GOST 32690-2014 Juices and Juice Products Determination of pesticides by tandem high performance liquid mass spectrometry (HPLC-MS MS)《果汁和果汁产品 采用串联高效液相质谱分析 (HPLC-MS MS) 测定农药》.pdf

1、 , () INTERSTATE COUNCIL FOR STANDARDIZATION, METROLOGY AND CERTIFICATION (ISC) 32690 2014 - (-/) 2015 326902014 II , - 1.092 . 1.2 2009 . -, . , , , 1 - ( ) 2 3 , (- 25 2014 . 45-2014) : ( 3166) 00497 ( 3166) 00497 AM BY KG RU 4 19 - 2014 . 897- 326902014 - 1 2016 . 5 - : - EN 12393 ( ) Foods of pl

2、ant origin Multiresidue methods for the determination of pesticide residues by GC or LC-MS/MS ( - . - -); - EN 15637:2008 Foods of plant origin Determination of pesticide residues using LC-MS/MS following methanol extraction and clean-up using diatomaceous earth . - - (); - CEN/TR 15641:2007 Food an

3、alysis Determination of pesticide residues by LC-MS/MS Tandem mass spectrometric parameters ( . -) CEN/NC 275 . 6 326902014 III - , . () - - . , , 2015 -, - 326902014 IV 1 01 2 . 01 3 02 4 , , , . 02 5 . 03 6 . 03 7 . 05 8 . 06 9 08 10 08 11 . 08 () -/ 10 () / . 13 () 27 () -/ . 28 . 35 326902014 1

4、- (-/) Juices and Juice Products. Determination of pesticides by tandem high performance liquid mass spectrometry (HPLC-MS/MS) 2016 01 01 1 - - - ( -/) - 0,0001 0,1000 /. - . 2 - : 12.1.00491 . . 12.1.00776 . - 12.1.01076 . . - 12.1.01979 . . - OIML R 76-12011 . - . 1. . 177074 ( 104283, 478880) . -

5、, , , . 36962013 . 5725-12003 ( ) -. 1. 5725-22003 ( ) -. 2. 1631787 . / 170252009 - 2533682 . . 2631384 . , 2667185 , -. 326902014 2 2831189 . - 2903091 . - . 2922791 ( 835/181) . . 1. 32689.12014 . - 1. 32689.22014 . - 2. 32689.32014 . - 3. - , 1 , - . (), - () . , , , , . 3 , - -/ - Electrospray

6、Ionization (ESI) - Selected Reaction Monitoring (SRM). 4 , , -, -/* - 10 3000 (. . .), 0,1 . . , , - , - / 1000:1, 0,0001 0,1000 /, , ; - , 50 ; - - 5 18. , - 0,001 OIML R 76-1. . , 3000 g ( -). 100 . , 120 ./. , 200 . 16317. (*) 5 3. - 98 %. * -/ . * (), , ChemElut (Varian, Palo Alto, CA, USA) . -

7、. 326902014 3 , 200 0,025 . - , 0,03 %. . , . . . 4233, . . . , . . . 1 3696. 0,001; 0,005 0,010 3 0,0001, 0,0002 0,001 3 . 2 3. 2- 1, 2 5 3 29227. 100 1000 3 - 28311. 80 3. 50, 100 200 3 25336. 2- 25, 50 250 3 1770. 25336. 2- 25 50 3 2 2 1770. 50, 100 250 3 25336. 50 3 25336. 10 50 3 25336. ( ) 1,5 3. 50, 250 1000 3 , - . () 4 0,45 . , , , - , -. 5 26313. 26671, 32689.1, 32689.2 32689.3. 6 6.1 , - 32689.1, 32689.2 32689.3. 6.2 6.2.1 -, . - ( ). 6.2.2 200 3 20 80 - . -. ( ). 326902014 4 1 . 6.3