KS M 0180-2009 Standard test method for halogen(F Cl Br) and sulfur content by oxidative pyrohydrolytic combustion followed by ion chromatography detection (Combustion ion chromato.pdf

1、 KSKSKSKS KSKSKSK KSKSKS KSKSK KSKS KSK KS KS M 0180 (F, Cl, Br) KS M 0180 :2009 2009 9 4 http:/www.kats.go.krKS M 0180:2009 : ( ) ( ) ( )MPT ( ) : (http:/www.standard.go.kr) ： ： 2009 9 4 20090517 ： ： ( 025097300) (http:/www.kats.go.kr). 10 5 , . KS M 0180:2009 (F, Cl, Br) Standard test method for h

2、alogen(F, Cl, Br) and sulfur content by oxidative pyrohydrolytic combustion followed by ion chromatography detection (Combustion ion chromatographyCIC) 1 . , . 1.1 10 mg/kg1 500 mg/kg / 10 mg/kg 1 500 mg/kg 1 , . 1.2 1 500 mg/kg / 1 500 mg/kg . , . 1 2 . . ( ) . , (ethylene), (propylene) (naphthas),

3、 (reformates), (HF alkylate) (gasoline), (diesel fuel), LPG, LNG, (solvents), (polymers), (rubber) , , (organic waste disposal), , (solvents) , (Set maker) (parts), (, ) , , , , KS M 0180:2009 2 KS M 0035, EN 14346, Characterization of waste-calculation of dry matter by determination of dry residue

4、or water content EN 14582, Characterization of waste-halogen and sulfur content-oxygen combustion in closed system and determination methods EN 15002, Characterization of waste-preparation of test portions from the laboratory sample EN ISO 3696, Water for analytical laboratory use-specification and

5、test methods (ISO 3696：1987) ASTM D 3120, Total sulfur by microcoulometry ASTM D 3246, Total sulfur in gases oxidative microcoulometry ASTM D 3761, Total fluorine in coal by the oxygen bomb combustion / ISE (Ion selective electrode) ASTM D 3961, Sulfur in aromatics ASTM D 4208, Total chlorine in coa

6、l by the oxygen bomb combustion/ISE (Ion selective electrode) ASTM D 4239, Standard test methods for sulfur in the analysis sample of coal and coke using high temperature tube furnace combustion methods ASTM D 4301, Standard test methods for total chlorine content of epoxy resins ASTM D 4929, Test m

7、ethods for organic chloride in crude oil ASTM D 5366, Standard practices for rubber determinations of bromide in the presence of chloride by oxygen bomb combustion ASTM D 5453, Total sulfur with UV fluorescence ASTM D 5808, Chlorine in aromatics ASTM D 5987, Standard test method for total fluorine i

8、n coal and coke by pyrohydrolytic extraction and ion selective electrode ion chromatograph methods ASTM D 6428, Total sulfur in liquid aromatic hydrocarbons and their derivatives (Combustion & electrochemical determination) ASTM D 6667, Standard test method for determination of total volatile sulfur

9、 in gaseous hydrocarbons and liquefied petroleum gases by ultraviolet fluorescence ASTM D 7359, Standard test method for total fluorine, chlorine and sulfur in aromatic hydrocarbons and their mixtures by oxidative pyrohydrolytic combustion followed by ion chromatography detection (Combustion ion chr

10、omatographyCIC) JIS R 1603, Methods for chemical analysis of fine silicon nitride powders for fine ceramics JIS R 1616, Methods for chemical analysis of fine silicon carbide powders for fine ceramics JIS R 9301, Alumina powderDetermination of fluorine content JIS Z 7302, Densified refuse derived fue

11、lTest method for sulfur contentTest method for total chlorine contents 3 . 3.1 (SOx) . 3.2 (HX) (X 2 ) . 4 KS M 0180:2009 3 . (F, Cl, Br) (Combustion ion chromatography method) 5 5.1 , . (HX), (X 2 ) (SOx) . . 5.2 , , ( “EN ISO 3696 1 ”) . 5.2.1 (H 2 O 2 ), 30 %(m/m) 5.2.2 , , , 1 000 mg/kg 20 mL 30

12、 % H 2 O 2 3 mL 1 000 mL . 20.0 mg/kg H 2 O 2900 mg/kg . 1 , , . 2 (：, , , ). 5.2.3 , 99.7 %(v/v) 5.2.4 , 99.99 %(v/v) 5.2.5 , (WO 3 ), (Fe 3 O 4 ) 5.2.6 , 90 % 110 % , , , . , , . a) , . 4- (4-fluorobenzoic acid) 0.5 g, 4- (4-chlorobenzoic acid) 2.0 g, 2.0 g 55.5 g . 1.130 g/kg , 7.547 g/kg 6.170 g

13、/kg . b) . KS M 0180:2009 4 4- (4-bromobenzoic acid) 0.25 g, 59.5 g . 1 656 g/kg . 5.2.7 (1 000 mg/kg), (NaF) 2.210 g 1 000 mL . 5.2.8 (1 000 mg/kg), (NaCl) 1.648 g 1 000 mL . 5.2.9 (1 000 mg/kg), (KBr) 1.489 g 1 000 mL . 5.2.10 (1 000 mg/kg), (Na 2 SO 4 ) 1.479 g 1 000 mL . 5.2.11 (1 000 mg/kg), (K

14、H 2 PO 4 ) 4.394 g 1 000 mL . 5.2.12 (1 000 mg/kg), (CH 4 O 3 S) 1.000 g 1 000 mL . 5.2.13 (1 000 mg/kg), (C 6 H 8 O 7 ) 1.000 g 1 000 mL . 5.2.14 (1 000 mg/kg), (H 2 C 2 O 4 ) 1.000 g 1 000 mL . (：, , , ). 5.3 . 5.3.1 , , . 5.3.2 , , 5.3.3 , 1 0005 . 5.3.4 , 10 mL 20 mL 1/2 , . KS M 0180:2009 5 . 5

15、.3.5 , KS M 0035 . . 5.3.6 , , , 5.3.7 , . 5.3.8 , , , , 0.1 mg 5.4 1 4 , 7 . 7 , . 250 m , PVC . . . (5.2.6) 250 m . KS M 0180:2009 6 , . 5.5 5.5.1 . 5.5.2 . 5.5.3 2 3 . 5.6 20 mg 30 mg 0.1 mg , , 900 1 000 15 . , . 2 9001 100 400 mL/min 200 mL/min 0.1 mL/min1.5 mL/min 5 mL20 mL 5.6.1 . 5.6.2 , , ,

16、 . 5.7 ( ) . F, Cl, Br S (mg/kg) Kg M S C Y) (A KS M 0180:2009 7 F, Cl, Br S (mg/kg) Kv V S C Y) (A D , g/mL A / C , mL(1 mL1g) Kg , / , g/g Kv , / , g/mL M , VD, g S , ( / ；y) ( ；x) V , M/D, mL Y y , ( / ；y) ( ；x) y 5.8 . a) b) c) d) (F, Cl, Br) 153787 1 92 3 (13 ) (02)26240114 (02)262401489 http:/

17、 KS M 0180 :2009 KSKSKS SKSKS KSKS SKS KS SKS KSKS SKSKS KSKSKS Standard test method for halogen(F, Cl, Br) and sulfur content by oxidative pyrohydrolytic combustion followed by ion chromatography detection(Combustion ion chromatography CIC) ICS 71.040 Korean Agency for Technology and Standards http:/www.kats.go.kr