KS D ISO 10111-2012 Metallic and other inorganic coatings－Measurement of mass per unit area－Review of gravimetric and chemical analysis methods《金属和其他无机覆层 单位面积质量的测量 重量法和化学分析方法概述》.pdf

1、 KSKSKSKSKSKSKSK KSKSKS KSKSK KSKS KSK KS KS D ISO 10111 KS D ISO 10111:2012 2012 11 10 http:/www.kats.go.krKS D ISO 10111:2012 : ( ) ( ) () NS () ( ) : (http:/www.standard.go.kr) ： ：2002 11 28 ：2012 11 10 2012-0601 ： ： ( 02-509-7274) (http:/www.kats.go.kr). 10 5 , . KS D ISO 10111:2012 i ii 1 1 1.1

2、 .1 1.2 .1 1.3 1 1.4 2 2 2 3 .2 4 2 5 .3 6 .3 6.1 .3 6.2 .3 6.3 3 6.4 .3 7 3 7.1 3 7.2 .3 7.3 4 8 .4 9 .4 9.1 4 9.2 .4 9.3 .4 10 5 10.1 5 10.2 .5 A( ) 6 12 KS D ISO 10111:2012 ii 2000 1 ISO 10111, Metallic and other inorganic coatings Measurement of mass per unit area Review of gravimetric and chemi

3、cal analysis methods . KS D ISO 10111:2012 Metallic and other inorganic coatings Measurement of mass per unit area Review of gravimetric and chemical analysis methods . . , . 1 1.1 , , , . . KS D ISO 3892 , . 1.2 A , . 1.3 - . , ( - ) . . KS D ISO 10111:2012 2 . 1.4 . . 2.5 mg/cm2 1 cm2 , 0.1 mg/cm2

4、 2.5 mg 25 cm2 . . . . ( ) . 2 . . ( ) . KS D ISO 2079, KS D ISO 3892, KS D ISO 8407, ISO 2080, Metallic and other inorganic coatings Surface treatment, metallic and other inorganic coatings Vocabulary ISO 2081, Metallic and other inorganic coatings Electroplated coatings of zinc with supplementary

5、treatments on iron or steel ISO 2082, Metallic coatings Electroplated coatings of cadmium on iron or steel ISO 2093, Electroplated coatings of tin Specification and test methods ISO 2106, Anodizing of aluminium and its alloys Determination of mass per unit area(surface density) of anodic oxidation c

6、oatings Gravimetric method ISO 4522 1, Metallic coatings Test methods for electrodeposited silver and silver alloy coatings Part 1：Determination of coating thickness ISO 4524 1, Metallic coatings Test methods for electrodeposited gold and gold alloy coatings Part 1：Determination of coating thickness

7、 ISO 7587, Electroplated coatings of tin-lead alloys Specification and test methods 3 KS D ISO 2079 ISO 2080 . 4 . a) . b) . c) . KS D ISO 10111:2012 3 , , . 5 A.1(8. 9. ) . 6 6.1 (8. 9. ). 6.2 . . 6.3 , , . 100 mm2 . . 6.4 , . 1.5 mg/cm2( 0.9 m) , 120 3 . ( ) , . 7 7.1 , . 5 % (KS D ISO 3892 ). 7.2

8、 . . (rule) . KS D ISO 10111:2012 4 . . 7.3 . , , . . ( ) , ( ) . . s2rml= l ： m ： r ： s ： 8 . , . - . 9 9.1 , . 9.2 , , ( ) . 0.1 mg . . 9.3 9.3.1 . a) (9.3.2 ) ( A ). b) ( A ) (9.3.3 ). KS D ISO 10111:2012 5 9.3.2.2 9.3.3.2 . 9.3.2 9.3.2.1 ( , , ) , . ( A ) , . 9.3.2.2 , . . 9.3.3 9.3.3.1 ( A ). (

9、 , , ) , . 9.3.3.2 , . . 10 10.1 A mg/cm2 . Am=A m ： (mg) A ： (cm2) 10.2 d m . cA10=d A： (mg/cm2) C： (g/cm3) . 19.3 g/cm3 17 g/cm3 . ( 1 ). , . KS D ISO 10111:2012 6 A ( ) A.1 . 9.3.2 9.3.3 . . . A.1 ( .) a b 1) 20 80 2) 1 90 ( .) . . 3 . . . 1) 1 L (SbCl3) 200 g 2) 1 L (SnCl2) 100 g (H2O) 1 2 1) 2)

10、 (1 4 ). 38 , . 85 % (H3PO4) 35 mL 3 (CrO3) 20 g/L ISO 2106 3, 4 , , . HAE 3 300 g/L5 , , 3.9 mg/dm2 . . 3 500 g/L 50 g/L . . (NH4NO3) 300 g/LISO 2082 10.1.2 6 . KS D ISO 10111:2012 7 A.1 ( ) a b 1 L (Sb2O3) 200 g 7 . 800 mL 20 g 200 mL ISO 2082 10.1.2 7, 8 . (NH4)2S2O8 5 % 10 % (NH4OH) 7 . 1) (NaNO

11、3) 2) 1： HNO3 1 9 (326354) NaNO2 2 , , 2) 30 . ( .) 1) 98 % 2 % 2) (6570) % 1： 1 KS D ISO 3892 4.5.2 10 1) (370500) 25 ( ). 2) 1530 . ( .) 1： (6570) % 1 KS D ISO 3892 4.5.1 10 3 1 . ( .) 1) 1 % 500 mL 2) 10 1) 10 50 mL . 2)( .) Cr(III) Cr(VI) . ()=445 nm . 1) (KNO3) 100 g1 L (KCl) 100 g 2) (NaCl) 10

12、0 g 1 L 11 1) , . 2) , . 1) 100 g 1 L 100 g 2) 100 g 1 L 12 1) , . 2) . (NaCN) 50 g/L (KCN) 5 g/L KS D ISO 3892 4.4 15 A/dm2 . 12 g/L 13 20 mA/cm2 . KS D ISO 10111:2012 8 A.1 ( ) a b 1) 200 g (Na2S)750 mL , (S) 20 g 1 L . 2) 20 % 14 1) . , 2) . 3 500 g/L 50 g/L15 13 1.2 m/min . 1： 4 . . . , , Fe-Ni-

13、Co (1 3) 1 ISO 4524 1 . . . . . - 90 % (H3PO4) 16 (180190) . 2.5 m 10 . 3 500 g/L 50 g/L . . 1) , 2) 1 1 3) 10 % 3 17 13 . CrO3 . 2) . 1) 65 g 10 g 100 g 1 L2) 65 g 20 g 100 g 1 L16 (75 85) 1) 2) . 7 m 30 . . 1 4 14 . . . . KS D ISO 10111:2012 9 A.1 ( ) a b ( ) 1 (65 70) % 1 KS D ISO 3892 1 . ( ) 65

14、 % 35 % KS D ISO 3892 18 75 5 15 . 4 % 12 % Na4EDTAc 9 % 75 % 18 70 5 . 2530 % (NH4)2CrO7 20 g KS D ISO 3892 3 5 . 20 g/L 19 . . 1) 4 % 12 % Na4EDTA 9 % 75 % 2) 5 % 3 95 % 18 1) 70 5 . 2) 70 15 . ( , ) 3 50 g/L KS D ISO 3892 20 (755) 15 , , . ( ) 100 g/LNa4EDTA 90 g/L 4 g/L KS D ISO 3892 (755) 5 . (

15、 ) 180 g/L 90 g/L 20 10 , . ( ) 1) 2.2 % 27.4 % 70.4 % 2) 5 % 3 95 % 18 1) 2) 25 5 . 19 1 21 80 . 1) 19 12) ISO 4522 1 22 (6070) , . KS D ISO 10111:2012 10 A.1 ( ) a b 90 g 15 g 1 000 mL ISO 4522 1 (24) V . 30 g/L 21 (34) V . 30 g/L ISO 4522 1 4 V . 1) 100 g/L 2) 1 3 23 (7788) 12 A/dm2 , 515 12 , 12

16、 . 200 g/L 23 (terne) , , . ISO 2093 22, 24 95 . 40 % . . 120 g/ 1 L 21 1530 . 20 g / 1 L ISO 2093 25 1 . - 10 mL (urea) 15 g 10 mL( 10) 80 mL 26 0.1 m/min . 0.5 mgdm-2min-1 . - 6 % 50 mL 40 % (HBF4) 50mL ISO 7587 . - 20 g/L 1 000 mL ISO 7587 . - 27 (180200) . - 20 g/L 30 g/L 27 . . . KS D ISO 10111:2012 11 A.1 ( ) a b 1) 1 L 20 g 32 g 2) 100 mL 1) 5 mL 100 mL 28 2) . , 38 . 20 g 100 g 50 g KS D ISO 8407 . 38 . 20 g 800 mL 200 mL ISO 2081 8 . 500 mL 3.2 g 2 g 1 L 29 , . 1： 1 28 1： 1