KS I ISO 16000-5-2009 Indoor air－Part 5：Sampling strategy for volatile organic compounds(VOCs)《室内空气 第5部分 挥发性有机化合物(VOCs)取样法》.pdf

1、 KSKSKSKSKSKSKSK KSKSKS KSKSK KSKS KSK KS KS I ISO 16000 5 5： (VOCs) KS I ISO 16000 5:2009 2009 12 18 http:/www.kats.go.krKS I ISO 16000 5:2009 : ( ) ( ) () ( ) : (ISO/TC146) () ( ) () : (http:/www.standard.go.kr) ： ：2006 11 28 ：2009 12 18 2009-0830 ： ： (ISO/TC146) ( 02-509-7266) (http:/www.kats.go.

2、kr). 10 5 , . KS I ISO 16000 5:2009 5： (VOCs) Indoor air Part 5： Sampling strategy for volatile organic compounds(VOCs) 2007 1 ISO 16000 5, Indoor air Part 5： Sampling strategy for volatile organic compounds(VOCs) , . 1 . , , . . KS I ISO 16000 1 . 2 . . ( ) . KS I ISO 16000 1, 1： KS I ISO 16000 6,

3、6： Tenax TA , MS/FID KS I ISO 16000 8, 8： KS I ISO 16017 1, , / / KS I ISO 16017 2, , / / 2： 3 (VOCs) . , . (WHO)2 KS I ISO 16000 5:2009 2 ( 1 ). 1 2 a kPa a VVOC 0 50 100 15 , , , VOC 50 100 240 260 10 2Tenax 1), , SVOC 240 260 380 400 10 2 10 8PUFb XAD 2 1) POM 380 a (WHO) . bPolyurethane foam( )

4、 . . 1 , . 3. 2 TVOC(total volatile organic compounds) KS I ISO 16000 6 . 4 VOCs . . , , . , , . VOCs . VOCs . . . VOC , . VOCs . VOCs . A VOCs VOCs . VOC 4 . 1) 1 . . KS . , . KS I ISO 16000 5:2009 3 . , , , , , , , , , , , , . VOC VOC . “ ” VOCs( ) . KS I ISO 1600035 KS I ISO 16000 46 . 5 5.1 VOC

5、s VOCs . VOC KS I ISO 16017 1 KS I ISO 16017 2 . VOCs (active sampling) KS I ISO 16000 6 ( B ). 5.2 , 1 . VOCs ( ) VOCs . VOCs (KS I ISO 16017 1 ). 5.3 , . ( ) ( ) . KS I ISO 16017 2 . 6 6.1 . , . 6.2 KS I ISO 16000 5:2009 4 6.2.1 . VOCs VOC . , . , . 6.2.2 6.2.2.1 . , , , , , . VOC , . VOC . 6.2.2.

6、2 ( ) 15 , 8 ( .) . . KS I ISO 16000 6 . , 5 . 1 . 6.2.2.3 (VAC) , 3 . (KS I ISO 16000 8 ). ( , ) 1 . . (KS I ISO 16000 8 ). , . VOC . VOC . (comfort zone) , VOC . KS I ISO 16000 5:2009 5 6.2.3 (exposure studies) . , 24 , . VO , . , . . . . KS I ISO 16000 1： 2004 D . 6.2.4 VOC . , . VOCs , . VOCs .

7、KS A ISO 773019 . KS A ISO 724320, KS A ISO 793321, ISO/TR 1107922 . 6.2.5 VOCs , . , , . . . ( ) ( ) (KS I ISO 16000 1023 24 ). . (KS I ISO 16000 6). ( ) , ( 2 ). 6.2.6 . . . , VOC 2 12 . KS I ISO 16000 5:2009 6 6.3 . . , , . , ( ) . 2 VOC . VOC , ( , ) ( , ) . , , . 6.4 , ( , ) . . , ( ) . VOC , .

8、 , . 2 VOCs , . X Y PVC , , , , , , , , , , KS I ISO 16000 5:2009 7 2 ( ) VOCs , X Y , , coalescing , film forming reaction products, film degradation products X Y , , VOCs VOCs X Y (桐油 ), , , co-solvents , , , , , VOCs KS I ISO 16000 5:2009 8 6.5 . VOC . . , , , , . . . . 1 2 m , 1 2 m . , 1 1 . (

9、) . 2 m( ) . . HVAC , . 6.6 6.6.1 VOCs TVOC . , . VOCs GC . , . , TVOC . VOCs TVOC . , , VOCs VOCs GC . 6.6.2 . , . KS I ISO 16000 229 D . ( ) . , . , . 6.7 . . . VOCKS I ISO 16000 5:2009 9 . ( ) ? , ? VOCs ? ? ? ( ) ? ? KS I ISO 16000 5:2009 10 A ( ) A.1 KS I ISO 16000 6 CAS number a kPa(25 ) Aroma

10、tic hydrocarbons Benzene 71-43-2 80 10.1 Toluene 108-88-3 110 2.9 Ethylbenzene 100-41-4 136 0.93 m/p-Xylene 108-38-3/106-42-3 139/138 0.67 0.87 o-Xylene 95-47-6 144 0.7 n-Propylbenzene 103-65-1 159 0.3 1,2,4-Trimethyl benzene 1,3,5-Trimethyl benzene 95-63-6 108-67-8 169 165 0.15 0.2 2-Ethyltoluene 6

11、11-14-3 165 0.4 Styrene 100-42-5 145 0.88 Naphthalene 91-20-3 218 0.01 4-Phenylcyclohexene 31017-40-0 251 Aliphatic Hydrocarbons n-C6 n-C16n-Hexane 110-54-3 69 20.1 n-Heptane 142-82-5 98 4.7 n-Octane n-Nonane 111-65-9 111-84-2 126 151 1.4 0.5 n-Decane n-Undecane 124-18-5 1120-21-4 174 196 0.13 0.14

12、n-Dodecane 112-40-3 216 0.04 n-Tridecane n-Tetradecane 629-50-5 629-59-4 235 253 0.003 4 0.001 3 n-Pentadecane 629-62-9 270 n-Hexadecane 2-Methylpentane 544-76-3 107-83-5 287 60 0.000 926 16 3-Methylpentane 96-14-0 63 Ca.16 1-Octene 111-66 121 2.3271-Decene 872-05-9 170 0.2227Isobutene 115-11-7 7 25

13、7(20 )27KS I ISO 16000 5:2009 11 A.1 KS I ISO 16000 6 ( ) CAS number a kPa(25 ) Cycloalkanes Methylcyclopentane 96-37-7 18.3 Cyclohexane 110-82-7 81 12.7(20 ) Methlcyclohexane 108-87-2 101 5.73 Terpenes 3-Carene 13466-78-9 167 -Pinene 80-56-8 156 527-Pinene 18172-67-3 164 5 Limonene 138-86-3 170 0.1

14、9 Alcohols 2-Propanol 67-63-0 82 32(20 )271-Butanol 71-36-3 118 4.4272-Ethyl-1-hexanol 104-76-7 182 0.11(20 )27Benzyl alcohol 100-51-6 205 0.3(20 )27Glycols/Glycol ethers 2-Methoxyethanol 109-86-4 124 125 0.8 2-Ethoxyethanol 110-80-5 135 0.51 2-Butoxyethanol 111-76-2 171 0.1 1-Methoxy-2-propanol 107

15、98-2 118 1.2(20 ) 2-Butoxyethoxyethanol 112-34-5 231 0.003(20 ) 2-Phenoxyethanol 122-99-6 245 0.001(20 ) Aldehydes Butanal 123-72-8 76 12.2(20 ) Pentanal 110-62-3 103 3.4(20 ) Hexanal 66-25-1 129 3.5(20 ) Nonanal 124-19-6 190 192 0.048 Benzaldehyde 100-52-7 179 0.13(20 ) Ketones Methylethylketone 7

16、8-93-3 80 10.3 Methylisobutylketone 108-10-1 117 0.8 Cyclohexanone 108-94-1 156 0.45 Acetophenone 98-86-2 202 0.13(15 ) Halocarbons Trichloroethene 79-01-6 87 2.7 Tetrachloroethene 127-18-4 121 1.87 1,1,1-Trichloroethane 71-55-6 74 2.7 1,4-Dichlorobenzene 106-46-7 173 1.2 KS I ISO 16000 5:2009 12 A.

17、1 KS I ISO 16000 6 ( ) CAS number a kPa(25 ) Esters Ethyl acetate 141-78-6 77 9.7 Butyl acetate 123-86-4 126 1.9 Isopropyl acetate 108-21-4 85 6.3 Methoxypropyl acetate 108-65-6 145 146 2-Ethoxyethyl acetate 111-15-9 156 0.16 Dimethyl phthalate 131-11-3 284 0.001 3282,2,4-Trimethyl-1,3- pentanediol monoisobutyrate 25265-77-4 244 2,2,4-Trimethyl-1,3- pentanediol diisobutyrate 6846-50-0 280 Other 2-Pentylfuran 3777-69-3 120 THF(Tetrahydrofuran) 109-99-9 67 19.3(20 ) a . KS I ISO 16000 5:2009 13 B ( ) .