1、 542882010 27 2002 . 184- , 1.02004 . 1 - ( ) - , 42 31 3 27 2010 . 1129-4 312008 - (ASTM D 312008 Standard test method for trace quantities of sulfur in liquid petroleum hydrocarbons byoxidative microcoulometry). - 1.52004 ( 3.5). - -, 5 - , - . () . - , , 2012 , - - II 5428820101 12 13 24 25 26 .3
2、7 .58 .79 .810 811 812 (QA) .1013 .1114 1115 .14 X1 () (QC)14 X2 () , 14 15 () ( ) .17 542882010III Light liquid petroleum hydrocarbons. Determination of trace quantities of sulfur by oxidative microcoulometry 201207011 1.1 3,0 1000 / , , - 26 274 ( 80 F 525 F). , ( 4806), ( 4814), (Ed 75-Ed 85) ( 5
3、798) , , 10 %. - . 02.03 .1.2 , , 1.1, 1000 /, , , - . , , , .1.3 , , ., -, . - (/).1.4 -, . - , . 79.2 : 1193 - (ASTM D 1193, Specification for reagent water) 1298 , ( ) API (ASTM D 1298, Test method fordensity, relative density (specific gravity), or crude petroleum and liquid petroleum products b
4、y hydrometermethod) 4052 (ASTM D 4052, Test method for density and relative density of liquids by digital density meter) 4057 (ASTM D 4057,Practice for manual sampling of petroleum and petroleum products)1 542882010 4177 (ASTM D 4177, Practice for automatic sampling of petroleum and petroleum produc
5、ts) 4806 -, (ASTM D 4806,Specification for denatured fuel ethanol for blending with gasolines for use as automotive spark-ignition enginefuel) 4814 (ASTM D 4814, Specification for automotive spark-ignition engine fuel) 5798 (Ed75-Ed85) - (ASTM D 5798, Specification for fuel ethanol (Ed75-Ed85) for a
6、utomotive spark-ignitionengines) 6299 (ASTM D 6299, Practice for applying statistical quality assuranceand control charting techniques to evaluate analytical measurement system performanc) OSHA 29 FR, 1910.1000 1910.1200 (OSHA Regulations 29 CFR, paragraphs1910.1000 and 1910.1200)3 3.1 , 900 1200 ,
7、50 %80 % 20 %50 % (, , . .). - , , -, . , (I c215 t), c, - , .3.2 -I3c45+SO2+H2O c174 SO3+3I+2H+. (1) 3Ic174I3c45+2. (2)3.3 SO2 - , .4 4.1 - , , , . -, , .5 5.1 , - 10 , , 1000 .5.1.1 , .5.2 - (, Ni, V, Pb . .) 500 / (ppm).2 5428820106 6.1 , - . 1 , - .6.2 2.6.3 , 900 C1200 , SO2. . - .6.4 , , - - -
8、3 5428820101 (100 ); 2 ; 3 ; 4 ; 5 ;6 ; 7 - 1 1 ; 2 ; 3 ; 4 ; 5 ; 6 ; 7 ;8 ; 9 ; 10 2 , . , . -.6.5 : ; : ; ; . , Ag/AgCl, . , -. , - , . , . , . .6.6 , - . - . , .6.7 (), - (mV) -.6.8 . , - -.6.9 . , -, , SO2. -. . , , , .6.10 . , 5 80 3. 80 % .6.11 . .6.11.1 . (-) . - -. , , . (. 6.11.2).6.11.1.1 (). - , -.
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