KS I ISO 12039-2006 Stationary source emissions-Determination of carbon monoxide carbon dioxide and oxygen-Performance characteristics and calibration of automated measuring system.pdf

1、KSKSKSKS SKSKSKS KSKSKS SKSKS KSKS SKS KS 2006 11 28 http:/www.kats.go.krKS I ISO 12039 , KS I ISO 12039： 2006 (2011 ) I ISO 12039： 2006 : ( ) ( ) KIST ( ) : (http:/www.standard.go.kr) ： ：2001 12 6 ： 2 006 11 28 ：2011 12 26 2011-0623 ： ： ( 02- 509-7270) (http:/www.kats.go.kr). 10 5 , . ICS 13.040.40

2、 KS I ISO , 12039： 2006(2011 ) Stationary source emissions Determination of carbon monoxide, carbon dioxide and oxygen Performance characteristics and calibration of automated measuring systems 2001 1 ISO 12039 Stationary source emissions Determination of carbon monoxide, carbon dioxide and oxygen P

3、erformance characteristics and calibration of automated measuring systems , . 1. CO2, CO O2 , . . . (paramagnetism)(O2) (magnetic wind)(O2) (differential pressure)(Quinke)(O2) (magnetodynamics) (zirconium oxide)(O2) (electrochemical cell)(O2 CO) (infrared absorption)(CO CO2) . . 2. . . KS M 9403 KS

4、M ISO 6145 2 2 ： KS M ISO 10396 KS M ISO 10849 ( ) 3. . 3.1 (air point) 3.2 (AMS ： automated measuring system) CO, CO2, O2 , . I ISO 12039： 2006 2 3.3 (analyser) AMS . 3.4 (calibration gas) AMS , . AMS . 3.4.1 (span gas) . 3.4.2 (zero gas) (zero point) . 3.5 (calibration) AMS , 2 . . 3.6 (calibratio

5、n interval) AMS , . 3.7 (comparative measurements) AMS , . , . 3.8 (comparative method) CO, CO2, O2 . (AMS) . 3.9 (duct) . 3.10 (mass concentration) , . 1. mg/m3 . 2. ppm mg/m3 . (mg/m3) (ppm)4.22rMT2733.101p Mr： T： (K) p： (Pa) 3.11 (lag time) , 10 % 3.12 . 3.13 (live zero) 0 . , . 420 mA 0 10 % 0 %

6、 , 3.2 mA 5 mA . 3.14 (period of unattended operation) 95 % 7 . 3.15 (response time) 90 % / . I ISO 12039： 2006 3 3.16 rise time： (fall time) 10 90 %(90 10 %) 10 % . 3.17 AMS(verified AMS) AMS 4. sA . AMS , . s AMS CO, CO2 O2 sc sD sx0 5. KS M ISO 10396 (probe) , . . KS M ISO 10396 . CO2, CO, O2 , .

7、 (dry basis) , . , (wet basis) . 6. (sampling) KS M ISO 10396 . 7. 7.1 7.2 7.5 . 7.2.4 . 7.2 (CO/CO2) 7.2.1 (NDIR) . . a) ( ： parallel beam method) 2 . (reference cell) , (sample cell) . . b) (single beam method) 3 . (interference filter technique)： , , . I ISO 12039： 2006 4 . (gas filter correlatio

8、n technique)： . . , (crosssensitivity effects) . . (single beam single wavelength technique)： . , / , . c) (FTIR： Fourier transform infrared spectroscopy) . , . 7.2.2 CO2 20 % CO2 . CO 6 mg/m3(510 6 ) 62 500 mg/m3( 5 % ) . . CO2 CO , . 7.2.3 () . , , , , . 7.2.4 (performance characteristics) 8. . 7.

9、3 (paramagnetic method)(O2) 7.3.1 . . . . a) . (zero) . . b) . . , . , (thermal conductivity techniques) . c) . ( N2) . . 7.3.2 O2 25 % . 100 %( ) . 7.3.3 . NO NO2 . . A.4.2.3 . 7.3.4 8. . 7.4 (O2) I ISO 12039： 2006 5 7.4.1 (yttria stabilized zirconium oxide cell) . 600 , . . , . . . . . Nernst . E2

10、1ln4 ppFRT E： R： T： F： (Faraday) p1： (reference gas) p2： (process gas) Nernst . 7.4.2 O2 25 % . 7.4.3 , . 7.4.4 8. . 7.5 (O2 CO) 7.5.1 O2 CO . . , (counter electrode) . (emf) . . 7.5.2 25 % . 20 4 000 mg/m3 CO . 7.5.3 . , , , SO2, , CO2, H2 . 7.5.4 8. . I ISO 12039： 2006 6 8. (performance characteri

11、stics) A.1 . CO2, CO . A , A.1 . . sA , . A.4.2.1 95 % . / ( ) . A.1 10 % ( 95 % ). . 9. 9.1 / (instrument/supplier report) . a) b) c) d) e) A.4 A.1 f) AMS 9.2 / (commissioning/verification test report) . a) b) , c) d) e) f) g) h) AMS i) j) , , k) , l) m) n) I ISO 12039： 2006 7 A() A.1 CO, CO2 O2 (A

12、MS) . (calibration) , (checking) (setting) A.4.1 . . , ( , ) . ( , ) . . AMS AMS . A.2 , . . . ( , ) ( AMS .) . AMS sA AMS . AMS AMS (duct) . AMS ( , AMS , 70 % ) , AMS . A.1 . . . A.3 A.3.1 (zero gas) . (5.0 .) . ZrO2 “ (air point)” . ZrO2 0 mV ( 21 % O2 ). 0.4 % . . A.3.2 , . . . I ISO 12039： 2006

13、 8 A.4 A.4.1 A.4.1.1 ( , ). , ( , 1 ). ( ) . . A.4.1.2 . (A.3.1) . 70 80 % (A.3.2) . (non-extractive point monitor)(path monitors) , AMS . (span) . A.4.1.3 AMS A.4.1.2 , AMS . (probe) ( ). . AMS , . , , . A.4.1.4 , (linear analytical function) , ( 20 %, 40 %, 60 %, 80 %, 90 %). KS M ISO 6145 2 . 10 . . A.4.2 A.4.2.1 AMS . (A.3.1) (A.3.2) A.4.1.3 , . . a) b) (chamber) , . . . (beam) , . . I ISO 12039： 2006 9 . (furnace) . . A.4.2.2 (live zero) 10 % . A.4.2.1 AMS (A.3.1) , 5 30 . . 95 % x . x 0x 2sx0 0x ： sx0： A.4.2.3 A.4.