1、 , ()INTERSTATE COUNCIL FOR STANDARDIZATION, METROLOGY AND CERTIFICATION (ISC) 31792null2012, - 317922012II, - 1.092 . - 1.22009 . -, . , , , 1 , - ( )2 ()3 , (- 1 2012 . 51) : ( 3166) 00497 ( 3166) 00497 AM BY KZ KG MD - RU UZ 4 29 - 2012 . 1629- 317922012 1 2013 .5 5318420086 - , . () - . , - - ,
2、2014 -, - 317922012III1 12 13 , 24 35 , , , .35.1 35.2 45.3 .55.4 .56 -n- .76.1 , .76.2 Bio-Beads SE-X3 86.3 / - 86.4 .107 117.1 / . 117.2 117.3 .127.4 .17 7.5 .18 7.6 .18 7.7 .18 8 () 198.1 - .198.2 218.3 228.4 .22 8.5 22 8.6 .25 8.7 26 8.8 26 8.9 27 () (TEQ) / 28 () 29 () / 31 () .331 20130701 1 1
3、7 -n- : 2,3,7,8-n-, 2,3,7,8-n-; 1,2,3,4,7,8-n-; 1,2,3,6,7,8-n-; 1,2,3,7,8,9-n-; 1,2,3,4,6,7,8-n-; -n-; 2,3,7,8-; 1,2,3,7,8-; 2,3,4,7,8-; 1,2,3,4,7,8-; 1,2,3,6,7,8-; 2,3,4,6,7,8-; 1,2,3,7,8,9-; 1,2,3,4,6,7,8-; 1,2,3,4,7,8,9-; , 14 - (): 3,3,4,4-; 3,4,4,5-; 2,3,3,4,4-; 2,3,4,4,5-; 2,3,4,4,5-; 2,3,4,4,
4、5-; 3,3,4,4,5-; 2,3,3,4,4,5-; 2,3,3,4,4,5-; 2,3,4,4,5,5-; 3,3,4,4,5,5-; 2,2,3,3,4,4,5-; 2,2,3,4,4,5,5-; 2,3,3,4,4,5,5- , . , - - - - - , . 0,1 0,5 /. - , - .2 : 12.1.00776 . . 20176 . 177074 ( 104283, 478880) . -, , , . 265278 . 416676 . . 420477 . . 317922012 , - Fish, marine invertebrates and prod
5、ucts of their processing.Determination of dioxins and dioxin-like biphenyls content by GC-MS method 3179220122 432877 . . 670972 . 699577 . -. 763685 , , -. 929374 . 996886 . 2001093 . 241042001* . 2533682 . , 2849890 . . 2922791 ( 83580) . . 1. , 1 , - . (), (-) . , , , , .3 , 3.1 -:3.1.1 -n-/; /:
6、-n- .3.1.2 ; S/S: / , - 1312, - .3.1.3 ; R/S: - 1312 /, - S/S, , - .3.1.4 -: -, - , - , ., / .3.1.5 ; TEQ: / , , - , 2,3,7,8-n- 1 ( ).3.1.6 : -, / , - (2 TEQ, /).3.2 : -n-; -n-; -n-; -n-; -n-; ;* 532282008 -. 1. . . 3179220123 ; ; ; ; . , - IUPAC, , 1,2,3,4,5-n-.3.3 () : 77 3,3,4,4-; 81 3,4,4,5-; 10
7、5 2,3,3,4,4-; 114 2,3,4,4,5-; 118 2,3,4,4,5-; 123 2,3,4,4,5-; 126 3,3,4,4,5-; 156 2,3,3,4,4,5-; 157 2,3,3,4,4,5-; 167 2,3,4,4,5,5-; 169 3,3,4,4,5,5-; 170 2,2,3,3,4,4,5-; 180 2,2,3,4,4,5,5-; 189 2,3,3,4,4,5,5-.3.4 - .4 / , , . 2,3,7,8- LD50= 0,05 /, 1. , /, , , ., , - . - . , , , ., , , - , , , . , - , , .5 , , , 5.1 - , 50 600 . 3179220124 , 2,3,7,8- ( /) 1,0 5:1 (, -95, DFS, JMS-700, Agilent-5975, Varian-320MS, ITMS-240MS, ITQ 900GC/MS, TSQ Quantum ). 30(60) , 0,25 - (DB-5MS, VF-5MS) () SP-Sil88, DB-DIOXIN ( , 2,3,7,8-
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