NAVY MIL-D-82659-1979 DIETHYLENE GLYCOL DIBUTYL ETHER TECHNICAL《技术性二甘醇二丁酯醚》.pdf

1、MIL-D-82659 (OS) 31 January 1977 Superseding (See Section 6) Beneficial comments (recommendations , additions , deletions) - and any pertinent data which may be of use in improving this document should be addressed to: Commanding Officer, Naval Ordnance Station, Standardization Division (611), India

2、n Head, MD 20640 by using the self-addressed Standardization Document Improvement Proposal (DD Form 1426) appearing at the end of this document or by letter. MILITARY SPECIFICATION DIETHYLENE GLYCOL DIBUTYL ETHER This specification is approved for use by the Naval Sea Systems Command, Department of

3、the Navy and is available for use by all Departments and Agencies of the Department of Defense. 1. SCOPE 1.1 Scope. This specification covers one grade diethylene glycol dibutyl ethe.r referred to herein as “The material“. 2. APPLICABLE DOCUMENTS 2.1 Issues of documents. The following documents of t

4、he issue in effect on date of invitation for bids or request for proposal, form a part of this specification to the extent specified herein. STANDARDS Military MIL-STD-105 Sampling Procedures and Tables for Inspection by Attributes MIL-STD-129 Marking for Shipping and Storage MIL-STD-1218 ACS Chemic

5、als PUBLICATIONS Naval Sea Systems Command (Code Ident 10001) OD 18893 Water Content, Determination of (Copies of specifications, standards, drawings, and publications required by suppliers in connection with specific procurement functions should be obtained from the procuring activity or as directe

6、d by the contracting officer.) THIS DOCUMENT CQNTABIMS - c3 PAGES. Provided by IHSNot for ResaleNo reproduction or networking permitted without license from IHS-,-,- - , _ MIL-D-82657 68 W 7779306 0123081 T W MIL-D-82659 (OS) 2.2 Other publications. The following documents form a part of Unless othe

7、rwise this specif-ication to the extent specified herein. indicated, the issue in effect on the date of the invitation for bids or the request for proposal shall apply. CODE OF FEDERAL REGULATIONS 49 CFR 100-199 Transportation (The Code of Federal Regulations is available from the Superintendent of

8、Documents, U.S. Government Printing Office, Washington, DC 20402. Orders should specify “49 CFR 100-199 (latest revision)“. ) NATIONAL MOTOR FREIGHT TRAFFIC ASSOCIATION, INC., AGENT National Motor Freight Classification (Application for copies should be addressed to American Trucking Associations, A

9、ttn: Tariff Order Section, 1616 P Street, Washington, DC 20036.) UNIFORM CLASSIFICATION COMMITTEE, AGENT Uniform Freight Classification (Application for copies should be addressed to the Uniform Classi- fication Committee, Room 1106, 222 South Riverside Plaza, Chicago, IL 60606.) (Technical society

10、and tehnical association specifications and standards are generally available for reference from libraries. are distributed among technical groups and using Federal agencies.) They 3. REQUIREMENTS 3.1 Material. The material shall be diethylene glycol dibutylether in amber liquid form. 3.2 Chemical a

11、nd physical properties. The chemical and physical properties shall be in accordance with TABLE I. 3.3 TJorkmanship. The material shall be uniform, free from contaminmts, foreign material or any other defect that would prevent its use for the purpose intended. 2 Provided by IHSNot for ResaleNo reprod

12、uction or networking permitted without license from IHS-,-,-MIL-D-2659 b M 9979706 0123082 1 W 1 Property MIL-D- 82 6 5 9 (OS) Vaaues minimum I maximum Assay, volume % 95.0 I pH .- I 7*5 I I 6.0 Water content, wt% - O. 30 Color 4 - Specific Gravity, 25125C O. 960 4. QUALITY ASSURANCE PROVISIONS 0.98

13、0 4.1 Responsibility for inspection. Unless otherwise specified in the contract, the contractor is responsible for the performance of all inspection requirements as specified herein. in the contract, the contractor may use his own or any other facilities suitable for the performance of the inspectio

14、n requirements specified herein unless disapproved by the Government. The Government reserves the right to perform any of the inspections set forth in the specification where such inspections are deemed necessary to assure supplies and services conform to prescribed requirements. Except as otherwise

15、 specified 4.2 Inspection conditions. Unless otherwise specified (see 6.2), all inspections shall be performed under the following conditions: a. Temperature: Room ambient 18 to 35C (65 to 95F) b. Altitude: Normal ground c. Vibration: None d. Humidity: Room ambient to 95 percent relative., maximum 4

16、 .-3 Sampling. 4.3.1 K. Unless otherwise specified in the contract (see 6.21, a lot shall consist of all material manufactured in one continuous production run or in one batch, under essentially identical conditions, from the same raw materials, and to be offered for acceptance at one time. Several

17、batches, manufactured from the same raw materials, may be blended to form a uniform larger batch which shall then constitute a lot for inspection purposes. 4.3.2 Sampling. Sampling for quality conformance inspect ion shall be in accordance with inspection Level I of MIL-STD-105. unit shall be one un

18、it package or container of material. shall consist of sufficient material to perform the quality conformance tests as specified in 4.4. The sample Each sample 3 Provided by IHSNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-MIL-D-82659 68 999990b 0323083 3 W MIL-D-

19、82659 (OS) 4.4 Quality conformance inspection. Each sample obtained in accordance with 4.3.2 shall be subjected to the tests and examination of 4.5. The acceptable quality level (AQL) shall be 2.5% defective. When specified in the contract (see 6.2), the contractor shall furnish test reports showing

20、 quantitative results for all quality conformance tests specified for each lot of material. 4.5 Tests. Unless otherwise specified herein, all chemicals shall be ACS grade in accordance with MIL-STD-1218. 4.5.1 Visual examination. All samples shall be visually examined to verify conformance to the wo

21、rkmanship requirements. 4.5.2 pH. pH shall be determined in accordance with the following: a. Reagents: 1. Distilled water, carbon dioxide free. 2. Fisher Certified buffer solution, S - B - 98, pH 4.00 25C. 3. Fisher Certified buffer solution, S - B - 116, pH. 10.00 25C. b. Apparatus : 1. pH meter w

22、ith glass-calomel electrode pair. 2. Filter paper. c. Procedure: Weigh approximately 10 grams (g) of sample into a beaker, add 25 milliliters (mi) of distilled water and stir for a minimum of 5 minutes. Filter the mixture and determine pH on the filtrate using a pH meter with glass-calomel electrode

23、 pair which has been calibrated against the known buffer prior to use. d. Report the results of a minimum of 2 determinations and their average. 4.5.3 Assay. Assay shall be determined in accordance with the following: a. Reagents: 1. Sodium chloride. 2. Sodium hydroxide. 4 Provided by IHSNot for Res

24、aleNo reproduction or networking permitted without license from IHS-,-,-MIL-D-82657 68 W 7777906 OL230LI 5 W Volume remaining in column, ml 4.0 5.0 6.0 7.0 8. O 9.0 b. Apparatus: Cassia flask, 110 ml. Diethylene glycol dibutyl ether (percent) 47 58 68 78 89 99 c. Preparation of sodium chloride solut

25、ion: Add 300 g of sodium chloride to one liter of distilled water. Stir the solution and adjust the pH to between 10 and 11 using concentrated sodium hydroxide solution. Stir the solution a minimum of 20 minutes or until essentially all the salt dissolves. Let the solution stand a minimum of 2 hours

26、. Filter the supernatant liquid directly into a clean bottle. d. Procedure: Pipet 10 ml of the sample into a 110 ml Cassia volumetric flask containing 75 ml of distilled water at 21 k 1C and 5 ml of concentrated sodium chloride solution. Stopper the flask and invert 20 times to permit the trapped ai

27、r to agitate (almost emulsify) the sample and water. to fill the graduated column to about 109.5 ml. Stopper the flask and invert 20 times to complete the mixing. in a 21 t. 1C water bath until the sample separates from the water and collects in the graduated column. Determine the volume of the plas

28、ticizer in the graduated column by reading the bottom of the meniscus. The oil layer must be clear; if not, make a new determination. (TABLE II provides a range of percent assay versus volume remaining in column in tabular form for information.) Add sufficient 21 k 1C water Place the Cassia flask e.

29、 Calculation: Assay, volume % = 0.10417(A) + 0.05501 (100) where: 0.10417 = density factor A = volume.of plasticizer remaining in column, ml 0.0550 = solubility constant f. Report the results of a minimum of 2 determinations and their average. 5 Provided by IHSNot for ResaleNo reproduction or networ

30、king permitted without license from IHS-,-,-MIL-D-82659 (OS) 4.5.4 Water content. The water content shall be determined in accordance with 4.5.4.1 or 4.5.4.2. In the event of controversy the results obtained by the method of 4.5.4.1 shall be determinative. 4.5.4.1 Preferred method for- water content

31、. The preferred method for determination of the weight percent (wt%) water content shall be in accordance with OD 18893. - 4.5.4.2 Alternate method for water content. The alternate method for determination of water content shall be in accordance with the following: a. Reagents: 1. Dry toluene (less

32、than 0.005 percent water). 2. Methylene blue, very finely ground. b. Apparatus: 1. Moisture trap, coated with Hydrophobic Monomers (see 6.4) 2. Erlenmeyer flask, 500 ml, 24/40 standard taper (ST). 3. “Glas-Col“ mantle heating element, 500 ml Erlenmeyer. 4. West Condenser, 24/40 ST (Corning 2740, or

33、equal) with 300 ml jacket. 5. Rubber tubing 3/16 inch inside diameter (approximately 4 inches long). c. Procedure: Add 24.9 to 25.1 g of sample, weighed to the nearest 0.01 g, to 100 g of dry toluene in an Erlenmeyer flask, stopper the flask, and mix well. Cover the flask with a “Glas-Col“ mantle. A

34、ttach a piece of rubber tubing to the tip of the calibrated capillary of the water trap, and close the tubing. to the moisture trap, and approximately 1 mg of finely ground methylene blue. Assemble the apparatus and reflux the toluene with the sample for at least 1 hour at a rate of approximately 12

35、0 drops per minute. Allow the apparatus to cool for approximately 15 minutes, then wash the condenser walls with three 5 to 10 ml portions of dry toluene. Force the water column back and forth in the bottom of the moisture trap to collect all the water and to mix the methylene blue thoroughly with t

36、he water, then slowly open tubing to move the blue tinted water, as an unbroken column into the graduated capillary. Add approximately 2ml-f dry toluene d. Calculation: Water content, wt% = (A)(0.04) x 100 where: A = water reading, ml 0.04 = weight factor e. Report the results of a minimum of 2 dete

37、rminations and their average. 6 Provided by IHSNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-MIL-D-82657 68 m 7779906 0123086 7 m 4.5.5 Color. Color shall be determined in accordance with the following : a. Apparatus: Hellige varnish comparator, model number 605

38、equipped with number 62OC-40 and number 62OC-42 color disks, and sample tubes number 605V-T, or equivalent. Procedure: b. Place the comparator so that the oval glass plate in the back of the instrument faces directly toward the light, taking care that pronounced shadows do not cause uneven illuminat

39、ion of the observation fields. Indirect natural lighting should be used. Insert a color disk, placing the center of the disk on the ring so that the number plates face the operator. sufficient amount of sample to provide full exposure in the observation field. the sample and standard through the two

40、 central openings of the apparatus. between the sample and a standard. If an exact color match cannot be obtained, determine the color number by interpolation of the standard numbers between which the sample lies. Fill a clean, dry tube with a Flace the tube in the right opening of the apparatus. Ob

41、serve Rotate the color disk until a color match is found Record the number of the standard. c. Report the results of a minimum of 2 determinations. 4.5.6 Specific gravity. Specific gravityY25/25“C, shall be determined in accordance with the following: a. Apparatus: 1. Fisher chain gravitometer or eq

42、uivalent. 2. Thermometer, -20 to lOO“C, with 1C subdivisions. b. Procedure: Level the balance. With the roller weight at 0.0 and the movable scale at 0.000, place the empty cylinder on the platform so that the plummet will swing freely in the cylinder. the zero balance of the instrument. If necessar

43、y, adjust to zero. Mix a portion of the sample for a minimum of 1 minute and transfer an amount to the cylinder sufficient to cover the entire plummet. Place the cylinder containing the sample and a thermometer into a cooling batch until the cylinder and contents reach a temperature at a minimum of

44、1C below that specified for the test. Remove the cylinder from the bath and remove the thermometer. Place the cylinder on the balance with the plummet inserted into the sample. temperature rises to 25 1C as indicated by the plummet thermometer, move the rider to the right, notch by notch until the p

45、osition is found which is just insufficient to cause the plummet to drop. will give the first 2 units for the specific gravity of the liquid. Bring to a final balance by raising the chain weight slide. second and third decimal places are read off the numbers on the graduated scale. Check When the Th

46、is The 7 Provided by IHSNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-. MIL-D-82659 68 9999706 0323087 O W MIL-D-82659 (OS) c. Report the results of a minimum of 2 determinations and their average. 4.6 Packaging inspection. The packaging, packing and marking shal

47、l be inspected to verify conformance with the requirements of Section 5. 5. PACKAGING 5.1 Packaging and packing. Unless otherwise Specified in the contract (see 6.2), packaging and packing shall be Level C. 5.1.1 Level C. Unless otherwise specified in the contract (see 6.2), packaging and packing of

48、 diethylene glycol dibutyl ether shall be in accordance with standard commerical practice applicable to the type of material. The packaging and packing shall be of such construction and materials that the contents will be adequately protected against loss or contamination. Container size shall be as

49、 specified in the contract (see 6.2). Containers shall conform to Uniform Freight Classification, National Motor Freight Classification or to rules of other carriers applicable to the mode of transportation and shall be suitable for indoor storage at 32C (90F) maximum. 5.2 Marking. In addition to any special marking required by the contract (see 6.2), each container shall be marked in accordance with MIL-STD-129 and