GOST R 55460-2013 Alcoholic production Identification Method for determination the relation of isotopes C13 C12 carbon dioxide in sparkling wines and fermentation drinks《酒精制品 识别 气泡.pdf

1、 554602013 . 13/12 1 - , - ( )2 091 - 3 27 2013 . 213-4 5 . 2014 . 1.02012 ( 8). ( 1 ) , -. () . , - - (gost.ru) , 2014 , - - II 5546020131 12 13 24 25 , , 26 .37 .38 49 410 , . . 511 612 6 () 7III 554602013 . 13/12 lcoholic production. Identification. Method for determination the relation of isotop

2、es13C/12C carbon dioxide insparkling wines and fermentation drinks 201407011 13/12 ( c10013) -. , , -,c10013O2288. c10013O2, , - , .2 : 5725-12002 ( ) . 1. 5725-22002 ( ) . 2. 5725-62002 ( ) . 6. 12.0.00490 . - . 12.1.00491 . . 12.1.00588 . - 12.1.00776 . . - 12.2.007.075 . . 12.4.00983 . . . 12.2.0

3、852002 , . . - 12.4.02175 .1 554602013 12.4.10383 . , . 805085 . . 317302012 . - - - , 1 , . , , . , - , - (). , - , , , , . , -, , , .3 :3.1 PDB: Belemnitella Americana PDB ( , ).PDB . PDB-VPDB. c10013 c10013PDB=131213121312CCCCCCc230c232c231c231c246c248c247c247c45c230c232c231c231c246c248c247c247c2

4、30c232c231c231c246c248c247PDBc247PDBc215 1000,(1)1312CCc230c232c231c231c246c248c247c247PDB 1312,0,0112372.4 - , 44, 45, 46, - 2, , -, - PDB(c10013PDB).5 , , - -:- , . . . 170;- (/), .900;- , /c68,( 10 % m/z 44), .95;- (13/12), , : .0,01; .0,1.2 554602013 - - . , :- IAEA-CH-6 sucrose 506 (c10013C = 1

5、0,4 );- NBS22 oil, 427 (c10013C = 29,7 ). . ( ), , 2 3. 0,01 3 . 1 % .:- 8050 99,8 %, ;- 99,9999 %. , , -.6 31730.7 7.1 .7.2 :- 1000 C;- () .3c215 105;- () - .1,1c215 105;- .0,002 3.7.3 , . - . 2 - - ( ). - . c10013O2 . c10013O2 . . . , - 0,06 . , ( ). c10013O2 0,5 .7.4 : , ( 1 2), , (), . - . (. ,

6、.1) - ( ), , . - ( 1 2), -, 2 3. - (-3 554602013 1), ( 2), , ( ), , 2 3.8 . 1, . 1 . . 2 , . 2 . : - ( ), , -, . 0,002 3 - .* -. , , c10013C , , - . . c10013C . (c10013C) . 5725-1 5725-2.9 9.1 c10013C , , - (1), -c10013/=()RRR c45c215 1000,(1) R R c10013C .9.2 , 3 10013 1313 13 13c215c45c215c43c43c100c100c100c100c100CCCC C123max min()c163 R0,95,(2) c10013Cmax, c10013Cmin - , ;c10013C1, c10013C2, c10013C3 , ;CR0,95 , %. ( ), , ()CR0,95, 1, = 0,95. - c10013, .4 554602013* , - . 1 13/12