KS M 1997-2010 Determination of bisphenol A contents in polycarbonate food container《聚碳酸酯食品容器中双酚A分析方法》.pdf

1、 KSKSKSKS KSKSKSK KSKSKS KSKSK KSKS KSK KS KS M 1997 A KS M 1997 :2010 2010 12 22 http:/www.kats.go.krKS M 1997:2010 : ( ) ( ) OCI ( ) : (http:/www.standard.go.kr) ： ：2005 8 9 ：2010 12 22 2010-0639 ： ： ( 02-509-7270) (http:/www.kats.go.kr). 10 5 , . KS M 1997:2010 A Determination of bisphenol A cont

2、ents in polycarbonate food container 1 A . 2 (dichloromethane) , A . 3 . . ( ) . KS I 3002, KS M 0033, KS M 8509, (PCB )() KS M 8513, ( )() KS M ISO 63532, 2：1 4 4.1 , KS M 8509 . 4.2 , KS M 8513 . 4.3 , KS M ISO 63532(R18) . 4.4 , KS I 3002 A 4( A3) HPLC . 4.5 , 50：50 4.6 ABisphenol A(4,4 -isopropy

3、lidene diphenol, BPA) 99.9 % . KS M 1997:2010 2 4.6.1 A A(4.6) 0.1 g 0.000 1 g 100 mL (4.3) . 1 mL 100 10 mg/L A . 1 mL, 5 mL, 10 mL, 15 mL 20 mL 100 mL 0.1 mg/L2.0 mg/L . 5 . 5.1 , . . (excitation) 275 nm, (emission) 305 nm 1.0 mL/min( A 3 5 .) 20 L 5.2 , 250 mm4.5 mm, 10 m C8 C18 . 5.3 , 0.000 1 g

4、 . 5.4 5.5 5.6 , (451) . 5.7 , 20 mL 100 mL 5.8 , 300 mL 5.9 , 0.5 mL, 1 mL, 5 mL 10 mL 5.10 , 300 mL 5.11 , 9 cm . 5.12 , 30 mm . 5.13 , 0.45 m . 6 6.1 1 g 300 mL 20 mL . 20 mL KS M 1997:2010 3 . 20 mL , 0.45 m . 6.2 . . 6.3 ( 30 mg/L, 20 mg/L, 10 mg/L, 1 mL) . 7 7.1 (5.1) (4.5) 4.6.1 6. , 20 L . 7

5、.2 0.1 mg/L2.0 mg/L . 3 . 7.3 , 20 L . 15 % . . 7.4 . , , . 8 . a) ( , , ) b) c) d) e) , f) KS M 1997:2010 4 A () mi 0 2 4 6 8 10 12 14 16 18 Norm. 0 2 4 6 8 10 12 14 16 18FLD1 A, Ex=275, Em=305 (BPABPA15001.D)6.194 A.1 A KS M 1997:2010 5 KS M 1997 :2010 , . 2005 . 1 A . 2 () (FDA) J. E. Biles A , A

6、 HPLC A , . 3 1 Biles, J. E., McNeal, T. P., Begley, T. H. and Hollifield, H. C. Determination of bisphenol A in reusable polycarbonate food-contact plastics and migration to food-simulating liquids. J. Agric. Food Chem. 45: 3541-3544 (1997) 2 , , 6. A 153787 1 92 3(13) (02)26240114 (02)262401489 http:/ KS M 1997 :2010 KSKSKS SKSKS KSKS SKS KS SKS KSKS SKSKS KSKSKS Determination of bisphenol A contents in polycarbonate food container ICS 71.040 Korean Agency for Technology and Standards http:/www.kats.go.kr