originally for material used for air induction system (AIS) applications. 2.1 LIMITA

3、TIONS This material does not contain UV stabilizers, long term exposure to direct sunlight will cause chalking and loss of gloss. 3. REQUIREMENTS 3.1 STANDARD REQUIREMENTS FOR PRODUCTION MATERIALS Material suppliers and part producers must conform to the Companys Standard Requirements For Production

4、 Materials (WSS-M99P1111-A). 3.1.1 Note: Many 4D resin specifications prior to 2011, identified certain requirements with the symbol (s), which indicated that the mean and +/- 3 sigma values were to be reported. The specification minimum, maximum or range was established using 3 sigma values. For 20

5、11 and beyond, refer to Table 1 for number of samples required for each test to establish specification limits. 3.1.2 This specification is based on virgin materials, however materials with recycled content as defined by WRS-M99P42-A1 (post-consumer and/or postindustrial recyclates and repolymerised

6、 recycled materials) should be used whenever technically feasible and following all materials and PV testing required by Ford Materials Engineering. 3.1.3 The use of regrind is permitted, for economic / environmental reasons, with compliance as indicated in Ford Engineering CAD and Drafting Standard

7、 E-4. 3.1.4 Performance Criteria: Parts using this specification shall meet the appropriate performance specifications, WSS-M15P50-B/Latest. 3.1.5 As specified in WSS-M99P1111-A, paragraph 3.2, Ford Materials Engineering may request a Control Plan and Certificate of Analysis (CoA) containing lot tes

8、ting requirements which must include, but are not limited to: Melt Flow Rate Impact Strength, Notched Charpy at 23C Flexural Modulus ENGINEERING MATERIAL SPECIFICATION WSS-M4D1028-A1 Copyright 2013, Ford Global Technologies, LLC Page 2 of 5 3.2 SAMPLE PREPARATION Unless otherwise specified all tests

9、 shall be carried out on test specimens cut (in accordance with the ISO methods specified) from parts. Specimens are tested with the as-molded thickness of the part and are not machined to meet the thickness requirements of the Standard Test Methods except where necessary for fixturing. Greater vari

10、ation in test values can be anticipated when evaluating materials that are thinner than recommended by an applicable Industry Standard/Test Method. The test specimens A and D shall be molded using molding conditions defined in ISO 1873-2. See Table 1 for the number of samples required. Specimens sha

11、ll be as follows: Specimen A 150 minimum x 10 x 4.0 +/- 0.2 mm (ISO 527-2, Specimen Type 1A) Specimen B 355 x 100 x 1.0 +/- 0.1 mm (ISO 3795) Specimen C 145 x 60 x 3.2 +/- 0.2 mm Specimen D Center of Specimen A, 80 x 10 x 4.0 +/- 0.2 mm Specimen E 100 mm diameter x 3.2 mm Specimen F 80 mm diameter x

12、 3.2 mm Specimen G 90 mm x 200 mm Specimen H 50 +/- 1 mm diameter x 3.2 +/- 0.2 mm Specimen I 100 mm x 150 mm, min 3.3 MATERIAL PROPERTIES 3.3.1 Melt Flow Rate 0.3 3.0 g/10 minutes (ISO 1133 230 C, 2.16 kg) 3.3.2 Density 0.89 0.92 g/cm3 (ISO 1183, Method A) 3.3.3 Tensile Strength at Yield 19 MPa min

13、 (ISO 527-1 and ISO 527-2, Specimen A, 50 mm/minute test speed) 3.3.4 Tensile Modulus 0.9 GPa min (ISO 527-1 and ISO 527-2, Specimen A, 1 mm/minute test speed) 3.3.5 Impact Strength, Notched Charpy (ISO 179-1/1eA, Specimen D) 3.3.5.1 At 23 +/- 2 C 45, kJ/m2 min Report Break Type 3.3.5.2 At -40 +/- 2

14、 C 1.5, kJ/m2 min Report Break Type The test specimen must be conditioned for minimum of 6 hours at the above specified temperature prior to impact test. Low temperature testing shall be done within the cold chamber, if not possible, test may be conducted outside, but within 5 seconds. 3.3.6 Heat De

15、flection Temperature 44 C min (ISO 75-1 and ISO 75-2, Specimen D, flatwise, 0.34 +/- 0.1 mm deflection. At 1.80 MPa) ENGINEERING MATERIAL SPECIFICATION WSS-M4D1028-A1 Copyright 2013, Ford Global Technologies, LLC Page 3 of 5 3.3.7 Heat Aging Performance (ISO 188, 150 +/- 50 air changes/h, 1000 h at

16、120 +/- 2 C. After heat aging test specimens are to be conditioned in a desiccator for 3 - 5 h at 23 +/- 2 C. Unaged property values shall be determined at the time of the aged properties determination) 3.3.7.1 Tensile Strength at Yield, Change +/- 25% max (Test Method per Para 3.3.3) 3.3.7.2 Impact

17、 Strength, Notched Charpy, Change +/- 25% max (Test Method per Para 3.3.7, specimens to be notched before Heat Aging) 3.3.8 Flammability (ISO 3795/SAE J369, Specimen B, smooth surface) Burn Rate 100 mm/minute max 3.4 MATERIAL PROPERTIES REPORT ONLY Values are retained in Ford Materials Database . 3.

18、4.1 Elongation at Yield Report Value, % (ISO 527-1 & ISO 527-2, Specimen A 50 mm/minute test speed) 3.4.2 Molding Shrinkage (ISO 294-3 and 294-4/ISO 2577, 60 x 60 x 2.0 +/- 0.1 mm injection molded specimen B) After 48 h at 23 +/- 2 C Flow Report Value, % Cross Flow Report Value, % 3.4.3 Coefficient

19、of Linear Thermal Expansion (ISO 11359-2 TMA) -30 +/- 2 C to 100 +/- 2 C Flow Report Value, mm/mm/ C Cross Flow Report Value, mm/mm/ C 3.4.4 Flexural Modulus Report Value, GPa (ISO 178, Specimen D, 64 mm support span, 2 mm/minute test speed 3.4.5 Impact Strength, Notched Izod (ISO 180/1A, Specimen D

20、) 3.4.5.1 At 23 +/- 2 C Report Value, kJ/m2 Report Break Type ENGINEERING MATERIAL SPECIFICATION WSS-M4D1028-A1 Copyright 2013, Ford Global Technologies, LLC Page 4 of 5 3.4.5.2 At -40 +/- 2 C Report Value, kJ/m2 Report Break Type The test specimen must be conditioned for minimum of 6 hours at the a

21、bove specified temperature prior to impact test. Low temperature testing shall be done within the cold chamber, if not possible, test may be conducted outside, but within 5 seconds. 3.4.6 Heat Deflection Temperature Report Value, C min (ISO 75-1 and ISO 75-2, Specimen D, flatwise, 0.34 +/- 0.1 mm de

22、flection. At 0.45 MPa) 3.4.7 Poissons Ratio Report Ratio (ISO 527-1 and ISO 527-2, Specimen A 1 mm/minute test speed) 3.4.8 Supplemental Information The following curves are to be submitted with the data packages: FTIR TGA DSC CLTE Engineering Stress/Strain at 23 C, -40 C, 80 C 4. GENERAL INFORMATIO

23、N The information given below is provided for clarification and assistance in meeting the requirements of this specification. Contact for questions concerning Engineering Material Specifications. 4.1 TYPICAL PROPERTIES USING METHODS IN SECTION 3.4 Para. Test Typical Value Units 3.4.1 Elongation at

24、Yield 5 - 10 % 3.4.2 Molding Shrinkage After 48 h at 23 +/- 2 C Flow Cross Flow 1.1 1.8 1.1 1.5 % % 3.4.3 Coefficient of Linear Thermal Expansion -30 to 100C Flow Cross Flow 11 - 16 13 - 16 E-5 mm/mm/ C E-5 mm/mm/ C 3.4.4 Flexural Modulus 0.8 1.9 GPa 3.4.5 Impact Strength, Notched Izod At 23 +/- 2C

25、At -40 +/- 2C 11 - 60 2 - 8 kJ/m kJ/m 3.4.6 Heat Deflection Temperature At 0.45 MPa 70 - 85 C 3.4.7 Poissons Ratio 0.4 0.5 N/A ENGINEERING MATERIAL SPECIFICATION WSS-M4D1028-A1 Copyright 2013, Ford Global Technologies, LLC Page 5 of 5 4.2 MATERIAL IDENTIFICATION FOR RECYCLING PURPOSES PP (ISO 1043/1

26、1469) Table 1: Minimum Sample Size Initial Approval New Manufacturing Location for Previously Approved Material Para. Test Minimum Lots Specimens per Lot Total Test Specimens Lots Specimens per lot Total Test Specimens 3.1.1 WSS-M99P1111-A 3.1.5 WSS-M15P50-B/Latest Reference performance specificatio

27、n 3.1.1 Melt Flow 3 1 3 1 1 1 3.3.2 Density 1 3 3 1 3 3 3.3.3 Tensile Strength at Yield* 3 5 15 1 5 5 3.3.4 Tensile Modulus 3 10 30 1 10 10 3.3.5 Impact Strength Notched Charpy (per condition)* 3 10 30 1 10 10 3.3.6 Heat Deflection Temperature* 1.80 MPa 3 2 6 1 2 2 3.3.7 Heat Aging Performance 3.3.7

28、.1 Tensile Strength at Yield, Change 1 5 5 3.3.7.2 Impact Strength, Notched Charpy, Change 1 10 10 3.3.8 Flammability 1 5 5 3.4 Material Properties Report Only 3.4.1 Elongation at Yield 3 5 15 1 5 5 3.4.2 Mold Shrinkage 1 5 5 1 5 5 3.4.3 Coefficient of Linear Thermal Expansion 1 3 3 3.4.4 Flexural M

29、odulus 3 10 30 1 10 10 3.4.5 Impact Strength, Notched Izod 1 10 10 3.4.6 Heat Deflection Temperature 0.45 MPa 3 2 6 3.4.7 Poissons Ratio 1 2 2 3.4.8 Curves - FTIR - TGA - DSC - CLTE - Stress/Strain 1 1 1 per test * For these requirements the 3 sigma value from the raw data is used to meet the requirements. 5. SUMMARY OF REVISIONS 2013 12 13 Removed limitation regarding low impact resistance at low temperatures. Added TGA in 3.4.8 Added FT in 3.4.8 description