KS C IEC 62321-2009 Electrotechnical products-Determination of levels of six regulated substances(lead mercury cadmium hexavalent chromium polybrominated biphenyls polybrominated d.pdf

1、 KSKSKSKSKSKSKSK KSKSKS KSKSK KSKS KSK KS KS C IEC 62321 6 ( , , , 6 ,PBBs, PBDEs) KS C IEC 62321:2009 2009 9 14 http:/www.kats.go.krKS C IEC 62321:2009 : ( ) ( ) ( )MPT ( ) : (http:/www.standard.go.kr) ： ：2005 11 18 ：2009 9 14 2009-0548 ： ： ( 02-509-7300) (http:/www.kats.go.kr). 10 5 , . KS C IEC 6

2、2321:2009 i . 1 1 1 2 2 3 , . 2 3.1 2 3.2 . 3 4 5 4.1 . 5 4.2 . 6 4.3 . 6 4.4 . 7 4.5 (LOD) (LOQ) 8 4.6 8 4.7 8 5 9 5.1 . 9 5.2 , 9 5.3 . 10 6 X (XRF) . 11 6.1 . 11 6.2 , 14 6.3 . 14 6.4 14 6.5 . 15 6.6 . 18 6.7 . 19 6.8 . 20 6.9 21 7 CV-AAS, AFS, ICP-OES/MS , , 22 7.1 . 22 7.2 , 23 7.3 . 24 7.4 25

3、7.5 27 7.6 28 8 ICP-OES/MS AAS , 29 8.1 . 29 8.2 , 30 KS C IEC 62321:2009 ii 8.3 . 31 8.4 32 8.5 35 8.6 36 9 ICP-OES/MS AAS . 36 9.1 . 36 9.2 , 37 9.3 . 38 9.4 39 9.5 40 9.6 40 9.7 42 10 ICP-OES/MS AAS , . 42 10.1 . 42 10.2 , 43 10.3 . 44 10.4 45 10.5 47 10.6 . 50 A( ) GC-MS PBB, PBDE . 51 A.1 . 51

4、A.2 , 51 A.3 . 52 A.4 52 A.5 53 A.6 . 54 A.7 GC-MS 57 A.8 . 59 A.9 62 A.10 PBB, PBDE 62 A.11 63 A.12 . 64 B( ) 6 . 67 B.1 . 67 B.2 , 67 B.3 . 68 B.4 68 B.5 68 B.6 71 C( ) 6 . 72 C.1 . 72 C.2 , 72 C.3 . 73 C.4 74 KS C IEC 62321:2009 iii C.5 74 C.6 77 C.7 78 D( ) X (XRF) 79 D.1 . 79 D.2 . 79 D.3 80 D.

5、4 XRF IIS2 81 E( ) CV-AAS, AFS, ICP-OES ICP-MS , , . 86 E.1 . 86 E.2 87 F( ) ICP-OES, ICP-MS AAS , , . 88 F.1 (ICP-OES) . 88 F.2 (ICP-MS) 89 F.3 (AAS) . 89 G( ) ICP-OES, ICP-MS AAS , . 90 G.1 (ICP-OES) . 90 G.2 91 G.3 (ICP-MS) 91 G.4 (AAS) . 92 H( ) ICP-OES, ICP-MS AAS , . 93 H.1 93 H.2 (ICP-OES) .

6、94 H.3 95 H.4 (ICP-MS) 96 H.5 (AAS) . 96 97 KS C IEC 62321:2009 6 ( , , , 6 , PBBs, PBDEs) Electrotechnical products Determination of levels of six regulated substances(lead, mercury, cadmium, hexavalent chromium, polybrominated biphenyls, polybrominated diphenyl ethers) 2008 1 IEC 62321, Electrotec

7、hnical products Determination of levels of six regulated substances(lead, mercury, cadmium, hexavalent chromium, polybrominated biphenyls, polybrominated diphenyl ethers) , . 1 (Pb), (Hg), (Cd), 6 Cr(Vl) (PBB) (PBDEs) . . . 1 IEC (Publicly Available Specification：PAS) .1) . . “ (unit)” “” “ (homogen

8、ous material)” 2 IEC Technical Specification IEC/TS 6247612) . 1) IEC 62596 2) . KS C IEC 62321:2009 2 2 . . ( ) . KS I ISO 5961, KS M ISO 3696, KS Q ISO/IEC 17025, ISO/IEC Guide 98:1995, Guide to the expression of uncertainty in measurement (GUM) 3 , 3.1 . 3.1.1 (analyte) 3.1.2 (calibrant) ( ) 3.1.

9、3 (calibration blank) , 3.1.4 (Certified Reference Material： CRM) , , , . KS A ISO Guide 3023.1.5 (digestate) 3.1.6 (electronic assembly) 1 , . KS C IEC 60730 1： 2002, H.2.5.93 KS C IEC 62321:2009 3 3.1.7 (electronic components) , . , , , , , , (relays) KS C IEC/PAS 62239： 200843.1.8 (electronics) ,

10、 3.1.9 (Field Replaceable Unit： FRU) ( ) , , . IEC Guide 114： 2005, 3.753.1.10 (matrix) 3.1.11 (Performance-based Measurement System： PBMS) , , . , , , . 3.1.12 (reference material) , KS A ISO Guide 30, modified 3.2 AAS ABS AFS ASTM BCR BL KS C IEC 62321:2009 4 BSA N,O- BSTFA N,O- CCC CCFL CFR CRM C

11、V-AAS CV-AFS DBOFB 4,4- DIN Deutsches Institut fr Normung DMDCS EC EDXRF X ( ) EI EN EPA EVAC Ethylene vinyl acetate FEP - FP FRU GC GC-MS - GLP HPLC-UV - ICP-MS ICP-OES IS IIS IUPAC (International Union of Pure and Applied Chemistry) JIS LN LOD LOQ MDL NIST (National Institute of Standards and Tech

12、nology) NMIJ (National Metrology Institute of Japan) OctaBB OctaBDE OL PAS PBB PBDE PBMS PC PE PE-HD PFA KS C IEC 62321:2009 5 PS-HI PTFE PTV PVC PWB QA QC RH RSD SIM ( ) SOP SRM TFM US (United States) WC WDXRF X ( ) XRF X ( ) 4 4.1 . , . . / : . . . , KS C IEC 62321:2009 6 ( , KS Q ISO 17025) . 4.2

13、 “ (sample)” . , . . . . . . , (FRU) . . . (PAS： IEC 62596) . 4.3 1 . 1 , ( , ) ? . ? ? (PWB/ ) KS C IEC 62321:2009 7 . ( ) ( ). . ( , , ) , ( ) . . 5. . 6. XRF ( X X ) . . XRF , . , . 1 7. 10. A, B C . . 1 (PWB/) (5. ) ashing ( ) PBB/PBDE GC/MS( A ) GC/MS( A ) Cr(VI) / ( C ) - / ( B ) / ( C ) Hg CV

14、-AAS, CV-AFS, ICP-OES, ICP-MS(7. ) Pb/Cd ICP-OES, ICP-MS, AAS(8. ) ICP-OES, ICP-MS, AAS(9. ) ICP-OES, ICP-MS, AAS(10. ) , . 4.4 . . ( ) ( ), ( ) KS C IEC 62321:2009 8 . 4.5 (LOD) (LOQ) , . , (： ) . , . (： ) . 6 3 5 . . IUPAC 6 3 , (US EPA) (Students t) (6 99 % t 3.36) . . 10 % (2 10) . 4.6 . . 1) ,

15、2) 3) ID(： ) 4) , 5) , ( ) 6) (LOD) (LOQ) 7) mg/kg 8) ( ) . (QC) (： , ) . “ / XXX”( ) 4.2 4.6 . 4.7 , (PBMS) KS C IEC 62321:2009 9 . . . 5 5.1 5.1.1 , . . . , . . , . 5.1.2 (： ), , . . . (WC) , , . . . . . / / , . , . 5.2 , . a) 4 mm 1 mm b) 25 m (WC) , 6 ( 1 mm ). 1 mm / . c) (Freezer)： / , , , KS C IEC 62321:2009 10 d) (： ) e) ： 0.000 1 g . f) ( ) g) h) , i) j) (LN2) . . . k) l) m) n) (LN2 ) 5.3 5.3.1 . , . a) ： 40 mm40 mm 5.2 h). b) ： 40 mm40 mm 5.2 h). c) ： / 5.2 h) 5 mm5 mm . 5.2 h). 5.3.2