1、 KSKSKSKSKSKSKSK KSKSKS KSKSK KSKS KSK KS KS I ISO 10849 ( )KS I ISO 10849:2008 2008 9 2 http:/www.kats.go.krKS I ISO 10849:2008 : ( ) ( ) ( ) : (http:/www.standard.go.kr) : :1998 12 24 :2008 9 2 2008-0471 : : ( 02-509-7266) (http:/www.kats.go.kr). 10 5 , . KS I ISO 10849:2008 ( ) Stationary source
2、emissions Determination of the mass concentration of nitrogen oxides Performance characteristics of automated measuring systems 1996 1 ISO 10849, Stationary source emissions Determination of the mass concentration of nitrogen oxides Performance characteristics of automated measuring systems , . 1 .
3、. NO NOX(NONO2) . (N2O) . . , . (differential) 1 . 2 . . KS M 9403, KS M ISO 7996, ( ) KS M ISO 9096, ( ) KS M ISO 9169, KS I ISO 10849:2008 2 KS M ISO 10396, 3 . 3.1 (AMS) 3.2 3.3 (AMS) 3.4 , 3.5 1 3.6 , . 2 KS M ISO 11564 (NEDA) . ( , , ) . 3.7 sA . sA 1 ( A ). sC: sD: sX: 3 sA . KS I ISO 10849:20
4、08 3 . . . sA . . 4 sA . , . sA . . 5 sC sD , . sC sA sA . sC sA , sA . 3.8 3.9 mg/m3 6 ppm(10 6), mg NO/m3, mg NO2/m3 . NO: 1 ppm(V/V ) 1.34 mg/m3 NO2: 1 ppm(V/V ) 2.05 mg/m3 (273 K, 101.3 kPa) . . mg NO2/m3 . 3.10 3.11 3.12 , , , (KS M 9403) KS I ISO 10849:2008 4 7 7 . 3.13 . 4 . . . (in-situ) . .
5、 , (NO NO2) , . NO . . NO . NO2 . . . 5 5.1 5.1.1 KS M ISO 10396 . 1 a) NO . 5.2 . NO2 ( ) NOX . . NO2 , NO2 NO2 . NO2 1 b) . . , . KS I ISO 10849:2008 5 KS M ISO 10396 . KS M ISO 9096 . , . 5.1.2.15.1.2.8 , (: HCI, SO3 NO2 ). 1 9 2 10 NO 3 11 4 ( ) 12 5 ( ) 6 13 7 14 8 15 16 NO/NOX 1 5.1.2 5.1.2.1
6、a) NO b) NO/NOX KS I ISO 10849:2008 6 . 220 (PTFE) . 250 NO:NO2 . . NO: NO2 . 5.1.2.2 10 m . . 5.1.2.3 PTFE . ( ) 15 K . 4 mm (48 mm ). 5.1.2.4 . . 25 . . NO2 . NO2 . NO2 . 5.1.2.5 ( ) . 30500 L/h . 5.1.2.6 2 , , PTFE 1 2 m . 5.1.2.7 , . 5.1.2.8 NO2/NO NO NO2 ( ). , . KS I ISO 10849:2008 7 ( ) . , .
7、 . (NO NO2) , NO . NO2 NOX NO . 95 % , NO2 . KS M ISO 7996 , NO . 2 . NO , . NO NO2 . NO: NO2 , (NO NO2) . 95 % , . NO ( ) . NO (NO NO2) . N2O NO . N2O5 NO . 1 NO 2 3 4 5 ( ) 6 7 2 NO2/NO 5.1.3 . . . , . . (01 mg/m3, 5 mg/m3, 10 mg/m3 25 mg/m3) . KS I ISO 10849:2008 8 5.2 . 6. . 5.2.1 KS M ISO 7996
8、. NO (O3) NO2 , NO2 . , NO2 5903 000 nm . NO . 3 . . NO2/NO , NO, NOX NO2 . 1020 000 mg/m3 . 0200 mg/m3 . (CO2) . CO2 H2O . CO2 . 1 19 2 10 3 11 4 NO2/NO 12 5 13 6 14 7 15 8 3 KS I ISO 10849:2008 9 5.2.2 (NDIR) . . , vmax 1 876 cm 1( 5.3 m) NO . 4 NDIR . 2 , , ( ) . NO NO . NO . . 0200 mg/m3 , . . 1
9、 5 2 6 3 7 4 8 4 NDIR 5.2.3 (NDUV) NDUV . . NO . 5 . 226 nm NO . NO . 2 KS I ISO 10849:2008 10 . , . NO . 2 . , . 226 nm 23 nm . . NO NO . 2 4 . NO . . 0200 mg/m3 . UV SO2 . . NO2 . 1 7 2 8 3 NO 9 4 10 5 11 6 12 5 NDUV 5.2.4 ( ) . ( ) . . KS I ISO 10849:2008 11 5.2.4.1 . . , , . 5.2.4.1.1 5.2.4.1.2
10、2 . 5.2.4.1.1 6 . 218233 nm . NO SO2 . . , , 2 . 218233 nm . , . NO , NO . , 0150 mg/m3 . (SO2) . KS I ISO 10849:2008 12 1 13 1)2 14 1)3 15 4 16 5 17 6 18 7 19 ( ) 8 1)20 9 21 10 22 ( )1)11 23 12 24 1) 6 ( ) 5.2.4.1.2 UV . 2002 000 nm . . , . NO2 . NO NO2 0150 mg/m3 . 5.2.4.2 1) . KS I ISO 10849:200
11、8 13 . . 7 . ( 2 ) . ( ) . . 350 ( ) . 1 6 2 7 3 8 4 9 5 7 ( ) 6 A 1 . KS I ISO 10849:2008 14 1 a ( A ) ( sA) ( ) 2 %b 4 %b, c 200 s 5 %b, dA.4.2.1.1 A.4.2.1.2 A.4.2.1.3 A.4.2.2.2 a NO/NO2 . b c CO2, CO, SO2, H2O NH3 . ( ) HCl HF . , ( N2O) . d3.7 2 1 . . sA , , . 8 B.1 . 2 1 . 9 ( , A.4.2.2.2 ) . . 1 10 % ( 95 % ). . 10 1 , NDIR NDUV ( ) . 1 2 . 2 aNO2 mg/m3
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