KS I ISO 22478-2007 Water quality-Determination of certain explosives and related compounds-Method using high-performance liquid chromatography (HPLC) with UV detection《水质 某炸药及其相关化.pdf

1、 KSKSKSKS KSKSKSK KSKSKS KSKSK KSKS KSK KS KS I ISO 22478 (HPLC) KS I ISO 22478 ：2007 (2012 ) 2007 12 7 http:/www.kats.go.krKS I ISO 22478：2007 : ( ) ( ) ( ) () ( ) () : (http:/www.standard.go.kr) ： ：2007 12 7 ：2012 12 27 20120787 ： ： (ISO/TC147) ( 02-509-7270) (http:/www.kats.go.kr). 10 5 , . KS I

2、ISO 22478：2007 .1 1 .1 2 .1 3 2 4 4 4.1 .4 4.2 .4 4.3 .4 4.4 .5 4.5 .5 4.6 .5 (Hexogen) 5 5 6 6 7 .7 8 .7 8.1 .8 (conditioning) 8.2 8 8.3 .8 (HPLC) 9 9 9.1 .9 9.2 .10 9.3 10 9.4 11 10 12 10.1 .12 10.2 12 11 .12 12 .13 A() HPLC 14 B() 1 .20 C() (Tetryl)(CE) .23 D() .25 i KS I ISO 22478：2007 (2012 ) (

3、HPLC) Water qualityDetermination of certain explosives and related compoundsMethod using high-performance liquid chromatography (HPLC) with UV detection 2006 1 ISO 22478, Water qualityDetermination of certain explosives and related compoundsMethod using high-performance liquid chromatography (HPLC)

4、with UV detection , . . . . . 1 , , (nitrotoluene), (nitroamine), (nitrate ester) 1 ( ) . (nitroaromatic) (nitramine) 0.10.5 g/L( 0.05 g/L .) . (0.5 g/L ). , . 2 . . ( ) . KS I ISO 22478：2007 KS M ISO 3696, KS M ISO 56671, 1： KS M ISO 56672, 2： KS M ISO 56673, 3： 3 / (polystyrene/divinylbenzene-base

5、d) . , (HPLC) , (UV-PDA) . 1 (armaments) . / a CAS b g/mol A.1 A.2 A.3 A.4 2,4,6- (2,4,6-Trinitrophenol) PA (Picric acid) 88-89-1 229.1 1 2 1 a 1,3,5,7- -1,3,5,7- (1,3,5,7-Tetranitro-octahydro- 1,3,5,7-tetrazocine) HMX (Octogen) 2691-41-0 296.2 2 1 2 b 1,3,5- 1,3,5-(1,3,5-Trinitro- hexahydro-1,3,5-t

6、riazine) RDX (Hexogen) 121-82-4 222.1 3 3 4 d 2,2,4,4,6,6- (2,2,4,4,6,6- Hexanitrodiphenylamine) - (Hexyl) 131-73-7 439.2 4 19 3 c (Ethylene glycol dinitrate) EGDN 628-96-6 152.1 5 4 5e (Diethylene glycol dinitrate) DEGN 693-21-0 196.1 6 5 6f 1,3,5- (1,3,5-Trinitrobenzene) 1,3,5-TNB 99-35-4 213.1 7

7、6 7g 1,3- (1,3-Dinitrobenzene) 1,3-DNB 99-65-0 168.1 8 7 9i N-N-2,4,6- (N-Methyl-N-2,4,6- tetranitroaniline) CE (Tetryl) 479-45-8 287.2 9 8 8 h (Glycerol trinitrate) NG (Nitroglycerine) 55-63-0 227.1 10 9 10 j 2,4,6- (2,4,6-Trinitrotoluene) 2,4,6-TNT TNT 118-96-7 227.1 11 10 11k 4-2,6- (4-Amino-2,6-

8、dinitrotoluene) 4-A-2,6- DNT 19406-51-6 197.1 12 11 12l 2 KS I ISO 22478：2007 1 (armaments) .() / a CAS b g/mol A.1 A.2 A.3 A.4 2-4,6- (2-Amino-4,6-dinitrotoluene) 2-A-4,6- DNT 35572-78-2 197.1 13 12 13m 2,6- (2,6-Dinitrotoluene) 2,6-DNT 606-20-2 182.1 14 13 14n 2,4- (2,4-Dinitrotoluene) 2,4-DNT 121

9、-14-2 182.1 15 14 15o 2- (2-Nitrotoluene) 2-NT 88-72-2 137.1 16 15 17q (Pentaerythritol tetranitrate) PETN (Nitropenta) 78-11-5 316.2 17 18 16p 4-(4-Nitrotoluene) 4-NT 99-99-0 137.1 18 16 18 r 3-(3-Nitrotoluene) 3-NT 99-08-1 137.1 19 17 19 s (Diphenylamine) DPA 122-39-4 169.24 20 a , b 1 . (Octogen)

10、 (HMX) (Hexogen) (RDX) (Picric acid) (PA) (Ethylene glycol dinitrate) (EGDN) (Hexyl) (Diethylene glycol dinitrate) (DEGN) 1 3 KS I ISO 22478：2007 (Nitropenta) (PETN) (Nitroglycerine)(NG) (Tetryl)(CE) 2- (2-Nitrotoluene) 2,4- (2,4-Dinitrotoluene) 2,6- (2,6-Dinitrotoluene) 2-4,6- (2-Amino-4,6-dinitrot

11、oluene) 4-2,6- (4-Amino-2,6-dinitrotoluene)2,4,6- (2,4,6-Trinitrotoluene)(TNT)1,3- (1,3-Dinitrobenzene)1,3,5- (1,3,5-Trinitrobenzene) (Diphenylamine) (DPA)3- (3-Nitrotoluene)4- (4-Nitrotoluene) 1 () 4 4.1 , KS M ISO 56671, KS M ISO 56672, KS M ISO 56673 7. . 4.2 , , . 4.3 8.2 (mononitrotoluene) . 4

12、KS I ISO 22478：2007 4.4 , . , , . . 4.5 , , . (Tetryl)( C ) . (Tetryl) . 4.6 (Hexogen) (Hexogen) (nitroaromatic) . 5 HPLC . , HPLC . . 5.1 KS M ISO 3696 1 . . 5.2 99.996 % , , 5.3 99.996 % , 5.4 /(polystyrene /divinylbenzene) (, 900 m 2 /g ). 1 L 1 g/L (Octogen)(HMX) 85 % . 5.5 , CH 3 OH 5.6 (Aceton

13、itrile), CH 3 CN 5.7 , NaCl 5.8 (Potassium dihydrogen phosphate solution), c(KH 2 PO 4 )0.025 mol/ L(3.40 g/L) 5 KS I ISO 22478：2007 5.9 (Orthophosphoric acid), w(H 3 PO 4 )85 % 5.10 1 . . 5.11 . 100 mL 100 mg (5.5) . (Hexyl) (Octogen) (Acetonitrile)(5.6) (Hexyl) (Octogen) . 6 . ( 6 ). 5.12 (Stock s

14、olution) . 100 mL (5.11) 1 mL (5.5) . 6 . 6 . 5.13 . , 5.12 5 , / (5050 ) . 6 . , . 5.14 (Hexyl) (Picric acid) , (Potassium dihydrogen phosphate solution)(5.8) 0.025 mol/L pH (Orthophosphoric acid)(5.9) . 6 . , (perfluorinated) . 6.1 1 000 mL 6.2 6.3 0.751.5 m, (binder) 6 KS I ISO 22478：2007 6.4 (po

15、lyamide) , 0.20.45 m (pore size), HPLC 6.5 (polypropene) /(polystyrene/divinylbenzene) (5.4) 6.6 1 mL, 10 mL, 100 mL 6.7 100 mL 6.8 pH 6.9 , , 6.10 ： (tapered) 6.11 (：PTFE ), 6.12 . a) b) c) d) e) 200400 nm (PDA) f) g) ( A .) 7 . 4 (, ). 3 . 4 . . 8 7 KS I ISO 22478：2007 8.1 (conditioning) 1 000 mL

16、(6.5) /(polystyrene/divinylbenzene) (5.4) 0.2 g . (5.5) 3 mL 5 (Acetonitrile) 3 mL 10 mL . . 8.2 , (6.3) . , 1 000 mL (5.7) 5 g . 8.1 1 000 mL/hr , 1 mL (5.1) . (5.2) 10 . /(Acetonitrile) (5050 ) 2 mL 3 mL , 5 . (6.10) 0.5 mL (keeper) . 40 (150200 hPa) (6.9) 0.8 mL . (mononitrotoluene) . / (5050 ) 1

17、.0 mL . , (6.4) HPLC . 8.3 (HPLC) 8.3.1 HPLC . (drift) , , . . 8.3.2 1 (thermostatted) . , (cyanophase) ( A ) . (Hexyl) (Picric acid) , pH 3pH 4(5.14 ) . 8.3.3 200400 nm (PDA) . 8 KS I ISO 22478：2007 8.3.4 , . (5.1) 1 000 mL . , . 8.3.5 . 2 % , 10 . ( ). . . . . . (8.3.2 ) . 9 9.1 . . . . , 0.55 g/L

18、 . . a) (9.2 ) b) (9.3 ) , 1 1 , 5 . 10.1 10.2 . 2 . 9 KS I ISO 22478：2007 2 i e g 9.2 HPLC (9.4 ) . ( 5 ) , . , (y) i , y ie ( ) (x) g/L , ie . (1) . y ie m i ie b i (1) y ie： ie i ( . ： ) m i： i ( )(： L/ g) ie： i , /L b i： (y) i , (： ). . . 10 % , , . , , , . , . HPLC . 9.3 , (9.4 ). 5 (5.1) (spike). , 1 L (5.13) 1 mL . 8. (spiked) . . (y) i , y ieg ( ) , (x) g/mL , ieg , (2) , y ieg ieg . 10 KS I ISO 22478：2007 y ieg m ig ieg b ig (2) y ieg： ieg i ( . ： ) m ig： i ( , ： L/ g) ieg： i , g/L b ig： (y) i , (： ). (9.4 ), , (batch) . , A i , . , i A , A i . A i (9.4 ). 9.4 ,