GMW GMW17022-2013 Polypropylene Copolymer 鈥 Low Density UV Stable Mineral Filled Issue 1 English.pdf

1、 WORLDWIDE ENGINEERING STANDARDS Material Specification GMW17022 Polypropylene Copolymer Low Density, UV Stable, Mineral Filled Copyright 2013 General Motors Company All Rights Reserved December 2013 Page 1 of 7 1 Scope 1.1 Material Description. This specification describes low density material grad

2、es of mineral filled polypropylene copolymer, ultraviolet (UV) stable, pellet form, injection molding compounds. 1.1.1 Additional Characteristics. Materials certified to this material specification may have additional characteristics, e.g., paintable, mar and scratch resistance, elastomer modified,

3、etc. Possible additional characteristics are defined in GMW3013. 1.2 Symbols. The material abbreviation according to ISO 11469 is GMW17022P-PP/PE-M07. 1.3 Typical Applications. Typical applications include the following: interior trim. 2 References Note: Only the latest approved standards are applic

4、able unless otherwise specified. 2.1 External Standards/Specifications. AATCC 23 ISO 179/1eA ISO 1133 ISO 3451-1 ASTM D3763 ISO 188 ISO 1183-A ISO 6603-1/2 ASTM E831 ISO 294 ISO 1873-2 ISO 11359-2 ISO 75-1/2 ISO 527-1/2 ISO 3167 ISO 11469 ISO 178 ISO 1050 2.2 GM Standards/Specifications. GM9302P GMW

5、3221 GMW14162 GMW16172 GMW3013 GMW3232 GMW14444 GMW16853 GMW3059 GMW3235 GMW14688 GMW3205 GMW3417 GMW15634 2.3 Additional References. TMC003 Material Safety Data Sheet guidance documents (available at ). 3 Requirements Materials approved to this specification shall meet the requirements of GMW3013,

6、General Requirements for Handling of Technical Terms of Delivery for Plastics. 3.1 Requirements on Test Specimens. Unless otherwise specified, injection molding of test specimens shall be accomplished per ISO 294 with the conditions for injection molding from ISO 1873-2. Test methods and specimen di

7、mensions are also to be in accordance with ISO 1873-2 with the following additions: use ISO 3167, Type 1A (GMW3221), thickness 4 mm, for tensile and flexural properties. All tests shall be performed on specimens 40 h minimum after molding and immediately following a conditioning period of 24 h minim

8、um in a controlled atmosphere per GMW3221, Code A, unless otherwise specified. All tests shall be performed on unannealed specimens. 3.2 Requirements on Delivery. Important physical, mechanical and thermal properties that characterize the material are summarized in Table 1 and Table 2. Note: For eac

9、h product, the requirements to Table 1 and Table 2 shall be documented by Certification Statement according to GMW3013. The color shall be specified on drawings, in material specifications and otherwise. Copyright General Motors Company Provided by IHS under license with General Motors CompanyNot fo

10、r ResaleNo reproduction or networking permitted without license from IHS-,-,-GM WORLDWIDE ENGINEERING STANDARDS GMW17022 Copyright 2013 General Motors Company All Rights Reserved December 2013 Page 2 of 7 The values specified in Table 1 shall be met by test specimens in natural or black; the values

11、specified in Table 2 shall be met by integrally colored test specimens. For integrally colored grades where other additive systems (e.g., stabilizer) are used, the impact values shall not decrease more than 10% from specified minimum value. 3.3 Chemical Requirements. All parts manufactured from mold

12、ing compounds shall be resistant to the media they contact at their place of use. 3.4 Compound Properties. See Table 1 and Table 2. The following are also required for full specification approval. The minimum number of lots per test required is one in natural: Tensile Modulus, Poissons Ratio, Stress

13、-Strain Curve at multiple temperatures, e.g., +23 C, +85 C, -30 C; and Multiaxial Impact Curve. See GMW3013 for the test procedures. 3.5 Performance Requirements. Performance requirements, e.g., flammability, fogging or resistance to odor, shall be specified on part drawings or in component specific

14、ations. All finished parts for interior applications shall meet the requirements according to GMW14444. Table 1: Compound Properties (Black or Natural) Property Standard Units Type T1 Requirements ISO Symbol ISO 11469 N/A PP/PE-M7 Filler Content ISO 3451-1 Method A (at +750 C) % 6 to 9 Density (Targ

15、et Range) ISO 1183-A g/cm3 0.950 0.015 Melt Flow Rate MFR230/2.16 ISO 1133 g/10 minimum 15 to 25 Melt Volume Flow Rate MVR230/2.16 ISO 1133 cm3/10 minimum 16 to 26 Flexural Modulus ISO 178, 2 mm/minimum test speed MPa 2000 to 2400 Tensile Modulus ISO 527-1 ISO 527-2 Specimen 1A, 1 mm/minimum test sp

16、eed MPa 2100 to 2600 Tensile Stress at Yield ISO 527-1 ISO 527-2 Specimen 1A, 50 mm/minimum test speed MPa 26 Tensile Stress at Yield after Heat Aging (1000 h 5 h at 100 C 3 C) Note 1 ISO 527-1 ISO 527-2 50 mm/minimum test speed % Retention 100 Note 2 Multiaxial Impact at 23 C ISO 6603-1/2 Specimen

17、60 mm diameter x 2 mm, or 60 mm x 2 mm x 2 mm plaque 4.4 m/s speed J at maximum load 25 Multiaxial Impact at (minus) -30 C ISO 6603-1/2 Specimen 60 mm diameter x 2 mm, or 60 mm x 2 mm x 2 mm plaque 4.4 m/s speed J at maximum load 10 Multiaxial Impact at 23 C ASTM D3763 6.6 m/s speed J at maximum loa

18、d 15 Copyright General Motors Company Provided by IHS under license with General Motors CompanyNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-GM WORLDWIDE ENGINEERING STANDARDS GMW17022 Copyright 2013 General Motors Company All Rights Reserved December 2013 Page 3

19、 of 7 Property Standard Units Type T1 Requirements Multiaxial Impact at (minus) -30 C ASTM D3763 6.6 m/s speed J at maximum load 8 Notched Charpy Impact at 23 C ISO 179/1eA kJ/m2 4.0 Notched Charpy Impact at -30 C ISO 179/1eA kJ/m2 2.0 Notched Charpy Impact After Heat Aging (1000 h 5 h at 100 C 3 C)

20、 Note 1, Note 3, ISO 179/1eA Retention % 75 Mold Shrink, 48 h After Molding, Flow Direction ISO 294, plaque size 101.6 mm x 152 mm x 3.2 mm % Target Range 0.80 to 1.30 Mold Shrink, 48 h After Molding, Cross Flow Direction ISO 294, plaque size 101.6 mm x 152 mm x 3.2 mm % Target Range 0.90 to 1.40 Mo

21、ld Shrink, 48 h at 80 C After Molding, Flow Direction ISO 294, plaque size 101.6 mm x 152 mm x 3.2 mm % Target Range 1.00 to 1.40 Mold Shrink, 48 h at 80 C After Molding, Cross Flow Direction ISO 294, plaque size 101.6 mm x 152 mm x 3.2 mm % Target Range 1.10 to 1.50 Heat Deflection Temperature (HDT

22、) - Method B, 0.45 MPa, Flatwise ISO 75-1 ISO 75-2 80 mm x 10 mm x 4 mm, unannealed C 105 HDT - Method A, 1.8 MPa, Flatwise ISO 75-1 ISO 75-2 80 mm x 10 mm x 4 mm, unannealed C 55 Coefficient of Linear Thermal Expansion (CLTE) - Flow Direction ASTM E831 or ISO 11359-2 10-6 mm/mm C Target Range 6.0 t

23、o 10.0 CLTE - Cross Flow Direction ASTM E831 or ISO 11359-2 10-6 mm/mm C Target Range 7.0 to 12.0 Fogging GMW3235-B, condensable constituent mg 2.0 Copyright General Motors Company Provided by IHS under license with General Motors CompanyNot for ResaleNo reproduction or networking permitted without

24、license from IHS-,-,-GM WORLDWIDE ENGINEERING STANDARDS GMW17022 Copyright 2013 General Motors Company All Rights Reserved December 2013 Page 4 of 7 Property Standard Units Type T1 Requirements Odor GMW3205 B, specimen 100 mm x 150 mm x 3.2 mm Minimum 6 Minimum 6 Emissions GMW16853 GMW15634 Volatile

25、 Organic Compound (VOC) value Semi-volatile Organic Compound (SVOC) value g/g VOC: 400 g/g SVOC: 400 g/g Paintability GMW16172 Not applicable Table 1 for Interior Plastics Note 1: Heat aging for 1000 h 5 h at +102 C 3 C according to ISO 188 Method A (air oven method). Note 2: Aged specimens shall ha

26、ve retention 100% relative to unaged specimens tested concurrently. Note 3: Impact specimens for Charpy testing shall be notched prior to aging. Aged specimens shall have retention 75% relative to unaged specimens tested concurrently. N/A = Not applicable. Table 2: Compound Properties (Integrally Co

27、lored) Property Standard Units Type T1 Requirements Colorfastness to Light, Natural Weathering Color Change Surface Defects Weather Resistance per GMW3417-L1-F2-G1-T5 Test at the following intervals: 1250 MJ/m2 (30 000 ly), 2300 MJ/m2 (55 000 ly), 3350 MJ/m2 (80 000 ly), 4400 MJ/m2 (105 000 ly) E E

28、= 3 .0 maximum No objectionable defects allowed. Note: Test specimen required to be returned to customer at each interval. Colorfastness to Light, Accelerated Color Change Surface Defects Xenon Arc according to GMW14162/D/ 300 kJ/m2 and 1240.8 kJ/m2 E E = 3 .0 maximum No objectionable defects allowe

29、d. Note: Separate test panels are required for each exposure. Colorfastness to Artificial Light GMW14162/C/ 26 MJ/m2 Rating Rating of minimum 4 (Also there shall be no more than a noticeable change in hue or chrome, and no objectionable tackiness, blotchiness, loss of grain, wrinkling or other undes

30、irable effects.) Notched Charpy Impact at 23 C ISO 179/1eA kJ/m2 3.0 Flammability GMW3232 mm/minute No burn or flame front transmission across the surface at a rate greater than 100 mm/minute. Stress Mark Susceptibility GM9302P Stress Evaluation Test (SET) SET= 2.5 maximum Copyright General Motors C

31、ompany Provided by IHS under license with General Motors CompanyNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-GM WORLDWIDE ENGINEERING STANDARDS GMW17022 Copyright 2013 General Motors Company All Rights Reserved December 2013 Page 5 of 7 Property Standard Units T

32、ype T1 Requirements Colorfastness to Burnt Gas AATCC 23 or ISO 1050 G02 light neutral or light gray E; YI E 1.5; YI 2.0 Scratch Resistance GMW14688-A-10N; GM NAAE Interior WPEPGLD Plastic Color Submission Plaque Across all grains except modified Kruz For initial approval in MATSPC, Test one (1) lot

33、in ebony (black), grey and neutral. For color approval, each color must be tested. For other regions use Master Plaques with the grains, colors and gloss levels as defined in the Acceptance Requirements Document (ARD) sheet of the corresponding GM Program L 0.5 Scratch Resistance after Heat Aging No

34、te 1 GMW14688-A-10N; GM North American Appearance Engineering (NAAE) Interior WPEPGLD Plastic Color Submission Plaque For initial approval in MATSPC, Test one (1) lot in ebony (black), grey and neutral. For color approval, each color must be tested L Across all grains except modified Kruz Note 2 Emi

35、ssions GMW15634 Volatile Organic Compound (VOC) value Semi-volatile Organic Compound (SVOC) value g/g g/g Requirements see GMW16853 Note 1: Heat aging for 168 h at 100 C 5 C according to ISO 188 Method A (air oven method). Test after 24 h recovery. Note 2: Aged specimens shall have at least the same

36、 scratch results relative to unaged specimens tested concurrently. 4 Manufacturing Process Not applicable. 5 Rules and Regulations 5.1 Legal Regulations. All materials must satisfy applicable laws, rules, regulations and recommendations valid in the country of usage. 5.2 Language. In the event of co

37、nflict between the English and domestic language, the English language shall take precedence. 5.3 Inspection and Rejection. Samples of components or materials released to a GM material specification shall be tested for conformity with the requirements of this material specification and approved by t

38、he responsible Engineering department prior to commencement of delivery of bulk supplies. A new approval must be received for any changes, e.g., properties, manufacturing process, location of manufacture, etc. If not otherwise agreed, all testing and documentation normally required for initial relea

39、se must be completed. It is the responsibility of the supplier to inform the customer in a timely manner, without solicitation, and to include documentation of all modifications of materials and/or processes and to apply for a new release. If not otherwise agreed, all release tests shall be repeated

40、 and documented by the supplier prior to commencement of delivery of non-conforming bulk supplies. In individual cases, a shorter test can be agreed to between the responsible Engineering department and the supplier. Copyright General Motors Company Provided by IHS under license with General Motors

41、CompanyNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-GM WORLDWIDE ENGINEERING STANDARDS GMW17022 Copyright 2013 General Motors Company All Rights Reserved December 2013 Page 6 of 7 5.4 Material Safety Data Sheets/Safety Data Sheets (MSDS/SDS). For new product sub

42、missions, or when a change in chemical composition of an existing product has occurred, a complete copy of the Material Safety Data Sheet/Safety Data Sheet must be submitted in compliance with the Globally Harmonized System of Classification and Labeling of Chemicals (GHS) requirements or other coun

43、try-specific MSDS/SDS requirements. In addition, product MSDS/SDS submissions must be in compliance with specific country General Motors TMC003 Material Safety Data Sheet/Safety Data Sheet guidance documents where available. 5.5 All materials supplied to this standard must comply with the requiremen

44、ts of GMW3059, Restricted and Reportable Substances for Parts. 6 Approved Sources Materials supplied to this specification must be approved by General Motors. A list of approved materials can be found in MATSPC. This GM Material File is provided to third parties to reduce redundant testing of materi

45、als. If approved material already listed is used, the part supplier can use GM Material File reference for Production Part Approval Process (PPAP) material approval. If the decision is made to use a not yet approved material, contact Materials Engineering for details on the approval process. The mat

46、erial approval process must be completed prior to PPAP start date of the part supplied to General Motors. 7 Notes 7.1 Glossary. MATSPC: Global repository of GM approved materials for corresponding GM Engineering Standards. 7.2 Acronyms, Abbreviations, and Symbols. ARD Acceptance Requirements Documen

47、t CLTE Coefficient of Linear Thermal Expansion DSC Differential Scanning Calorimetry GHS Globally Harmonized System of Classification and Labeling of Chemicals HDT Heat Deflection Temperature MFR Melt Flow Rate MSDS Material Safety Data Sheet MVR Melt Volume Flow Rate N/A Not applicable NAAE North A

48、merican Appearance Engineering PPAP Production Part Approval Process SDS Safety Data Sheet SET Stress Evaluation Test SVOC Semi-volatile Organic Compound UV Ultraviolet VOC Volatile Organic Compound WPEPGLD Gloss Master Designation Copyright General Motors Company Provided by IHS under license with General Motors CompanyNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-GM WORLDWIDE ENGINEERING STANDARDS GMW17022 Copyright 2013 General Motors Company All Rights Reserved December 2013 Page 7 of 7 8 Coding System This standard shall be referenced in othe