NAVY MIL-D-16791 G-1990 DETERGENTS GENERAL PURPOSE (LIQUID NONIONIC)《清洁剂一般用途(液体非离子物质)》.pdf

1、MIL-D-Lb?SLG 79 999990b 03b7888 iI INCH-POUND MIL-D-16791 G - SUPERSEDING 27 February 1985 (see 6.7) MIL-D-16791 F MILITARY SPECIFICATION DETERGENTS, GENERAL PURPOSE (LIQUID, NONIONIC) This specification is approved for use by all Department and Agencies of the Department of Defense- 1. SCOPE 1.1 Sc

2、ope. This specification covers both water-soluble and oil-soluble nonionic detergents for use in preparing cleaning solutions which are effective in, and rinsable with, either fresh or sea water. 1.2 Classification. Detergent (nonionic) shall be of the following types, as specified (see w 6.2): Type

3、 I - Water-soluble Type II - Oil-soluble. 2. APPLICABLE DOCUMENTS 2.1 Government documents. 2.1.1 Specifications and standards. The following specifications and standards form a part of this document to the extent specified herein. Unless otherwise specified, the issues of these documents are those

4、listed in the issue of the Department of Defense Index of Specifications and Standards (DODISS) and supplement thereto, cited in the solicitation (see 6.2). Beneficial comments (recommendations, additions, deletions) and any pertinent data which may be of use in improving this document should be add

5、ressed to: Commander, Naval Sea Systems Command, SEA 5523, Department of the Navy, Washington, DC 20362-S 101 by using the self-addressed Standardization Document Improvement Proposal (DD Form 1426) appearing at the end of this document or by letter. AMSC NIA FSC 7930 DISTRIBUTION STATEMENT A. Appro

6、ved for public release; distribution is unlimited. Provided by IHSNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-MIL-D-Lb?lLG 79 9 999990b 03b7889 b W MILD- 16791 G SPECIFICATIONS FEDERAL PPP-B-640 PPP-c-% PPP-D-729 PPP-P-704 W-F-800 STANDARDS FEDERAL FED-STD-313

7、MILITARY MIGSTD-105 Boxes, Fiberboard, Corrugated, Triple-Wall Cans, Metal, 28 Gage and Lighter Drums, Shipping and Storage, Steel, 55-Gallon (208 Liters) Pails, Metal, (Shipping, Steel, 1 through 12 Gallons) Fuel Oil, Diesel Material Safety Data, Transportation Data and Disposal Data for Hazardous

8、Materials Furnished to Government Activities Sampling Procedures and Tables for Inspection by Attributes MIGSTD-129 Marking or Shipment and Storage MILSTD-147 Palletized Unit Loads (Unless otherwise indicated, copies of federal and military specifications and standards are available from the Naval P

9、ublications and Forms Center, (ATIN NPODS), 5801 Tabor Avenue, Philadelphia, PA 19120-5099.) 2.2 Non-Government publications. The following documents form a part of this document to the extent specified herein. Unless otherwise specified, the issues of the documents which are DOD adopted are those l

10、isted in the issue of the DODISS cited in the solicitation. Unless otherwise specified, the issues of documents not listed in the DODISS are the issues of the documents cited in the solicitation (see 6.2). 2 Provided by IHSNot for ResaleNo reproduction or networking permitted without license from IH

11、S-,-,-MILD-16791G AMERICAN SOCIETY FOR TESTING AND MATERIALS (ASTM) D 93 Standard Test Methods for Hash Point by Pensky-Mariens Closed Tester (DOD adopted) D 95 Standard Test Methods for Water in Petroleum Products and Bituminous Materials By Distillation (DOD adopted) D3699 Standard Specification f

12、or Kerosine (DOD adopted) E 326 Standard Test Method for Hydroxyl Groups By Phthalic Anhydride Esterification (Application for copies should be addressed to the American Society for Testing and Materials, 1916 Race Street, Philadelphia, PA 19103.) (Non-Government standards and other publications are

13、 normally available from the organizations that prepare or distniute the documents. These documents also may be available in or through libraries or other informational seMces.) 23 Order of pi.ecedence. In the event of a conflict between the text of this document and the references cited herein, the

14、 text of this document takes precedence. Nothing in this document, however, supersedes applicable laws and regulations unless a specific exemption has been obtained. 3. REQUIREMENTS w 3.1 Material. The detergent shall be a liquid, nonionic surface active agent containing a mnimum of 99 percent activ

15、e ingredient for type I and type II. It shall be the alkyl aryl polyether alcohol (alkyl phenol ether of polyethylene giycol) type where the alkyl group is iso-octyl or iso- nonyl, or the linear alkyl polyether alcohol (alkyl ether of polyethylene glycoi) type where the alkyl group is linear primary

16、 or secondary alkyl. 3.1.1 Appearance. Detergent shall be a liquid at 77 degrees Fahrenheit (OF) (25 degrees Celsius (?C). A slight haze is permissible. 3.1.2 Water content. Water content shall not exceed 0.5 percent (see 4.4.1). 3.13 Ash content. Ash content shall not ex it is an extension to the b

17、asic eye protection. If swallowed, induce vomiting and call a physician. For eyes, flush with plenty of water and get medical attention. May be irritating to the skin. Use of chemical gloves is recommended. For most cleaning operations, 1/4 to ln ounce of detergent in a gallon of fresh water or sea

18、water, preferably hot, is sufficient. Very heavy soils may require as much as 1 ounce of product. DO NOT EXCEED RECOMMENDED MIX SHALL BE USED. SKIN IRRITATION OR OTHER ALLERGIC REA(3TION MAY OCCUR IF THESE INSTRUCTIONS ARE DISREGARDED. For some applications, the additions of 1 to 2 ounces of an alka

19、li, such as sodium metasilicate or machine dishwashing compound, will improve performance. If alkalies are used, the solution shall be prepared with fresh water. Scrub, mop or wipe the solution into the oily soil and then rinse away the loosened soil with either fresh water or sea water. Cold water

20、rinsing is satisfactory but hot water may be used when it is desired to have steel surfaces dry quickly. Small accessible areas may also be wiped dry if rinsing cannot be done easily. QUANTITY. IF CLEANING BY HAND - CHEMICAL PROTECTIVE GLOVES Closed systems such as compressed air lines, heat exchang

21、ers and similar items may be cleaned by recirculating a hot solution of the detergent for 1 to 3 hours followed by rinsing.“ 33 Type II, oil-soluble. 33.1 Solubility in kerosene. Detergent shall form a clear solution in kerosene and shall remain clear (see 4.4.8). . potassium hydroxide per gram of s

22、ample (see 4.4.11). 33.2 Hydroxyl number. The detergent shall have a maximum hydroxyl number of 150 mg of 5 Provided by IHSNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-333 Labeling. Unless otherwise specificd (see 6.2), each container of type II detergent shall

23、be durably and legibly labeled in accordance with MIL-STD-129 as follows: “DETERGENT (Oil-soluble, nonionic) WARN1 N G Do not take internally. Keep out of eyes. Use chemical workers goggles to prevent material from being splashed into eyes when being mixed and/or applied. In addition to goggles, a p

24、lastic face shield may be used to protect the face. NOTE: The face shield is not to be used in lieu of chemical workers goggles; it is an extension to the basic eye protection. If swallowed, induce vomiting and call a physican. For eyes, flush with plenty of water and get medical attention. May be i

25、rritating to the skin. Use of chemical gloves is recommended. This product, when dissolved in the proportion of 5 fluid ounces per gallon of kerosene, diesel fuel oil, high fiash coal tar naphtha and similar hydrocarbon solvents will remove heavy deposits of grease, oil, sludge, some types of rust-p

26、reventive compounds and other similar soils. Kerosene and diesel fuel oil solutions are useful on petroleum oils and greases. Rust-preventive compounds, oxidized sludges, asphaltic and bituminous contamination are best removed with solutions of detergent in aromatic solvents such as the coal tar and

27、 petroleum aromatic naphthas. The solution of detergent in solvent is brushed, sprayed (nonatomizing spray) or flowed onto the soil, allowed to soak for 5 to 30 minutes and then rinsed with hot or cold fresh water or sea water. Scrubbing the solvent into the soil will improve results. IF CLEANING BY

28、 HAND - CHEMICAL PROECIWE GLOVES SHALL BE USED. SKIN IRRITATION OR OTHER ALLERGIC REACIION MAY OCCUR IF THESE INSTRUCTIONS ARE DISREGARDED. A hot water rinse will promote rapid drying. If many small objects are to be cleaned, a tank of solvent solution will be convenient for dipping the pieces which

29、 then can be rinsed in a tank of water or under pressure spray. WARNING Solvent solutions of detergent (oil-soluble), in the amount recommend-ed, will not have flash points significantly different from that of the straight solvent. Therefore, the same precautions against fire hazard shall be observe

30、d as required for the particular solvent used.“ 6 Provided by IHSNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-MIL-D-Lb?SLG 79 999990b 03b79r T MILD-16791G 3.4 Workmanship. The detergent shall be a clear homogeneous liquid free of dirt or foreign matter. The qual

31、ity of the cleaning compound shall conform to the levels established herein. 3.5 Material safety data sheet (MSDS). The contracting activity shall be provided a material safety data sheet at the time of contract award. The MSDS shall be provided in accordance with the requirements of FED-STD-313. Th

32、e MSDS shall be included with each shipment of the material covered by this specification (see 6.5). 4. QUALKY ASSURANCE PROVISIONS 4.1 Responsibility for inspection. Unless otherwise specified in the contract or purchase order (see 6.2), the contractor is responsible for the performance of all insp

33、ection requirements (examinations and tests) as specified herein. Except as otherwise specified in the contract or purchase order, the contractor may use his own or any other facilities suitable for the performance of the inspection requirements specified herein, unless disapproved by the Government

34、. The Government reserves the right to perform any of theinspections set forth in the specification where such inspections are deemed necessary to ensure supplies and services conform to prescribed requirements. 4.1.1 Responsibility for compliance. All items shall meet all requirements of sections 3

35、 and 5. The inspection set forth in this specification shall become a part of the contractors overall inspection system or quality program. The absence of any inspection requirements in the specification shall not relieve the contractor of the responsibility of ensuring that all products or supplies

36、 submitted to the Government for acceptance comply with all requirements of the contract. Sampling inspection, as part of the manufacturing operations, is an acceptable practice to ascertain conformance to requirements, however, this does not authorize submission of known defective material, either

37、indicated or actual, nor does it commit the Government to accept defective ma terial. 4.2 Sampling for quality conformance inspection. Sampling and inspection shall be performed as specified in 4.3.1 and 4.4, except where otherwise indicated. For purposes of sampling, an inspection lot for quality c

38、onformance inspection shall consist of all material of the same type offered for delivery at one time. 43 Examination of detergent. The material shall meet the requirements and be of the specified composition (see 3.1 and 6.3). 43.1 Examination of the detergent. The detergent shall be examined in ac

39、cordance with the classification of defects specified in 4.3.1.1 through 4.3.1.2. The lot size, for purpose of determining the sample size, shall be expressed in units of filled containers of detergent of the same type for examination in 4.3.1.1 and 4.3.1.2. 7 Provided by IHSNot for ResaleNo reprodu

40、ction or networking permitted without license from IHS-,-,-MIL-D-Lb771G 77 979990b 0367875 L MIL-D- 167916 43.1.1 Examination of tbe deteqent cootainer for derd in closure,appearance, markings, construction and workmanship. The sample unit for this examination shall be one flled container. Sampling

41、shall be in accordance with table II. TABLE D. Inspection levels for eramnation.423 Lotsize o - 15 16 - 50 51 - 150 151 - 500 501 - 330 331 - 35,000 35,001 - over Sample size 2 3 5 8 13 u) 32 1AU defeuive items shall be replaced with acceptable items prior to lot acceptance. bspect sampie size until

42、 reject criteria is reached If reject criteria is reached, reject the 31f entire sample is inspected and reject criteria is not reached, accept the lot. lot or iiispect the entire iot. Examine Defect Container Labeling Not specified type, size or style container Any evidence of leakage from any part

43、 of the container, including cap closure, any unsound seam Any break, dent or other defect in body of container which may affect serviceability Closures not as specified; not equipped with screw cap and inner seal (as applicable) Exterior coating not as required Label, lithographing, printing or ste

44、nciling pertaining to the applicable information, and instructions for detergent use of the specified type material omitted, illegible, in- correct, incomplete or smeared Appearance of detergent Presence of dirt or foreign matter Not clear liquid (see 3.1.1) Not homogeneous 8 Provided by IHSNot for

45、ResaleNo reproduction or networking permitted without license from IHS-,-,-MIL-D-Lb?SLG 79 9399906 03bf89b 3 MILD- 167916 43.13 Examination of the dc(crtcir hr bclects in net contents. The sample unit for this examination shall be one filled container. Sample size shall be in accordance with table I

46、II. The average net contents shali be not less han the specified or indicated quantity. - Lataae Sample Sae -pt Reject 0-25 2 O 1 26 - 150 3 O 1 151 - 1m 5 O 1 131 - 35,000 8 O 1 35,001 - over 13 O 1 AU defective items sha bt replaced witb acceptable items prior to lot acceptance. bqca Sample size u

47、ntil reject criteria is rexixxi. 31f entire sampie is insptctad and reject criteria is not reached, accept the lot. reject aiteria is cicched, reject te lot oc inspect the entire lot. 4.4 Testing of the detergent. The detergent shall be tested for the characteristics in table IV (see 6.3). One quart

48、 of material shall be drawn from each of five shipping containers and compited. The test sample shall consist of a 2quart composite. Duplicate determinations shall be made on the composite. The average of the two determinations shall comply with the requirements when numerical results are specified.

49、 Both determinations shall pass when pass or fail requirements are applicable. Tests shall be conducted as specified in 4.4.1 through 4.4.11. 0 9 Provided by IHSNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-MIL-D-Lb79LG 79 9999906 03b7897 5 Characteristic Water content: Type1 I)peu typen: TypeIand Ash content Nitrogen Sulfur Phosphorus ability EmuisiIying Distilled water Sea water Type 11 Dis